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Volume-5, Issue-6, December-2015


International Journal of Engineering and Management Research
Page Number: 61-69

Performance and Emission Characteristics of CI Engine with Methyl


Esters of Palm Stearin under Varying Compression Ratios and Fuel
Injection Pressures
A. R. Babu1, G. Amba Prasad Rao2, T. Hari Prasad3
1
Research Scholar, Department of Mechanical Engineering, National Institute of Technology, Warangal, Telangana State,
INDIA
2
Professor, Department of Mechanical Engineering, National Institute of Technology, Warangal, Telangana State, INDIA
3
Professor, Department of Mechanical Engineering, Sree Vidyanikethan Engineering College, Rangampet, Tirupati, Andhra
Pradesh, INDIA

ABSTRACT Diesel fueled compression ignition engines are


Of late, use of biodiesel derived from edible oils, non- invariably used in light, medium and heavy duty
edibles oils and animal fats oils is gaining interest among applications. On large scale, they are being used in
research community for meeting stringent emission norms and transportation sector. The versatility of diesel engines is due
meet fuel demands. Palm Stearin is obtained upon to its high fuel conversion efficiency, lower fuel cost, safe
fractionation of palm Olien oil. The present work deals with
operation and high reliability. The increased automotive
experimental investigations conducted on a direct injection
diesel engine under two compression ratios of (16.5 and 19) population over the past two decades has raised the
with different fuel injection pressures (190, 210 and 230 bars) pollution at alarming levels. Moreover, the heavy
at a constant speed of 1500 rpm employing methyl esters of dependence on petroleum derived fuel (diesel fuel) is not
Palm Stearin. The results were compared with the baseline only draining country’s exchequer but also raising the
data on the performance of the engine, when it was run with doubts of its accessibility in future years. Thus the twin
petrol-diesel at a rated FIP of 190 bar and CR 16.5. From the problems of large scale exploitation of petroleum derived
results, the trends of BTE with PSME were found to be similar fuels and associated pollution has made the researchers to
to the baseline results. It was observed that the BTE was high find viable alternate fuels. The intensive research has led to
at injection pressure of 210 bar and CR 16.5 with respect to
the development of various alternate fuels like, alcohol
other PSME trends of 190 and 230 bar.However, the engine
performance was superior with CR19 at the rated injection fuels, natural gas, hydrogen, vegetable oils etc.
pressure of 190 bar. The peak pressures with higher CR were
observed to higher. The engine emissions in terms of HC, CO
and Smoke opacity were lower but the NOₓ were found to be NOMENCLATURE
increased due to the better combustion. The study revealed
that palm stearin could be explored as a source for producing Baseline Petro-diesel
biodiesel in order to utilize palm derived oils effectively with BTE Brake Thermal Efficiency
environmental concern. BSFC Brake specific fuel consumption
CO Carbon Monoxide
Keywords--- CI engine, Palm Stearin Methy Esters, Fuel CR Compression Ratio
injection pressures, Compression ratios, Engine EGT Exhaust Gas Temperature
performance, Exhaust emissions FIP Fuel Injection Pressure
HC Hydro Carbons
NaOH Sodium Hydroxide
NOₓ Nitrogen Oxides
I. INTRODUCTION PSME Palm Stearin Methyl Ester

