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an accurate description of the pore geometry and fluid function of the water saturation only. The water relative
properties is not possible. permeability for displacements where the water saturation is
Stone’s empirical models, and others developed before increasing may be different from cases where the water
recent studies of three-phase flow, suffer from three major saturation is decreasing. Experimentally it has been found that
limitations. First, they were developed for water-wet media that the water relative permeability is a function of its own
but are applied to reservoir rocks, which are rarely water-wet. saturation, but the effect of hysteresis, or the direction of
Although Stone1,2 discussed extensions to oil-wet media we saturation change, is small.3,7
will show that some of the assumptions made in this analysis The gas is the most non-wetting phase and occupies the
were wrong. Second, the models fail to account for the largest pores. Again we could assume that the gas relative
trapping of oil and gas for any displacement sequence. Larsen permeability is a function of gas saturation only. Although the
and Skauge21 extended Stone’s model I to allow for gas experimental evidence is not so clear, the consensus is that this
trapping during repeated WAG cycles. Jerauld22 presented a approximation is valid, although several experiments have
model for Prudhoe Bay relative permeability that accounted shown large differences between the relative permeabilities for
for oil and gas trapping. We will use a modification of these the gas saturation increasing and for the gas saturation
approaches. Third, the functional form of the relative decreasing.4,7
permeability at low oil saturation, often the regime of greatest In three-phase flow, oil being intermediate-wet, occupies
interest for enhanced oil recovery projects and contaminant the intermediate sized pores. Empirical models predict the
clean-up, disagrees with recent experimental results. three-phase relative permeability, kro, as a function the oil
We will develop a model that overcomes the limitations relative permeability in the presence of water only, kro(w), and
listed above. It is based on saturation-weighted averages of the oil relative permeability in the presence of gas (and
the two-phase relative permeabilities, which was first normally irreducible or connate water), kro(g). Unfortunately,
suggested by Baker3 and shown by him in a thorough review however, there is no two-phase experiment that reproduces the
of the literature to be superior to Stone’s models. Saturation- pore occupancy of the three-phase case — for oil/water
weighted interpolation is applied to all three phases, as displacements the oil is in the largest pores, whereas for
suggested by Hustad and Hansen.23 We will include gas and gas/oil displacements, the oil is in the smaller pores.
oil trapping based on the work of Land24 and Carlson,25 which Considering more realistic distributions of pore occupancy
enables three-phase relative permeability to be estimated for controlled by different wettabilities does not alter this
any saturation path. We will also introduce a model for oil conclusion — there is no definitive way to estimate three-
layer drainage that allows the oil relative permeability to be phase relative permeability from two-phase data. Thus any
extrapolated to low saturation. The model is extended to empirical model, without exception, will be making at best an
ensure smooth changes in relative permeability with changing estimate of relative permeability, and can never replace direct
oil and gas composition, and to give the correct limits to the measurement, or a more physical approach using network
oil and gas relative permeabilities for miscible flow. The modeling.
model is then successfully tested against the extensive three-
phase data of Oak et al.4,5 Stone’s Models I and II
To motivate this work, we first discuss pore occupancy to Stone1,2 proposed two empirical three-phase relative
demonstrate the difficulty of predicting three-phase relative permeability models. He assumed that the porous medium
permeability, introduce Stone’s models and saturation- was water-wet and that the water and gas relative
weighted interpolation, and then review the recent permeabilities are functions only of their own saturations.
