RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions

Date: 26 Nov 2017

NSEC - 2017 / CODE : C322 / SOLUTIONS

1.
Di iculty : Medium

Topics :

Ionic equilibrium,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
2.
Di iculty : Medium

Topics :

GOC,

In III-N atom, N L.P. is not involved in resonance. 

3.
Di iculty : Easy

Topics :

Chemical Kinetics,

 is a complex reaction.

rate 
it is a 2nd order.

4.
Di iculty : Medium

Topics :

Solutions,
Colligative properties,

More the intermolecular forces.

Higher the surface tension.
Lower the vapour pressure.
Higher the B.P.

5.
Di iculty : Easy

Topics :

Chemical Bonding,

Bigger size of   does not favor multiple bond formation.

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
6.
Di iculty : Medium

Topics :

AMINES,

7.
Di iculty : Medium

Topics :

Thermodynamics,

Since  is a state function function depends only on initial and final states of system.

8.
Di iculty : Medium

Topics :

Chemical equilibrium,

Rate of reaction   is conc. of each reactant is double than rate will become 16 times the initial
rate.

9.
Di iculty : Easy

Topics :

Chemical Bonding,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions

10.
Di iculty : Easy

Topics :

Alkenes,

11.
Di iculty : Easy

Topics :

Alcohols,
Ethers,

12.
Di iculty : Easy

Topics :

Thermodynamics,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
13.
Di iculty : Medium

Topics :

Thermodynamics,

Randomness decreases , thus 

14.
Di iculty : Medium

Topics :

Volumetric analysis,

Mass                     45 kg         60kg
    

            
 Limiting reagent
To completely remove 60 kg water

    Mass of   (in kg)

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
15.
Di iculty : Medium

Topics :

GOC,

16.
Di iculty : Medium

Topics :

Electrochemistry,

 is the best R.A.

17.
Di iculty : Medium

Topics :

Electrochemistry,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
18.
Di iculty : Medium

Topics :

Electrochemistry,

Reduction takes place at Cathode

So, Silver will deposit on the Medal (Cathode) according to the reaction  [At Cathode]

19.
Di iculty : Easy

Topics :

Atomic Structure,

For

20.
Di iculty : Easy

Topics :

P-block,

Due to weak Vander Waal forces between   molecules

21.
Di iculty : Easy

Topics :

Chemical equilibrium,

 must be negative 
 Exothermic reaction
 

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
22.
Di iculty : Easy

Topics :

Gaseous State,

 cannot be a straight line

23.
Di iculty : Easy

Topics :

Stereochemistry,

24.
Di iculty : Easy

Topics :

Ethers,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
25.
Di iculty : Medium

Topics :

Coordination Compounds,

dichlorodioxalatochromate (III)

26.
Di iculty : Medium

Topics :

Gaseous State,

            
Mass       
Moles                     

27.
Di iculty : Medium

Topics :

Mole concept,

1 mol 

28.
Di iculty : Medium

Topics :

P-block,

 more stable due to inert pair e ect and 6s e- becomes inert towards bonding.

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions

29.
Di iculty : Medium

Topics :

GOC,

Rate of hydrogen abstraction   stability.

30.
Di iculty : Medium

Topics :

Alkenes,

31.
Di iculty : Medium

Topics :

Chemical Bonding,

Due to more EN di erence between oxygen and nitrogen as compare to   and .

32.
Di iculty : Medium

Topics :

CARBONYLS,

33.
Di iculty : Medium

Topics :

Chemical Bonding,

 Both are lewis acid.

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
34.
Di iculty : Medium

Topics :

Coordination Compounds,

Can show cis & trans geometry and ionisation isomerism by Br & Cl.
Optically inactive due to POS.

35.
Di iculty : Medium

Topics :

Volumetric analysis,

1 mole pyrethrin reacts with 4 mol 

  500 mg reacts with   mols of 

36.
Di iculty : Medium

Topics :

Alkenes,
Alkynes,

(I) Methylated product with Me-I represents there are   groups.

(II) 1 mole compound   2 mol 
It represents there are two   groups.
(III) Ozonolysis gives 

37.
Di iculty : Medium

Topics :

Polymers,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
38.
Di iculty : Medium

Topics :

Gaseous State,

Initial vol ratio 

    
Here,   vol of   will react with   vol of   thus   of   is le .
Now, 
                
Here,   vol of   requires   vol of   
Thus   and   reacts completely.

39.
Di iculty : Medium

Topics :

Chemical Kinetics,

rate
If  is halved and   is double then initial rate will be twice the initial rate
 New rate 

40.
Di iculty : Medium

Topics :

Mole concept,

C, D

(A) 

(B) Molar mass of 

      1 millimol of

41.
Di iculty : Medium

Topics :

Gaseous State,

Higher value of 'a' makes gas to be liquify easily.

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
42.
Di iculty : Medium

Topics :

Alkenes,

43.
Di iculty : Medium

Topics :

GOC,

Leaving group nature   stability of resulting anion.

44.
Di iculty : Medium

Topics :

Coordination Compounds,

In metal carbonyls back bonding is possible.

45.
Di iculty : Medium

Topics :

Chemical equilibrium,

              
Initial                                                    
Final                                                   

        

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
46.
Di iculty : Medium

Topics :

Thermodynamics,

47.
Di iculty : Easy

Topics :

CARBONYLS,

 It is carbonyl

 It is ketone

 It is substituion, not addition.

