Sie sind auf Seite 1von 15

Corros Rev 2015; aop

Original article

K. Sadananda and A.K. Vasudevan*

Crack growth behavior of 4340 steel under


corrosion and corrosion fatigue conditions
DOI 10.1515/corrrev-2015-0034 studies have been focused on one or the other aspect of the
Received November 17, 2014; accepted July 26, 2015 material behavior. In this paper, we will examine (a) the
material response in the light of two-parameter approach
developed by the authors for fatigue crack growth, (b)
Abstract: Crack initiation and growth behavior in 4340 the application of the failure diagrams that focus on the
steel under static and cyclic loads in various environ- propagating and nonpropagating conditions, (c) the role
ments are examined using the two-parameter approach of internal stresses that are either in situ generated and/
developed by the authors. It is shown that environmental or provided by preexisting stress concentrations, (d) the
effects can be time dependent, stress dependent, or both, interplay of the mechanical and chemical driving forces
depending on the amplitude, peak stress, and aggressive- causing the crack growth, and finally (e) their limiting
ness of the environment. It is shown that the tests under roles under given loading conditions. The purpose of the
vacuum are required to establish the reference state for analysis is essentially to focus on the extent of our current
the quantification of the chemical driving forces involved understanding, identifying where additional data are
in crack initiation and growth in aggressive environments. required for developing predictive relations for service
Failure diagrams are proposed by extending the Kitagawa- loads and environments.
Takahashi diagram for fatigue. It is shown that these can
be used to quantify the mechanical and chemical internal
stresses required to cause both initiation and growth of an
incipient crack in a smooth as well as notched specimens.
2 Materials and methods
Conditions for propagating and nonpropagating incipient
cracks that are initiated under stress concentrations are 2.1 Background
also discussed, taking the example of the 4340 steel data
available. AISI 4340 steel is a nominally 1.8% nickel-chromium-
molybdenum low-alloy steel of high hardenability, with
Keywords: 4340 steel; crack initiation and propagation; high strength and toughness in relatively large sections,
Kitagawa diagram; mechanical and chemical internal achieved with a quench-and-temper heat treatment. Its
stresses; notch stress concentration; two driving force typical composition is as follows (in weight percent):
parameter. C = 0.34–0.44, Si = 0.1–0.35, Mn = 0.55–0.9, P  ≤  0.4, S  ≤  0.4,
Cr = 0.65–0.95, Mo = 0.2–0.35, Ni = 1.55–2.0, and the balance
Fe. There are equivalent British and Japanese steels

1 Introduction within the composition range. The alloy strength varies


from 930 to 1400 MPa depending on the heat treatment.
In general, its ductility and the environmental suscep-
The 4340 steel is the typical steel used in service, which
tibility inversely vary with its strength. Its applications
has been extensively evaluated in the past. Available
include high-strength heavy-duty shafts, aircraft landing
data in the literature are extensive, although most of the
and power transmission gears, axles, spindles, couplings,
pins, etc. Although temper embrittlement due to the seg-
*Corresponding author: A.K. Vasudevan, Technical Data Analysis
regation of S and P can occur depending on the heat treat-
Inc., 3190 Fairview Park, Falls Church, VA 22043, USA,
e-mail: akruva@gmail.com
ment, its susceptibility to hydrogen embrittlement is also
K. Sadananda: Technical Data Analysis Inc., 3190 Fairview Park, well documented. Studies have been made using smooth,
Falls Church, VA 22043, USA notched, and precracked specimens under different loads

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
2      K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel

and external environments, as well as under precharged the kinetics of any other superimposed crack nucleation
conditions (Gangloff, 2003; Gangloff & Wei, 1977; Page & and growth process, such as fatigue. The environmental
Gerberich, 1982). In this paper, we only examine the rel- contributions can be only quantified in terms reduction
evant data from the literature that can help us in under- in the material resistance, taking into consideration inert
standing the generic material response under significant environment as reference. Hence, any lack of material
environmental and mechanical loading conditions. data in an inert environment will hinder the proper quan-
tification of the environmental effects on the nucleation
and growth of a crack. Unfortunately, there are not much
2.2 E nvironmentally assisted crack of data available for different materials in inert environ-
­nucleation and growth ment to help us in understanding and quantifying the role
of environments in accentuating the crack initiation and
Figure  1 shows schematically the crack nucleation and growth.
growth in smooth, notched, or precracked specimen. Given that crack is a high-energy defect, its nuclea-
Environment can accelerate crack nucleation and growth tion and growth require stress concentration. Hence, in
process for a given applied stress, or reduce the stress smooth specimen, localized heterogeneous deformations
necessary for nucleation and growth for a given time. enhance the local buildup of internal stresses, which
Although the required stress that cause nucleation and/ help in the nucleation, and growth of the crack. Inter-
or crack growth decreases with increasing concentration nal stresses are normally generated via dislocations,
and/or time, there is threshold stress or minimum stress and hence material microstructure and flow properties
below which no further reduction occurs. This is similar become important considerations in failure process. The
to endurance limit under fatigue. For a cracked speci- presence of grain boundaries and interfaces provides the
men, this is called the threshold stress intensity factor, low-energy paths for both nucleation and propagation of
KISCC, which depends on material-environment conditions. cracks, as well as for the environmental accentuation of
In essence, stress is the primary factor in contributing to the damage. Hence, associated fractographic information
crack nucleation and growth, and environment enters would help in understanding the mechanisms involved.
through reduction in the material resistance. The reduc- In the following, we examine the crack nucleation and
tion depends on the specifics of the localized material- growth kinetics in smooth, notched, and precracked spec-
environmental reactions and their kinetics in relation to imens of 4340 steel to understand the material behavior,
particularly in aqueous environments.
Figure  2A shows schematically the typical material
Crack initiation to growth behavior of environmentally sensitive materials under
cyclic loads, as depicted earlier by McEvily and Wei (1972).
There are three distinct limiting thresholds, ΔK threshold
for fatigue, KISCC threshold under static loads, and KIC for
fracture toughness for overload fracture. Here K stands
for linear elastic stress intensity factor. Type A behavior
(Figure 2A) shows that environment accelerates fatigue
crack growth even when the applied stresses are below
Smooth Notch Fracture mechanics KISCC. Here the environmental contribution to fatigue
Crack growth
depends predominantly on the time of exposure of the
σf
Stage III crack tip to the environment. It is obvious that the process
con1 Failure
Initiation
that contributes to this superimposed environmental
Stage II
effect should be different from that which contributes to
da/dt

σapl
Plateau
σth KISCC. That process does not seem to be available during
Stage I
KISCC static or stress corrosion crack growth. Hence, this process
Time
Kapl accentuates only the crack growth under cyclic loads
but by itself does not independently contribute to crack
Figure 1: Schematic illustration of crack initiation to growth and
growth. As the crack growth rate due to fatigue process
failure of a crack in a smooth-notched-cracked specimen. σth is the
threshold stress for smooth specimen, and KISCC is the threshold
increases with stress, this environmental contribution
stress for a fracture mechanics specimen. Notch specimen falls decreases because the exposure time for a unit increment
between these two limiting conditions. of crack length decreases. Thus, we have an interplay of

