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Chemical Admixtures
Presentation by-
Ketan Sompura, Ph.D
Sika Corporation
Construction Admixtures
Admixtures are those ingredients in concrete other than
cement, water, and aggregates that are added to the
mixture immediately before or during mixing to give the
concrete special properties.
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Construction Reasons For Using Admixtures
S Increase Strength
S Improve Mix Workability
S Improve early strengths
S Control set time
S Reduce Permeability
S Control Efflorescence
S Improve Color Vibrancy
S Meet Durability Requirements
S Control Shrinkage
S Improve mix economics
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Construction Admixture Types
S Water-Reducers
S Accelerators
S Retarders
S Air Entrainment
S Specialty
SViscosity Modifiers
SCorrosion Inhibitors
SAnti Wash-out
SASR Controlling
SShrinkage Reducers
SWater-Repellent Admixtures...etc
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Construction ASTM Classification of admixtures
S ASTM C 494
S Type A – Water reducer
S Type B – Retarding admixture
S Type C – Accelerating admixture
S Type D – Water reducing and retarding
S Type E – Water reducing and accelerating
S Type F – High range water reducer
S Type G – High range water reducing and
retarding admixture
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Construction Water Reducers
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Construction Water Reducers
S Definition as per ACI 116.R-2:
Admixtures that either increase slump of freshly-mixed
mortar or concrete without increasing water content OR
maintain slump with a reduced amount of water, the effect
being due to factors other than air entrainment.
S Benefits:
S Increase in strength
S Increase in workability
S Cement reduction
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Construction Water Reducer- Types
SLignosulfonates
SNaphthalene based (SNF)
SMelamine based (SMF)
SVinyl Copolymers
SPolycarboxylate based
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Construction
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Water/Cement System Without a Water
Construction Reducing Admixture
Further growth of hydration products
CEMENT GRAINS will cause stiffness and LOSS OF
WORKABILITY
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Construction Mechanism of Action for a Conventional
Water Reducing Admixture
Dispersant
molecules Dispersion
caused by electrostatic
repulsion
decrease of the W/C ratio
Cement particles
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Construction Mechanism of Polycarboxylate-
Based Admixtures
S Dual mechanism of
S Electrostatic Repulsion
S Steric Hinderence
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Construction Mechanism of Action for a Polycarboxylate
based Water Reducing Admixture
Dispersion
Polycarboxylate dispersant molecules
caused by electrostatic repulsion
and steric hindrance
decrease of the W/C ratio
Cement particles
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Polycarboxylate
Construction Conventional Water
Reducer Water Reducer
2L
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Construction
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Construction General Definition
Accelerators
▲ Increase the rate of hydration of the cement
▲ Reduce the set time of concrete
▲ Increase the early age strength of concrete
Retarders
▲ Slows down the rate of hydration of cement
▲ Increases the time of set
▲ Slow down the rate of early age strength development
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Construction Accelerators
Accelerator Faster Set Time
Control
Set time
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Construction Accelerators
Uses
▲ In cold weather, to avoid concrete from freezing when it is
plastic or/and to maintain normal setting behavior and strength
development.
▲ To increase productivity (faster stripping of formwork)
▲ Compensate for the delay in set or strength gain due to use
of SCMs such as Fly ash or Slag.
▲ Rapid repair of pavement sections
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Construction Accelerator - Types
▲ Soluble Inorganic salts Chlorides Triethalomine
▲Soluble Organic Compounds Bromides Calcium
Formate
▲Quick setting admixtures Fluorides
Urea, Oxalic
▲Miscellaneous solid admixtures. Carbonates
acid
Thiocynates
Lactic acid
Aluminates Silicates Nitrites, Nitrates
Compounds
Carbonates Carbonates Thiosulfates, of amines
Silicates, and
Silicates
Aluminates and formaldehyde
alkali hydroxides
Cement Compounds:
C3S, C2S, C3A, C4AF
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Construction Calcium Chloride
▲ One of the most effective accelerators known.
Disadvantages
▲ Potential for corrosion
▲ Acceleration of Alkali Silica reaction
▲ Reduction in freeze thaw and sulfate resistance
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Hardening Accelerator /
Construction Strength Accelerator
Advantages:
S Increases high early strength, but may not significantly
influence the time of set.
S Enables addition of accelerator at the plant rather than
addition at site
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Factors influencing accelerator
Construction performance
▲ Ambient temperature
▲ Concrete temperature
▲ Requirements of early set and strength
▲ Accelerator dosage
▲ Cement content, Cement Type, SCM
▲ W/Cm
▲Testing method
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Construction Retarders
▲ Slows down the rate of hydration of cement
▲ Increases the time of set
Uses
▲ Reduces faster slump loss during hot weather.
