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DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL

DOC. NO.: PPL-HGPP-LAB/SOP/003


REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED


PROCEDURE

Pakistan Petroleum Limited

STANDARD PROCEDURE FOR


DETERMINATION OF RVP
OF LPG AND CRUDE OIL / NGL
OPERATING

Document No. :PPL-HGPP-LAB/SOP/003


Original Issue Date : 12-04-2016
Revision : 0riginal
Last Date of Revision : XX-YY-ZZZZ
STANDARD

Prepared by Reviewed by Approved by

Abdul Qadir Syeed Aslam Shah M.Ali Khan


Lab Chemist Plant Manager PEIC, HGPP

Standard Operating Procedure Page 0 of 7


DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL
DOC. NO.: PPL-HGPP-LAB/SOP/003
REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED

Copyright: © Pakistan Petroleum Limited


All rights reserved except as permitted by Pakistan Petroleum Limited. No
Part of this document may be reproduced or distributed in any form and by
any means or stored in a database or retrieval system without the prior
written permission from Top Management

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Standard Operating Procedure Page 1 of 7


DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL
DOC. NO.: PPL-HGPP-LAB/SOP/003
REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED

TABLE OF CONTENTS

S. NO. CONTENTS PAGE NO.

DISTRIBUTION LIST 3

TERMS AND DEFINATIONS 4

LIST OF ABBREVIATIONS 5

1 PURPOSE 6

2 SCOPE 6

3 RESPONSIBILITIES AND AUTHORITIES 6

4 PROCEDURE 6

4.1 DETERMINATION OF RVP 6

4.2 INSTRUCTIONS FOR DETERMINATION OF RVP 7

5 RELATED DOCUMENTS AND RECORDS 7

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DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL
DOC. NO.: PPL-HGPP-LAB/SOP/003
REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED

DISTRIBUTION LIST

Plant Manager
Laboratory

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DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL
DOC. NO.: PPL-HGPP-LAB/SOP/003
REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED

TERMS AND DEFINITIONS

TERM DEFINITION

LPG Liquefied petroleum gas composed of 60% propane &


40% butane.

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DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL
DOC. NO.: PPL-HGPP-LAB/SOP/003
REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED

LIST OF ABBREVIATIONS

LPG Liquefied Petroleum Gas


NGL Natural Gas Liquids
RVP Reid Vapor Pressure
ASTM American Society for Testing & Materials

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DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL
DOC. NO.: PPL-HGPP-LAB/SOP/003
REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED

1. PURPOSE:

RVP test method determines the gauge vapor pressure of petroleum commodities particularly of
light products like LPG, Gasoline, NGL and Crude oil. Determination of vapor pressure is
important for safety reasons to ensure that the maximum operating design pressures of storage
& handling will not be exceed under normal operating temperature conditions.

2. SCOPE:

This test method covers the determination of gauge vapor pressure of petroleum products as
per ASTM D-1267-89.

3. RESPONSIBILITIES AND AUTHORITIES:

 Plant Manager & shift in charge is overall responsible to maintain this documented
procedure for analysis.
 The lab chemist is responsible to follow guidelines given in procedure.

4. PROCEDURE:

4.1 DETERMINATION OF RVP:

1) Before to proceed for the determination of RVP, it is to ensure that the bath is filled with
water to desired level.
2) Energize the heater & stirrer of bath to maintain the temperature of water at 100F.
3) Take sample in lower chamber as per outlines given in ASTM D-1267 and connect with
upper chamber, then hang / immerse this assembly in water bath maintained at temperature
of 100F.

Standard Operating Procedure Page 6 of 7


DETERMINATION OF RVP OF LPGAND CRUDE OIL / NGL
DOC. NO.: PPL-HGPP-LAB/SOP/003
REV: ORIGINAL

PAKISTAN PETROLEUM LIMITED

4) Observe the gauge pressure at equilibrium when RVP apparatus is at same temperature as
of water and report after correcting gauge error, if exist and correcting to a standard
barometric pressure as per guide lines given in ASTM test method.
5) Maintain the log of RVP reading in registers for log of results of miscellaneous samples.
4.2 INSTRUCTIONS FOR DETERMINATION OF RVP:

1) Pressure gauge which is the part of RVP apparatus to be checked for accuracy. Its
calibration to be carried out at two months interval / on when inaccuracy is suspected.
2) Temperature of water to be maintained at 100F before to immerse the RVP apparatus.
3) Guide lines as established in ASTM standard for sample filling in lower chamber need to
follow.
4) Before to observe the reading of gauge, it is to ensure that the temperature of RVP
assembly is same as of water bath.
5) Before reporting, convert the observed gauge vapor pressure to a standard barometric
pressure of 760 mmHg by using the equation given in ASTM D-1267.

5. RELATED DOCUMENTS AND RECORDS

1) ASTM D 2163-91

2) Lab Analysis Report


PPL-HGPP-LAB/CR/FM/001

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