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel      3

A (a) Type-A (b) Type-B (c) Type-C

Predominantly a Predominantly a Time + Stress


time dependent stress dependent dependent
process process processes
da/dN

nm ive
t
en
ro s
v i es
en ggr
A

Kmax → KIC

Kmax → KIC

Kmax → KIC
rt
Ine

Kmax → KISCC

Kmax → KISCC
KISCC

Threshold Kmax,th KIC > KISCC KISCC KIC > KISCC KISCC KIC > KISCC

Kmax

B
Frequency Frequency
Cycle
dependent
da/dN

(a) ∆K Kmax

Frequency
Frequency
Time
dependent
da/dt

(b) ∆K Kmax

Figure 2: (A) Schematic representations of inert and environmental effects on fatigue crack growth showing early classification due to
McEvily and Wei (1972). (B) Representation of frequency effects in cycle and time-dependent processes in terms ΔK and Kmax.

cycle-dependent process due to fatigue and time-depend- crack growth contribution due to static load is zero as
ent process due to crack tip chemical driving forces. In the applied stress intensities are below KISCC. The type B
the following, we use the terms chemical driving force behavior shown in the figure involves contribution from
and chemical stress somewhat interchangeably, although fatigue and stress corrosion crack growth, and the linear
it is the stress that is computed and is represented in all summation of the two can be applicable only in this case,
figures. The time-dependent accentuation of crack growth if there is no synergism between the two. The contribution
due to environment should itself depend on frequency from the stress corrosion becomes important only when
of testing, as increasing frequency reduces the time of the Kmax at the crack tip exceed KISCC. This stress-dependent
exposure to environment and crack growth moves toward contribution increases with the increase in stress although
a cycle-dependent process. By contrast, decreasing fre- the time of exposure of crack tip decreases with increasing
quency increases the time of exposure of the crack tip to crack growth rate. Hence, this environmental contribution
the aggressive environment, enhancing the environmen- is more of a stress-dependent process than a time-depend-
tally induced time-dependent process. The type A behav- ent process. There may be additional synergetic effects as
ior cannot be computed by linear summation rule because a function of R ratio and frequency. For example, KISCC

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
4      K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel

itself can be reduced at high frequencies and R ratios for pure fatigue condition, ΔK = Kmax. In the 3-D plot, one
because of the ripple-load effects that were found earlier can make cuts at constant da/dN and represent the data
(Pao, Bayles, & Yoder, 1991) in some structural steels. The in terms of ΔK and Kmax for different da/dN values starting
type C behavior in the figure is a combination of types A from da/dN = 0, which represents the threshold condition.
and B, and hence the linear summation rule does not work Thus, we have to recognize that fatigue threshold is not a
fully for this case. single value but a curve involving two parameters with the
The simplest way to find out if the crack growth limiting thresholds ∆Kth∗ and ∆K max,th

. The crack growth
process is time or cycle dependent is to represent the trajectory is defined by the variation of these two limiting
data in terms of both da/dN vs. ΔK, and da/dN or da/dt values with crack growth rate (Figure 3C). The pure fatigue
vs. Kmax, for a given R ratio, but at different frequencies. process is designated by the 45° line in this plot. Any
If the process is purely cycle dependent, the data should deviation from this line represents a superimposed Kmax-
collapse on da/dN vs. ΔK plot because crack growth is dependent process. In the environmentally accelerated
predominately frequency independent. If the process is process, the deviation from this 45° line represents the
purely time dependent, then the collapse occurs in da/dt environmental contribution. To develop the crack growth
vs. Kmax plot, see Figure 2B. If both are present as in the trajectory maps, the tests have to be done for a range of
case of type C, then such collapse does not occur or occurs R ratios that scan the material behavior in the full range
in a limited range where one or the other process is domi- of ΔK and Kmax values. For expediency, at least two tests,
nant. We will use this procedure in analyzing the crack one at low R ratio and the other at high R ratio, have to be
growth data in 4340 steel. evaluated.
It should be recognized that when crack growth rate
(da/dN or da/dt) is represented in terms of Kmax and ΔK, we
2.2.1 Two-parametric approach for fatigue
are only accounting the crack growth in terms of mechani-
cal crack tip driving forces. The contribution from environ-
Unlike the static case (such as stress corrosion), cyclic
ment enters through chemical potential gradients, which
loads involve two load parameters for unambiguous
cannot be quantified directly. Hence, to evaluate these
(Sadananda & Vasudevan, 2004). They involve cyclic
contributions, it is important to have crack growth rate
amplitude and mean or maximum stress. Hence, ideally,
data in an inert state as a reference. For the same crack
fatigue crack growth needs to be represented in a 3-D plot
growth rate, it is then possible to measure the changes in
(Figure 3), involving da/dN vs. ΔK and Kmax with the rec-
the mechanical driving forces due to contribution from
ognition that one cannot have ΔK without Kmax. Hence,
Chemical forces. Unfortunately, crack growth rate data in
vacuum or inert environment for many materials including
Alloy 4340 are not available. In Figure 3C, trajectory path,
B Kmax,th*
the 45° line, provides some reference in which a measure
A da/dN ry of the environmental contribution can be estimated,
to
<0 jec although actual data would help in computing correctly
R >0 Tra
R
da/dN4 the contribution to each of the two parameters, Kmax and
∆K

4
2
3 ΔK. The reason is environment can affect both ΔK and Kmax
1 parameters, although the effect on Kmax is more dominant
Threshold ∆Kth*
in general. Here the chemical forces help in the reduction
Kmax
Km
ax of Kmax component required for crack growth, which can
∆K C be quantified using the trajectory map. However, the lack
Θ=45°
R=
R=0
c
pla ons of inert or vacuum data required to establish the reference
ax *

ne t
would prevent the quantification of the environmental
m
K
∆K*

Fatigue requires two


*=

th
row
∆K

load parameters ck g contributions to crack growth for life prediction. For mate-
Cra jectory
tra
3-D representation rials that are extremely environmentally sensitive, ultra-
Kmax* high vacuums are required to establish the reference inert
material behavior. With this background, we examine the
Figure 3: (A) Three-dimensional representation of fatigue crack
crack growth behavior in AISI 4340 steel reported in the
growth in terms of two parameters ΔK and Kmax. (B) Two-dimensional
representation by taking cuts at various da/dN. (C) Crack growth
literature.
trajectory map showing the variation of the two limiting values of ΔK There is also a question of how to quantify the envi-
and Kmax vary with increasing crack growth rate. ronmental effects during fatigue crack growth. For