▲ Enables longer haul times
▲ Delays set time, allows time for finishing operations
▲ Reduces temperature of concrete at early stages
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Construction Retarders
Retardation Delayed Set Time
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Construction Retarders - Types
▲Sugar derivatives
▲Hydroxycarboxylic acid
▲Lignosulphonates
▲Tartaric acid and salts
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Construction Hydration Control admixture
S Applications:
S High retardation or long slump life
S Returned concrete
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Factors influencing performance of
Construction retarders
▲ Ambient temperature
▲ Concrete temperature
▲ Control concrete (slump)
▲ Cement content, Cement type, SCM
▲ W/Cm
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Construction
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Why do we use Air Entraining
Construction Admixtures (AEA’s) ?
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Construction QUIZ QUESTION :
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Construction ANSWER :
SDuring freezing process,
water increases its
volume up to 9%.
SPressure developed
during this volume
change reaches up to
200MPa (29 000psi)
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Construction Freeze thaw conditions
Freezing temperatures are not always detrimental for
concrete. To observe freeze thaw damage,
following two conditions must be fulfilled.
⇓
PRESSURE
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Construction How do AEA’s work?
S When temperatures surrounding concrete decreases below
the freezing point of water, water present in pores and
capillaries of concrete starts to freeze and expand.
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Construction What does entrained air voids do in
concrete?
S If air content increases 1%, then compressive
strength decreases about 5%
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Construction
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Construction Specialty products
SAnti-washout and viscosity modifying
admixture
SShrinkage Reducing admixture
SCorrosion inhibitors
SASR mitigation admixture
SAdmixture for Pervious Concrete
SFlowable Fill admixture (CLSM)
SSurface Retarder
SFinishing Aid
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Anti- Washout Admixtures &
Construction Viscosity Modifying Admixtures
How they work:
S Water soluble cellulose ether or acrylic type polymers
S They increase the viscosity of water in the mix.
S This results in increased thixotropy and improved resistance
to segregation
Applications:
S Under water concreting
S Self Compacting concrete
S Increase cohesion in case of gap graded aggregate mixes.
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Anti- Washout Admixtures &
Construction Viscosity Modifying Admixtures
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Construction
Shrinkage Reducing Admixtures (SRA)
S Drying Shrinkage:
S Loss of moisture from
hardened concrete surface
S Volume of concrete reduces
and it shrinks
S Water in capillary exerts
forces on capillary wall
How Shrinkage reducing admixtures work:
S Reduces surface tension of the liquid
S Forces on the wall are reduced
Concrete
S Less Shrinkage
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Construction Corrosion Inhibitors types
SCalcium Nitrite based
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Construction Calcium Nitrite based
S A layer of Ferric oxide protects the steel from corrosion in
concrete
S This layer can be damaged by carbonation or chloride
ingress, which can lead to corrosion.
S Calcium nitrite admixture fortifies the ferric oxide passivating
layer
S Thereby protects steel from corroding
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Construction Migratory corrosion inhibitors
S Dual mechanism
S Migrating inhibitor – Penetrates through the concrete to
the steel reinforcement and gets absorbed on the surface
S Displaces chloride ions from steel surface and forms a
continuous film
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Alkali silica reaction mitigating
Construction admixture
Lithium Nitrate based admixture
z What is ASR?
Alkali’s + Reactive Silica ASR Gel
(Na, K from (Aggregates)
Cement)
Cracks Concrete
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Construction ASR mitigating admixture
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Construction Pervious concrete
A concrete
- that contains little or no sand
- which forms a system of highly
permeable and interconnected voids
- allows 3-8 gallons of water per
minute to pass through 1 sq.ft
Typical Properties:
Compressive strength – 500 – 4000 psi
Voids – 15 to 25%
Unit weight – 100 to 125 pcf
Permeability – 3 to 8 gallons/ minute per
sf.ft
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Construction Pervious concrete admixture
Benefits:
S Improves aggregate to cement paste bond
S Improves Strength and workability
S Aids discharge from truck, easy to place
S Reduces bleeding and improves cohesion
S Dosage : 10 – 25 liter / m3
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Construction Flowable fill admixture
Uses:
S To produce controlled low strength materials (CLSM)
used as flow able fill
Application:
S Use 454 gram bag (1 lb) to produce 0.77 m3 (1 cyd)
of CLSM
S Add all mix ingredients and mix for 5-7 minutes.
S Material volume increases by 25 to 35%.
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Construction Surface Retarding admixture
Applications:
S Exposed aggregate surface for architectural purposes
S Used when concreting done in layers to improve mechanical
key
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Construction Finishing aid admixture
Benefits:
S Enhances finish on concrete flatwork
S Eliminates addition of water to aid finishing
S Prevents plastic shrinkage cracking
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Construction
Admixtures for Manufactured
concrete products
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Construction
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Construction MCP Applications
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Construction MCP Applications
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Construction MCP Applications
SConcrete Pipe
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Construction MCP Applications
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Construction MCP Applications
S Concrete Pavers
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Construction MCP Applications
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Construction MCP Applications
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Construction Why use admixtures for MCP products?
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MCP Admixtures
Construction
S Plasticizers
S Accelerating Plasticizers
S Accelerators
S Water-Repellent
Admixtures
S Efflorescence-Controlling
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Construction
Thank you...............
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