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DOI 10.1007/978-3-642-27851-8_181-3
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Pigment, Ceramic
Guillermo Monros*
Departamento de Química Inorgánica y Orgánica, Universitat Jaume I, Edifici Científico-Tècnic, Castelló, Spain
Synonyms
Colorant; Dye; Paint; Stain; Tint
Definition
A ceramic pigment is usually a metal transition complex oxide obtained by a calcination process
which shows three main characteristics: (a) thermal stability, maintaining its identity when temper-
ature increases; (b) chemical stability, maintaining its identity when fired with glazes or ceramic
matrices; and (c) high tinting strength when dispersed and fired with glazes or ceramic matrices.
Other characteristics as high dispensability in vehicles, high refractive index (in order to avoid
transparency and to increase its tinting strength), acid and alkali resistance, and low abrasive strength
are also suitable.
The main coloring methods of ceramics are based on dyes or pigments. Strictly a dye or soluble
colorant is a colored substance that interacts with the matrix to which it is applied and usually is
soluble in the media of application called matrix or substrate. Conversely, ideally a pigment or stain
is a colored substance insoluble in the pigmented matrix, is stable in the matrix (it does not interact
with the matrix), and, in the case of ceramic pigments used in stoneware or glazes, is stable when
temperature increases (thermal stability). Obviously a pigment must have a high tinting strength
relative to the materials it colors. As a general rule, ceramic stains and ceramic pigments look pretty
much the same before and after firing, but not dyes, based on raw oxides as well as salts such as
carbonates or nitrates, because they decompose in firing and dissolve in the glazes or stoneware
(Fig. 1a) [1a].
1. Grinding. The raw materials (usually oxides or carbonates) are carefully mixed in mills such as
ball mills often with mineralizer agents (inorganic salts as NaCl, NaF, and KNO3) in order to
facilitate the pigment crystallization.
2. Calcination. The mixture is then calcined in either batch kilns or continuous calciners.
3. Washing. After calcination, the powders are washed to eliminate residual salts from mineralizers
and other leaching components in order to avoid future firing defects and environmental
affections.
*Email: monros@qio.uji.es
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1,2
b
1
820ºC
0,8
absorbancia
925
0,6
0,4
0,2
0
200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400
longitud de onda (nm)
975
1025
Fig. 1 (a) Ideal behavior of interaction of pigments (dispersion) and dyes (dissolution) with the matrix. (b) Color
evolution with the firing temperature of screen printing (90 threads/cm) deposition of a Co-Ti ink (1 w.% in the organic
polyol media) under a glazed CaO-ZnO-SiO2 monoporosa tile (previously fired at 1,080 C)
4. Micronization. The mixture is then ground to the necessary fineness in mills. Micronizers and jet
mills are used to break agglomerates.
5. Tinting strength control. The final production step involves careful control of the color tone.
Because these pigments are formed at high temperatures, they generally offer superb thermal
stability and are relatively inert. This results in excellent weathering and light fastness properties.
Most of these pigments have superior acid and alkali resistance. They are nonmigrating and
nonbleeding in nature and do not interact with substrates. The principal disadvantage of ceramic
pigments is their low tinting strength. In addition, some are relatively high in cost. This is
particularly true with cobalt-containing pigments. Some of these pigments are difficult to disperse.
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However, the recent development of easily dispersed ceramic pigments should eliminate this
problem. A final concern is the inherent hardness of these pigments. Their hardness can lead to
processing system damage through abrasion. When using ceramic pigments, processing system
components designed for use with abrasive materials should be considered [1b].
Overview
Stable fired pigments solve some of the problems found in using dyes such as: (a) the use of
hazardous raw materials, because many of the unstable oxides or salts used as direct dyes are soluble
or toxic, its calcination, by combining these elements along with clays, silica, alumina, etc., makes
them stable giving a safety manipulation, is the case of vanadium pentoxide a toxic substance that is
safety used in the zirconium vanadium blue zircon ceramic pigment, (b) volatilization in the kiln
which is colored by the fumes such as it occurs using vanadium oxide or chromium oxide, and (c) the
own stability of the color avoiding chemical reactions of the dye with the components of the glaze,
for example, eskolaite Cr2O3, used as natural green dye, reacts with tin oxide and silica of the glazes
producing malayaite Cr-CaSnSiO5 pink precipitates, and then a pink undesired coloration is given,
or reacts with zinc oxide of the glaze to crystallize ZnCr2O4 spinel, imparting undesired blue-brown
color; the use of the cobalt-zinc-alumina-chromite blue-green pigment gives a trustworthy stable
range of color from green to blue.
