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V-shape (Bent) 1
*According to VSEPR, 2lone pair + 2bond pair = bent
(ii) Arrange the H-N-H bond angles in descending order for the three
species: NH2-(g), NH3(g) and NH4+(g). Explain your ordering.
– NH2- has lp-lp repulsion, NH3 has lp-bp repulsion, NH4+ has
bp-bp repulsion only ½
– As lp-lp repulsion > lp-bp > bp-bp ½
– greater repulsion = smaller H-N-H bond angles ½
– ∴ NH4+ >NH3 > NH2- ½
(iii) Excess NH3(g) reacts with Cl2(g) in two steps to give N2(g) and
NH4Cl(s). It is known that NH3(g) functions as a reducing agent and as
a base in the reaction. For each step, write the chemical equation and
state the function of NH3(g).
*This question is a bit difficult, esp. when you are nervous during
exam, just try your best.
(7 marks)
2008-AL-CHEM 1-1 1
1. (b) Both nickel(II) bromide and cobalt(II) bromide react with triethylphosphate,
PEt2 (Et represents C2H5), forming metal complexes with the general
formula M(PEt2)2Br2; where M is either Ni or Co.
(i) The nickel complex can occur in two forms, one of which has a net
dipole moment whereas the other does not. The cobalt complex,
however, occurs in only one form.
Information:
1. The complex’s formula is ML4 (L = ligand), therefore, it must be
sq. planar for d8
2. Nickel occurs in 2 forms (1 with net dipole moment)
3. Cobalt only occurs in 1 form
_______________________________________________________
– Trans-sq. planar complex can cancel out dipole moment of Br ½
→ no net dipole moment
– Cis- sq.planar complex is not symmetrical ½
→has dipole moment
– d7 doesn’t favor the formation of sq.planar complex ½
→ tetrahedral only ½
(ii) Will the cobalt complex have a net dipole moment? Explain.
– Yes ½
– the dipole moment cannot cancel out in tetrahedral complex ½
2008-AL-CHEM 1-2 2
2. (a) Three reagent bottles each containing 0.5 M KI(aq), 14 M HNO3(aq) and 0.02
M KMnO4(aq) have been kept in the laboratory for a long time. The table
below lists the observation for each of the bottles.
Solution Observation
0.5 M KI(aq) The liquid is pale yellow.
14 M HNO3(aq) There are brown fumes above the yellow
liquid.
0.02 M KMnO4(aq) There are brown stains on the interior wall of
the bottle.
In each case, account for the observation and write the relevant chemical
equation(s).
0.5 M KI(aq)
0.02 M KMnO4(aq)
(6 marks)
2008-AL-CHEM 1-3 3
2. (b) The diagram below shows the design of a hydrogen-oxygen fuel cell:
(ii) One advantage of using hydrogen-oxygen fuel cells is that they do not
emit air pollutants. Suggest ONE other advantage of using
hydrogen-oxygen fuel cells.
(4 marks)
2008-AL-CHEM 1-4 4
3. (a) Answer the following multiple-choice questions.
(i) Which one of the following ions is most ready to donate electrons?
A. Al3+
B. Fe2+
C. Cu2+
D. Zn2+
Answer: B
(ii) Which one of the following molecules has a zero dipole moment?
A. BF3
B. PH3
C. SO2
D. HCl
Answer: A
(iii) Which one of the following graphs represents the distribution of
molecular speeds of one mole of a gas at two different temperatures
T1 and T2, where T2 > T1?
A. B.
C. D.
Answer: C
Explanation: (i) Have you ever heard about Al , Cu or Zn3+? ☺
4+ 3+
(ii)
(iii) maxwell’s distribution, T2 must be flatter + higher average
molecular speed, both are from the origin (there must be molecules
with speed = 0)
(iv) by definition
2008-AL-CHEM 1-5 5
3. (a) (iv) Which one of the following equations represents the change
corresponding to the standard enthalpy change of atomization of
iodine?
A. ½ I2(s)→ I(g)
B. I2(l) → 2 I(g)
C. I2(s) → 2 I(g)
D. I2(g) → 2 I(g)
Answer: A
(4 marks)
(b) Account for the following observations:
(i) The boiling point of magnesium bromide is lower than that of sodium
bromide.
*straightforward question
(4 marks)
2008-AL-CHEM 1-6 6
4. (a) Identify A, B, D, E, F and G in the following reactions:
(i)
A: 1
(ii)
B: 1
(iii)
D: 1
(iv)
E: 1
(v)
F: HCN 1 G: 1
(6 marks)
2008-AL-CHEM 1-7 7
4. (b) Consider the substitution reaction shown below:
***
Propagation
***
***
Termination
***
(5 marks)
2008-AL-CHEM 1-8 8
5. (a) Arrange the following compounds in order of increasing acidity. Explain
your ordering.