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel      5

example, which is the independent variable and which A 10-4


is the dependent variable? In simple terms, should one 4340 steel
express the changes in crack growth rates for a given 10-5 Newman et al.
applied mechanical forces or changes in the crack tip 10-6
air

driving forces for a given crack growth rates as depicted in

da/dN (m/cycle)
the trajectory maps? It appears to be convenient to define 10-7
and quantify the changes in the crack growth rates for
10-8
a given ΔK or Kmax, as has been done by many investiga- R=0.1
R=0.4
tors in the past. The problem becomes complicated if one 10-9 R=0.7
recognizes, as has been done in our analyses, that fatigue R=0.8
R=0.9
involves two load parameters, and the effect of environ- 10-10
R=0.95
ment differs in each. Hence, it is convenient to define the
10-11
environmental contribution in terms of the changes in the 1 10 100
∆K (MPa (m)0.5)
crack tip driving forces needed to cause the same crack
growth rate, using the inert environment as reference B 10-4
stated (Figure 3C). 4340 steel
10-5 Newman et al.
air
10-6

3 C
 rack growth under fatigue
da/dN (m/cycle)

10-7

in AISI 4340 steel 10-8 R=0.1


R=0.4
10-9 R=0.7
Figure 4 shows the fatigue crack growth of AISI 4340 steel R=0.8
in ambient air. The data were collected from Newman, 10-10 R=0.9
R=0.95
Vizzini, and Yamada (2010). Following the conventional
10-11
procedure, data are represented in terms of ΔK for differ- 1 10 100 1000

ent R ratios (Figure 4A). If crack growth is purely cycle Kmax (MPa (m)0.5)

dependent, crack growth rates per cycle, da/dN, for dif-


Figure 4: (A) Fatigue crack growth (da/dN) vs. ΔK, in ambient air,
ferent R ratios tend to crowd together when represented for different R ratios. The data were collected from Newman et al.
in terms of ΔK but spread out when represented in terms (2010). (B) Same data in panel a, but represented in terms of Kmax.
of Kmax. By contrast, if crack growth is time dependent, In comparison with Figure 3A, the data are spread out more in terms
crowding occurs in terms of Kmax and not in terms of ΔK of Kmax.
because Kmax is more sensitive than ΔK to a time-depend-
ent process. If crack growth involves both processes, then
data spread out in terms of both ΔK and Kmax. One can plot da/dt instead of da/dN; however, because
Examining Figure 4A indicates that da/dN fatigue all tests were done at the same frequency, the results
data seem to spread out more in the threshold regime will remain the same. To evaluate the material behavior,
and seem to converge with increasing crack growth rate ΔK-Kmax values were generated for different crack growth
around Paris regime and spreads out again in the overload rates using the raw data from Figure 4A from which the
fracture regime. It was shown before (Vasudevan, Sadan- limiting values ΔK* and Kmax∗
are determined for various
anda, & Holtz, 2005) that under inert environments, crack crack growth rates, and these limiting values are plotted
growth rate data as function of R ratio collapse essentially as trajectory map in Figure 5. Each point along the line in
into one curve with no noticeable R ratio effects. The the trajectory map represents a crack growth rate. Hence,
absence of R ratio effects in inert environments (ultrahigh the increasing ∆K ∗ -Kmax

values represent the changing
vacuums for reactive metals) happens only when crack crack tip driving forces required to force increasing crack
growth is purely cycle dependent. In such cases, the crack growth rate. Because of the 2-D nature of the plot, the crack
growth trajectory follows the 45° line in Figure 3C. The growth rate could not be represented in the figure. The
deviation from the 45° line, therefore, becomes a measure 45° line represents the behavior when ∆K ∗ = Kmax∗
, which
of environmental contribution. is pure fatigue behavior. Figure 5 shows the deviation in
Figure 4B shows the same da/dN data in terms of Kmax the crack growth behavior of 4340 steel in ambient air. The
showing large spread in the data in terms of the variable. curve deviates more at low crack growth rates and slightly

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
6      K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel

14 distilled water, and NaCl salt solution at ambient air (Weng,


4340 steel Zhang, Kalnaus, Feng, & Jiang, 2013). Crack growth data
12 Crack growth trajectory map
A
are presented in terms of both da/dN vs. ΔK and da/dt vs.
10
Kmax. The material behavior changes with the environment,
B with frequency and R ratio. Figure 6A, for example, shows
∆Kth* (MPa(m)0.5)

Pure fatigue line


8 that the data converge at high R ratios in the Paris regime
C
while they are spread out at low. The behavior is similar
6
to that observed in Figure 4A. In distilled water (Figure 6B
4
and C), the behavior is distinctly different. On the basis of
da/dt-Kmax, the behavior is more similar to stress corrosion
2 test, particularly at high R ratios. At low R ratios and low
ΔK values, there is deviation more resembling the type A
0
0 4 8 12 16 behavior in Figure 2A. This becomes even more prominent
Kmax,th* (MPa(m)0.5) in the NaCl environment as can be seen in Figure 6D and
E. The behavior is approaching that of type C (Figure 2),
Figure 5: Crack growth trajectory path in relation to pure fatigue where both time dependent (Type a) and stress dependent
trajectory. If A and B are equivalent crack growth rates in inert and
(Type b) are being superimposed on fatigue crack growth.
air environments, AB represents changes in the crack tip driving
force, with AC and CB components corresponding to changes in ΔK The representative trajectory maps cannot be drawn due
and Kmax components. to limited data in terms of R ratio. It is obvious that life
prediction under such environment and loading condi-
tions cannot be done using simple rule of mixtures. The
moves toward the inert line. With the increasing crack best bet is to use the crack growth rate data relevant to
growth rate, it essentially remains with constant shift for that particular environment for service applications in
the remaining crack growth rates. Although the deviation those environments, recognizing that changing the envi-
from the pure fatigue line provides a measure of environ- ronment can change the material behavior.
mental contribution, the exact contribution requires the
relevant trajectory data for the inert environment. Figure 5,
for example, provides a hypothetical case that assumes
such data are available. If points A and B are equivalent 4 Crack initiation to propagation
crack growth rates in inert and aggressive environments,
respectively, then vector AB designates the change in the The previous analysis pertains to the growth of preexisting
applied stresses to enforce the same crack growth rates. crack using linear elastic fracture mechanics methods. In
The vector AB can be split into AC and CB, where CB is a smooth specimen or even in a notched specimen, crack
perpendicular to the ∆K ∗ = K max