experimental literature on three-phase flow. An analysis of The Stone I model1 assumes that the water and gas block
these experiments leads us to develop an extension of the flow of the oil phase, and that the degree of blocking is
saturation-weighted interpolation that accounts for different computed from the two-phase relative permeabilities. The
wettabilities, oil and gas trapping, and layer flow. version of the Stone I model normally used in simulators was
proposed by Aziz and Settari26 and includes a normalization to
Pore Occupancy in Three-Phase Flow ensure that the model reduces smoothly to the two-phase data
Fig. 1 is a schematic histogram of pore occupancy in a water- when Sg = 0, or Sw = Swi:
wet medium. Fig. 1(a) shows the pore occupancy for a two-
S oe k ro ( w) k ro ( g )
phase oil/water displacement. This may be a primary k ro =
drainage, imbibition or secondary drainage experiment. Fig. (
k ro( wi ) (1 − S we ) 1 − S ge ) …………..………………(1)
1(b) is for a gas/oil displacement. This is usually primary
drainage of gas into oil and initial (irreducible) water Swi. where:
The water, being the most wetting phase, occupies the S o − S om
smallest pores, regardless of whether oil and/or gas is present. S oe = ………………………………….…(2)
1 − S wi − S om
Hence it is assumed that the water relative permeability is a
SPE 56474 AN EMPIRICAL MODEL FOR THREE-PHASE RELATIVE PERMEABILITY 3
(a) (b)
Number Number
of pores of pores
Oil Oil Gas
Water
Pore size Pore size
(c)
Number
of pores
Oil
Water Gas
Pore size
Fig. 1• A schematic of the pore occupancy for a water-wet medium. (a) For two-phase oil/water displacements, the water resides in the
smallest pores, while oil is in the largest pores. (b) For two-phase gas/oil displacements (even with irreducible water present, which is not
indicated for clarity), oil occupies the smaller pores and gas the largest pores. (c) In three-phase flow, water is still in the small pores, and
gas in the large pores. This indicates that the water and gas relative permeabilities are functions of only their own saturation. The oil
occupies the intermediate-sized pores, indicating that the oil relative permeability is a function of two saturations and that no empirical model
based on two-phase data can exactly predict the oil relative permeability for three-phase flow.
When Eq. (7) predicts kro < 0, the relative permeability is set to
S w − S wi
S we = ……………………………………(3) zero. The oil relative permeabilities are measured at the oil
1 − S wi − S om saturations given for model I.
Fayers and Matthews7 studied seven three-phase
Sg experiments and showed that overall Stone’s I model with Som
S ge = …………………………………....(4) given by Eq. (5) was superior to Stone II. Later Fayers27
1 − S wi − S om
proposed other equations for Som to improve the match
kro(wi) is the oil relative permeability measured at irreducible between Stone’s model I and experiment.
water saturation with no gas present. kro(w) is computed at So =
1 - Sw, and kro(g) is computed at So = 1 - Sg - Swi — at different Saturation-Weighted Interpolation
oil saturations than in the three-phase situation being Baker3 used saturation-weighted interpolation between the
predicted. two-phase values to find the three-phase oil relative
Som is the three-phase residual oil saturation. Fayers and permeability:
(S w − S wi )k ro( w) + (S g − S gr )k ro( g )
Matthews7 suggested the form:
S om = λS orw + (1 − λ )S org ……………………….……...(5) k ro =
(S w − S wi ) + (S g − S gr )
……………..(8)
where:
where Sgr is the residual gas saturation in the two-phase
Sg oil/water experiment (normally zero since the oil/water
λ =1− …………………………………..(6) displacement is performed without any gas present). In Eq.
1 − S wi − S org
(8) the two-phase relative permeabilities are computed at the
Sorw is the residual oil saturation in the presence of water and three-phase oil saturation.
Sorg is the residual oil saturation in the presence of gas and In Stone’s models it is assumed that krw = krw(o) and krg =
irreducible water. krg(o). However, we could test this assumption by measuring
The Stone II model2 is based on an assumption of the two-phase gas/water relative permeabilities, krw(g) and krg(w)
segregated flow and does not require a residual oil saturation (in the presence of an initial oil saturation Soi, which is
to be defined: normally zero since the gas/water displacement is performed
( )(
k ro = k ro ( w) + k ro( wi ) k rw( o ) k ro ( g ) + k ro ( wi ) k rg ( o ) ) with no oil present). There is no guarantee that krw(g) = krw(o),
and krg(o) = krg(w). Indeed, as we show later, this will not be
(
− k ro( wi ) k rw( o ) + k rg ( o ) ) ….…(7)
4 M.J. BLUNT SPE 56474
true for oil-wet media. To account for this, a simple extension used the same method to study the effects of spreading
of Eq. (8) gives: coefficient and wettability. It is difficult to use these two
papers to assess the accuracy of three-phase relative
(S o − S oi )k rw(o) + (S g − S gr )k rw( g )
permeability models since the two-phase gas/oil relative
k rw = permeabilities are not compared with three-phase data.