48.
Di iculty : Medium

Topics :

Ionic equilibrium,

If pH increases reaction favours in forward direction.

   depends on pH.

49.
Di iculty : Medium

Topics :

GOC,

Rate of    substitution   electrophilicity of 

  

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
50.
Di iculty : Medium

Topics :

CHEMISTRY IN EVERYDAY LIFE,

In addition to the partial pressure of carbon dioxide, the oxygen saturation of hemoglobin and the partial pressure of oxygen in
the blood also influence the a inity of hemoglobin for carbon dioxde. The Haldane e ect is a phenomenon that arises from the
relationship between the partial pressure of oxygen and the a inity of hemoglobin for carbon dioxide. Hemoglobin that is
saturated with oxygen does not readily bind carbon dioxide. However, when oxygen is not bound to heme and the partial
pressure of oxygen is low, hemoglobin readily binds to carbon dioxide.

51.
Di iculty : Medium

Topics :

Alcohols,

Reagent should be PCC/PDC.

PCC is pyridinium chlorochromate.

52.
Di iculty : Medium

Topics :

Mole concept,

Option A is incorrect as   cannot be last and if weight of hydrated sample is estimated less than the actual weight,
then the result should be less than what is given.

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
53.
Di iculty : Medium

Topics :

CARBOXYLIC ACIDS AND ITS DERIVATIVES,

54.
Di iculty : Medium

Topics :

P-block,

 Maximum  of   is 

So it will react as a reducing agent.

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
55.
Di iculty : Medium

Topics :

Metallurgy,

at 
graph (I) is above (II)
So,   is better reducing agent than  .

56.
Di iculty : Medium

Topics :

Thermodynamics,

57.
Di iculty : Medium

Topics :

P-block,

 is more stable than   

 is more stable than  due to inert pair e ect.

58.
Di iculty : Medium

Topics :

Gaseous State,

59.
Di iculty : Medium

Topics :

Ethers,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
60.
Di iculty : Medium

Topics :

Aromatic compounds,
Alkyl halides,

61.
Di iculty : Medium

Topics :

Coordination Compounds,

 unpaired electron
 unpaired electorn
 is strong field ligand and   is weak field ligand

62.
Di iculty : Medium

Topics :

Alkyl halides,

In   carbocation is formed more stable carbocation will be more reactive stability of carbocation d > c > b > a

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
63.
Di iculty : Medium

Topics :

Chemical Bonding,

                                                                                                          

B.O =

                       B.O =  = 1.5

                    B.O =  = 2.5

                    B.O = =1

64.
Di iculty : Medium

Topics :

Ionic equilibrium,

                                

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
65.
Di iculty : Medium

Topics :

Mole concept,

2 milli mole 4 milli mole

unreacted   2 milli mole
so reacted   0.5 mole.

40 ml, 0.1   4 milli mole 

       So 2  millimole    unreacted

 reacted = 0.5 mole
So mass of I atom =   for   oil 

So for   oil  = 

66.
Di iculty : Medium

Topics :

Solid State,

metal deficiency defect : these contain lesser number of positive particles than negative particles. These defects arise due to
cation vacancies or anions occupying interstital sites the extra negative charge is balanced by oxidation of some of the nearby
metal ions. Thus, this e ect occurs when metal shows variable valency. ., Crystals with metal deficient defects
are semiconductors of p-type.

67.
Di iculty : Medium

Topics :

Gaseous State,

KE only depends on Temp so it will increase

68.
Di iculty : Medium

Topics :

Stereochemistry,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
69.
Di iculty : Di icult

Topics :

Coordination Compounds,

Oxidation state of   is   electronic  configuration

70.
Di iculty : Easy

Topics :

GOC,

Nucleophilicity   e– donation

 has crowded lone pair

but    has less crowded lone pair.

71.
Di iculty : Medium

Topics :

Aromatic compounds,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
72.
Di iculty : Di icult

Topics :

Atomic Structure,

The Energy of an electron in the ground state of H atom is -13.6eV. The energy of free electron will be zero

73.
Di iculty : Di icult

Topics :

Mole concept,

Ar is gas 
Volume of Ar atom = 

              

                            

Volume of one atom at STP

                     
                    

% volume occupied by atom      

                    
                    
              

74.
Di iculty : Easy

Topics :

Electrochemistry,

Let                      
     
                                                      
So decreases by 

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
75.
Di iculty : Easy

Topics :

Mole concept,

                    
Total volume a er reaction = 5+ 0.5 = 5.5
 

76.
Di iculty : Medium

Topics :

BIOMOLECULES ,

77.
Di iculty : Medium

Topics :

Phenols,

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 RAO IIT ACADEMY / NSEC - 2017 / Code : C322 / Solutions
78.
Di iculty : Easy

Topics :

Ionic equilibrium,

colourless                          colours (Y) 

In strong alkaline solution equilirium will shi in forward direction as  ion wll consumed hence colour Y will observed

79.
Di iculty : Easy

Topics :

Volumetric analysis,

Molarity of 
Molarity of 

so  few drops of the neutralized solution from titration II were le behind in the flask

80.
Di iculty : Easy

Topics :

Mole concept,

                                               
Total volume a er reaction = 5+ 0.5 = 5.5

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