How to give trustworthy and safety color to ceramics is the main proposal of pigment production
because adding color to our ceramics is needed to produce ceramic art and it cannot be a tricky
proposition. Working with paints, the color you put on your piece is the color of the final paint, but in
ceramics the fire also builds the color. Pigment research is addressed to obtain new ceramic pigments
in order to reach three main purposes:
(a) High thermal stability pigments, addressed to new materials as porcelainized stoneware and
correlated use of ink-jet printing techniques, that require obtaining adequate particle size of
pigments or precursor solutions that produce the pigment “in situ,” during thermal processing of
substrate.
(b) High chemical resistance pigments, adapted to new glazes and ceramic matrices avoiding
particle pigment solubilization or degradation when it reacts in ceramic processing.
(c) Eco-friendly pigments, with low environmental affection evaluated on its complete life cycle:
raw material preparation, transport, processing, product distribution, and waste management.
(d) Pigments for industrial digital printing (ink-jet). Ink-jet decoration is a relatively recent meth-
odology. Elmquist designed the first practice application of CIJ (continuous ink-jet) in 1951 for
tape recorder. Winston developed the first teletype printer by CIJ, and in 1968 the first
commercial printer 9600 from AB Dick appeared. A continuous flow of electrical conductive
ink drops is thrown to substrate and selectively dispersed by an electric field in the CIJ ancient
technology. The DOD (drop on demand) ink-jet was developed later in order to produce only the
demanded drops. Firstly, in TIJ (thermal ink-jet) technique, the drops were produced from
pressure of bubbles generated into the nozzles by a local heating mechanism. Now, in the PIJ
(piezoelectric ink-jet) technique, the drops are produced by pressure due to the deformation
when an electric field is applied to a piezoelectric piece disposed in the nozzles.
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Digital decoration technology is widely developed in other materials (textile, paper, etc.),
basically using TIJ technique. It has been claimed for surface ceramic tile decoration due to several
advantages based on the fact of absence of contact between the applicator and the decorated surface:
(i) High resolution of images. The ink-jet technique allows to throw 2,000–5,000 drops/cm in a
strictly controlled way. Using serigraphy, chalcography, or flexography methods, the resolution
is very limited. Therefore photographic quality images could be carefully reproduced by ink-jet
digital monitored application.
(ii) Low raw strength of tile and short enameling line required. Due to the absence of contact
applicator surface, the raw strength is limited only to the adequate manipulation of raw tile, and
then the thickness of piece can be reduced. The number of decoration operations is reduced
sometimes at one because it can be applied four colors in a selective way at the same time;
likewise the reduced weight of ink deposited and relatively low water concentration reduce the
drying time between successive applications, and therefore the length of industrial enameling
line is drastically reduced.
(iii) The topography of the tile surface is not limited and relief surfaces can be easily decorated.
(iv) Reduction of necessary ink (1 g/m2), fully recycling and washing operations eliminated.
(v) Simplicity of the decoration process because it can be limited to only one decoration step using
the simultaneous four-color application CMYK (cyan, magenta, yellow, black).
The main difficulty for ink-jet application in ceramic tile industry is the ink that must show
specific properties, basically:
(i) High stability, because the precipitation, agglomeration, or viscosity changes can obstruct the
nozzles.
(ii) High color strength is necessary due to reduced weight of ink deposited by dropping;
on contrary, diffused and weak colors are obtained and poor decoration is produced.
(iii) Neutral pH is required in order to prevent corrosive effects on the nozzles, but conductivity is
not required in both PIJ or TIJ technologies; contrarily in ancient CIJ technique, the electric
charge capacity of drops was necessary for their selective dispersion by an electric field.
There are three main families of digital inks: (a) soluble salts such as cobalt nitrate (CYAN),
mixture of chromium nitrate and iron nitrate (MAGENTA), mixture of antimony nitrate. nicke and
stabilized titania (YELLOW), and mixtures of cobalt and iron nitrates (BLACK) are used for
producing “in situ,” when decorated ceramics are fired, classical ceramic pigments such as
Co2SiO4 olivine blue pigment, Fe(Fe,Cr)2O4 iron chromite brown spinel, (Ti,Ni,Sb)O2 chro-
mium-antimony yellow rutile, and CoFe2O4 black spinel, respectively; (b) colloidal or
ultramicronized classical pigments particles dispersed using dispersant agents; and (c) nanoparticles
of classical ceramic pigments, produced by “soft chemistry” such as polyol or sol-gel routes, or
metals absorbed on stable sol particles of oxohydroxy compounds of Al, Ti, Sn or Zr (purple of
Cassius and its analogous with Cu).