line. AC and CB thus rep- needs to be initiated before it propagates. It was shown
resent the environmental contributions to ΔK* and Kmax ∗
that for the analysis of both initiation and propagation
components, respectively, to accomplish the same crack phases of a crack as well as for the quantification of the
growth rate. These complexities are inherent in the fatigue nonpropagating conditions of initiated cracks, the failure
crack growth because the tests can be done at constant ΔK diagrams are useful. These are developed by extending
or constant Kmax or at constant R, and environmental con- the original Kitagawa-Takahashi diagram (Kitagawa &
tributions for each test can be different. Unfortunately, the Takahashi, 1976) for fatigue crack growth. A schematic
crack growth data of 4340 steels for different R ratios in illustration of the failure diagram is shown in Figure 7. In
inert environment are not available. It is important to do this diagram, a horizontal line with an endurance limit of a
such tests for the quantification of environmental contri- smooth specimen Δσe as the limiting value is connected to
bution. The assumption that all R ratio effects are due to the fracture mechanics threshold value ΔKth. In this case,
crack closure only misrepresents the problem and contrib- both values correspond to the same R ratio. The horizontal
utes to errors in the correct quantification of the material line and the crack growth line intersect at crack length ac.
behavior. The trajectory maps, however, provide a measure Kitagawa-Takahashi showed experimentally that for crack
of how the two driving forces for fatigue crack growth lengths less than ac, the endurance limit remains the same.
change due to the presence of environment. The diagram has been interpreted by considering that the
Figure  6A–E provides the crack growth behavior of threshold stress decreases for crack lengths less than ac,
the alloy at two different frequencies and R ratios in air, merging with the smooth specimen endurance value when

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel      7

A 10-3 B 10-3
4340 steel 4340 Steel
Cycle-dependent
air regime Distilled water
10-4 10-4

da/dN, mm/cycle
da/dN, mm/cycle

10-5 10-5
R=0.1, 10 Hz R=0.1, 10 Hz
R=0.5, 10 Hz
R=0.25, 10 Hz
-6 -6 R=0.1, 20 Hz
10 R=0.5, 10 Hz 10
R=0.5, 20 Hz
R=0.1, 20 Hz

10-7 10-7
2 4 6 8 10 30 50 1 10 100
∆K (MPa (m)0.5) ∆K (MPa (m)0.5)

C 10-2 D 10-3

4340 Steel 4340 Steel


NaCl Environment
Distilled water
10-3 10-4
da/dN, mm/cycle

da/dN, mm/cycle

10-4 10-5
R=0.1, 10 Hz

R=0.5, 10 Hz R=0.1, 10 Hz
10-5 10-6
R= 0.1, 20 Hz R=0.5, 10 Hz

R=0.5, 20 Hz

-6
10 10-7
1 10 100 1 10 100
0.5
Kmax (MPa (m) ) ∆K (MPa (m)0.5)

E 10-2
4340 Steel
NaCl Environment

10-3
da/dN, mm/s

10-4

R=0.1, 10 Hz

R=0.5, 10 Hz
10-5

10-6
1 10 100
Kmax (MPa (m)0.5)

Figure 6: (A) Crack growth rate in air at three R ratios and two frequencies. The data merge at higher crack growth rates. (B) Crack growth
rate in distilled water at two R ratios and two frequencies. (C) The data from panel b is replotted in terms of (da/dt) as a function of Kmax. The
data collapses, indicating the predominately the time-dependent crack growth. (D) Crack growth data in NaCl environment as a function of
ΔK. (E) The crack growth data in panel d is replotted in terms of (da/dt) vs. Kmax. At higher Kmax, the data merge indicative of time-dependent
process.

the crack length goes to zero (Tanaka, Nakai, & Yamashita, By considering that fatigue is a two-load parameter
1981). Under this scenario, the specimen endurance and problem, we have shown that (a) the crack growth behav-
the thresholds for long crack growth depend on R ratio, ior of long crack is a fundamental material property for
thereby resulting in a separate diagram for each R ratio, as a given environment; (b) there are two limiting thresh-
shown by Usami and Shida (1979). olds, ΔKth and Kmax,th; and (c) Kmax,th ≥ ΔKth. Hence, the

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
8      K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel

Original Kitagawa-Takahashi the internal stresses that need to be generated by cyclic


diagram
plasticity to augment applied stresses for crack initiation
ac and propagation. For example, for smooth specimen,
Experimental they represent the dislocation processes that generate the
∆σe data and curve
intrusions and extrusion and thus local stress concentra-
∆σ =∆Kth/{y(TTa)0.5} tions where crack can initiate. Endurance limit then is the
minimum stress below which the cyclic plasticity will not
Log (∆σ)

Endurance
be sufficient to generate the required internal stresses for
Non-propagating
crack nucleation or for a preexisting crack to propagate

∆σ
cracks ∆σe
further. In the giga-cycle regime, crack nucleation can
NF
shift from surface to internal inhomogeneity, which is
close to surface where local cyclic plasticity can generate
Log (crack length)
the required internal stresses for propagation. Thus, the
Figure 7: Original Kitagawa-Takahashi diagram connecting the modified Kitagawa-Takahashi diagram in Figure 8 unifies
endurance of smooth specimen and the crack growth threshold the crack nucleation, short crack growth regime with
of fracture mechanics specimen, thus defining nonpropagating
long crack growth thresholds. Most important to note is
regime.
that the internal stress triangle defines both the minimum
local stress and its stress gradient required to ensure the
previous diagram can be represented in terms of two incipient crack that is nucleated propagates continuously
limiting thresholds and endurance limits (Sadananda, to failure. For example, if the applied stress is at A, then
Sarkar, Kujawski, & Vasudevan, 2009): ΔKth and Δσe, or the local stress needs to be increased to a minimum level
Kmax,th and σmax,e. However, Kmax,th and σmax,e representation indicated by B for crack to initiate, and the gradient has to
is more convenient because time-dependent environmen- be such that crack can grow along paths B to C and C to D
tal effects can easily be represented by Kmax variable. The to become long enough for it to grow even under remote
R ratio dependence is then reduced to the dependence on applied stress. In this example, remote stress is the endur-
ΔK or Kmax. The modified diagram is shown in Figure 8. The ance limit. Hence, for crack less than ac, the internal stress
diagram is further modified by extrapolating the crack magnitude and the minimum gradient have to be fulfilled
growth threshold line and fracture line (KIC line) to crack to ensure crack growth. Otherwise, growing crack can get
lengths less than ac to meet the y-axis at σIN and σf, the arrested, resulting nonpropagating cracks. In the case of
crack initiation stress and failure stress for smooth speci- crack initiated at very sharp notches, although the magni-
men, respectively. The physical interpretation for the inter- tude of the internal stress is high to nucleate a crack, the
nal stress triangle thus formed has been provided before internal stresses fall down rapidly, resulting in nonpropa-
(Sadananda & Sarkar, 2013). In essence, it corresponds to gating cracks. For this reason, the fatigue stress concentra-
tion factor, KF, differs from the elastic stress concentration
factor. The modified Kitagawa-Takahashi diagram hence-
ac forth is called “failure diagram” because it is applicable
E σf
Modified Kitagawa- to all subcritical crack growth phenomena, where internal
Takahashi diagram
B σIN
stresses and their gradients, short crack growth analysis,
F σ=KIC/{y(πa)0.5} nonpropagating cracks, etc., are equivalently applicable.
C a* The diagram connects the behavior of smooth specimen to
Internal stress that of fracture mechanics specimen. The notched speci-
Cr reg

