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1 AITS-FT-III-PCM (Sol.

)-JEE(Main)/18

FIITJEE JEE(Main)-2018
ANSWERS, HINTS & SOLUTIONS
FULL TEST – III
(Main)

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS


ALL INDIA TEST SERIES

1. D 31. B 61. B
2. B 32. C 62. C
3. A 33. C 63. A
4. B 34. B 64. B
5. C 35. B 65. A
6. D 36. C 66. A
7. C 37. D 67. D
8. D 38. C 68. A
9. D 39. A 69. D
10. D 40. B 70. D
11. C 41. C 71. B
12. C 42. C 72. A
13. D 43. D 73. C
14. C 44. C 74. A
15. B 45. B 75. D
16. B 46. A 76. D
17. A 47. B 77. A
18. D 48. C 78. A
19. D 49. C 79. C
20. D 50. D 80. B
21. B 51. B 81. C
22. A 52. B 82. B
23. D 53. C 83. C
24. B 54. C 84. C
25. B 55. D 85. C
26. B 56. A 86. D
27. C 57. B 87. C
28. D 58. D 88. B
29. D 59. D 89. D
30. A 60. D 90. B

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AITS-FT-III-PCM (Sol.)-JEE(Main)/18 2

Physics PART – I

SECTION – A

1. δR/R = 2δu/u + 2cot2θ δθ

2. If s be their separation at time t then,


s² = (0.4-80t)² + (0.6-60t)²
where t is in hour, s in km. Minimise s using calculus.

3. The horizontal acceleration of Block 1 is always greater than that of block 2.

4. The normal reaction vanishes when the person loses contact with the surface:
mv²/r = mg cos θ;
Conservation of energy gives:
1/2 mv² + mgr cos θ = 1/2 mu² + mgr; where u² = 0.5gr

1 2
5. The droplets fall a distance gt in time t, and the number of the droplets and hence their mass
2
is proportional to dt. Computing the CM of the droplets using the definition, we get the result.

ma2
6. For an equilateral triangle of side a, moment of inertia is about an axis passing through its
12
CM and perpendicular to plane - the result of the integration is similar to that of a solid cone along
its axis: a factor of 3/5.
3  ma2 
I   
5  12 

7. The maximum loss occurs when the


collision is "head-on" and the
minimum is when it collides at an end. 0.5
Assume that the particle strikes the
rod (of length 2L) perpendicularly at a
distance x from its centre. Apply
conservation of momentum and
angular momentum to calculate the 0.4
final velocity of the rod and also its
angular velocity. The fractional loss in
KE = 1/[3(x/L)² + 2]
0.3

0.2
0.1 0.5 0.9

8. We take θ = (10) cos (t); calculate t when  = 5. This gives t = 2/3 (s). The period is 2 times
this.

9. Use Kepler's Law of Periods.

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3 AITS-FT-III-PCM (Sol.)-JEE(Main)/18

10. If m be the mass of water displaced, the buoyant force is mg, while the mass of the extra water
that has to be pushed "out of the way" is effectively m/2.

11. Taking torques about the hinge, we get:


In the 1st case, mgL/2 =p AL/2
In the second case, mgL/4 = p' AL/2

12. When the wheel gets just lifted τ = mg(3r/5). But when a torque of 2τ is applied, we can write:
mg(3r/5) = Iα,
where I = 2mr².
The horizontal acceleration is rα(4/5).

101
13. The final pressure is p  kPa ; kx = pr2 where x = 0.2, the compression in the spring and
2
r = 0.05 the radius of cylinder.

14. With reservoirs at 273 K, 173 K:


W 273  173
  0.37
Q 273
With reservoirs at 373 K, 173 K:
W  373  173
  0.54
Q 373
W  W = (0.54  0.37)Q = 0.17 Q

2w 1
15. T ; f
v T

3 volt
16.  e t/  ;  = RC = 6 s
(3  5)volt
 t  6 s.