Since the nineteenth century, needs on color stability, glaze resistance, and sure management lead
to stabilized fired pigments. On these pigmenting systems, chromophore agents (usually first raw
transition heavy metals and p metals) are inertized in high-thermal and low-solubility ceramic
matrices.
The main mechanisms of origin of color based on the stabilization-inertization of chromophores
are the following:
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(a) Structural mechanism. In this case the chromophore cations (usually transition metals that
absorb, as it is discussed below, selected visible wavelengths by d-d electron transitions) are
forming the ceramic network such as Co(II) in Co2SiO4 olivine. In other structural cases, a solid
solution is obtained: pigmenting cations substitute structural cations in ceramic matrix as V4+
substitutes Zr4+ in ZrSiO4 zirconium vanadium blue zircon (a cyan pigment also named Turkish
blue zircon or turquoise zircon) formulated by CPMA as (V,Zr)SiO4. The above-discussed
classical pigments Fe(Fe,Cr)2O4 (iron chromite brown spinel with iron in solid solution into
chromite network) and (Ti,Ni,Sb)O2 (chromium-antimony yellow rutile with Sb+5 and Cr3+ in
solid solution into rutile lattice), are also solid solutions.
(b) Inclusion mechanisms. Colored nanoparticles protected into high stable host crystals (e.g. Fe2O3
hematite into zircon crystal particles that gives the pink coral of iron in the zircon ceramic
pigment) are the origin of color in this case.
(c) Mordant mechanism. The origin of color is in this case a metal-based dye stabilized by a mordant
compound. The final color depends on the mordant used, due to the formation of metal
complexes that cause a change in the molecular orbital energies and hence a shift in UV-Vis
absorption bands; e.g. Au in Sn(OH)4 mordant substrate on Cassius purple pigment [1a].
In agreement with above-described purposes of research on new ceramic pigments, three main
limitations can be pointed out: (a) thermal and chemical stability, (b) structure base, and
(c) environmental safety. These limitations are described and illustrated with three examples.
The Co2+ ion dissolves in ceramic glazes and imparts an intense blue color to ceramic glazes up to
0.05 w.% and could be used in novel dye ink-jet application in ceramics. This color intensifies in the
presence of ZnO, due to the crystallization of a solid solution of Co2+ in willemite (Zn,Co)2(SiO4)2,
or in the presence of BaO which precipitates cobalt-celsian solid solution (Ba,Co)(SiO4)2. In glazes
containing MgO and TiO2, cobalt gives green colorations, due to crystallization of green cobalt-
ilmenite CoTiO3 more stable in boron glazes [1c].
The color evolution with the firing temperature of screen printing (90 threads/cm) deposition of a
Co-Ti ink (1 w.% in the organic polyol media) over a glazed “monoporosa” tile (previously fired a
1,080 C) is shown in Fig. 1b. The green coloration at low temperatures (820, 925 C) is associated
to cobalt-ilmenite CoTiO3 crystallizations with Co2+ in octahedral coordination (absorption bands at
350 nm in the UV range, 700 nm in the visible red wavelength, and 1,200 nm in the IR range, in the
spectral and color rendering of Fig. 1). When temperature increases, the cobalt-ilmenite CoTiO3
decomposes and Co2+ solubilizes in the glaze giving intense blue color associated to Co2+ in
tetrahedral coordination (absorption bands at 530 nm green, 590 nm orange, and 650 nm red and
high reflectivity at 430 nm blue wavelength). At low temperature the color is associated to a pigment
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Fig. 2 (a) ZrSiO4 structure from CPMA classification, S.G. I41/ with D2d symmetry for SiO4 group and dodecahedral
D2d for ZrO8, (b) CMYK subtractive color model, (c) RGB additive color model, (d) the CMYK zircon palette (cyan
(Zr,V)SiO4 DCMA 14-42-2, pink (Zr,Fe)SiO4 DCMA 14-44-5, yellow (Zr,Pr)SiO4 DCMA 14-43-4) including a Cr,Co-
ferrite as black component, all 3 % enameled in monoporosa glaze, (e) particles of black spinel pigment by SEM
mechanism (particles of ilmenite crystallization on the glaze surface), but at high temperatures, the
color is due to a dye mechanism (cobalt dissolution in glaze).
