ANSWER KEY

EXERCISE # I

Q.1 C Q.2 B Q.3 D Q.4 C Q.5 C Q.6 B Q.7 C

Q.8 C Q.9 B Q.10 C Q.11 D Q.12 B Q.13 D Q.14 D

Q.15 C Q.16 C Q.17 B Q.18 D Q.19 C Q.20 B Q.21 C

Q.22 B Q.23 A Q.24 B Q.25 1s2 2s2 2p6 3s2 3p6 3d1 4s2 Q.26 A

Q.27 C Q.28 B Q.29 A Q.30 C Q.31 B Q.32 C Q.33 B

Q.34 C Q.35 C Q.36 C Q.37 C

EXERCISE # II

Q.1 B,C,D Q.2 B,C Q.3 B,C,D Q.4 A

Q.5 B Q.6 A Q.7 (A) R, (B) P,S (C) S (D) Q,S

Q.8 (A)P,Q,R (B) P (C) P,Q,R Q.9 (A) Q (B) S (C) P (D) R

Q.10 A Q.11 A,D Q.12 B,C

[8]
Assertion Reason :

Q.4 Statement-1 : The groundstate configuration of Cr is [Ar] 3d54s1

Statement-2 : The energy of atom is lesser in 3d5 4s1 configuration compared to 3d4 4s2 configuration.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

Q.5 Statement-1 : Li and Mg shows diagonal relationship.

Statement-2 : Li and Mg are diagonal to each other in the periodic table.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

Q.6 Statement-1 : Minimum principal quantum number of an orbital belonging to 'g' sub-shell
is 5.
Statement-2 : For a given value of principal quantum number (n), l may have values 0 to
(n–1) only.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
Match the column :

Q.7 Match the following :

Column I Column II
(A) C12H22O11 (P) 8 NA atoms / mol
(B) CH3COOH (Q) 14 × NA atoms / mol
(C) Ca(OH)2 (R) 45 NA atoms / mol
(D) CH3COOC2H5 (S) 2 NA of O-atoms / mol

Q.8 Match the following:

Column I Column II
(A) Same number of unpaired (P) Na+, Mg2+, F¯
electrons are present in

(B) Same number of electron (Q) F¯, Mg, O2–

in s & p subshells.

(C) Same number of electrons with (R) Mg, Ne, O2–

the l = 1

[6]
Q.24 112.0 ml of NO2 at 1atm & 273 K was liquefied, the density of the liquid being 1.15 gm/ml. Calculate
the volume of and the number of molecules in the liquid NO2.
(A) 0.10 ml and 3.01 × 1022 (B) 0.20 ml and 3.01 × 1021
(C) 0.20 ml and 6.02 × 10 23 (D) 0.40 ml and 6.02 × 1021

Quantum number

Q.25 A neutral atom of an element has two K, eight L, nine M and two N electrons then electronic configuration
of the element is __________.

Q.26 Correct set of four quantum numbers for valence electron of rubidium( Z = 37) is
1 1 1 1
(A) 5, 0, 0, + (B) 5, 1, 0, + (C) 5, 1, 1, + (D) 6, 0, 0, +
2 2 2 2

Q.27 The correct set of quantum numbers for the unpaired electron of chlorine atom is
n l m n l m
(A) 2 1 0 (B) 2 1 1
(C) 3 1 1 (D) 3 0 0

Q.28 The total number of neutrons in dipositive zinc ions with mass number 70 is
(A) 34 (B) 40 (C) 36 (D) 38

Q.29 Principal quantum number of an atom represents

(A) Size of the orbital (B) Spin angular momentum
(C) Orbital angular momentum (D) Space orientation of the orbital

Q.30 Which of the following sets of quantum numbers represent an impossible arrangement
n l m ms n l m ms
1 1
(A) 3 2 –2 (B) 4 0 0
2 2
1 1
(C) 3 2 –3 (D) 5 3 0
2 2

Q.31 The explanation for the presence of three unpaired electrons in the nitrogen atom can be given by
(A) Pauli’s exclusion principle (B) Hund’s rule
(C) Aufbau’s principle (D) None of these

Q.32 The maximum number of electrons that can be accommodated in the Mth shell is
(A) 2 (B) 8 (C) 18 (D) 32

Q.33 Which quantum number will determine the shape of the subshell
(A) Principal quantum number (B) Azimuthal quantum number
(C) Magnetic quantum number (D) Spin quantum number

Q.34 Which of the following has maximum number of unpaired electron (atomic number of Fe 26)
(A) Fe (B) Fe (II) (C) Fe (III) (D) Fe (IV)

[4]
 EXERCISE # I
Atomic weight
Q.1 One atomic mass unit in kilogram is
(A) 1/NA (B) 12 / NA (C) 1/1000 NA (D) 1000 / NA

Q.2 The number of g-atoms of nitrogen in its 7 gm is equal to number of g-atoms in

(A) 6 gm Mg (B) 28 gm Fe (C) 30 gm Ca (D) 20 gm Hg

Q.3 2 isotopes of an element are present in 1 : 2 ratio of number, having mass number M and (M + 0.5)
respectively. The mean mass number of element will be
(A) 3M + 1 (B) 1.5 M + 0.5 (C) 0.5 M + 0.5 (D) None of these

Q.4 A sample of nitrogen contains 90% N14 and 10% N15 isotopes. The average number of neutron
per atom is
(A) 14.10 (B) 7.05 (C) 7.10 (D) 14.20

Q.5 From 2 mg calcium, 1.2 × 1019 atoms are removed. The number of g-atoms of calcium left is
(A) 5 × 10–5 (B) 2 × 10–5 (C) 3 × 10–5 (D) 5 × 10–6

Q.6 Three isotopes of an element have mass numbers M, (M+1) and (M+2). If the mean mass number is
(M + 0.5), then which of the following ratio of number may be accepted for M, (M+1) and (M+2) in the
order
(A) 1 : 1 : 1 (B) 4 : 1 : 1 (C) 3 : 2 : 1 (D) 2 : 1 : 1

Molecular weight

Q.7 The number of electron in 3.1 mg NO3¯ is

(A) 32 (B) 1.6 × 10–3 (C) 9.6 × 1020 (D) 9.6 × 1023

Q.8 The number of neutrons in 0.45 g water, assuming that all the hydrogen atoms are H1 atoms and all the
oxygen atoms are O16 atoms, is
(A) 8 (B) 0.2 (C) 1.2 × 1023 (D) 4.8 × 1024

Q.9 A gaseous mixture contains CO2 (g) and N2O (g) in a 2 : 5 ratio by mass. The ratio of the number of
molecules of CO2 (g) and N2O (g) is
(A) 5 : 2 (B) 2 : 5 (C) 1 : 2 (D) 5 : 4

Q.10 Number of oxygen atoms present in 1.61 gm of Na2SO4.10H2O is equal to number of atoms in
(A) 3.0 gm C2H6 (B) 18.0 gm C6H12O6
(C) 0.98 gm H2SO4 (D) 8.0 gm SO3

Q.11 Which of the following contain largest number of carbon atoms?

(A) 15 gm ethane, C2H6 (B) 40.2 gm sodium oxalate, Na2C2O4
(C) 72 gm glucose, C6H12O6 (D) 35 gm pentene, C5H10

Q.12 If the mass of proton is doubled and that of neutron is halved, the molecular weight of CO2, consisting
only C12 and O16 atoms, will
(A) not change (B) increase by 25% (C) decrease by 25% (D) increase by 50%

[2]