(S o − S oi ) + (S g − S gr )
…………......(9)
However, their results could be predicted from a fractal model
of the pore space, using information obtained from capillary
(S w − S wi )k rg ( w) + (S o − S oi )k rg (o) pressure measurements.31
k rg = …………….(10)
(S w − S wi ) + (S o − S oi ) Norwegian Studies. Skauge et al.32 and Eleri et al.33 used
gamma-ray emission from tracers to image saturation
Stone vs. Saturation-Weighted Relative distributions during three-phase displacements in water-wet
Permeabilities sandstones. They studied the impact of initial water saturation
An exhaustive literature review by Baker3 compared the on oil recovery and the effects of hysteresis. Their work was
prediction of three-phase relative permeability for eight sets of the inspiration for Larsen and Skauge21 who proposed a new
data on water-wet media using 12 different empirical empirical model for gas relative permeability to account for
correlations. He concluded that the Stone models performed gas trapping and hysteresis.
poorly, while saturation-weighted interpolation gave the best Nordvedt et al.34 used X-ray scanning to image three-
agreement. Further work by the same group at Amoco5,28 also phases during gas injection into chalk samples. Relative
demonstrated inaccuracies in Stone’s models. Delshad and permeabilities were obtained by using an optimization method
Pope8 compared seven empirical three-phase relative to match the measured saturations to those obtained from a
permeability models against three experiments. Again they reservoir simulator. Again it is not clear if this process is
showed that saturation-weighted interpolation was superior to unique. While there was considerable scatter in their data, the
Stone’s models. They obtained even better agreement by oil relative permeability was, to within experimental error, the
using a model due to Pope that had a free parameter to match same as the two-phase oil/water curve. Stone’s model I gave
the data in the three-phase region. However, this model did poor predictions of recovery.
not so well in the (usual) case where the three-phase data are
not used in the predictions. Grader and O’Meara. Grader and O’Meara35 studied gas
In summary Baker,3 and Delshad and Pope8 have provided injection into different initial oil saturations in a bead pack
excellent and definitive reviews of the literature which reach a using analogue fluids with low interfacial tensions to minimize
clear conclusion — Stone’s models sometimes give poor end effects. They used a modified JBN analysis to calculate
predictions, while saturation-weighted interpolation is the best the relative permeabilities. To within experimental error the
model presently available. It makes sense therefore to use three-phase oil relative permeability for these drainage
saturation-weighted interpolation as the basis of our empirical displacements was a function of only the oil saturation. This
model. implies that a single two-phase gas/oil displacement with
irreducible water could be used to predict three-phase data for
Review of Recent Three-Phase Data gas injection.
We will now review the experimental literature published after
Baker’s study. These data sets will form the basis of later Winfrith Group. Naylor et al.36 used a radioactive tracer
discussion of layer drainage and oil trapping. Table 1 technique to measure in-situ saturation distributions in water-
summarizes the results presented here. wet Clashach sandstone during a three-phase displacement.
Relative permeabilities were calculated from these saturations,
Work from the Institut Français du Pétrole. Kalaydjian et assuming that the capillary pressure was negligible. They
al.29 measured steady-state and unsteady-state three-phase concluded that asymptotically the oil relative permeability
relative permeabilities. They studied the effect of the oil tends to zero at zero irreducible oil saturation, and that for
spreading coefficient, defined as: their experiments, the oil relative permeability appeared to be
a function of only oil saturation. Similar results were obtained
C so = γ gw − γ ow − γ go ………………………………...(11) by Goodyear and Jones,37 who noted that at low oil saturation
the relative permeability appeared to be fit by kro ∝So2.
where γgw is the gas/water interfacial tension, γow is the
oil/water interfacial tension, and γgo is the gas/oil interfacial
tension. They showed that a system with Cso > 0 had a lower Amoco Group. Oak et al.4 and Oak5 performed a series of
irreducible oil saturation and higher oil relative permeability steady-state experiments on water-wet Berea sandstone and
than a system with Cso < 0. They found relative permeabilities presented two-phase gas/oil, oil/water and gas/water data.
for unsteady-state measurements by history matching the They showed that Stone’s models I and II did not reproduce
production curves. This is, however, a non-unique process if their data accurately. Fig. 2 shows the three-phase oil relative
the capillary pressures are not known. Vizika and Lombard30 permeability from Oak et al.4
SPE 56474 AN EMPIRICAL MODEL FOR THREE-PHASE RELATIVE PERMEABILITY 5
Oak28 measured three-phase relative permeabilities in a pressure gradient in the gas (air) was negligible and using
core treated with silanes to alter its wettability. Interpretation capillary pressures measured in analogue experiments. For a
is difficult because the three-phase oil relative permeability given fluid system, the oil relative permeability was a function
lies below the two-phase data near the end points, even though of its own saturation only and independent of initial condition.
