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Power generation by different waste heat


recovery methodologies with reference to
cement works in Pakistan: A case...

Conference Paper · October 2012


DOI: 10.1109/ICET.2012.6375473

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Power Generation by Different Waste heat recovery
Methodologies with reference to cement works in
Pakistan
A case study for cement industry in Pakistan

S. Ali Abbas Kazmi1, M. Zahir Khan2


Electrical Engineering Department
1,2
University of Engineering and Technology
Peshawar, Pakistan
engrkazmi_15186@yahoo.com, zahirkhan@nwfpuet.edu.pk

Abstract² Cement industry is one of the strongest candidates load, bill and cement production cost. It also ensures normal
for waste heat recovery (WHR) due to the reason that about 40% kiln operation during time off demand (TOD) when each
of heat utilize for clinker production process is exhausted to cement factory has to reduce load as instructed by NTDC and
atmosphere from exhausts of suspension preheater (SP) and air reduction in emission reduction of GHG like CO2 that is a
quenching chamber (AQC), without utilization. In this paper,
major contributor to the global warming and environmental
different technologies for power generation by WHR system are
discussed, as main concern nowadays is increasing power pollution and can be capitalized in-terms of selling of carbon
generation by different WHR technologies by the same source. credits as per implementation of methodology by clean
The demonstration is done on a case study where WHR unit is development mechanism with reference to Kyoto Protocol [2].
not yet installed. Comparison of power generation is done
utilizing different methodologies along with their results. The
applied CDM methodology applied and resultant emission II. GENERAL OVERVIEW OF PAPER
reductions are also shown. The conclusions are given for the best
system that is suitable as per our limitations and operational
A. Specification of demonstration Project
conditions. The monitoring policy of waste hear recovery power our project is done on Askari Cement Limited (ACL), situated
plant for billing and power usage is also devised. The advantages near Hassan-Abdal, Punjab province in Pakistan. It is 3700
and barriers in-terms of installation of waste heat recovery tons per capacity of cement plant with single production line;
system are also mentioned. It can be a role model for other third also it has no captive power plant previously nor is waste heat
world countries like Pakistan, for sustainable development. recovery system installed yet. It has automation of ABB with
Index Terms² Waste Heat Recovery (WHR); Waste Heat
medium voltage of 6.3KV and 50Hz. This effort is done for
Recovery System (WHRS), Suspension Preheater (SP); Air demonstration purpose to give an approach that how a WHRS
Quenching Chamber (AQC); Waste Heat Recovery Power Plant is installed on a plant in which WHRPP is not installed yet and
(WHRPP); National Transmission and Dispatch Company an overall view of the project. For this purpose, different
(NTDC); Greenhouse Gases (GHGs); Clean Development effective techniques employed worldwide are utilized to sort-
Mechanism (CDM), Organic Rankine Cycle (ORC). out the best WHRS in terms of operation, maintenance and
have correlation to our requirements.
I. INTRODUCTION
Cement industry is one of the main industries of Pakistan in
which about 40% of heat produced in clinker production B. Different WHRPG Technologies worldwide
process is exited to atmosphere causing pollution to the The three major technologies used in the world are
environment as well [1]. Also the shortage of power all around discussed as per their power production, auxiliary equipment
the world especially in Pakistan, economical concerns and high consumption [3]. The WHRPP steam based rankine cycle like
energy requirements demands a standby system that is single flash system and dual pressure system can be considered
environment friendly for producing a reasonable power in Asia and south-Asia because the exit gases temperatures are
quantity. Waste Heat Recovery System full fills all the criteria. high form SP and AQC of cement plants situated here and also
As cement industry in Pakistan are located in those areas where working medium used is water which is environment friendly,
waste heat gases are comparatively high and they can be good safe, low cost and abundant. The Organic Rankine Cycle
candidates for installation of WHRS. It results in partial system is simple in configuration and best for low temperature
reduction on dependence of national grid like National waste heat recovery but has limited power generation due to
Transmission and Dispatch Company in Pakistan in-terms of certain factors like pinch points, working fluid decomposition