3m1m2 T v 1 T 1 m2
17. Tension, T  g; v  ;   (where, m1  2m2)
2(m1  m2 )  v 2 T 3 m2

 2
18. The change in flux  = r B , where r = 0.2 m
2

Average emf =
 / 2
Current = average emf / resistance

V m
19. Using dimensional analysis or otherwise t   some numerical factor
A RT
t  1 1.7
Substituting the values we get   0.6
t 2 1.2

20. Force  25(0.4iˆ  0.4k)


ˆ  2iˆ  20ˆj

21. The correct answer can be determined by dimensional analysis.

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AITS-FT-III-PCM (Sol.)-JEE(Main)/18 4

D
22. = AB = 20 m
2d
where  = 2 m
D = 150 m
 d = 7.5 m

23. From geometry  = (180  2)


d 2d
So, 
dt dt

24. When the switch closes at VC = 2V/3 the capacitor discharges through R2 = 3R
T(discharge) = 3RC n 2 (since the voltage halves).
The charging occurs through R1 + R2 = 9R
T (charge) = 9RCn2
T = 12 RC n 2  8.4 RC

25. When the left end is positive, upper diode conducts and lower diode is cut off.
Req = R
When right end is positive the lower diode conducts.
3R 7R
Req  R  
4 4
( V)2  4  1 ( V)2
 Power = 1     0.8
R  7  2 R

26. The object must be located at the centre of the curvature of the mirror for this to happen.
For the inverted image formed directly by the lens we can write
1 1 1 v 3
  , 
v u 10 u 2

27. This occurs when the angle of incidence is equal to the Brewster angle: tan  = .

 q 2
28. If the sphere has a uniform mass density (total mass m), then  , where L = mR2  .
L 2m 5

 1 1  E0 2n
29. h  En 1  En  E0  2    4 , for large n.
n (n  1)2  n

m1v1  m2 v 2
30. mn 
v 2  v1
14  (4.7  10 6 )  1 (3.3  10 7 )
  1.16
3.3  107  4.7  10 6

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5 AITS-FT-III-PCM (Sol.)-JEE(Main)/18

Chemistry PART – II

SECTION – A

31. 

CaF2  2
 Ca  2F

s 2s
4
2s  2  10
s  104
K sp  4s3  4  10 12

32. d-orbital is 5-fold degenerate in absence of magnetic field.

33. NaCl  i  CRT glu cos e  1 0.1 RT


 2  0.1RT  0.1 RT
= 0.2 RT NaCl  glucose
Tb NaCl  2  0.1K f Tb urea  0.1 K f
Hence Tb urea   Tb NaCl
Tf glu cos e   0.1 K f Tf KCl  2  0.1 K f
Tf  0.2 K f
Tf glu cos e   Tf KCl

34. k  AeEa /R600


Ea 20 

k c  Ae R500
k  kc
Ea Ea  20 

R  600 R  500
Ea Ea  20

6 5
5
Ea  Ea  20
6
5
20  Ea  Ea
6
Ea  20  6
Ea  120 kJ / mol

35. Melting point of ice decreases hence more amount of H2 O    will form on increasing pressure.

36. H  aq.  OH  aq.  H2O   

r H   f HH2 O     f H H aq.   f H OH 


     
57.32  285.84   0   f H OH aq 
    
 f H OH aq  228.52 kJ / mol
  

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AITS-FT-III-PCM (Sol.)-JEE(Main)/18 6

37. 4Fe  10HNO3  4Fe  NO3 2  NH4NO3  3H2O

1 1 2
38. KE 
2
m  v 2   9  10 31  2.2  106
2
 
2
31
1 9  10  2.2  10
KE  
6
 
2 1.6  1019
KE  13.61 eV
PE  2  KE  2  13.61  27.22 eV

40. Mo   No  n  Factor


Mo BaCl2   160  2  320
Mo  K 3PO4   140  3  420
Mo KCl  100  1  100
Mo Ba PO4 2 
 3 Mo BaCl2   2 oMK3PO4   6Mo HCl
 3

 3  320  2  420  6  100


= 1200
K  1000
Mo 
s
1.2  105  1000
s
1200
1 10 5
K sp Ba PO    108 s5
 3 4 2

5
 108  105  
 1.08  10 23

42. [Co(NH3)4(ONO)2]Cl [Co(NH3)4(NO2)2]Cl linkage


NO2 NO2
H3N NH3 H3 N NO 2

Co Cl Co Cl geometrical

H3N NH3 H3 N NH3

NO2 NH3
[Co(NH3)4(ONO)Cl]ONO [Co(NH3)4(ONO)2]Cl ionization.