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Among these alternate fuels, vegetable oils are best obtained for waste cooking oil methyl esters when
suited for diesel fuel since its properties are close to petro- compared with diesel. B40 blend yielded maximum brake
diesel. Though, vegetable oils offer advantages such as thermal efficiency and reduction in emissions of CO, HC
renewable, self sustainability, however, their straight use in and NOₓ emissions at 50% load [9]. Waste plastic oil
engines is restricted mainly due to its high viscosity. The yielded 80% higher thermal efficiency, 25% higher NOₓ,
vegetable oils are mainly classified as edible and non-edible 5% higher CO, and 15% higher HC emissions when
oils. Edible oils are sunflower oil, groundnut oil, coconut compared with diesel fuel. Also, 100% waste plastic oil can
oil, olive oil, palm oil etc. Neem oil, Jatropha oil, Cotton be used to run the engine [10]. It was observed that 20%
seed oil, Pongamia oil and castor oil are few examples of Fish Oil Methyl Esters (FOME) delivered almost same
non-edible oils. Since there is a demand for edible oils from brake thermal efficiency with lower HC, CO and soot
domestic uses, fuels should be explored from non-edible emissions, but higher NOₓ emissions when compared to
oils. diesel fuel [11]. It was observed that there was a reduction
Attempts made by the researches to reduce the in NOₓ, HC and CO emissions along with a marginal
viscosity of vegetable oils and animal fats and subsequent increase in CO2 and smoke emissions with increase in
its use led to processes such as micro emulsion, pyrolysis, biodiesel proportion in diesel for the entire load. The
preheating, blending and transesterification. Among these, ignition delay, maximum heat release rate and combustion
transesterification has gained wide acceptance by the duration were lower for biodiesel –diesel blends when
research community for conversion of untreated oil to compared to diesel [12]. It is said that karanja oil blends
esterified oil and its subsequent use in engines. They show similar performance and reduced UBHC, CO and
observed that transesterification improved fuel properties smoke opacity and increased NOₓ emissions when
over those of unprocessed vegetable oils. The converted compared to diesel fuel. The biodiesel derived from karanja
vegetable oils from raw oil to corresponding methyl/ethyl and its blends could be used in a conventional diesel engine
esters popularly called as BIODIESEL[1]. without any modifications [13].
The prospects of bio-diesel production from It is observed from the literature that various
vegetable oils in India. They have also given the yield and researchers have contributed to the implementation of
production cost of various methyl esters, in general processed or methyl/ethyl ester vegetable oils in engines by
produced from non-edible oils[2].The fuel properties of adopting higher injection pressures for making blends [14-
karanja methyl ester and tests were carried out to study the 23]. Efforts were made by researchers to lower the NOₓ
performance and emissions of a diesel engine. They emissions from the biodiesel fuelled engines with the
conducted experiments to examine the characteristics like addition of EGR and other oxygenated additives [24-26].
torque, power, specific fuel consumption and emissions Palm stearin is obtained upon fractionation of palm
with varying proportions of karanja methyl ester-diesel olien oil. Though it finds applications in shortenings and
blends. They observed reduction in exhaust gas emissions, margarine. Very few have explored its use as source for
increase in torque, brake thermal efficiency, and reduced production of biodiesel and its subsequent use in engines.
brake specific fuel consumption when engine was run with Few researchers also made use of heterogeneous method of
karanja esterified oil and finally concluded that such oil producing biodiesel using metal doped methoxides [27-32].
suitable fuel for diesel engines[3].Karanja oil and its blends In the present study an attempt is made to utilize neat
have considerable effect on CI engine emissions and methyl esters obtained from non-edible oil derived from
performance [4]. The variation of injection pressure reduced Refined Bleached & Deodorised (RBD) Palm Stearin. For
the emissions and maximized the performance at both full this purpose experimental studies were carried out by
and part loads of a CI engine [5]. It was reported that blends varying compression ratio and fuel injection pressure with
of PPME with diesel up to 40% by volume (B40) yielded an objective of improving the performance and reducing the
better engine performance and reduced the emissions [6]. harmful emissions of the engine.
The power output of the engine with blends of cotton oil
soap stock biodiesel and diesel fuel decreased by 6.2% and II. MATERIALS AND METHODS
5.8% respectively. Also, a BSFC value with blended fuels
was observed to be increased by 10.5% [7]. It was reported
Preparation of Methyl Esters from Palm Stearin.
that advanced injection timings with Canola oil methyl
From the literature review, it is found that most of
esters (COME) for its complete combustion. Also, the brake
the research works have been carried out on a number of
specific fuel consumption, brake specific energy
alternative fuels especially biodiesel produced from
consumption for COME are higher than diesel [8]. It was
different kinds of vegetable oils and animal fats .To begin
reported that at an optimum compression ratio, the engine
with laboratory samples of Palm Stearin methyl esters of
performance was observed to be better when compared with
Refined, Bleached & Deodorized (RBD) Palm Stearin were
other compression ratios. Also, at higher compression ratios
prepared by adopting standard transesterification process
longer ignition delay, maximum rate of pressure rise, lower
described by Fangrui Ma and Milford A. Hanna (1999). In
heat release rate and higher mass burnt fraction were
the present case methanol and NaOH as ingredients were
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used. The procedure of making oil from Palm stearin to compression ratio and rated speed of 190 bar, 16.5 and 1500
final biodiesel is presented in the form of flow chart, Fig.1 rpm respectively. During the experiments, the engine speed
and Fig.2 as given below. Table-1 gives the comparison of (1500rpm) and engine coolant outlet temperature (650C)
important properties of fuels under consideration were maintained constant so as to obtain a steady state
condition of the engine. The results with these details were
treated as baseline data. The equipment/instrumentation
employed is schematically shown as Fig.3. The smoke
opacity of the exhaust gas was measured by smoke Opacity
meter (Make: INDUS Smoke Meter; Model: OMS-103).
Exhaust gas composition was measured using
MORTH/CMVR/TAP-115/116 Part-VIII based exhaust gas
analyzer (Make: INDUS Scientific Pvt Ltd, 5-Gas
Analyzer; Model: PEA-205). This analyzer measures CO,
HC, CO₂, O₂, and NO ₓ in the ex hu ats gas. The
measurement range and accuracy of the exhaust gas
analyzer are given in Table-3. Further experiments were
continued with neat PSME by varying fuel injection
pressures from 190 bar to 230 bar in steps of 20 bars and a
higher compression ratio of 19
Fig. 1. Flow Chart of Biodiesel Production from Palm
Stearin
TABLE- 2. TEST ENGINE SPECIFICATIONS