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In 2010 the Color Pigments Manufacturers Association (CPMA) actualized the classification and
chemical description of the complex inorganic color pigments in the fourth edition [2]. CPMA
describes the industrial ceramic pigment by a code such as CPMA 1-01-4. The first number on the
code is the corresponding number of the structure above discussed (in this case 1=baddeleyite), the
second set is the CPMA category number identifying each pigment within a given crystal class
(in this case 1=first ceramic pigment on the CPMA list), and the third set of numbers identifies the
color of the pigment as follows: (1) violet and red-blue; (2) blue and blue-green; (3) green; (4) yellow
and primrose; (5) pink, orchid, coral, and peach; (6) buff; (7) brown; (8) gray; and (9) black (in the
above case 4=yellow). Finally, CPMA also gives a classification based upon the predominant use of
these pigments; three use categories were adopted for guidance. Category A deals with pigments
suspended in glass matrices which require the highest degree of heat stability and chemical
resistance to withstand the attack of molten glass. Category B deals with pigments suspended in
plastics and other polymers which require only moderate heat stability. Category C deals with
pigments suspended in liquid vehicles which require little or no heat stability.
Among the more successful ceramic pigments which gives a complete CMYK palette of color, the
pigments based on zircon structure (number XIV in CPMA classification) shown in Fig. 2a and
discovered by C. A. Seabright in 1948 stand out.
(a) CYAN based on the vanadium blue zircon V-ZrSiO4 (CPMA number 14-42-2). CPMA describes
this pigment as an inorganic pigment and as a reaction product of high-temperature calcination in
which zirconium (IV) oxide, silicon (IV) oxide, and vanadium (IV) oxide in varying amounts are
homogeneously and ionically interdiffused to form a crystalline matrix of zircon. Basic chemical
formula: (Zr,V)SiO4. Its composition may include any one or a combination of the modifiers
alkali or alkaline earth halides. Use category A. Exceptionally suitable for coloring ceramic
glazes and clay bodies. Not generally used in porcelain enamels.
(b) MAGENTA based on the pink coral Fe-ZrSiO4 (CPMA number 14-44-5). CPMA describes the
zirconium iron pink (peach, coral) zircon, as an inorganic pigment, as a reaction product of high-
temperature calcination in which zirconium (IV) oxide, silicon (IV) oxide, and iron (III) oxide in
varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of
zircon. Basic chemical formula: (Zr,Fe)SiO4. Its composition may include any one or a combi-
nation of the modifiers alkali or alkaline earth halides. Use category A. Exceptionally suitable for
coloring ceramic glazes. Not generally used in clay bodies or porcelain enamels.
(c) YELLOW based on the yellow of praseodymium Pr-ZrSiO4 (CPMA number 14-43-4). CPMA
describes the zirconium praseodymium yellow zircon, as an inorganic pigment, as a reaction
product of high-temperature calcination in which zirconium (IV) oxide, silicon (IV) oxide, and
praseodymium (III, IV) oxide (Pr6O11) in varying amounts are homogeneously and ionically
interdiffused to form a crystalline matrix of zircon. Basic chemical formula: (Zr,Pr)SiO4. Its
composition may include any one or a combination of the modifiers alkali or alkaline earth
halides. Use category A. Exceptionally suitable for coloring ceramic glazes and clay bodies. Not
generally used in porcelain enamels.
(d) BLACK usually obtained from spinel structure in CPMA classification such as the ferrite
(Mg0,5Fe0,5)(Co0,5Fe1,4Cr0,1)O4 shown in Fig. 2d. CPMA describes the iron cobalt chromite
black spinel as an inorganic pigment and as a reaction product of high-temperature calcination in
which iron (II) oxide, cobalt (II) oxide, iron (III) oxide, and chromium (III) oxide in varying
amounts are homogeneously and ionically interdiffused to form a crystalline matrix of spinel.
Basic chemical formula: (Co,Fe)(Fe,Cr)2O4. Its composition may include any one or a
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FeNdO3 CrNdO3
unmineralised BaF2+MgF2 flux agent unmineralised BaF2+MgF2 flux agent
a powder optical lens view (x40)
NdFeO3
oo
Unmineralised
p p p p pp pp p p pp p p p p
BaF2+MgF2
20 30 40 50 60 º2Θ
c enamelled samples.