978-1-4673-4451-7/12/$31.00 ©2012 IEEE


at high temperature, high cost of working fluid, environmental due to pinch point that restricts mass flow and cause
concerns like they destroy ozone layer (being mostly CFCs and temperature limitation effect on temperature, so results in
refrigerants) etc. The Kalina cycle employs a mixture of water comparatively less power generation capability for our
and ammonia and the power generation by this system directly environment [5]. It is also not used due to the reason that the
depends upon the concentration of the mixture applied pressure working fluid used in ORC is very costly (25$/Kg), they are
and temperature. It has a complex system it generally overlaps flammable, cause serious environmental threats and have
with the WHR conditions of cement plants in Pakistan. All the comparatively large boiler (heat exchanger) as compare to
results are proved by simulations programs on Matlab. steam rankine cycle. The auxiliary equipment required in such
system is of small consumption usage up to 6% of the power
generated by WHRPP based on such technology. It has a high
C. Emission Reductions
cost of purchase and high cost of maintenance due to high price
Another advantage by this WHRS technology is the of fuel and other factors but it is very easy to operate [6].
reduction of GHGs like CO2. The CO2 reduction plays an Another technology gaining popularity worldwide is Kalina
important task of reduction of global warming and cycle based which employs a mixture fuel containing a specific
environmental production. The CDM methodology that can be proportion of ammonia and water. It absorbs more heat and
used for our case study is AMS-IIIQ for small scale projects result in more power generation as compare to steam based
for waste gases and emission reduction. It generates carbon rankine cycle. The auxiliary equipment required in such system
credentials that can be sold to international market to generate is of high consumption usage up to 14% of the power
additional income helps in further fast payback as compare to generated by WHRPP based on such technology. The power
without CDM as per Kyoto protocol of UNFCCC [2] and [4]. generation by this technology is highly affected by ammonia
water concentration. It is very costly and demands a high level
of observation and maintenance [7]-[8].
III. WASTE HEAT RECOVERY POWER GENERATION
METHODOLOGIES
The exit waste gases quantity and quality majorly depends A. Cement Plant Data Required for Waste Heat recovery
upon the capacity of kiln of cement plant. The more of the Power Generation by WHRPP majorly depends upon
capacity of cement plant, the more power is produced as shown process parameters of the cement plant. Typical parameters of
in figure 1. demonstration study (3700 tons per day) are shown in table I.
Plot of Cement Plant Capacity vs Power Generation via Waste Heat recovery System
25
TABLE I. TYPICAL WASTE GAS CONDITIONS FOR PROJECT

20 Serial Waste heat Gases Parameters of Cement Plant


No. Parameter Unit Value

15
1 Preheater Gases Temperature Û& 380
Power in MW

2 SP boiler Gases Temperature Û& 220


10
3 Clinker cooler Gases Temperature Û& 370

4 Mass flow of Preheater exhaust gas (kg/s) 92


5
5 Mass flow Clinker cooler exhaust gas (kg/s) 63
3
0 6 SP exhaust gases mass flow-rate m /h 167500
1000 2000 3000 4000 5000 6000 7000 8000 9000 10000
Cement Plant Kiln Capacity
7 AQC exhaust gases mass flow-rate m3/h 192500
Fig. 1. Power Production vs. Cement plant Capacity. 3
8 Density of waste exhaust gas of AQC kg/m 2.12
3
Different waste heat technologies used in world are steam 9 Density of waste exhaust of SP kg/m 1.82
based rankine cycle like single flash system and dual pressure
system especially for comparatively high temperature
environment like in asia especially in South-Asia due to the B. Equations and Units
reason that the fuel used in it is water which is safe, cheap and
environment friendly. The auxiliary equipment required in The temperature range starts from temperature of working
such system is of normal consumption usage up to 10% of the fluid T1 to maximum temperature attained of working fluid by
power generated by WHRPP based on such technology. It has boiler, that is T4 and the temperature range is between T1 to
affordable price with many factors that can be manipulate T4.
easily as per conditions of temperatures in cement industries of Boiler: Waste heat gases send to boiler for heat addition to
Pakistan [1]. Other system that is simple in proportion and the working fluid at high pressure and high temperature, It is
mostly used in Europe is ORC which are excellent for further divided into economizer, preheater and super heater
comparatively very low temperature based WHR but limited respectively:
Economizer: From pump to boiler to raise fluid temperature C. Simulation results and comparison of different Waste heat
[9]. recovery techniques.
The different techniques utilized worldwide for waste heat
4 P[ȡ[& x (T2-T1) (1) recovery systems constitutes of general (single flash
p
technology), dual pressure technology, ORC technology and
Preheater: To Preheat working fluid to steam. kalina cycle technology due to the reason of effective power
generation. The main parameter involves two main input
4 P[ȡ[& x (T3-T2) (2) parameters, temperature of the flue gases and flow of gas [3].
p
The schematic diagram of single flash based WHRPP
system is shown in figure 2, showing its working. The Flasher
Super-heater: To heat steam to super-heated saturated steam. not only removes oxygen but also increase temperature of less
saturated steam for its reuse in turbine for power generation.
4 P[ȡ[& x (T4-T3) (3)
p

Boiler Efficiency [10]:


િB =0.8
Boilers combine Efficiency: For both AQC and SP Boilers.
િBC =0.8×0.8=0.64
Actual Heat recovered:

QA = િBC î>ĮîPîȡî& × (T4-T1)] (4)


p

Actual Heat recovered in KWt: Fig. 2. Schematic Diagram of Single Flash based WHRPP.