43. O Cl
p  d 
O Cl
p   d
S p   p p  p p   p  p  d  S p  d 
p   d S p  p S C S O O
O O
O

45. Pb2+ and Hg2+ both will precipitate out by H2S in dil. HCl.

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7 AITS-FT-III-PCM (Sol.)-JEE(Main)/18

46. Oxidising power increases with increase of oxidation number of central atom.
Mn (O.S.) in MnO4  7
Cr (O.S.) in Cr2O72  6
V (O.S.) in VO2  5

47. Na2 S2O3  Cl2  H2O  NaHSO4  HCl

48. Ozone oxidizes alakaline solution of KI.

51. F F
n C C CF 2 CF 2
n
F F Teflon

52. Millon’s test, Biuret test, Ninhydrin test are used for protein.

54. H

18 
18 +
H O
O 

O
H H

18 18
O  O H O

O
H

55. CH2CHO

1
CHO
 H attack
CHO 
1
on 1

1 2 CHO
CH2 CH2 CHO CHO
 H a tta ck
 1   
on 3
2 3
CH2 CHO CHO
 H attack

2
on 2

CHO

56. H H
O OH O
CH3 NO 2

   acidic strength 

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AITS-FT-III-PCM (Sol.)-JEE(Main)/18 8

57. CH3 CH3


 CH 
3 2 NH  H2N N
O2N F  O2N N
CH3 CH3

58. O
POCl3
C NH2   C N  H2 O

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9 AITS-FT-III-PCM (Sol.)-JEE(Main)/18

Mathematics PART – III

SECTION – A

5 9 15 23
61. cot 1  cot 1  cot 1  cot 1  ..... 
3 3 3 3
 2 1   3 2   n 1 n 
        
1 3 3 1 3 3 1 3 3
= tan    tan    .....  .....  tan    .....
 1 2  1   1 3  2   1 n  1  n 
     
 3 3  3 3  3 3 
n 1 1
 Sn  tan1  tan1
3 3
  
lim Sn   
n  2 6 3

62. Clearly tangents at P and Q intersect at right angle. Let S is point of intersection
 P, Q, R, S are cyclic
 S lies on the director circle of hyperbola
 S  a2  b2 cos , a 2  b 2 sin  
 The chord with midpoint (h, k) i.e. circumcentre will be same as equation of the chord of
contact w.r.t. S
xh yk h2 k 2 x a2  b2 cos  y a2  b2 sin 
    and   1 are identical comparing and
a2 b2 a2 b2 a2 b2
2
x2  y 2  x2 y2 
removing Q locus i   
a2  b2  a2 b2 

63. Let O (origin) is circumcentre of ABC and position vectors of A, B, C A


  
and P are a , b , c and p P
  E
     b  c  a  b  c  p H
Hence OH  a  b  c , OD  , OE  O
2 2
   a  p   
DE  OE  OD  , AP  p  a B D C
2
 
  p 2  a 2  
 DE  AP  = 0 since p  a
2

1 3 2 1
x  x  x3 1
64. It is equal to    x  f  x     dx which is less than  dx 
 4  2   4 16
0 0

65. f(x) = anxn + an – 1xn – 1 + an – 2xn – 2 + ..... + a0, [x] = m then f(m) = anmn + an–1mn – 1 + ..... + a0
f(f(m) + 1) = an(f(m) + 1)n + an – 1(f(m) + 1)n – 1 + ..... + a0
kf(m) + an + an – 1 + ..... + a0 = kf(m) + f(1)
f  f  m   1 f 1
Since k = integer
f m  f m 
 m = 1 hence x  [1, 2)

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AITS-FT-III-PCM (Sol.)-JEE(Main)/18 10

66. Total such numbers are (3  2)  (3!) = 36


Sum of all such numbers 66666  18 = 1199988

67. (z + )2 = z  z2 + 2 + z = 0
z 1  3 i 2 4
   arg(z) – arg() = or
 2 3 3

              a2 3
68. p  q  q  r  r  p   q  p    r  p   q  p r  p sin60º 
2

6
69. (x + y + z)6  general term x  y z 
  
 +  +  = 6,   0 then total number of solution = 8C2 – 7 = 21
    
aa ab ac
   2     
70. a b c   b  a b b bc
      
c a c b cc

x z
y
2 
z x
71. 1 +  + 2 = 0 and  y = x3 + y3 + z3 – 3xyz
 2
z  x
y
 2
= (x + y + z)(x + y + z2)(x + y2 + z) = 0
= (x + y + z)((x – y)2 + (y – z)2 + (z – x)2) = 0
 Either x = y = z or x + y + z2 = 0

72. Denominator of all terms equal to  2an1 


2  n  n  1 
Numerator = (2nd + (2n – 2)d + ..... + 2d) = d
2

AL1 L1M1 A
73. 
AB BC
L1 M1
1 LM a M2
  1 1  L1M1 = L2
n 1 a n 1 L3 M3
AL2 L 2M2 2 L 2M2 2a
    L 2M2 
AB BC n 1 a n 1 Mn
Ln
a 2a 3a na an
 The required sum is    .....   B C
n 1 n 1 n 1 n1 2

n  1 1  1 1  1 1 n 1 1 
74. C0     nC1     nC2     .....  nCn  1  
 2 3   3 4   4 5   n  2 n  3 
1 1