G
ac im

σ=Kmax,th/{y(πa)0.5}
men falls in between these two extremes.
kg e

A
σmax,e. D
ro
wt
h
Log (σ)

Non-propagating
cracks Crack growth at
constant σ H 5 F ailure diagram for stress
corrosion
Log (cl)

Figure 8: Modified Kitagawa-Takahashi diagram for fatigue. The


Failure diagram for stress corrosion is given in Figure  9.
diagram is now defined in terms of Kmax and σmax thresholds. Crack The threshold stress σth for smooth specimen forms the
growth initiation as well as failure is indicated. limiting stress values on the stress axis (y-axis) for a given

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel      9

Failure diagram Here it consists of two components. One is the local defor-
σf*
σIN mation at the crack tip, which can accelerate the crack
B
c1 growth process by creating internal stresses. The local
ac
Log (stress)

σth KIC/{√(πa) σf
Internal stress con1 Failure deformation itself could be accentuated by, say, adsorp-
C
σth*
cS A
D KISCC/{√(πa)} Initiation tion or chemisorption or by the reduction of the resistance
σapl
σth
to deformation or plastic flow. Enhanced localized defor-
Non-propagating Time mation that aids the cracking process by way of building
cracks
internal stresses is the essence of the hydrogen-enhanced
Log (crack length) local plasticity (HELP)-type of mechanisms. Many acro-

σth
σth*

Con
nyms have been used in the literature to characterize the
interdependent mechanisms involving environment and
Figure 9: Failure diagram for stress corrosion connecting thresholds local plasticity. Figure 9 defines the essential role of these
for smooth specimen, σth, and for fracture mechanics specimen, KISCC.
interactive processes in terms of building the necessary
σ ∗th is the limiting threshold with increasing concentration.
internal stresses and their gradients, which is applicable
to all subcritical crack growth processes. Using this figure,
concentration C1. With increasing concentration, this one can define, in essence, the mechanical equivalent
threshold also reaches a limiting threshold stress value of chemical forces. Ultimately, measurable entity is only
σ ∗th , as shown in Figure 9. The crack growth threshold the mechanical force, and the role of chemistry can only
line for a long crack is represented by KISCC. As in fatigue, be deduced using a pure inert environment as reference.
we consider the long crack threshold KISCC as a material Thus, operating chemical forces can only be expressed
property and is therefore independent of crack length. as reduction in the mechanical forces required for crack
Internal stress triangle forms (Figure 9) as the horizontal increment using inert state as reference. This can be done
line joining the smooth specimen threshold joins the KISCC without knowing the details of the chemical and/or elec-
line. The critical crack length ac is the minimum crack trochemical forces involved in contributing to the local net
length that can grow under the imposed applied stress in internal stresses at the crack tip regime. Although Figure 9
the concentrated aggressive environment. For lengths less provides only the requirement of mechanical stresses for
than ac, either chemical or mechanical internal stresses continuous crack growth, it does not provide the rate of
are needed to force the crack to move from incipient stage crack growth or crack growth kinetics. As these concepts
to the sustaining-growth stage. The required internal are relatively new, there are not many experimental data
stresses have to meet in terms of both the magnitude and available in the literature for their validation. Figure  10,
the gradient as designated by the internal stress triangle for example, illustrates the role of H environment in terms
to ensure continuous crack growth from its inception. of reduction in the stress necessary for crack initiation
Otherwise, the incipient crack nucleated will get arrested, and failure. Here we are using the stress value at very low
resulting in nonpropagating crack, just as was observed H concentration as reference for convenience. If the curve
during fatigue crack growth (Sadananda & Vasudevan,
2011).
40
Considering that y-axis represents the mechani-
cal stress, the significance of the internal stress triangle
4340 steel
should be understood. For example, if the initial crack size 35
Gangloff, 1986
and applied stress is represented by A in Figure 9, then
Kth (MPa (m)0.5)

Chemical stress contribution


internal stress has to be generated for A to move to posi- 30

tion B for that crack to move continuously to cause failure,


and the internal stress gradient has to be such to move 25
point B to point C along BC when the remote applied stress
is sufficient to move the crack C to D to cause failure. Thus, 20
Figure 9 defines the minimum internal stress magnitude
and its gradient required to cause continuous crack growth 15
and failure. If the magnitude and/or gradient requirements 100 101 102 103

are not met, then we have nonpropagating stress corro- H Pressure (KPa)

sion cracks. The question then pertains to the nature and Figure 10: Chemical stress contribution can be defined using the
the source of the internal stress during stress corrosion. close to inert behavior as reference.

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
10      K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel

is unique for that environment, as the authors seem to Stress fields and gradients ahead of the notch tip can vary
imply, then one can define the mechanical equivalent of depending on the stress concentration factor Kt, notch tip
chemical forces for that environment for life prediction. In radius ρ, and material flow stress in relation to applied
addition, Figure 9 also provides chemical stress gradient stress. Figure 12 shows schematically how the stress fields
in terms of equivalent mechanical stress gradient repre- can vary under elastic-plastic conditions. Most important
sented by the internal stress triangle. It is the gradient in to note is that with increasing Kt, peak stress increases and
the chemical driving forces as the crack length increases, the stress gradients become sharp, which can affect the
which is reflected in terms of mechanical stress gradient. growth of an incipient crack originating from the notch
Failure diagram thus provides a measure of the localized tip. El Haddad, Topper, and Smith (1979) were the first one
chemical driving forces and their gradients as the crack to address this problem in a somewhat empirical way. The
grows in the combined mechanical and chemical driving stress intensity factor Kplc for an incipient crack emanat-
forces. ing from an elastic-plastic notch tip has been analyzed
Figure  11 provides an example of the application (Sadananda & Sarkar, 2013) for a 2-D case, and the results
of failure diagram for 4340 steel in H2SO4 environment, for selected Kt values are shown in Figure 13. After passing
where the authors have studied the stresses for crack ini- the regime of peak stress of the notch, the stress intensity
tiation at different notch configurations. Figure 11 demon- of the incipient crack decreases and reaches a minimum
strates that notch tip stresses for crack initiation exceed
the KISCC line. For a more critical evaluation of the previ-
ously mentioned concepts, tests are required using very Notch tip stress fields under elastic – plastic conditions
Peak stress
sharp notches in the propagating and nonpropagating
Stress gradient
regimes, as was done under fatigue crack growth.
Elastic notch