QAMW = િBC î>ĮîPîȡî& × (T4-T1)] × 0.001163 (5)


p The schematic diagram of single flash based WHRPP
system is shown in figure 3, showing its working. It
Where: 0.001163 = (1/860) Units in KW incorporates an additional boiler for make use of drained/bled-
off steam for some more power generation and little high
else shut off value drain operate for emergency situations process efficiency for electrical power production as we are
Turbine practical Efficiency: interested in electrical power only.
િT =0.75
// The rest of the steam is bled off to flasher or secondary
boiler for regenerative use.
Actual work done by turbine in KWt:

PAMWT = િBC × િT î>ĮîPîȡî& × (T4-T1)] × (6)


p
0.001163

else shutoff valve operate in case of reverse power


Generator practical Efficiency:
િG =0.90
Actual work done by Generator in KWe: Fig. 3. Schematic Diagram of Dual Pressure based WHRPP.

PAMWG = િG × PAMWT (7) The schematic diagram of organic rankine cycle (ORC)
based WHRPP system is shown in figure 4, showing its
else Generator trip
Condenser along with cooling tower, for cooling working working. It has very simple configuration and is very easy to
fluid to take its temperature to relatively low. use but it is good for low temperature heat recovery for power
Pumps (multistage) to take back working fluid back to aerator generation and limited in used due to high maintenance cost,
and to boiler section (Economizer). operation cost and high cost of working fluid in addition to
else emergency exit environment hazards [6].
Superheated
Steam
6 31.4545 31.4545 49.9596 33.566
by AQC boiler
(T/h)
Superheated
Steam
7 13.8810 13.8810 15.7509 16.4855
by SP boiler
(T/h)
Auxiliary
8 0 5.6666 0 0
Boiler
Superheated
9 45.3355 51 65.7105 50.0515
Steam (T/h)
Fig. 4. Schematic Diagram of ORC based WHRPP.
Output of
10 8.6713 8.9702 5.9139 9.8738
Turbine (KW)
Output of
The schematic diagram of kalina based WHRPP system is 11 Generator 7.8042 8.0732 5.3226 8.8864
shown in figure 5, showing its working. (KW)
Auxiliary
12 0.7804 0.8477 0.3194 1.2441
Power (KW)
Net power
13 7.0238 7.2255 5.0032 7.6423
output (KW)
Process
14 27.6480 27.7344 30.9251 40.5000
efficiency (%)

IV. EMISSION REDUCTION AND CDM METHODOLOGIES


To calculate the quantity of GHGs reductions like CO2
reduction by the project implementation, the CDM
methodology used as per our project demonstration case
study, is AMS-111Q , which is approved methodology for
Fig. 5. Schematic Diagram of Kalina based WHRPP.
small scale projects for Waste energy recovery
(gas/heat/pressure) projects version 4 (CDM methodology
The kalina cycle has complex working but higher
process and electrical efficiency. But the power generation is guide). The emission reduction can be calculated during a
limited to a specific level of 10MWe due to design and process certain year y given by equation [4]:
limitations [11]. It has high cost of system, operation,
maintenance cost and auxiliary equipment power consumption ERy = EBy ±EPy (8)
but for small single line based old cement plants, these are
better choices for utilization and giving a new life to cement Where:
plant because in future only those cement plants will be in ERy = GHG emission reduction due to WHRPP during y year
competition which will install this system on right time with in (tons of CO2)
additional advantage of sharing one third load of cement plant EBy = GHG emission production in absence of WHRPP
with production of carbon credentials as an additional source of during y year in (tons of CO2).
income. The overall comparisons of all WHRPP systems are EPy = GHG emission production after WHRPP during y year
shown in table 2 on the basis of simulation results [12]. in (tons of CO2). This parameter is considered to be zero.
Enet,y = Net electricity used by the plant = 6000KW.
EFy = Emission Factor of Pakistan = 0.483 (tCO2/MWh).
TABLE II
COMPARISON OF WHRPP BASED ON DIFFERENT TECHNOLOGIES
General/
EBy = Enet,y× EFy (9)
Sr. Dual
Parameters Single ORC Kalina
#: Pressure
Flash That results in reduction of 20866 tons of CO2 per MWh
AQC Boiler and if CDM commitment period is 5 years along with 18$/14
1 24.479 24.479 16.687 34.772
input (MW)
tons of CO2 then the effects on payback is more visible.
SP Boiler
2 10.804 10.804 4.822 13.9872
input (MW)
Calculated
3 35.283 35.283 21.509 48.7592 V. EFFECT OF WHRPP ON CEMENT PLANT
input (MW)
Actual input The case study for demonstration is a 3700 tpd (tons per
4 28.2269 28.932 17.210 39.0076
(MW)
Effective heat
day) cement production plant with a maximum demand of
recovered by 19MW and we assume that we utilized single flash based
5 18.0652 18.6880 25.2118 21.9418
Boilers Output WHRPP system with gross electricity production of 7.2MW,
(KW) auxiliary consumption of maximum 1MW. The cost of clinker
production before WHRPP is based on actual data of 51.5 else
Kwh/tons and total cement production of 108.3251Kwh/tons. Net Bill = Bill of Received Power Net Bill = Bill of Received
The overall effect of WHRPP is shown in figure 6. [12]. Power
Clinker Prod in KWH/tons without WHRPP.
10
Clinker Prod in KWH/tons with WHRPP.
10
end if
9 9
end
8 8