 1  x  x dx    C0 x  C1x  C2 x  .....   1 


n n n 2 n 3 n n
Cn x n1 dx
0 0

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11 AITS-FT-III-PCM (Sol.)-JEE(Main)/18

1 1

 1  x  x dx    C0 x  C1x  C2 x  .....   1 


n 2 n 2 n 3 n 4 n n
Cn xn 2 dx
0 0
1 2 1  2  1
=   1  =
n  1n  2  n  2 n  1n  3  n  1n  2   n  3  n  2 n  3 
75. Coefficient of xn in (x + x2 .....)(x2 + x4 + x6 .....)(x3 + x6 + x9+ .....)
= x6(1 – x)–1(1 – x2)–1(1 – x3)–1
 None of the option can satisfy

76. Clearly (5, 15) is the mid point of the chord hence slope of normal to the
20  15 (10, 20)
chord is  1 , slope of chord = –1
10  5 27
Equation of chord (y – 15) = –(x – 5)
 x + y = 20 (5, 15)
 2x + 2y = 40
 p2013 + q2013 = (2)2013 + (2)2013 = 22014

77. Let origin is shifted to (1, 0) after this the equation will be
max{|x|, |y|} = k
Area = 4k2 = 100
k=5

1
 h3 h 5 
 h   .....   h
 tan1 h  h2 1
1  tan h  3 5 1
78.  
lim x 2 n x cot 1 x  lim n   = lim 2   1  lim  3
 
x  h 0
 h  h 0 h
 h  h  0 h 3

cos x  3 cos x  3
79. I 2
dx   2
dx
   
 1  2 sin  x   
1 sin x  3 cos x 
  3 
cosec x cot x  3 cosec 2 x 1
Dividing by sin2 x, we get I   2
dx  c
 cosec x  1  3 cot x  cosec x  1  3 cot x

sin x
= c
 
1  2sin  x  
 3

1 1
80. f x   1   x    x  1
2  x 2  x
1
 f  x  2  1 (A.M.  G.M.)
2
1
 f min = 2  1 which occurs when  x 
2
1 1
 x  n   n , n I
2 2

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AITS-FT-III-PCM (Sol.)-JEE(Main)/18 12

x3  x2  x  1 x4  1 x4 1
81.  dx   dx   x 5  1dx   x  1 dx
5
x 1 x 5

 1  x  1
1
=  n x 5  1  n x  1  c
5

82. Odd power of a skew symmetric matrix is always a skew symmetric matrix

83. F  G = {3, 6}, E  {F  G} = {1, 3, 6, 5, 7}


 P{E  {F  G)} = 0.13 + 0.12 + 0.13 + 0.08 + 0.06 = 0.52

84. Plane containing the line will be given as (4x – 2y – 10) + (5y – 4z + 3) = 0
 4x + (5 – 2)y + 4z + 3 – 10 = 0
The plane passing through (4, 3, 7) will give 
 16 + (5 – 2)y + 4z + 3 – 10 = 0
 –10 = 0   = 0
i.e., 4x – 2y – 10 = 0

1 1
85. Let f(x) = sin4 x – sin x cos x + cos4 x = 1  sin 2x  sin2 2x
2 2
1 2 1
Let sin 2x = t, f(x) = g(t)  g(t) = t  t 1
2 2
 9
Since t  [–1, 1]  f  x   0, 
 8

86. f  x   3  x  x  1 is well defined for x  [–1, 3]


1 1
f x   0 xR
2 3x 2 x 1
31
f(–1) = 2 and 12  4x  1  4x  4 gives x  1 
8
  31  
Hence,  x   1, 1  
  8  

87. n = 1, n + 1 =  ..... etc.


n/P
 P
 1 is P is divisor of n

88. ABC is isosceles and circumcentre of PQR is orthocentre of ABC and lies on a line  to
x – 3y – 31 = 0 passing through (0, 3)
89. Roots of the equation x2 + kx + 2 are irrational since k2 – 8 is not a perfect square as k > 12
a c sinC  sin A
So   3
1 2 sinC  sin A
90. At point of maxima f(x) = 0 and f(x) < 0
 f(x) = x2 – f2(x)  0
Since the curve x2 – y2 = a2 and x2 – f 2(x)  0
x12  y12  a2  Point lies outside hyperbola
Hence, 2 tangents

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