Fig. 2. Photograph of Biodiesel production

TABLE -1. PROPERTIES OF PALM STEARIN METHYL ESTERS


AND PETRO-DIESEL

III. EXPERIMENTAL PROGRAMME


Fig. 3. Computer Based Four Stroke Single Cylinder
The detailed specifications and schematic diagram
Variable Compression Ratio Multi Fuel Engine with Eddy
of the engine are given in Table-2 and Fig.3
Current Dynamometer
Initially the experiments were performed with
Petro-diesel maintaining rated fuel injection pressure, rated

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TABLE-3 : EXHAUST GAS ANALYZER AND SMOKE METER


SPECIFICATIONS

Fig. 4.1 Variation of BSFC with % Full Load Brake Power


at CR =16.5

b) Effect of Injection Pressure at CR = 19:


Further tests were performed on the engine with a
compression ratio of 19. The FIPs are again maintained as
190 bar to 230 bar. Fig. 4.2 shows the variation of BSFC of
the engine when it was from with PSME. In the same
IV. RESULTS & DISCUSSION Figure the baseline data is also compared. It is obvious from
the Figure that the BSFC values for an FIP of 190 bar are
Constant speed, performance and emission related close to baseline data. It is interesting to observe that higher
experiments are performed on a single cylinder DI CI compression ratio has played a vital role in obtaining better
engine with petro-diesel and PSME by varying fuel performance with neat biodiesel.
injection pressures and Compression Ratio of the engine.
The baseline data represent the information on the
performance of the engine when it was run with petrol-
diesel at rated FIP of 190 bar and CR = 16.5. The effect of
fuel injection pressure and CR are investigated on the
important characteristics of an engine and the same are
plotted and discussed appropriately.
4.1. Performance Characteristics of the engine at different
FIPs and CRs with PSME
a) Effect of Injection Pressure at CR = 16.5:
Figure 4.1 represents the variation of BSFC of the
engine with load when the engine was run with PSME by
varying the FIP from 190 bar to 230 bar in steps of 20 bar.
It can be observed that the trends of BSFC of the engine
with PSME are in line with petro-diesel operation.
However, the BSFCs of the engine are on the higher side Fig. 4.2. Variation of BSFC with % Full Load Brake Power
with biodiesel operation when compared to baseline at CR=19
performance. It is interesting to note that as the FIP was
increased, the BSFC values are decreasing. But the values 2. Comparison of BSFCs of engine for different FIPs and
with 210 bar are close to baseline values. It is required to CRs:
adopt higher injection pressures when a fuel with a higher From Fig.4.1 and Fig.4.2 the BSFCs of the engine
viscosity is used compared to petro-diesel. This is also due for load operation are extracted and compared in Fig.4.3(a)
to fact that as the FIP was increased smaller and smaller and Fig.4.3(b) In order to observe the role of compression
size droplets should have produced and which in turn mixed ratio, the best BSFCs obtained with CR= 16.5 and CR=19
thoroughly with available air and let near complete respectively are redrawn as Fig 4.3(c)
combustion. Further, increase in pressure beyond 210 bar From Fig.4.3(c) it can be noticed that compression ratio has
has not helped. Therefore, for this engine configuration it played a dominant role in achieving better performance. It
can be inferred that 210 bar could be an optimum injection can be concluded at this stage, either injection pressure can
pressure. be varied, maintaining the rated CR as it is or compression

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ratio can be increased by retaining the rated FIP. Therefore, 3. Comparison of Cylinder Pressure(bar) –Crank
it is estimated that either an increase in compression ratio of angle(Deg) of engine for different FIPs and CRs:
about 15% or an increase in FIP of about 10% is required to
achieve the performance of the engine with PSME in line
with petro-diesel fuel operation of the respective rated FIP
and CR.

Fig. 4.3(d). Comparison of best P-θdiagrams of engine with


PSME under Full Load conditions.

