Full mark – 70

CHEMISTRY TEST -2 Time – 2 hr

Each question carrying one mark (Q. No .1-4)
1 How many number of Hydrogen bonds formed by a water molecule .
2 Write the electronic configuration of the elements with atomic numbers : 24
3 How are bond order and bond length related each other
4 Round off each of the following lengths to retain two significant digits:
(a) 2.68 m (b) 2.62 m (c) 2.65 m
Each question carrying two mark(Q. No.5-14)
5. What designation are given to the orbitals having
n=2 l=1
n=4 l=3
6. Explain why hydrogen forms diatomic molecule while helium remainsMonoatomic
7 How many moles of NaHCO3 are contained in 33.6grams NaHCO3?

8 Calculate the wave number and wavelength of the spectral line observed in
hydrogen spectrum with n 1 = 2 and n2 = 3.
9 Ionic radius of Na ion is 0.95 A and the inter-nuclear distance between the ion-pairs in
NaCl ionic crystal is equal to 2.76 A. Calculate the radius of Cl-ion.

10 Arrange C, N, 0 and F in the decreasing order of their IE2 values.

11 using lewis symbol , represent the transfer of electron from Magnesium to Fluorine to
form the correct molecular formula
12 what is polar covalent bond , give two example by showing the partial ionic charge
and shifting of polarity
13 Assuming that the following reaction between oxygen and hydrogen goes to
completion, which one is limiting reagent if 10.0 grams of hydrogen are mixed with
64.0grams of oxygen?

14 Calculate the no. of σ-bond and Lone pair of electron in the following molecule
 Each question carrying three mark(Q.No.15-22)
15 Predict the structures and hybridization of the following. Indicate the direction of distortions from
the regular structures.
XeF4 , XeOF4
16 The Vividh Bharti Station of All India Radio, Delhi broadcasts on a frequency of 1368 kHz
(kilo hertz). Calculate the wavelength and wave number of the electromagnetic radiation emitted
by the transmitter.
2+
17 Define the term paramagnetism . Which one is paramagnetic between N2 and N .
18 why ClF3 have T-shape while BF3 have Trigonal planner
19 Explain the intermolecular forces between two Non polar molecules
20 Calculate the volume occupied by 7g CO at 27°C and 750 mm Hg.
21 At 0°C, the density of a gaseous oxide at 2 bar is same as that of nitrogen at 5 bar. What is the
molecular mass of the oxide?
22 Using ideal gas equation; show that at a given temperature density of a gas is proportional to gas
pressure p.
Each question carrying four mark(Q. No.23-25)
23 What are the important characterstics of gases and what are its parameters
24 Explain how the H-bond takesplace ? Briefly explain how the density of ice becomes lower
then water .
25 Derive the gas law for partial pressure . What is the effect of pressure when Z =1 on deviation of
ideal gas .
Each question carrying five mark(Q. No.26 & 27)
26 What are assumptions of kinetic theory of gases and what are the major difference between
Ideal gas and real gas
27 Write short notes
a. Intermolecular H-bonding
b. Cause of real gas deviation from ideal gas
c. Hybridisation of C2H4