the displacement began at the end of a two-phase experiment. For spreading oils (Cso close to zero), the oil saturation
Baker38 reviewed all the Amoco data, totaling around dropped to 1% or lower after several weeks of drainage and
3,000 measurements, including results from two oil-wet field kro ∝ So2. For non-spreading oils (Cso < 0), there was trapping
cores. The water relative permeability was a function of water of oil. They did not measure the two-phase oil/water relative
saturation only for water-wet media, and showed little permeabilities.
hysteresis. In intermediate-wet and oil-wet systems, the water DiCarlo et al.40 extended this work to study the effect of
relative permeability showed some hysteresis and was a wettability by using sand packs with different amounts of oil-
function of two saturations, but could be successfully wet and water-wet grains mixed together. For a fully oil-wet
predicted using saturation-weighed interpolation. For the oil system, the oil phase relative permeability (here the most
phase, saturation-weighted interpolation also gave accurate wetting phase) resembled the water relative permeability for a
predictions. Stone’s models, in contrast, did poorly for oil-wet water-wet system. However, the behavior of the intermediate-
and intermediate-wet media. The oil relative permeability was wet fluid was very different. Water does not spread on oil,
a function of two saturations and was a function of saturation and so the water relative permeability in an oil-wet system
path. The gas relative permeability was a function only of gas resembled non-spreading oil in a water-wet medium. Gas
saturation, but displayed strong hysteresis and appeared to be relative permeabilities were measured in analogue
insensitive to wettability changes. However, there was some experiments. The gas relative permeability was higher for
evidence that in oil-wet media, the gas relative permeability water-wet packs than oil-wet packs at the same gas saturation.
did depend on two saturations. In an oil-wet medium, gas was not necessarily the most non-
wetting phase. Gas/water contact angles of over 100o were
Stanford Group. Sahni et al.39 used a CT scanner to image measured, indicating that water was more non-wetting than
three-phase saturation distributions during gravity drainage in gas. They also showed that for oil-wet media, the gas relative
water-wet media. The relative permeabilities for oil and water permeability was a function of both its own saturation and the
were obtained directly from the saturations, assuming that the amount of oil and water present.
Reference Materials Type of displacement Irreducible oil kro ∝ So2? kro function
saturation of:
Kalaydjian et al (1993)29 Water-wet sandstone Steady and unsteady 0.1 – 0.31 No
state
Vizika and Lombard Sandpacks, various Gravity drainage 0.11 - 0.23 No
(1996)30 wettabilities
Skauge et al (1994)32 Water-wet sandstone Gravity drainage 0.16-0.4
Eleri et al (1995)33 Water-wet sandstone Steady and unsteady 0.12 - 0.20
state
Nordvedt et al (1996)34 Water-wet chalk Unsteady state
Grader and O’Meara Water-wet bead pack Unsteady state Tending to zero Yes So only
(1988)35
Naylor et al (1995)36 Water-wet sandstone Unsteady state Tending to zero Yes So only
Goodyear and Jones Water-wet sandstone Unsteady state Tending to zero Yes
(1995)37
Oak et al (1990)4 Water-wet sandstone Steady state Tending to zero Yes So and Sw
Oak (1990)5 Water-wet sandstone Steady state Tending to zero Yes if oil not So and Sw
trapped
Oak (1991)28 Intermediate-wet Steady state No So and Sw
sandstone
Baker (1993)38 Sandstones, various Steady state Tending to zero Yes if oil not So and Sw
wettabilities trapped
Jerauld (1996)22,41 Mixed-wet sandstone Various 0 – 0.35 No So and Sw
Sahni et al (1998)39 Water-wet sandpacks Gravity drainage 0.1 – 0.01 Yes So only
and sandstone Tending to zero
DiCarlo et al (1998)40 Sandpacks, various Gravity drainage 0.1 – 0.01 Yes if water-wet So only
wettabilities Tending to zero
Table 1• Summary of three-phase flow experiments published in 1988 or later. Blanks in the table indicate that the information cannot be
obtained from the papers.
