Beruflich Dokumente
Kultur Dokumente
SDS No.: 960239-001 (Version 2.3 ) Date 19.05.2014 (Cancel and replace : 16.05.2014)
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture : Anticaking agent for mineral based fertilisers and industrial ammonium nitrates.
Supplier CECA
Tensio-Actifs de Spécialités
Adresse postale : 89 Boulevard National
92250 LA GARENNE-COLOMBES
FRANCE
Téléphone: 01 49 00 38 00
Télécopie: 01 49 00 38 01
http://www.cecachemicals.com
+33 1 49 00 77 77
European emergency phone number : 112 (24/7)
National Chemical Emergency Centre Tel: 01865 407 333 (24/7)
2. HAZARDS IDENTIFICATION
Additional information:
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.
Hazard pictograms:
Hazard statements:
H304 : May be fatal if swallowed and enters airways.
H315 : Causes skin irritation.
H318 : Causes serious eye damage.
H373 : May cause damage to organs through prolonged or repeated exposure.
H410 : Very toxic to aquatic life with long lasting effects.
Precautionary statements:
Prevention:
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P314 : Get medical advice/ attention if you feel unwell.
P331 : Do NOT induce vomiting.
Disposal:
P501 : Dispose of contents/ container to an approved waste disposal plant.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
1
Chemical nature of the mixture :
Preparation based on fatty amines derivatives.
M-Factor Acute = 10
M-Factor Chronic = 1
Distillates (petroleum), solvent-dewaxed heavy paraffinic 265-169-7 64742-65- > 40 % Xn; R65 AH 1; H304
0 Nota L: DMSO Nota L: DMSO <3%
<3%
M-Factor Acute = 10
Alkylamine derivatives 263-089-7 61789-79- < 20 % N; R50 Aquatic Acute 1; H400
5 Xi; R38 Aquatic Chronic 2; H411
Xi; R41 Skin Irrit. 2; H315
Eye Dam. 1; H318
M-Factor Acute = 10
Nitriles – 61790-29- <5% Xi; R38 Skin Irrit. 2; H315
2 N; R50/53 Aquatic Chronic 1; H410
M-Factor Chronic = 10
1
: See chapter 14 for Proper Shipping Name
2
:See the text of the regulation for applicable exceptions or provisions : The transition time according to REACH Regulation, Article 23, is still
not expired.
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.
4.1. & 4.2. Description of necessary first-aid measures & Most important symptoms/effects, acute and delayed:
General advice:
Take off immediately all contaminated clothing. Wash contaminated clothing before re-use.
Inhalation:
Move to fresh air. Oxygen or artificial respiration if needed. Keep under medical surveillance. In case of persistent problems : Hospitalise.
Skin contact:
Wash off immediately with soap and plenty of water.
Eye contact:
Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately.
Ingestion:
Do NOT induce vomiting. Consult a physician. Risk of severe pulmonary problems in case of accidental aspiration.
5. FIREFIGHTING MEASURES
5.1.Extinguishing media
Suitable extinguishing media: Foam, carbon dioxide, dry powder extinguishers., Use suitable means to extinguish
neighbouring fires.
Specific methods:
In case of fire nearby, remove exposed containers. Collect contaminated fire extinguishing water separately. This must not be discharged into
drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Cool closed
containers exposed to fire with water spray. Ensure a system for the rapid emptying of containers.
Recovery:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Sweep up to
prevent slipping hazard.
Elimination:
Dispose of in accordance with local regulations.
Technical measures/Precautions:
Provide water supplies and ocular fountains near the point of use. Provide a catch-tank in a bunded area.
Hygiene measures:
See heading 4.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.
Packaging material:
Recommended: Stainless steel, Steel drum
To be avoided: Aluminium and copper alloys.
Appearance:
Physical state (20°C): liquid
Colour: beige, According to grade
Odour: No data available.
Olfactory threshold: No data available.
pH: Not applicable
pour point : > 20 °C
Boiling point/boiling range: No data available.
Flash point: > 150 °C (Standard NF T 60 103)
Evaporation rate: No data available.
Flammability (solid, gas):
Flammability: Not relevant
Vapour pressure: No data available.
All available data on this product and/or the components quoted in section 3 and/or the analogue substances/metabolites have been taken
into account for the hazard assessment.
11.1. Information on toxicological effects:
Acute toxicity:
Inhalation: Based on available data, the classification criteria are not met. Slightly or not harmful by
inhalation
Ingestion: Based on available data, the classification criteria are not met. Slightly or not harmful by
ingestion
Dermal: Based on available data, the classification criteria are not met. Slightly or not harmful in
contact with skin
Eye contact: According to its composition, can be considered as : Causes serious eye damage.
