3.28.

Derive an equation for the work of a mechanically reversible, isothermal

compression of 1 mole of a gas from an initial pressure p1 to a final pressure p2
when the equation of state is the virial expansion truncated to:

Z=1+B'P

How does the result compare with the corresponding equation for an ideal gas?

Diketahui : 1 mol dengan tekanan awal P1 dan tekanan akhir P2

Ditanya : persamaan yang membandingkan dengan gas ideal

Penyelesaian:

Dari mechanically reversible kita tahu bahwa:

𝑉2
W=− ∫𝑉𝐼 𝑃𝑑𝑉 (eq 3.25 hal.74)

Z=1+B'P ( di soal)

𝑃𝑉
Z= ( gas ideal)
𝑅𝑇

𝑃𝑉
= 1+B'P
𝑅𝑇

𝑅𝑇
V= 𝑃 (1 + B'P)

1
V=RT( + B')
𝑃

perbandingan keduanya terhadap tekanan :

𝑑𝑉 −1
= RT ( + 0)
𝑑𝑃 𝑃2

−𝑅𝑇
dV= dP
𝑃2

𝑉2
W=− ∫𝑉𝐼 𝑃𝑑𝑉
 𝑉2 −𝑅𝑇
W= ∫ PdV
𝑉𝐼 𝑃2

𝑉2 1
= RT∫
𝑉𝐼 𝑃
𝑑𝑃

𝑃2
=RT Ln |𝑃1

= RT (Ln P2 – Ln P1)

𝑃2
W= RT Ln
𝑃1