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Characterization of the chemical
Name compound = hypotheticum
Physico-chemical properties table 1:
Molecular weight = 78.11 [ 1E+02 ] g mol-1 0.0781 kg mol-1 Sludge loading rate (SLR) related to hydraulic retentiontime
Kow = 1.35E+02 [ 1E+03 ] (-) 134.9 (-) (HRT) and sludge retention time (SRT). HRT with primary
Vapour pressure = 3.97E+03 [ 1E+00 ] Pa 3971 Pa sedimentation (PS) and without; PS has no influence on SRT.
Solubility = 1.50E+03 [ 1E+02 ] mg L-1 19.169 mol m-3 SLR HRT (PS) HRT SRT nitrification
Ka = [ 1E-20 ] (-) 1E-20 (-) (kgBOD kgdwt-1 d-1) (hr) (hr) (d) (-)
Kb = [ 1E-20 ] (-) 1E-20 (-) 0.04 (low) 25.9 40.5 37.0 yes
Henry constant (H) = 207.15779 [ 2E+02 ] Pa m3 mol-1 207.16 Pa m3 mol-1 0.06 (low) 17.3 27 24.1 yes
Kp (raw sewage) = 2.01E+01 [ 2E+01 ] L kgdwt
-1
20.081 L kgdwt
-1
0.1 (low) 10.4 16.2 14.1 yes
Kp (activated sludge) = 2.48E+01 [ 2E+01 ] L kgdwt
-1
24.767 L kgdwt
-1
0.15 (medium) 6.9 10.8 9.2 yes
0.2 (medium) 5.2 8.1 6.8 no
Emission scenario 0.3 (high) 3.5 5.4 4.5 no
T air = 15 [ 15 ]centigrade 288 Kelvin 0.6 high) 1.7 2.7 2.2 no
T water = 15 [ 15 ]centigrade 288 Kelvin
Windspeed = 3 [ 3 ]m s-1 3 m s-1
Sewage flow = 200 [ 200 ]L person-1d-1 0.2 m3 person-1d-1
Number inhabitants = 1.00E+04 [ 1E+04 ]person 10000 person
0.15 ] kgBOD kgdwt d 0.15 kgBOD kgdwt d
-1 -1 -1 -1
Sludge loading rate (table 1) = 0.15 [
Bubble or surface aeration: b/s s [ s ] (-) s (-)
Emission rate chemical = 20000 [ 1 ] kg d-1 20000 kg d-1
Method 2: chemical is biodegradable in activated sludge batch test (draft ISO test)
Assumption: degradation according to first order kinetics with respect to the concentration in the slurry phase,
implying that biodegradation occurs both in the aqueous and the solids phase of activated sludge.
9-box
system characteristics interaction between chemical and system mass balance computation (9 boxes)
coef_9box_ 1 2 3 4 5 6 7 8 9 constant
general physico-chemical characteristics box 1 600.19256 -0.001038 0 0 -0.011468 0 -0.004153 0 0 0
Height air column = 10 m R= 8.314 J K-1 mol-1 box 2 -0.012001 0.0242828 -3.2E-06 0 0 0 0 0 0 229.40841
Area of the plant = 0.04 m2 PE-1 pKw = 14.36173 box 3 0 -9.64E-05 1.014E-05 0 0 0 0 0 0 2.0730685
pH = 7 box 4 0 0 -4.63E-06 4.63E-06 0 0 0 0 0 0
raw sewage box 5 -0.132554 -0.023148 0 0 0.1823256 -0.003099 0 0 0 0
defaults partition coefficients box 6 0 0 -2.31E-06 0 -0.099793 0.0031707 0 0 -6.9E-05 0
0.09 kgdwt PE d Kp raw sewage = 20.081299 L kgdwt-1
-1 -1
Input solids in raw sewage = 0.09 box 7 -0.048006 0 0 0 -0.023148 0 0.0273729 -2.22E-06 0 0
1.5 kgdwt L Kp PS = 20.081299 L kgdwt
-1 -1
Density solids raw sewage = 1.5 box 8 0 0 0 0 0 -7.12E-05 -7.15E-05 7.345E-05 0 0
0.45 kgdwt m Kp aerator = 24.766935 L kgdwt-1
-3
C susp solids raw sewage = calc. box 9 0 0 0 0 0 0 0 -7.07E-05 7.069E-05 0
Fraction oc raw sewage = 0.3 (-) 0.3 Kp SLS = 24.766935 L kgdwt-1
BOD in raw sewage = 54 g BOD PE d -1 -1
54 K air-water (KH) = 8.65E-02 (-)
Sablic1 = 0.81 coef_1_9box_ C