The variation of Cylinder pressure with respect to


crank angle for different CRs and FIPs are shown in Fig.
4.3(d). The results were compared with the baseline data on
Fig. 4.3(a). Variation of BSFC for PSME under Full Load the performance of the engine, when it was run with petrol-
for different FIPs and CR=16.5 diesel at a constant FIP of 190 bar and CR 16.5. From the
results, the trend of P-θlines with PSME was found similar
to the baseline of petro-diesel. It was observed that the Pθ
line was seen lower at injection pressure of 210 bar and at a
Compression ratio of 16.5 . where as in P-θline was also
found higher for Compression ratio of 19 at the rated
injection pressure of 190 bar with comparng the baseline
data of CR 16.5 and 190 bar.It was noticed that
compression ratio has played a dominant role in achieving
better performance. It can be concluded at this stage,
injection pressure can be varied, maintaining the rated CR
as it is or compression ratio can be increased by retaining
the rated FIP.
Brake thermal efficiency of the engine is an
important non-dimensional performance parameter that
represents the percentage of power developed by the engine
Fig. 4.3(b). Variation of BSFC for PME under Full Load to the amount of heat supplied. Thus, it is reciprocal of
for different FIPs and CR=19 BSFC of the engine. Fig.4.3(e) and Fig.4.3(f) represents
the variation of BTE with respect to the percentage of full
load power. It is oblivious from the two figures that engine
operation with PSME is better with increase in compression
ratio.

Fig. 4.3(c). Comparison of best BSFCs of engine with


PSME under Full Load conditions.

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Fig. 4.3(e). Variation of BTE with % Full Load Brake Fig. 4.4. Comparison of best CO Emissions of engine with
Power at CR =16.5 PSME under Full Load conditions

Fig. 4.3(f). Variation of BTE with % Full Load Brake Fig. 4.5. Comparison of best HC Emissions of engine with
Power at CR =19 PSME under Full Load conditions

4.2. Emission Characteristics of the engine at different


FIPs and CRs with PSME.
It was observed the effects of FIP and CR on the
engine performance. During the entire load range of
operation, the emissions of the engine were also measured.
Since the emissions of the CI engine will be significant at
full load operation, therefore, to observe the effect of FIP
and CR, the emission levels are compared for CO, HC,
Smoke Opacity and NOₓ in Figures 4.4, 4.5, 4.6 and 4.7
respectively.

Fig. 4.6. Comparison of best Smoke Opacity of engine with


PSME under Full Load conditions

This can be due to the fact that factors affecting for


formation of CO, HC and Smoke Opacity are almost
similar. It can also be observed that the levels of these

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emissions with PSME or far lower when compared to


emissions obtained with petro-diesel operation.

Fig. 4.9. Variation of VE with % Full Load Brake Power at


CR =19

This can be understood with the lower values of


Fig. 4.7. Comparison of best NOₓ Emissions of engine with volumetric efficiency obtained with neat biodiesel operation
PSME under Full Load conditions which is represented as Fig. 4.8. and Fig. 4.9
Also, because of its reactive nature the in-cylinder
Fig.4.7 shows the levels of NOₓ for different temperatures with biodiesel operation would be higher. This
conditions. It is interesting to notice that NOₓ levels are is also a reason for higher NOₓ levels, since the in-cylinder
higher with biodiesel compared to petro-diesel operation. temperatures are higher and yields higher exhaust
This is well established in the literature that NOₓ emissions temperatures. Fig.4.10(a) and Fig4.10(b) show the variation
increase with biodiesel operation due to the reactive nature of EGTs for CR=16.5 and CR=19 respectively. It can be
of biodiesel molecule at higher temperature and oxygen observed that with a biodiesel operation the EGTs are
present in its structure. Since the biodiesel molecule higher.
contains oxygen in its structure, the amount of oxidizer
required by the engine gets reduced.

Fig. 4.10(a). Variation of EGT with % Full Load Brake


Power at CR =16.5
Fig. 4.8. Variation of VE with % Full Load Brake Power at
CR =16.5

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observed in NOₓ emission with Palm Stearine


Methyl Esters compared to Petro-diesel operation
ix. Under full load operation and CR 19,A percentage
increase of about 17.51% was observed in NOₓ
emission with Palm Stearine Methyl Esters
compared to Petro-diesel operation
It is observed that compression ratio has a dominant
effect on performance where as fuel injection pressure as
played a vital role in the reduction of emissions.

VI. ACKNOWLEDGEMENTS
Authors thank the management of Sri
Venkateswara College of Engineering, RVS Nagar,
Fig. 4.10(b). Variation of EGT with % Full Load Chittoor for providing the necessary experimental facilities
Brake Power at CR =19 to perform this research.

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