AITS – 1 (MAIN) CHEMISTRY

CHEMISTRY (SOLUTION)

31. (1)
10  5 10  7
O 2 B.O.   2.5; O 2   1.5
2 2
10  8 10  6
O 22 B.O.   1; O 2 B.O.  2
2 2
B.O.  B.L. 

32. (3)

Pyrosilicate [Si2O7]6–

33. (2)
rA MB

rB MA
V 20 MB 1 MB
  
V 10 49 2 49
1
M B   49  12.25
4

34. (2)
E1  25eV, E 2  50eV
hc hc
E1  , E2 
1 2
25  2
 
50 1
1  2 2

35. (1)
n CO  n N 2
PCO  PN 2  1atm
2PN 2  1atm
PN 2  0.5 atm

36. (3)
[Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6]

37. (2)
Van arkel method is used to purification Ti & Zr
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38. (3)
PD2 PD2 4PD2
Kp  
PB PB PB1

39. (1)
The number of molecules of CO involves in the slowest step will be 0 because CO is not involve in
the slowest step i.e. rate determing step.

40. (3)
1s2, 2s2p6, 3s2p5 is the electronic configuration of chlorine, which has maximum electron affinity in
periodic table.

41. (2)

42. (1)
Brownian movement is independent of nature but depend on the size of particles and viscosity of the
solution. Smallest the size and lesser the viscosity of the solution. Smallest the size and lesser the
viscosity faster is the motion.

43. (3)
K2[HgI4] + KOH
K2[HgI4] formed by the reaction of HgCl2 and KI excess.
HgCl2 + 4KI   K2[HgI4] + 2KCl

44. (3)

45. (4)

46. (3)
Br
Br2 /CCl4 NaNH 2 /

  
Br

Zn/EtOH, 


47. (2)
Cis product is obtained when we used Lindlar’s catalyst and trans product is obtained when we use
Na/liq. NH3 or LiAlH4.

48. (3)
Because C-1 of both units are linked through glycosidic linkage.

49. (4)
Reaction of alcohol with SOCl2 / Pyridine involues attack of Nu-cleophile from back side.

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50. (3)
Electron releasing group decreases acidic strength and ortho effect increase acidic strength.

51. (3)
Nylon-6 is a polyamide molecule.
O

[ NH  CH 2 5  C]n

52. (3)
NO 2 NH2

Polymerisation conc. HNO3 Sn/HCl NaNO 2 , HCl

3HC  CH      
conc. H 2SO 4  
0  5o C

N2Cl

Phenol

dil NaOH
 N N OH

53. (4)
Phenol is more acidic than ethanol so pka of phenol is less than ethanol.

54. (2)
H3C CH3 H3C H3C
O3 , Zn  H 2O NH 2 OH
C C   C O  C N OH
H3C CH3 H3C H3C

H 2SO4
  H3C C NH CH3
O
55. (2)
[OH–] = 10–13, v = 10 ml = 0.01
– –15
 moles of OH ion = 10
– –15 8
 no. of OH ions = 10  NA = 6.023  10

56. (3)
In simple cubic a = 2r
3
4 3 4 a 1 3
Volume  r      a
3 3 2 6
57. (3)
 NaCl  iCRT
 2  0.1 R  T
 0.2 RT
 Na 2SO4  3  0.1 RT  0.3 RT
  Na 2SO4 / NaCl  1.5
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58. (2)
G o  H  T.So
Given that
H  382.64 kJ mol 1
So  145.6 J K 1mol 1
 145.6 103 kJ K 1
Or G o  382.64   298  145.6 103 
 339.3 kJ mol 1

59. (3)
Cr 2 d 4 4

Mn 2 d5 5

Fe2 d 6 4

Co2 d 7 3

Minimum Paramagnetic behavior = [Co(H2O)6]2+

60. (2)
Cu 2   1e   Cu  E10  0.15 v G10  n1 E10 F
Cu   1e   Cu E 02  0.50 v G 02  n 2 E 02 F
 1 nE 0 F   1 n1 E10 F   1 n 2 E 02 F
n1E10  n 2 E02 0.15 1  0.50 1
E0    0.325
n 2

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