6 M.J. BLUNT SPE 56474
0.1 spreading oil, when oil layers are not present throughout the
system and oil can be trapped.16
Stone’s I model allows for a residual oil saturation that is
normally taken to be the lowest oil saturation measured during
0.01 an experiment. We have suggested here that this may be ill
advised and that a zero residual is more appropriate for gas
injection. Furthermore, an empirical model should capture the
kro =0.025 So
2 correct functional form of the relative permeability at low
saturation. Unfortunately, the Stone model does not do this.
0.001
Balbinski et al.44 showed that Eq. (1) gives kro ∝ So-Som near
Som. Thus Stone I will tend to overestimate the oil relative
permeability at low oil saturations away from Som as noted by
previous authors.3,7 In contrast, Stone’s model II can give
0.0001 residual oil saturations that are larger than Sorw or Sorg, which
0.1 1 means that the values lie outside a monotonic extrapolation of
the two-phase values (see, for instance Fig. 1 of Ref. 27). This
Oil saturation tends to underestimate the oil relative permeability at low oil
saturation.
Fig. 2.• Oil relative permeabilities for a water-wet sandstone from For modeling gas injection processes where low oil
Oak et al.4 The points represent three-phase data at various saturations may be reached, or for contaminant clean-up and
gas/water injection ratios. The solid line is the two-phase
oil/water data, while the dashed line is for gas injection into oil transport applications, the correct modeling of the oil relative
and connate water. The line showing a quadratic fit to the data at permeability at low saturations is particularly important. Both
low saturation indicates a possible oil layer drainage regime. of Stone’s models make systematic errors.
Stone extended his model to oil-wet media by making
Arco Studies. Jerauld22,41 presented an detailed study of three assumptions:1 (1) the oil relative permeability is the same
three-phase relative permeability for Prudhoe Bay, a mixed- as the water relative permeability in a water-wet system; (2)
wet sandstone reservoir. An empirical model that accounted the water relative permeability is the same as the oil relative
for wettability, compositional effects, different saturation permeability for a water-wet medium; and (3) gas remains the
paths and the trapping of oil and gas was developed that most non-wetting phase and is unaffected by wettability
successfully matched the extensive data collected. This model changes. DiCarlo et al.40 showed that only assumption (1) is
will be discussed in more detail later. correct. Water in oil-wet media does not show a layer
drainage regime and there considerable water trapping. The
Overview. There are a number of features of these gas relative permeability is a function of both gas and oil
experiments that are not captured in current empirical models. saturations.
For water-wet media, the oil relative permeability In some of the experiments reviewed here35-37,40,41 the oil
extrapolates to zero irreducible oil saturation for most of the relative permeability was a function only of its own saturation,
experiments analyzed. This has been confirmed by other was independent of initial condition, and was similar to the
experiments that have found remaining oil saturations as low relative permeability measured for gas/oil displacements with
as 0.1% in water-wet media.42,43 For oil saturations below connate water present. This implies that in the absence of any
approximately So = Sorw we see kro ∝ So2. This quadratic oil/water data, a simple idea is to use the gas/oil data for the
behavior is illustrated in Fig. 2 for the Oak et al.4 data. whole three-phase region.
Several other more convincing examples are provided in the
papers listed in Table 1, and the results are summarized in Model Development
Fenwick and Blunt.16 The theoretical explanation16,39 is that We will now develop an empirical model for three-phase
oil resides in crevices in the pore space, between water next to relative permeability. We will do this in stages, which allows
the solid surface and gas in the center of the pores. The oil different amounts of experimental data to be incorporated.
saturation is proportional to the area occupied by this oil layer. The steps are as follows: (1) the base model (saturation-
The hydrodynamic conductance, and hence relative weighted interpolation); (2) layer drainage; (3) trapping and
permeability, is proportional to the oil area squared, leading to different saturation paths; and (4) capillary number
kro ∝ So2. This suggests a simple way to extrapolate the oil dependence and compositional consistency.
relative permeability to saturations lower than achieved in an
SPE 56474 AN EMPIRICAL MODEL FOR THREE-PHASE RELATIVE PERMEABILITY 7
Base Model. Eqs. (8), (9) and (10) are used to find the three- The contribution to the relative permeability from layers
phase relative permeabilities for oil, water and gas. To do this should vary as Sol2. We assume that it is also proportional to
six relative permeabilities from three experiments need to be the gas relative permeability, since, if all the gas is trapped,
measured: krw(o) and kro(w) from an oil/water displacement at a then the oil layers are not connected either and cannot flow.
