HELIOS EDUCORE 1

TEST SERIES NEET-2018

Topic : Gaseous State & Thermodynamics

Time : 90 Min Max. Mark : 80

* +4 for correct and –1 for incorrect. BEST OF LUCK

1. If Ne atom is there in a container at 127°C and 20 atmosphere pressure then

which is correct
(a) Vrms > Vav > Vmp (b) Vrms > Vmp > Vav
(c) Vrms = Vmp = Vav (d) Vrms < Vmp < Vav

2. Which is not obeying for Dalton’s law of partial pressure at room temperature
(a) He + Ne + O2 (b) CO2 + N2 + O2
(c) NH3 + HCl + O2 (d) N2 + O2 + CH4

3. If O3 is dissociating into O2 then molecular weight of O3 may be

(a) 48 (b) 64 (c) 40 (d) 50

4. If 20 liter container is containing He at 20 atmosphere pressure. If it is connected

with 40 liter container of He at pressure 20 atmosphere then find out final pressure.
(a) 20 (b) 30 (c) 10 (d)None

5. Find out correct relation between T1, T2, T3

(a) T1 > T2 > T3 (b) T3 > T2 > T1 (c) T1 = T2 = T3 (d) T2 > T1 > T3

6. Find out average kinetic energy ratio of 2 mole He and 20 mole H2 at 127°C.
(a) 1 : 10 (b) 10 : 1 (c) 1 : 1 (d) None
HELIOS EDUCORE 2

7. Find out correct about heat of formation :

(a) H2 + Cl2 → 2HCl (b) H2 + O → H2O
(c) H2 + 1/2O2 → H2O (d) H + F → HF
8. For which ∆H > ∆E
(a) N2(g) + 3H2(g) → 2NH3(g) (b) PCl5(g) → PCl3(g) + Cl2(g)
(c) H2(g) + Cl2(g) → 2HCl(g) (d) All are correct
9. Heat of formation of OH– is 5 Kcal then find out heat of formation of H2O at 25°C
H+ + OH– → H2O
(a) 10 Kcal (b) –8.7 Kcal (c) 2.5 Kcal (d) None
10. For CO, isotherm is of the type of as shown. Near the point A, compressibility
factor Z is
CO
pV
B Ideal
A

 b  b  a   a 
(a) 1 +  (b) 1 −  (c) 1 +  (d) 

1− 
V V RTV RTV 
11. When an ideal gas undergoes unrestrained expansion, no cooling occurs because
the molecules
(a) are above the inversion temperature
(b) exert no attractive force on the other
(c) do work equal to the loss in KE
(d) collide without loss of energy
12. Compressibility factor for H2 behaving as real gas is
 a   pb  RTV
(a) 1 (b) 1 −  (c) 1+  (d)
 RTV   RT  (1 − a)
–1
13. A mixture of nitrogen and oxygen has a density of 1.00 g L and the average
molecular weight of 31.2 g mol–1 at 27°C and 600 mmHg pressure. The mole
fraction of nitrogen, assuming ideal gas behaviour, is
(a) 0.78 (b) 0.60 (c) 0.40 (d) 0.22
14. Which of the following statements is wrong for gases ?
(a) Gases do not have a definite shape and volume
(b) Volume of the gas is equal to volume of container confining the gas
(c) Confirmed gas exerts uniform pressure on the walls of its container in all
directions
(d) Mass of gas cannot be determined by weighing a container in which it is
enclosed
HELIOS EDUCORE 3

15. Precisely 1 mol of helium and 1 mol of neon are placed in a container. Indicate the
correct statements about the system :
(A) Molecules of the two gases strike the wall of the container with same
frequency.
(B) Molecules of helium strike the wall more frequently.
(C) Molecules of helium has greater average molecular speed.
(D) Helium exerts larger pressure.
(a) B & C (b) C & D (c) A & D (d) A & B

16. Which of following statements are correct

(A) Average velocity of molecules of a gas in a container is zero
(B) All molecules in a gas are moving with the same speed
(C) If an open container is heated from 300 K to 400 K the fraction of air
which goes out with respect to originally present is 1/4
(D) If compressibility factor of a gas at STP is less than unity then its molar
volume is less than 22.4 L at STP
(a) A, B & C (b) A, C & D (c) A, B, C & D (d) A, B & D

17. Select the correct alternate about entropy

(a) lim S = ∞ (c)
lim S = 0 (b) lim S = 0 (d) S(liquid) > S(vapour)
T→∞ T→0 T→0
18. In an electrochemical cell DG = DH
 dEcell 
(a) T → 0  dT  = 0 (d) Both (a) and (c)
(b) T → ∞ (c)
P
19. In thermodynamics, a process is called reversible when
(a) surroundings and system change into each other
(b) there is no boundary between system and surroundings
(c) the surroundings are always in equilibrium with the system
(d) the system changes into the surroundings spontaneously

20. An ideal gas is allowed to expand both reversibly irreversibly in an isolated system.
If Ti is the initial temperature and Tf is the final temperature, which of the following
statements is correct?
(a) (Tf)irrev > (Tf)rev
(b) Tf > Ti for reversible process but Tf = Ti for irreversibly process
(c) (Tf)rev > (Tf)irrev
(d) Tf = Ti for both reversible and irreversible processes