ρ Peak position
6 C
 rack initiation and growth Stress profiles

at notches
Stress

The failure diagram connects the behavior of smooth


specimen and fracture mechanics specimen (Figure 1). dl

The behavior of notched specimen falls in between the Distance

two. For a smooth specimen, the internal stresses need to Figure 12: Notch tip stress fields under elastic-plastic conditions.
be generated by heterogeneous plasticity in the form of Peak stress and stress gradient change with increasing Kt.
dislocation pileups, cell walls, intrusions, and extrusions.
The preexisting notches provide stress concentrations to
some extent by localizing the deformation under stress. 8000
Crack emanating from a plastic notch
7000 Kt=6
ρ=0.5
6000 Kt=4
{x/ρ,Kpl}min
Stress intensity (Kpl)

Kt=3
σf=1880 MPa 5000
4340 steel
B 4000
Nominal stress (MPa)

1000

3000 For crack growth Kpl > Kmax,th


Chemical
stress C KIC-Line
2000 Kt=2
A D Non-propagating cracks
100 σth=175 MPa when {Kpl}min < Kmax,th
Exptal data 1000
KISCC-Line
0
Non-propagating cracks 0 5 10 15 20
x/ρ
10
10-5 10-4 10-3 10-2 10-1 100
Crack length (m) Figure 13: Stress intensity of an incipient crack emanating from a
notch under elastic-plastic conditions – arbitrary units. Note the
Figure 11: Failure diagram for 4340 steel generated based on the stress intensity goes through a minimum before it increases as
based on the Hiroshi and Mura data in H2SO4 solution. crack length increases.

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel      11

before it increases again with further increase in the crack conditions occur unless the applied stress is increased.
length. The decrease is due to sharp drop in the internal The previously mentioned equation provides the relation
stresses due to notch. The subsequent increase is due to between the Kplc and the notch severity Kt and notch tip
further increase in the crack length under the remote load. radius ρ.
This sharp reduction in the internal stress contribution Figure 14 shows the experimental data of Pao (2014)
explains why short cracks show decreasing and increasing on 4340 steel tested in vacuum using selected Kt and ρ
crack growth rates before they become one with those of values. Tests were done using single edge-notched speci-
the long crack. Hence, short crack acceleration and decel- mens, and the stress intensity for crack initiation is deter-
erations have nothing to do with the lack of crack closure mined using monotonically increasing loads to determine
but due to varying internal stress fields that are inherent when a detectable crack increment occurs. The computa-
with localized stress concentrations. Most important to tion of K is done considering notch as a sharp crack. Kplc is
note is that because the threshold for crack growth Kmax,th calculated using the previously mentioned equations for
is independent of crack length or notch configurations, the test specimens considering applied stress and their
crack arrest occurs when the minimum in Kplc in Figure 13 notch geometries. The results are shown in Figure 14.
falls below the crack growth threshold. Extensive analy- Because both Kt and ρ affect the stress fields and thus K
sis using different Kt’s and notch tip radii, ρ, showed that of short cracks, Kt/ρ is used as a characterizing parameter.
the stress intensity of an incipient crack growing in the The results show that (a) Kplc decreases essentially linearly
elastic-plastic stress field of a notch, Kplc, and the loca- with increasing severity of the notch and decreasing ρ.
tion where the minimum in Kplc occurs, X/ρ minimum, are Experimental Kint, which is calculated based on total crack
related to Kt as follows: length, is significantly higher than Kplc. However, with
increasing Kt/ρ, the experimental value drops continu-
( K plc / σ apl )min = 0.35 K t1.3 (1)
ously. The value of Kint for Kt/ρ close to 100 is for a fatigue
and precracked specimen, and therefore it can be considered
as close to the Kmax,th value of the material in vacuum
( X / ρ )min = 0.6 K t -0.46, (2)
because of lack of any better evaluation. Results indicate
and the continuous crack growth occurs only if Kplc ≥ Kmax,th. that for the specimen geometries and loads employed,
The condition for a crack to propagate continuously only when Kt/ρ is small, the initiated crack will con-
has been established as tinue to propagate for that applied load. For specimens
with higher Kt/ρ values (due to either higher Kt value or
2( K plc / σ apl ) min= ( √ ρ) (kt )1.3 , (3)
lower ρ value or both), Kplc is below Kint of the precracked
specimen. It implies that incipient crack nucleated at the
with the requirement that Kplc must exceed Kmax,th.
notch tip may become a nonpropagating crack unless
­Equation 3 indicates the elastic stress concentration factor
the applied stresses are increased further. In most of the
Kt and the notch tip radius ρ are involved in determining
the propagating or nonpropagating conditions, besides
the applied stress σapl. From the point of failure diagram
(Figure 9), the previously mentioned relations can be 200

expressed as 4340 steel

2( K plc / σ apl )min = ( √ ρ ) (K t ) ≥ K max,th = σ th √( πac ), (4)


1.3 ∗
150 Kint
Kplc or KInt (MPa(m)0.5)

Vacuum
from pao, 2014
where the threshold condition and the minimum crack
length requirements are imposed based on the failure 100

diagram. KInt-Crack
Kplc is the stress intensity of an incipient crack or short
50
crack nucleated at the notch tip. As the crack grows, the
Kplc
notch depth becomes part of the total crack, and the K of
the short crack should become the same as that of the long 0
100 101 102 103
crack. The previous equation only provides stress inten-
Kt/ρ
sity of the short crack at the minimum value (Figure  13)
and the condition for its continuous growth. If Kplc at Figure 14: Variation of Kplc and experimental Kint as function of Kt/r
the minimum falls below Kmax,th, then nonpropagating (data from P. Pao, unpublished, 2014).

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
12      K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel

J-integral tests, specimens show the R curve behavior, systems (Vasudevan & Sadananda, 2011). In essence, the
indicating that applied stresses need to be increased to time of exposure increases to arrive at sufficient chemical
overcome the material resistance to crack growth. These forces to accumulate to compensate the decreased applied
concepts are somewhat similar. mechanical forces. The balance between the mechani-
cal and chemical forces needed for a crack to grow can
be deduced from the flow diagram (Figure 9) for a given
7 C
 rack growth behavior in 4340 material and environment. Experimentally, Figure 15

