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WINKLER’S METHOD
Aim:
Principle:
+ +
In alkaline medium, dissolved oxygen oxides to . In acidic medium, it oxides
Iodide ion to free Iodine. The amount of iodine released which can be titrated with a
standard solution of is equivalent to the dissolved oxygen.
+ −
+ + → (Brown precipitate)
+ − +
+ + → + +
− − −
+ → +
Apparatus Required:
Reagents Required:
Conc. ,� ,� , , Starch
Procedure:
Standardisation of thiosulphate
Starch
Calculation:
Volume of solution (� )
Normality of solution ( )
As we know that, � =�
Therefore, =� /�
= ……..………………… �/
Determination of DO
Result