CIEL*a*b*=
d UV-Vis-NIR spectroscopy.
0,9
1
0,9 0,8
0,8 0,7
0,7 0,6
0,6 NdCrO3
NdFeO3 0,5
A
0,5
A
0,4
0,4
0,3 BaF2+MgF2 0,3
0,2 0,2 BaF2+MgF2
0,1 0,1
0 0
200 500 800 1100 1400 200 500 800 1100 1400
nm nm
Fig. 3 Samples fired at 1,200 C: (a) powder optical lens view (40), (b) DRX, crystalline phases. p(perovskite
MNdO3, M = Fe or Cr), o(neodymium oxide Nd2O3), (c) enameled samples, (d) UV-Vis-NIR spectroscopy
combination of the modifiers Al2O3, B2O3, CuO, MnO, NiO, or SiO2. Use categories A, B, and
C. Predominantly used for coloring category A substrates.
Adequate mixtures of above-described pigments may produce all range of visible colors, using
the subtractive color vision model CMYK (where C=cyan, M=magenta, Y=yellow, and K=key
associated to a mixture of C+M+Y which gives the black color) shown in Fig. 2b. in opposition to
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the additive color vision model RGB (R=red, G=green, B=blue) shown in Fig. 2c. Really the black
color is not necessary because it could be built mixing CMY, but in ink and paints, it is used in order
to simplify and to cheapen the printing manufacture. A detailed study of the CMY zircon pigments
can be found in several doctoral theses [4, 5]. Really the color given by CMY zircon pigments is
influenced by temperature and glaze or ceramic matrix; therefore usually a wider color palette must
be used on pigmenting ceramics.
A total of 44 chemical substances are listed in the CPMA classification referred exclusively to
industrial ceramic pigments. But the world of pigments is wider and, for example, on the industrial
classification, the main red colors do not appear: the unstable purple of Cassius discovered by
Johann Rudolph Glauber in 1659 and the sulfoselenide dated on 1909 and classified as harmful
substance due to cadmium presence. The reddish ceramic pigments have been during centuries the
driving force in the ceramic pigment field research [6]. The investigation on new host structures for
pigmenting also has received attention, but usually, searching the red shades.
As example, a new color alternative to classical zircon palette can be obtained from the perov-
skite, a new and versatile lattice for ceramic pigments not considered on CPMA classification of
industrial pigments. Neodymium perovskite pigments have been obtained by nonconventional
methods [7–9]. Red, blue, green, and gray ceramic pigments based on FeNdO3 perovskite
(unmineralized sample or using BaF2+MgF2 flux agent for red and blue pigments, respectively)
and CrNdO3 (unmineralized sample or using BaF2+MgF2 flux agent for green and gray pigments,
respectively) can be obtained by ammonia coprecipitation from a solution of NdCl3.6H2O,
FeCl3.6H2O, CrCl3.6H2O salts in water media.
Dried powders were successively fired at 1,000, 1,100, and 1,200 C during 6 h of soaking time,
and the obtained powders were 5 % enameled in a conventional glaze (1,050 C). Characterizations
of samples are shown in Figs. 3 and 4:
(a) Powder optical lens view (40) (Fig. 3a) shows red, blue, green, and gray color of the respective
perovskites.
(b) XRD (X-Ray Diffraction) analysis carried out on a diffractometer, using Cu Ka radiation, 20–70
2y range, scan rate 0.05 2y/s, 10 s per step, and 40 kV and 20 mA conditions, shows that
perovskite is the only crystalline phase detected in CrNdO3 samples, but residual Nd2O3 peaks
are always observed on FeNdO3 samples (Fig. 3b).
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Fig. 5 CrNdO3 fired at 1,100 C: (a) powder optical lens view (40), (b) enameled sample, (c) SEM micrograph of
powder (500 C), (d) SEM micrograph of powder (1,100 C)
(c) 5 w.% enameled samples in a conventional glaze (1,050 C) show the visual red, blue, green, and
gray color of the respective perovskite color associated to CIEL*a*b* color measurements
(Fig. 3c), which were measured following the CIE (Commission Internationale de l’Eclairage)
colorimetric method using a spectrophotometer, with standard lighting D65 (natural daylight)
and standard observer of 10 . On this method, L* is a measure of brightness (100=white,
0=black) and a* and b* of chroma (a*=green, +a*=red, b*=blue, +b*=yellow).