steels shows that differences in the values for distilled water,


NaCl, and H2SO4 are insignificant in the scale presented.
By contrast, the applied mechanical forces required for
We now examine our current understanding of the crack
the same incubation times are significantly higher for
growth behavior in 4340 steels based on extensive data
hydrogen gas, even if one considers any disparities in the
available in the literature. Because most of the tests are
specimen configurations or test conditions. If one con-
done in environments that affect the crack growth in one
siders that hydrogen is the damaging species involved in
way or the other, we examine here only the crack growth
all these, then it requires that hydrogen should be gener-
under static load. Figure  15 shows incubation time as a
ated at the crack tip by some chemical reaction and the
function of apparent stress intensity K for crack initia-
nascent hydrogen that formed should be diffused into the
tion in different environments. Incubation time is the time
crystal to cause the embrittlement of the material ahead
needed in a static test for the detectable initiation of crack
of the crack or notch tip. Thus, the sequence of processes
at the notched or precracked specimens. Conceptually, it
involves liquid penetration to the crack tip, reaction at
is similar to the number of cycles needed for crack initia-
the crack tip to generate atomic hydrogen, and diffusion
tion under cyclic load. Hence, incubation time involves the
into the material causing embrittlement. The slowest of
time needed for the crack tip damage process to proceed at
the processes will govern the kinetics. In the case of gas
the tip to the extent that remotely applied stresses become
hydrogen, for the reaction to be active, the presence of
sufficient to pop open a crack or extend existing crack, in
moisture may be required, thus slowing down the reac-
the case of fatigue, the time or number of cycles needed
tion kinetics. Figure 15 seems to indicate that reaction can
to build the necessary internal stresses to augment the
occur readily in all the three aqueous environments in
applied stresses for the crack to grow. For static loads, it
comparison with gaseous hydrogen. Correspondingly, the
is the time required for the chemical forces to accumulate
slopes of K versus time are also different.
to augment the applied mechanical forces to pop open a
Sieverts’ law states that hydrogen solubility in a
crack or extend the existing crack. The figure shows that
metal depends on the gas pressure, and therefore crack
the incubation time increases with the decrease in the
growth kinetics should vary with external gas pressure. A
applied stress intensity, as has been observed in several
classic experiment by Oriani and Josephic (1974) showed
that threshold stress intensity for crack growth in 4340
100 steel decreased with increase in gas pressure (Figure 16).
4340 steel In addition, they showed that stress intensities are
Hirose et al. 1994
higher for deuterium (D2) than those for H2 due to higher
H2-gas data based atomic mass. The slopes are interestingly close to 0.5 as
Kapparent (MPa (m)0.5)

on Clark & Landes


Sieverts’ law dictates. Similarly, Pao and Wei (1978) have
Slope ~ 0.15 determined the steady-state crack growth rates in hydro-
gen in 4340 steel and showed that the rate increases with
Distilled water the increase in pressure; again with the slope close to
3% NaCl
Slope ~ 0.5 0.1N H2SO4 that given by Sieverts’ law, (Figure  17). In essence, the
H2 gas
experiments indicated that hydrogen concentration in
the metal is an important variable in determining the
crack growth rates. Although concentration of hydrogen
10
10 100 1000 104 105 is pressure dependent, Sieverts’ law does not take into
Incubation time (s) account the crack growth kinetics for a given hydrogen
Figure 15: Incubation time versus apparent stress intensity for
concentration. The problem is hydrogen can contribute to
crack initiation in 4340 steels. (Y. Hirose, Z. Yajima and T. Mura, not only embrittlement but also enhanced local plastic-
Int. J. Ofshore & Polor Engrg. 4, 151–155, 1994). ity. Hence, plasticity-related mechanisms such as HELP,

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel      13

30 by alternate blunting and cleave process, and the cleav-


4340 steel age component increases with the increase in hydrogen
Oriani & Josephic (1974) pressure. Figure  18 shows the TEM micrograph showing
Threshold Kth (MPa (m)1/2)

how increasing hydrogen pressure decreases the plastic-


20 ity component and increases the cleavage resulting in
D2 sharper crack front. The crack tip angle α at the crack
H2
tip measured in terms of alpha decreases with hydrogen
Slope=0.45 pressure (cotangent α), increases with hydrogen pressure,
and levels off as pressure increases, reaching a saturation
value (Figure 19). The increase in temperature reduces the
cleavage component because of increased plasticity con-
10
101 102 103 104 105
tribution. They proposed that alternate cleavage and slip
Hydrogen pressure (Pa) occur intermittently contributing to the net crack growth,
as shown schematically in Figure  20. This mechanism
Figure 16: Effect of hydrogen pressure on threshold for crack
results in the local enhanced plasticity as well as cleav-
growth in 4340 steel.
age by the presence of hydrogen. Here the plasticity is
more of an unavoidable obstruction facilitated perhaps by

10-2
4340 steel
H2S
Pao & Wei (1977) 100 µm 100 µm
-3
10
da/dt (m/s)

Slope=0.57

10-4

10-5 1
10 102 103 104
PH S (Pa)
2
A B
Figure 17: Steady-state crack growth rate as a function of gas Figure 18: Vehoff and Neumann (1983) show that with increasing H
­pressure in 4340 steel. concentration, cleavage component increases in relation to blunting
component in Fe-Si alloys.

etc., have been proposed, and plasticity is known to dis- 15


sipate the local stresses and hence retard the embrittle- Fe-3% Si
aN -Relative cleavage crack increment

ment process. Hydrogen can reduce the stresses needed Vehoff & Rothe, 1983
313 K

for dislocation nucleation at the crack tip, thus blunting


the crack tip, and it can decrease the lattice frictional 10
343 K
stress to enhance the mobility of the dislocations. Other
complexities can also arise, such as dislocation trapping
by forming an environment, dislocation drag, and/or
5
dislocation transport of hydrogen atoms. One or several a <q H2 q
of these processes can occur in combination making the
analysis difficult. Cleavage comp. aN=cot(a )
Another classical work done by Vehoff and Neumann 0
10-1 100 101 102 103 104 105
(1979) and Vehoff and Rothe (1983) on Fe-Si alloys is
Pressure (H2) - Pa
of interest here to see how the blunting and cleavage
mechanisms can occur sequentially to contribute to net Figure 19: Change in the angle with change in gas pressure for an
crack growth. They showed that crack moves forward Iron alloy at two different temperatures.

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
14      K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel

Experimental basis embrittlement slowly takes over despite the local slip as
hydrogen accumulates at the crack tip.

e
an
Combined
pl
ip

8 Summary and conclusion


Sl

Cleavage
q a
aN Crack growth behavior under corrosion and corrosion
b <r fatigue of 4340 steel was examined by using the avail-
Slip and able data in the literature and by applying the two-load
cleavage parameter requirement developed by the authors for
have to be
a <q H2 q the characterization of fatigue damage. It is shown that
alternating
for crack based on the crack growth trajectory maps, environ-
growth ment affects crack growth from its inception to speci-
men failure. The effects vary with the environment.
Cleavage component = aN=cot(a )
Environmental effects on Crack growth can be time
From vehoff and neumann, 1979 dependent, stress dependent, or both. Environmental
Figure 20: Relative roles of blunting and cleavage during crack
contribution depends on the aggressiveness of the envi-
growth. ronment, the test frequency, and the magnitude of the
applied stresses. The quantification of the environmen-
tal contribution requires the reference data in an envi-
ronment-free condition, which is lacking for most of the
the reduction in the flow stress, but eventually cleavage
materials including for 4340 steel. Both the amplitude
occurs before slip is again facilitated.
ΔK and the peak stress intensity Kmax are affected by the
The analysis requires the detailed evaluation of hydro-
environment and need to be quantified for the reliable
gen behavior at atomic level, dislocation process at dislo-
prediction of the crack growth of components in service,
cation level, crack nucleation, and extension at fracture
which are subjected spectrum loads and varying envi-
mechanics level. Solanki (2014) is currently doing this,
ronments. It is shown that the use of failure diagrams
and the preliminary results indicate that dislocation glide
can help in quantifying the internal stresses arising
and cleavage alternate as the energies for each process
from both mechanical and chemical forces in causing
oscillate around the mean. This is shown schemati-
crack initiation and growth. The importance of both the
cally in Figure 21. Thus, analysis indicates that hydrogen
magnitude and the gradients of these stresses is shown
in the initiation and growth of an incipient crack and the
conditions under which the initiated crack can become
propagating or nonpropagating under given applied
loads and environments.