primary sedimentation Sablic2 = 0.1 box 1 0.0016662 0.0003602 0.0001825 0 0.0003024 0.0003021 0.0002536 0.0002915 0.0002949 9boxC 1 = 0.08301 g m-3
defaults box 2 0.0008245 41.233137 13.005031 0 0.0001496 0.0001495 0.0001255 0.0001442 0.0001459 9boxC 2 = 9486.1889 g m-3
Depth PS = 4m 4 box 3 0.0078335 391.73585 98705.726 0 0.0014215 0.0014203 0.0011922 0.0013704 0.0013863 9boxC 3 = 294491.23 g m-3
HRTPS = 2h 2.0 fugacity capacity Z(i) in box i box 4 0.0078335 391.73585 98705.726 216000 0.0014215 0.0014203 0.0011922 0.0013704 0.0013863 9boxC 4 = 294491.23 g m-3
Volume PS = 0.01666667 m3 PE-1 calc. Z(1) = 0.0004176 mol m-3 Pa-1 box 5 0.0029071 11.564826 6.4060683 0 12.104918 12.088125 0.0300976 11.35736 11.798905 9boxC 5 = 2666.3487 g m-3
Area PS = 0.00416667 m2 PE-1 calc. Z(2) = 0.0048272 mol m-3 Pa-1 box 6 0.093591 372.34011 279.70344 0 389.42304 711.07431 1.7587219 668.0873 694.0612 9boxC 6 = 85997.798 g m-3
C susp solids PS = 1.5E-01 kgdwt m
-3
calc. Z(3) = 0.1454058 mol m-3 Pa-1 box 7 0.0053883 9.810593 5.4400991 0 10.268605 10.279702 36.561402 10.762606 10.033751 9boxC 7 = 2261.9103 g m-3
Fraction oc solids PS = 0.3 (-) 0.3 Z(4) = 0.1454058 mol m-3 Pa-1 box 8 0.096006 370.63328 276.54332 0 387.64559 699.58532 37.287061 14273.99 682.84709 9boxC 8 = 85599.685 g m-3
Density solids PS = 1.5 kgdwt L
-1
1.5 Z(5) = 0.0048272 mol m-3 Pa-1 box 9 0.096006 370.63328 276.54332 0 387.64559 699.58532 37.287061 14273.99 14828.943 9boxC 9 = 85599.685 g m-3
Z(6) = 0.1554227 mol m-3 Pa-1
aerator Z(7) = 0.0048272 mol m-3 Pa-1
defaults Z(8) = 0.1554227 mol m-3 Pa-1 9boxin = 231.48148 g s-1 = 20000 kg d-1
Depth aerator = 3m 3 Z(9) = 0.1554227 mol m-3 Pa-1 9boxout = 103.71894 g s-1 = 8961.3166 kg d-1
HRT = 6.9 h calc. D = 1.28E+02 g s-1 = 11038.683 kg d-1
Volume aerator = 0.0575 m3 PE-1 calc. exchange rate parameters
Area = 0.01916667 m2 PE-1 calc. air-water in non-aerated basins
Oxygen requirement = 0.1725 kg BOD m-3 calc. Mackay et al. (1985):
0.002 kg O2 m K airM = 2.78E-03 m s-1
-3
Oxygen concentration = 0.002
Aeration rate (1.31E-05) = 0.0000131 m3 s-1 PE-1 1.3E-05 K waterM = 2.78E-05 m s-1
4 kgdwt m K pore waterM =
-3
C activated sludge = 4 2.78E-06 m s-1
Fraction oc activated sludge = 0.37 (-) 0.37 Liss & Slater (1974):
1.3 kgdwt L K airL&S =
-1
Density solids activated sludge = 1.3 4.00E-03 m s-1
K waterL&S = 4.17E-05 m s-1
solids liquid separation Schwarzenbach et al. (1993):
defaults K airS = 5.50E-03 m s-1
Depth SLS = 3m 3 K waterS = 5.89E-06 m s-1
HRTSLS = 6h 6.0 K air = 2.78E-03 m s-1
Volume SLS = 0.05 m3 PE-1 calc. K water = 2.78E-05 m s-1
Area SLS = 0.01666667 m2 PE-1 calc. air-water in aerated basins
C susp solids SLS = 0.03 kgdwt m
-3
0.03 Psi = 0.6 (-)
Fraction oc solids SLS = 0.37 (-) 0.37 kGa/kLa = 40 (-)
Density solids SLS = 1.3 kgdwt L
-1
1.3 DO2 = 0.007 kg O2 m
-3
Page 2
6-box
6-box
system characteristics
general
Height air column = 10 m
Area of the plant = 0.04666667 m2 PE-1
Raw sewage
defaults
0.09 kgdwt PE d
-1 -1
Input solids in raw sewage = 0.09
1.5 kgdwt L
-1
Density solids raw sewage = 1.5
0.45 kgdwt m
-3
C susp solids raw sewage = calc.
