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Calorific value (CV) of a fuel is a characteristic of fuel which is defined as the energy
liberated per kg of fuel burnt. Fuels are found in three phase viz. solid, liquid and gaseous.
Junker's calorimeter is used to measure the CV of gaseous fuels.
Where,
m1 and m2 are the mass of water in the copper calorimeter and water equivalent of bomb
calorimeter respectively.
mf is the mass of fuel sample whose calorific value is to be determined.
T1 and T2 are the final and initial temperature of the water sample. Tc is temperature
correction for radiation losses.
Cw is specific heat of water
Water equivalent of bomb calorimeter can be found out for particular bomb
calorimeter by first by doing an experiment based on known fuel sample whose calorific
value is already known. It depends on the manufacturer of the Bomb calorimeter.
Bomb Calorimeter is used for the measurement of the calorific value of fuel oils, gasoline
or petrol, coke, coal, combustion waste, foodstuffs and building materials etc.
A bomb calorimeter is also used for energy balance study in ecology and study of Nano-
material, ceramics, zeolite. The bomb calorimeter is helpful to study the thermodynamics
of common combustible materials.