Acknowledgments: The authors thank Dr. P.S. Pao, Naval


G Gdisl Research Labs, Washington, DC, and Dr. T. Romgopal,
DNV Labs, Ohio, for their technical inputs and discus-
sions on this topic.
Gclea

References
El Haddad MH, Topper TH, Smith KN. Prediction of non-propagating
Crack length cracks. Eng Fract Mech 1979; 11: 573–584.
Slip and cleavage alternating – with Gangloff RP. Hydrogen assisted cracking of high strength steels.
hydrogen cleavage become dominating In: Milne I, Ritchie RO, Karihaloo B, editors. Comprehensive
structural integrity. Volume 6. Amsterdam: Elsevier, 2003.
Figure 21: Discrete dislocations calculations confirm the alternat- Gangloff RP, Wei RP. Gaseous hydrogen embrittlement of high
ing cleavage and glide at the growing crack tip. strength steels. Met Trans 1977; 8: 1043–1053.

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM
K. Sadananda and A.K. Vasudevan: Crack growth behavior of 4340 steel      15

Kitagawa H, Takahashi S. Application of fracture mechanics to very Vehoff H, Rothe W. Gaseous hydrogen embrittlement on Fe-Si and
small cracks or cracks in the early stages. In: Proceedings of Ni-single crystal. Acta Met 1983; 31: 1781–1793.
the 2nd International Conference on Mechanical Behavior of Weng L, Zhang J, Kalnaus S, Feng M, Jiang Y. Corrosion fatigue crack
Materials. Metals Park, OH: American Society of Metals, 1976: growth of AISI 4340 steel. Int J Fatigue 2013; 48: 156–164.
627–631.
McEvily AJ, Wei RP. Corrosion fatigue: chemistry, mechanics and
microstructure. NACE-2, National Association of Corrosion
Engineers, 1972: 381–395.
Newman Jr JC, Vizzini AJ, Yamada Y. Fatigue crack growth data
Bionotes
bases and analysis for threshold behavior in rotorcraft
materials, DOT/FAA/AR/103. Washington, DC: Department of
K. Sadananda
Transportation, 2010.
Technical Data Analysis Inc., 3190 Fairview Park, Falls Church, VA
Oriani RA, Josephic PH. Equilibrium aspects of hydrogen induced
22043, USA
cracking of steels. Acta Met 1974; 22: 1065–1074.
Page RA, Gerberich WW. The Effect of hydrogen source on crack K. Sadananda (PhD in Metallurgy & Materials Engineering) retired
initiation in 4340 steel. Met Trans A 1982; 3A: 305–311. from the Naval Research Lab. in 2004 after 30 years as a Section
Pao PS. Naval Research Labs, Washington, DC, 2014. Unpublished Head of the Deformation and Fracture department. He has made
work. a major contribution to the fields of dislocation mechanics, high
Pao PS, Wei RP. Studies of subcritical crack growth in AISI 4340 temperature creep of metals, intermetallic and ceramics materials.
steel. Met Trans A 1978; 9A: 1147–1158. He has over 250 publications and 10 books. He received the Sigma-
Pao PS, Bayles RA, Yoder GR. Effect of ripple loads on stress Xi award in 1980, ASM George Burgess Award in 1999, ASM Fellow
corrosion cracking in structural steels. J Eng Mater Tech 1991; Award in 1999, Lifetime FDSM award in 2004 and Henry Marion
113: 125–129. Howe award in 2012.
Sadananda K, Sarkar S. Modified Kitagawa diagram and transition
from crack nucleation to crack propagation. Met Mat Trans A.K. Vasudevan
2013; 44A: 1175–1189. Technical Data Analysis Inc., 3190 Fairview Park, Falls Church, VA
Sadananda K, Vasudevan AK. Crack tip driving forces and crack growth 22043, USA
representation under fatigue. Int J Fatigue 2004; 26: 39–47. akruva@gmail.com
Sadananda K, Vasudevan AK. Failure diagram for chemically assisted
A.K. Vasudevan (PhD in Materials Science) retired from the US Navy
crack growth conference. Met Mat Trans 2011; 42A: 296–303.
during January 2014 and is currently working at Technical Data
Sadananda K, Sarkar S, Kujawski D, Vasudevan AK. A two parameter
Analysis, Inc at Falls Church, Virginia, USA. Prior to joining the Navy,
analysis of S-N fatigue life using Δσ and σmax. Int J Fatigue 2009;
he spent about 10 years at ALCOA Research Labs, where he devel-
31: 1648–1659.
oped high strength aerospace aluminum alloys. During his 25 years
Solanki K. Arizona State University, AZ, 2014. Unpublished work.
in the Navy, he directed research in the areas of bulk nanostruc-
Tanaka K, Nakai Y, Yamashita M. Fatigue growth threshold of small
tured materials for wear and corrosion applications, piezoelectric
cracks. Int J Fracture 1981; 17: 519–533.
materials, molybdenum disilicide materials and fatigue and fracture
Usami S, Shida S. Elastic-plastic analysis of the fatigue limit of a
of Navy structural alloys. He further directed the group to develop
material. Fat Eng Mater Struct 1979; 1: 471–482.
a fatigue life prediction model (called UniGrow) that has currently
Vasudevan AK, Sadananda K. Role of internal stresses on the
become important in the community. He has over 200 publications,
incubation times during stress corrosion cracking. Met Mat
12 patents and 12 books. He received the Sigma-Xi Award in 1983,
Trans 2011; 42A: 396–404.
ASM George Burgess Award in 2000, ASM Fellow in 2002, Navy
Vasudevan AK, Sadananda K, Holtz RL. Analysis of vacuum fatigue
Dual-Use Award in 2002, Lifetime FDSM award in 2008 and Henry
crack growth results and its implications. Int J Fatigue 2005;
Marion Howe Gold Medal in 2012.
27: 1519–1529.
Vehoff H, Neumann P. Crack propagation and cleavage initiation in
Fe-2.6%-Si single crystals under controlled plastic crack tip
opening rate in various gaseous environments. Acta Met 1979;
28: 265–272.

Brought to you by | New York University Bobst Library Technical Services


Authenticated
Download Date | 9/7/15 6:33 PM

Das könnte Ihnen auch gefallen