Fraction oc raw sewage = 0.3 (-) 0.3
BOD in raw sewage = 54 g BOD PE-1 d-1 54
aerator
defaults
Depth aerator = 3 m 3
HRT = 10.8 h calc.
Volume aerator = 0.09 m3 PE-1 calc.
Area = 0.03 m2 PE-1 calc.
Oxygen requirement = 0.27 kg BOD m-3 calc.
0.002 kg O2 m
-3
Oxygen concentration = 0.002
Aeration rate (1.31E-05) = 0.0000131 m3 s-1 PE-1 1.3E-05
4 kgdwt m
-3
C activated sludge = 4
Fraction oc activated sludge = 0.37 (-) 0.37
1.3 kgdwt L
-1
Density solids activated sludge = 1.3
Page 3
6-box
0.807 kgdwtkgBOD
-1
Y BOD = calc.
0.033 kgdwtPE d
-1 -1
Surplus sludge = calc.
0.006 kgdwtPE d
-1 -1
Emitted solids in effluent = calc.
SRT = 9.20 d calc.
0.15 kgBOD kgdwt d
-1 -1
Sludge loading rate = input
Page 4
6-box
6-box
Page 5
6-box
DO2 = 0.007 kg O2 m
-3
Page 6
6-box
XCH(7,9) = m3 s-1
XCH(9,7) = m3 s-1
Page 7
6-box
1 5 6 7 8 9 C
0.001543 0.000228 0.0002178221 0.0002346018 0.000208 0.000209 6boxC 1 = 0.052832
0.002115 8.367299 7.9786762342 0.0195386348 7.359678 7.645802 6boxC 5 = 1936.069
0.064993 256.9813 441.602406394 1.0735199272 407.342 423.1786 6boxC 6 = 59869.14
0.004499 7.097056 6.7828908369 36.5523843125 7.361007 6.499906 6boxC 7 = 1642.186
0.067408 256.1205 434.855473876 36.6137951179 14017.82 416.7131 6boxC 8 = 59657.68
0.067408 256.1205 434.855473876 36.6137951179 14017.82 14562.81 6boxC 9 = 59657.68
Page 8
6-box
1E+00
Page 9
6-box
constant_6box_
Page 10
output
Summary of distribution
to air 21.5
to water 22.6
via primary sludge 0.6
via surplus sludge 0.1
degraded 55.2
total 100.0 %
Concentrations
in air 8.30E-02 g m-3
in combined sludge 1.65E+05 mg kg-1
|___________ in primary sludge: 1.96E+05 mg kg-1
|___________ in surplus sludge: 6.58E+04 mg kg-1
in effluent (total) 2263.88565 mg l-1
|___________ dissolved 2.26E+03 mg l-1
|___________ associated 1.98E+00 mg l-1
in solids effluent 6.58E+04 mg kg-1
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output
Summary of distribution
to air 14.8
to water 16.4
via surplus sludge 0.1
degraded 68.7
total 100.0 %
Concentrations
in air 5.28E-02 g m-3
in surplus sludge 4.59E+04 mg kg-1
in effluent (total) 1.64E+03 mg l-1
|___________ dissolved 1.64E+03 mg l-1
|___________ associated 1.38E+00 mg l-1
in solids effluent 4.59E+04 mg kg-1
Page 12