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Among these alternate fuels, vegetable oils are best obtained for waste cooking oil methyl esters when
suited for diesel fuel since its properties are close to petro- compared with diesel. B40 blend yielded maximum brake
diesel. Though, vegetable oils offer advantages such as thermal efficiency and reduction in emissions of CO, HC
renewable, self sustainability, however, their straight use in and NOₓ emissions at 50% load [9]. Waste plastic oil
engines is restricted mainly due to its high viscosity. The yielded 80% higher thermal efficiency, 25% higher NOₓ,
vegetable oils are mainly classified as edible and non-edible 5% higher CO, and 15% higher HC emissions when
oils. Edible oils are sunflower oil, groundnut oil, coconut compared with diesel fuel. Also, 100% waste plastic oil can
oil, olive oil, palm oil etc. Neem oil, Jatropha oil, Cotton be used to run the engine [10]. It was observed that 20%
seed oil, Pongamia oil and castor oil are few examples of Fish Oil Methyl Esters (FOME) delivered almost same
non-edible oils. Since there is a demand for edible oils from brake thermal efficiency with lower HC, CO and soot
domestic uses, fuels should be explored from non-edible emissions, but higher NOₓ emissions when compared to
oils. diesel fuel [11]. It was observed that there was a reduction
Attempts made by the researches to reduce the in NOₓ, HC and CO emissions along with a marginal
viscosity of vegetable oils and animal fats and subsequent increase in CO2 and smoke emissions with increase in
its use led to processes such as micro emulsion, pyrolysis, biodiesel proportion in diesel for the entire load. The
preheating, blending and transesterification. Among these, ignition delay, maximum heat release rate and combustion
transesterification has gained wide acceptance by the duration were lower for biodiesel –diesel blends when
research community for conversion of untreated oil to compared to diesel [12]. It is said that karanja oil blends
esterified oil and its subsequent use in engines. They show similar performance and reduced UBHC, CO and
observed that transesterification improved fuel properties smoke opacity and increased NOₓ emissions when
over those of unprocessed vegetable oils. The converted compared to diesel fuel. The biodiesel derived from karanja
vegetable oils from raw oil to corresponding methyl/ethyl and its blends could be used in a conventional diesel engine
esters popularly called as BIODIESEL[1]. without any modifications [13].
The prospects of bio-diesel production from It is observed from the literature that various
vegetable oils in India. They have also given the yield and researchers have contributed to the implementation of
production cost of various methyl esters, in general processed or methyl/ethyl ester vegetable oils in engines by
produced from non-edible oils[2].The fuel properties of adopting higher injection pressures for making blends [14-
karanja methyl ester and tests were carried out to study the 23]. Efforts were made by researchers to lower the NOₓ
performance and emissions of a diesel engine. They emissions from the biodiesel fuelled engines with the
conducted experiments to examine the characteristics like addition of EGR and other oxygenated additives [24-26].
torque, power, specific fuel consumption and emissions Palm stearin is obtained upon fractionation of palm
with varying proportions of karanja methyl ester-diesel olien oil. Though it finds applications in shortenings and
blends. They observed reduction in exhaust gas emissions, margarine. Very few have explored its use as source for
increase in torque, brake thermal efficiency, and reduced production of biodiesel and its subsequent use in engines.
brake specific fuel consumption when engine was run with Few researchers also made use of heterogeneous method of
karanja esterified oil and finally concluded that such oil producing biodiesel using metal doped methoxides [27-32].
suitable fuel for diesel engines[3].Karanja oil and its blends In the present study an attempt is made to utilize neat
have considerable effect on CI engine emissions and methyl esters obtained from non-edible oil derived from
performance [4]. The variation of injection pressure reduced Refined Bleached & Deodorised (RBD) Palm Stearin. For
the emissions and maximized the performance at both full this purpose experimental studies were carried out by
and part loads of a CI engine [5]. It was reported that blends varying compression ratio and fuel injection pressure with
of PPME with diesel up to 40% by volume (B40) yielded an objective of improving the performance and reducing the
better engine performance and reduced the emissions [6]. harmful emissions of the engine.
The power output of the engine with blends of cotton oil
soap stock biodiesel and diesel fuel decreased by 6.2% and II. MATERIALS AND METHODS
5.8% respectively. Also, a BSFC value with blended fuels
was observed to be increased by 10.5% [7]. It was reported
Preparation of Methyl Esters from Palm Stearin.
that advanced injection timings with Canola oil methyl
From the literature review, it is found that most of
esters (COME) for its complete combustion. Also, the brake
the research works have been carried out on a number of
specific fuel consumption, brake specific energy
alternative fuels especially biodiesel produced from
consumption for COME are higher than diesel [8]. It was
different kinds of vegetable oils and animal fats .To begin
reported that at an optimum compression ratio, the engine
with laboratory samples of Palm Stearin methyl esters of
performance was observed to be better when compared with
Refined, Bleached & Deodorized (RBD) Palm Stearin were
other compression ratios. Also, at higher compression ratios
prepared by adopting standard transesterification process
longer ignition delay, maximum rate of pressure rise, lower
described by Fangrui Ma and Milford A. Hanna (1999). In
heat release rate and higher mass burnt fraction were
the present case methanol and NaOH as ingredients were
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used. The procedure of making oil from Palm stearin to compression ratio and rated speed of 190 bar, 16.5 and 1500
final biodiesel is presented in the form of flow chart, Fig.1 rpm respectively. During the experiments, the engine speed
and Fig.2 as given below. Table-1 gives the comparison of (1500rpm) and engine coolant outlet temperature (650C)
important properties of fuels under consideration were maintained constant so as to obtain a steady state
condition of the engine. The results with these details were
treated as baseline data. The equipment/instrumentation
employed is schematically shown as Fig.3. The smoke
opacity of the exhaust gas was measured by smoke Opacity
meter (Make: INDUS Smoke Meter; Model: OMS-103).
Exhaust gas composition was measured using
MORTH/CMVR/TAP-115/116 Part-VIII based exhaust gas
analyzer (Make: INDUS Scientific Pvt Ltd, 5-Gas
Analyzer; Model: PEA-205). This analyzer measures CO,
HC, CO₂, O₂, and NO ₓ in the ex hu ats gas. The
measurement range and accuracy of the exhaust gas
analyzer are given in Table-3. Further experiments were
continued with neat PSME by varying fuel injection
pressures from 190 bar to 230 bar in steps of 20 bars and a
higher compression ratio of 19
Fig. 1. Flow Chart of Biodiesel Production from Palm
Stearin
TABLE- 2. TEST ENGINE SPECIFICATIONS
ratio can be increased by retaining the rated FIP. Therefore, 3. Comparison of Cylinder Pressure(bar) –Crank
it is estimated that either an increase in compression ratio of angle(Deg) of engine for different FIPs and CRs:
about 15% or an increase in FIP of about 10% is required to
achieve the performance of the engine with PSME in line
with petro-diesel fuel operation of the respective rated FIP
and CR.
Fig. 4.3(e). Variation of BTE with % Full Load Brake Fig. 4.4. Comparison of best CO Emissions of engine with
Power at CR =16.5 PSME under Full Load conditions
Fig. 4.3(f). Variation of BTE with % Full Load Brake Fig. 4.5. Comparison of best HC Emissions of engine with
Power at CR =19 PSME under Full Load conditions
VI. ACKNOWLEDGEMENTS
Authors thank the management of Sri
Venkateswara College of Engineering, RVS Nagar,
Fig. 4.10(b). Variation of EGT with % Full Load Chittoor for providing the necessary experimental facilities
Brake Power at CR =19 to perform this research.
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