(d) UV-Vis-NIR (Ultraviolet-Visible-Near Infrared) spectroscopy of enameled samples, collected
using a spectrometer through diffuse reflectance technique, shows bands associated to Fe3+ in
octahedral coordination (in FeNdO3) or Cr3+ in octahedral coordination (in CrNdO3), respec-
tively, along with sharp bands associated to Nd3+ f-f transitions [12]. Samples with BaF2+MgF2
flux agent addition show similar bands to unmineralized samples, but the absorbance level
increases in the Vis-NIR range producing dark colors (dark blue and black color, respectively, on
Fig. 3c).
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a YV04 P P P P x=0.32
0.16
0.08
0.04
10 15 20 25 30 35 40 45 50 55 60 65 70
b 1.6
1.4
1.2
1 x=0.16
0.8
0.6 x=0.32 and 0.08
0.4
0.2 x=0.04
0
–0.2
200 400 600 800 1000 1200 1400 1600
wavelength (nm)
c
CE
The preparation method of ceramic pigment allows obtaining new and best ceramic pigments.
There are different new methods of preparing ceramic pigments that produce new microstructures
and solid solutions [1, 8].
Chemical methods as alternative to solid oxide reaction can be illustrated with above-discussed
CrNdO3 perovskite. A polyol route was used from NdCl3.6H2O and CrCl3.6H2O: salts were
dissolved in 200 ml of DEG (diethylene glycol) to prepare 5 g. of final product, then refluxed at
150 C during 2 h, and then charred at 500 C/1 h and fired at 1,100 C with soaking time of 6 h.
SEM micrograph of powders charred at 500 C shows aggregates of incipient cubes (Fig. 5c), well
developed in fired sample at 1,100 C (Fig. 5d). Powder develops, 5 w.% enameled in conventional
ceramic glaze (1,080 C), good black shades (L*a*b* = 50.5/0.6/1.0) without mineralizer
addition (compare Figs. 5b and 3c).
Therefore above neodymiums could be an example of alternative to cyan, pink, and black
pigments to the classical zircon color palette. Finally an alternative to yellow of praseodymium in
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Table 1 CIEL a*b* colorimetric coordinates for the CaxY2xVxSn2xO7 yellow pigments
Sample (x) L* a* b*
0.04 84.3 1.2 26.6
0.08 87.2 0.2 30.8
0.16 85.7 1.1 34.5
0.32 85.8 0.8 33.5
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(2–6 mm) is similar but more compact in CO sample and higher than in citrate powder (1–4 mm).
Also size of particles forming aggregates is higher for CE (500 nm) than for CO (300 nm) and higher
than CI powder (150 nm). Likewise SEM-EDX (Scanning Electron Microscopy-Energy Dispersive
X-Ray Spectroscopy) microstructural analysis of powders fired at 1,200 C (not shown) indicates
that codopants, vanadium, and calcium present a homogeneous distribution on samples. However
the global content of calcium is higher than vanadium, probably due to vanadium evaporation during
firing. Likewise the content of vanadium is slightly higher in CO and CE sample than in CI sample in
agreement with color intensity observed on glazed samples.
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Acknowledgments
Authors acknowledge the financial support given by FUNDACION CAJA CASTELLÓN-UJI,
P1-1B2010-09 project.
Cross-References
▶ CIELAB, L*, a*, b*; L*, C*ab, h
▶ Color Vision Model
▶ Colorant, Classification
▶ Dye, Inkjet
▶ Spectral and Color Rendering
References
1. (a) Monrós, G., Badenes, J.A., García, A., Tena, M.A.: El color de la Cerámica. Nuevos
mecanismos en pigmentos para los nuevos procesados de la industria cerámica, pp. 146–179.
Edited by Universitat Jaume I, ISBN 84-8021-449-X (2003). (b) R. A. Eppler Selecting
Ceramic Pigments. Am. Ceram. Soc. Bull. 66(11), 1600–1604 (1987) (c) Bucher, W., Schliebs,
R., Winter, G., Buchelin, K.H.: In: Industrial Inorganic Chemistry, VCH, Berlin (1989)
2. (a) CPMA: Classification and chemical description of the complex inorganic color pigments,
4th edn. Dry Color Manufacturers Association, Alexandria (2010) (b) DCMA: Safe Handling of
Color Pigments, Color Pigments Manufacturers Association Inc., 300 North Washington Street,
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