(i) Both reactions are of the same type. Name the type of reaction.
(ii) Suggest why reaction (2) gives a mixture of organic products while
reaction (1) gives only one monosubstitution product.
2008-AL-CHEM 1-9 9
5. (c) Answer the following multiple-choice questions.
(i) Which one of the following compounds is most reactive towards Br2?
A. B.
C. D.
Answer: B
(ii) Which one of the following compounds is most reactive towards
substitution with NaOH(aq)?
A. B. CH3(CH2)3Br
C. D.
Answer: A
(iii) Which one of the following compounds is most reactive towards
substitution with Cl2?
A. B.
C. CH3CH2CH2CH3 D.
Answer: B
(3 marks)
2008-AL-CHEM 1-10 10
6. Read the passage below and answer the questions that follow:
Silicates and aluminosllicates
Silicates occur in a wide variety of structures. Orthosilicates contain discrete
tetrahedral SiO42- anions with O atoms at the corners. Other silicates can be
considered as formed from the tetrahedral by sharing oxygen atoms, e.g.
disilicates contain Si2O76- ions and cyclic silicates contain (SiO2)n2n+ ions, where n
is an integer greater than 2. Polymers of silicates also exist including
one-dimensional chain silicates, two-dimensional sheet silicates and
three-dimensional network silicates.
(a) Suggest TWO reasons for the occurrence of silicates in a wide variety of structures.
ANY TWO, each 1
– Si-O bond is exceptionally strong
– SiO4 tetrahedra similar to diamond structure → stable
– Silicates adopt giant covalent tetrahedral network → stable
(2 marks)
2008-AL-CHEM 1-11 11
6. (b) Some liquid detergents contain sodium orthosilicate, Na4SiO4, to maintain a
moderately high pH.
(i) Suggest why detergents need to have a moderately high pH.
Represent SiO44- =
Si2O76- = 1 (SiO3)612- = 1
4-
*Remember to mention SiO4 = the triangle
(2 marks)
(d) Suggest why sodium zeolite A can function as a molecular sieve.
Size and distribution of negative charge are suitable for these ions 1
(ii) Suggest ONE way to regenerate exhausted sodium zeolite A.
2008-AL-CHEM 1-12 12
SECTION B
Answer ALL questions. Write your answers in the spaces provided.
7. (a) The diagram below shows the essential components of an instrument for
studying the kinetics of the reaction:
Colorimeter 1
(ii) What physical parameter of the reaction mixture is measured by this
instrument?
OR
naming x y axis ½ suitable shape ½
(3 marks)
-
(b) (i) Hydride ion, H , is a strong Bronsted base. Write the chemical
equation for the reaction of H- with water.
2008-AL-CHEM 1-13 13
7. (b) (ii) Suggest why the following hazard warning labels should be displayed
on a bottle of LiAlH4(s).
(4 marks)
2008-AL-CHEM 1-14 14
8. (a) Super glue works as an adhesive by addition polymerization as shown below:
(ii) The experiments were carried out to study the effects of NaOH(aq)
and H2O(l) on the polymerization. The conditions of the experiments
were the same except that one was conducted in the presence of
NaOH(aq) and the other in the presence of H2O(l). Figure 8.2 shows
the change of temperature of the two reaction mixtures with time.
2008-AL-CHEM 1-15 15
(b) Propenamide, the monomer of polypropenamide (also known as
polyacrylamide) is a potential carcinogen. The melting point of
propenamide is 84C and its solubility in water is 2.16gcm-3 at 30C.
2,3-dibromopropanamide ½
+ Br2 → ½
(iii) Suggest an instrumental method for the further characterization of the
derivative suggested in (ii). State clearly the expected results.
– Mass Spectroscopy ½
– Isotopic abundance of 79Br : 81Br = 1:1 ½
– Relative intensity of e/m M:M+2:M+4 = 1:2:1 ½
– Name a few other peaks ½
(M=molecular mass)
(5 marks)
END OF SECTION B
2008-AL-CHEM 1-16 16
SECTION C
Answer ONE question only, and write your answer in the AL(D) Answer Book.
The examiners are looking for the ability to analyse, to evaluate and to express ideas.
10. Write an essay on the application of the principle of green chemistry in industry.
(20 marks)
* everyone writes 12 principles + 2 applications in Q.10
if you are familiar with green chem. + only wants C-E grades, choose Q.10
if you aim higher grades + not bad in chlorine, better choose Q.9 as it is easier to
show how extraordinary you are
END OF PAPER
2008-AL-CHEM 1-17 17