ALKYLAMINES :
Risk of serious damage to eyes. (OECD Test Guideline 405)
Inhalation: Based on available data, the classification criteria are not met. not a respiratory sensitizer
Skin contact: Based on available data, the classification criteria are not met. Not a skin sensitizer
CMR effects :
Mutagenicity: Results from tests do not lead to considering the product as genotoxic
Carcinogenicity: Based on the available data, the substance is not suspected of having carcinogenic potential
Reproductive toxicity:
Fertility: Based on the available data, the substance is not suspected of having reprotoxic potential.
Foetal development: Based on the available data, the substance is not suspected of having developmental toxicity
potential.
Inhalation: Based on available data, the classification criteria are not met.
Repeated exposure: The substance or mixture is classified as specific target organ toxicant, repeated exposure,
category 2.
Aspiration hazard: According to its composition, can be considered as : , May be fatal if swallowed and enters airways.
Ecotoxicology Assessment: According to its composition, can be considered as : Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment. Do not dispose large quantities into the natural or
aquatic environment.
12.1. Toxicity :
Aquatic invertebrates:
ALKYLAMINES :
EC50, 48 h (Daphnia) : 0,011 mg/l (Method: OECD Test Guideline 202)
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC :
EC50, 48 h (Daphnia magna (Water flea)) : > 1.000 mg/l (Method: OECD Test Guideline 202) No effect
up to the limit of solubility
Aquatic plants:
ALKYLAMINES :
NOEC, 96 h (Algae) : 0,008 mg/l (Method: OECD Test Guideline 201)
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC :
EC50, 96 h (Desmodesmus subspicatus (green algae)) : > 1.000 mg/l No effect up to the limit of
solubility
ALKYLAMINE DERIVATIVES :
ErC50, 72 h : 0,0177 mg/l
Microorganisms:
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC :
EC20, 6 h (Pseudomonas putida) : > 1.000 mg/l
Aquatic invertebrates:
ALKYLAMINES :
NOEC, 21 d (Daphnia) : 0,013 mg/l (Method: OECD Test Guideline 211, reproduction)
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC :
NOEC, 21 d (Daphnia magna (Water flea)) : > 1.000 mg/l (Method: OECD Test Guideline 202 - Part 2,
Reproduction inhibition)
Biodegradation (In water): Based on the available information, it is not possible to conclude on the hasard potential of
this mixture.
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC :
Not readily biodegradable.
6 % after 28 d (Method: OECD Test Guideline 301 B)
ALKYLAMINES :
Readily biodegradable
ALKYLAMINE DERIVATIVES :
Readily biodegradable
75 % after 28 d (Method: OECD Test Guideline 301 F)
Global warming potential (GWP): Not relevant (due to the chemical structure)
Disposal of product: The product should not be allowed to enter drains, water courses or the soil. Incinerate in suitable
incineration plant, observing local authority regulations.
UN Environmentally
Regulation
number
Proper shipping name Class Label PG
hazardous
Other information
ENVIRONMENTALLY HAZARDOUS yes
ADR 3082 9 9 III
SUBSTANCE, LIQUID, N.O.S.(Alkylamines)
ADN 3082 ENVIRONMENTALLY HAZARDOUS 9 9 III yes
SUBSTANCE, LIQUID, N.O.S. (Alkylamines)
RID 3082 ENVIRONMENTALLY HAZARDOUS 9 9 III yes
SUBSTANCE, LIQUID, N.O.S. (Alkylamines)
IATA Cargo 3082 Environmentally hazardous substance, liquid, n.o.s. 9 9MI III yes
(Alkylamines)
IATA Passenger 3082 Environmentally hazardous substance, liquid, n.o.s. 9 9MI III yes
(Alkylamines)
IMDG 3082 ENVIRONMENTALLY HAZARDOUS 9 9 III Marine pollutant EmS Number: F-A, S-F
SUBSTANCE, LIQUID, N.O.S. (Alkylamines) Mark: MP
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture:
Listed in:
EU. REACH, Annex XVII, Marketing and Use Restrictions (Regulation 1907/2006/EC): Distillates (petroleum), solvent-dewaxed heavy
paraffinic; Baseoil - unspecified: Lubricating oils; Baseoil - unspecified: Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -
unspecified
UK REGULATION Chip3: Chemical (Hazard Information and Packaging for Supply) Regulations 2002
INVENTORIES:
EINECS: Conforms to
TSCA: Does not conform
AICS: Does not conform
DSL: This product contains one or several components that are not on the Canadian DSL nor NDSL lists.
ENCS (JP): Does not conform
KECI (KR): Does not conform
PICCS (PH): Does not conform
IECSC (CN): Does not conform
Update:
Thesaurus:
NOAEL : No Observed Adverse Effect Level (NOAEL)
LOAEL : Lowest Observed Adverse Effect Level (LOAEL)
bw : Body weight
food : oral feed
dw : Dry weight
vPvB : very Persistent and very Bioaccumulative
PBT : Persistent, Bioaccumulative and Toxic
This safety data sheet complies with international standard ISO 11014-1. In case of formulations or mixtures, it is necessary to ascertain that a
new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite
sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet
shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice
documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official
documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass
on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the totality
of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of
environment.
NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).