7 7
B. Barriers and advantages of WHRPP installation

Time in months
Time in months

6 6

5 5
1) Barriers: Barriers in installation of WHRPP includes
4 4
Barriers due to Cost of installation of WHRS. More the cost of
3 3
a project, less it is viable for investor. Barriers due to
2 2
investment have to be considered because investment
1 1
providing mechanism varies from bank to bank along with the
51.5 52 52.5 34 35 36 37 38
production of clinker in Kwh/tons Production of clinker in Kwh/tons familiarity of the financing mechanism with the technological
Fig. 6. Overall Effect of WHRPP on Clinker production. aspects of WHRS technology and related risks for
implementation of a project. It might be a risk that power
Cement Prod in KWH/tons without WHRPP. Cement Prod in KWH/tons with WHRPP. generation and internal rate of return (IRR) from WHRPP can-
10 10
be lower than expected, in this case the bank has an option not
9 9
to extend loan period other than grace period so an alternative
8 8
arrangement for the project must be their if any worse case
7 7
scenario happens. This also cause hurdle in implementation of
Time in months
Time in months

6 6
project. Barriers due to Technology for WHRPP mainly
5 5 depend on the type of equipment used. As there is no domestic
4 4 equipment for WHRPP is produced in Pakistan, so we are
3 3 dependent on other countries. The trained manpower is main
2 2 issue for running and smooth operation of WHRPP. As steam
1 1
based WHRPP is short magnitude version of conventional
108.2 108.4 108.6 108.8 73 74 75 76 77
Production of cement in Kwh/tons Production of cement in Kwh/tons steam based power plant with design change up to greater
Fig. 7. Overall Effect of WHRPP on Cement production. extent as per requirement of the process. So steam based
WHRPP is easy to handle by trained manpower. The ORC
WHRPP is even easier to handle but it requires high level
A. Monitoring Policy for Billing security of man power and handling of working fluid, as most
Either power produced can be utilized on site but it is costly of the organic fluids are volatile. Kalina cycle is even more
along with special arrangement in hardware so overall cost is complex in operation and difficult to handle because it
high and leads to a least robust system of power utilization requires high level of observe-ability and monitoring by
with subject to limited power generation availability from trained staff as a little change in concentration of water and
WHRPP only. A simple and better solution is to install reading ammonia in working fluid at high temperature can affect the
meters both on receiving power from national grid and amount of output power by the process. Also the maintenance
transmitting meter on WHRPP side from where the power is
staff at Kalina based WHRPP requires special training, as it is
transmitted to national grid. So overall bill will be units
relatively new technology, which further increase cost of
received from national grid from units generated from WHRPP
process and discourage investor to invest in such kind of
and also ensure availability of power from national grid during
shutdown and fault conditions. The algorithm for billing project. The main process restriction for WHRPP in cement
system is shown below: LQGXVWU\LVWKLVWKDWÛ&WHPSHUDWXUHPXVWEHNHSWDW63IRU
raw material and coal preheating, which do not allow
if PNET generated, maximum heat achievability from SP. Also waste gases that
Power transmitted to cement plant Main sub-station (MSS) to flow through process have high content of dust and stickiness
WAPDA/NTDC (National grid) giving reading on can cause damage to the boiler tubes in-terms of chocking.
sending/transmitting meter. Other barriers includes WHRPP capacity such as the WHRPP
else if P is not generated, Power taken from WAPDA/NTDC should produce that much significant power which helps kiln
(National grid), giving reading on receiving meter and cooler area to run at full capacity other than auxiliary
end if equipment even in-case of power shutdown from national grid
and barrier due to lack of vision [13].
if Power Produced by WHRPP 2) Advantages: The technical and economic advantages of
Net Bill = Bill of Received Power from WAPDA - Bill of WHRPP installation includes dependency reduction of
Transmitted/generated Power by WHRPP electrical load on national grid, CO2 reduction, It also
contributes to the smooth production process because NTDC ACL WAH, Mr Raza Mir, Manager(E), Bestway chakwal and
instructed all cement factories in Pakistan to make their load Mr Muraad SDM(E), Fecto cement company.
to minimum during TOD (Time-off Demand) which results in
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