The bainite transformation is intermediate between pearlite and martensite transformations.
The kinetics of this transformation and the structures formed exhibit features of both diffusive pearlite transformation and diffusionless martensite transformation. A mixture of the a-phase (ferrite) and carbide is formed as a result of the bainite transformation. The mixture is called bainite. The bainite transformation mechanism involves g ! a rearrangement of the lattice, redistribution of carbon, and precipitation of carbide. Most researchers are of the opinion that ferrite precipitates from austenite by the martensitic mechanism. This is attested to by the presence of retained austenite in alloyed steels, a similarity in the structure of lower bainite and martensite, and the resemblance of upper bainite to low-carbon martensite. Closeness of the bainite transformation to its pearlite and martensite counterparts can be explained as follows. The diffusive movement of atoms of the basic component, iron, is almost completely suppressed over the bainite transformation range. Then the g ! a formation of ferrite is difficult because pearlite precipitation is suppressed. However, carbon diffusion is rather active and causes precipitation of carbides. Over the intermediate range the g-phase crystals are formed through coherent growth similarly to martensite plates. But the a-phase plates are formed slowly rather than instantaneously. This is due to the fact that over the intermediate temperature range the a-phase can precipitate only from the carbon-depleted g-phase. Thus the growth rate of the a-phase crystals depends on the carbon diffusive removal rate. In this case, the martensite start point Ms in austenite rises and the martensite g ! a transformation takes place at temperatures above the temperature Ms typical of the steel with a given composition. At the instant of martensite transformation the carbon concentration remains unchanged. Only the crystal lattice is altered and a supersaturated a solution is formed. Carbide precipitates after g ! a transformation. 3.3.7 MORPHOLOGY OF THE BAINITE TRANSFORMATION A distinction is drawn between upper and lower bainite, which are formed in the upper and lower parts of the intermediate temperature range. The conventional boundary between the bainites is close to 3508C (6608F). Upper bainite has a feathery structure, whereas lower bainite exhibits an acicular morphology, which is close to that of martensite. The difference in the structures of upper and lower bainites is attributed to a different mobility of carbon in the upper and lower parts of the bainite temperature range. An electron microscopic analysis showed that the a-phase substructure of upper bainite resembles the substructure of massive martensite in low-carbon steels, while the a-phase structure of lower bainite approximates the structure of martensite in high-carbon steels. In upper bainite, carbide particles can precipitate both at lath boundaries and inside laths. This fact suggests that here carbides precipitate directly from austenite. In lower bainite, carbide is found inside the a-phase. This means that carbide is formed during precipitation of a supersaturated solid solution of carbon in the a-phase. Both upper and lower bainites exhibit a high density of dislocations inside the a-phase. Cementite is the carbide phase in upper bainite, and e-carbide in lower bainite. As the holding time is increased, e-carbide turns into cementite. The austenite grain dimensions have no effect on the martensite transformation kinetics.