remaining gas saturation Sgr (usually Sgr = 0); kro(g) and krg(o) Hence we find:
from a gas/oil displacement at an irreducible water saturation *
Swi; and krg(w) and krw(g) from a gas/water displacement at an k rg k ro (g)
k ol = * *2
S ol2 …………………………………...(14)
irreducible oil saturation Soi (usually Soi = 0). If the full curves k rg (o ) S ol
are missing, empirical fits to, for instance, a power-law or
Corey-type form can be made.8 If some of the data are krg(o)* is the gas relative permeability when Sg = Sg*.
missing, then for a water-wet medium, it can be assumed that The difference between the measured oil relative
krw(g) = krw(o) and krg(w) = krg(o). For an oil-wet medium, kro(w) = permeability and kol from Eq. (14) is the contribution to the oil
kro(g). If there is no oil/water data, it may be possible to take relative permeability due to bulk oil that fills the centers of the
kro(w) = kro(g). However, it is not safe to assume that the gas is pore space, kob:
always the most non-wetting phase and krg(w) = krg(o) unless the
k ob ( S o − S ol ) = k ro ( g ) ( S o ) − k ol ( S ol ) …………………(15)
system is water-wet.
Hustad and Hansen23 also applied saturation-weighted Using the measured data, kro(g)(So), Eqs. (12)-(15) are used
interpolation to all three phases. They normalized the to tabulate kob(Sob). This is shown schematically in Fig. 3.
saturations to allow irreducible saturations that varied linearly Note that for So > So*, Sol = Sg So* / Sg*, and decreases with
between their two-phase values. We do not do this, but increasing oil saturation, and thus kol also decreases.
instead account for trapping separately. Most reservoir rocks are not strongly water-wet, and the
spreading coefficient of the oil is rarely known with any
Layer Drainage. While the literature review above suggested certainty. Our suggestion is to allow a layer drainage regime
that at low saturation the oil relative permeability had a for a rock that spontaneously imbibes some water, meaning
characteristic quadratic form for water-wet media and that the Amott wettability index45 for water Aw is greater than
spreading oils, many laboratory experiments never reach these zero and to assume, unless there is evidence to the contrary,
low oil saturations, because of the time or capillary pressure that the reservoir oil is spreading.
required. However, lower saturations may be reached in the
reservoir during gas injection. A possible approach to this
problem is to extrapolate the measured oil relative
permeability to low saturation assuming layer drainage.
In the layer drainage model, the oil saturation is written as
a sum of two components: bulk oil Sob and oil in layers, Sol: Measured data
Log(kro(g))
S o = S ob + S ol ………………………………………...(12) kro(g)(So)
Trapping and Different Saturation Paths. The two-phase The advantage of this approach is that from two-phase
relative permeabilities used in a three-phase model are measurements and a single waterflood residual value to find
normally measured for just a single displacement: generally Cg, the gas relative permeability for any displacement path in
primary drainage of gas for krg(o) and kro(g), and secondary three-phase flow can be found. The disadvantage is that this
water injection for kro(w) and krw(o). However, many three- empirical method may not give accurate results. For instance,
phase displacements involve saturation changes that were not Jerauld22 showed that the Land24 model gave poor predictions
explored in the two-phase measurements. In theory two-phase for gas trapping in Prudhoe Bay cores. Instead, he proposed a
data for all possible initial conditions could be performed, as generalized form of the Land model that more accurately
suggested by Stone,1 and the appropriate two-phase relative matched the data. Furthermore, our model assumes that the
permeabilities used in the three-phase model. In reality this is same amount of gas is trapped by water, as by oil. If the
rarely, if ever, done. Furthermore, Oak5 showed that such an system is not water-wet this may not be true, and extensions to
approach is not reliable, because three-phase displacements the model may need to be considered.
explore saturation paths that cannot be described in terms of In a water-wet system we assume that oil is trapped by
their two-phase limits alone. Instead a simpler, more robust water, but not by gas. We can account for this by considering
method is required that uses relative permeabilities for only the trapping of hydrocarbon (oil+gas) by water using a Land
one gas/oil, oil/water, and gas/water displacement. model. The amount of oil trapped is the difference between
To accommodate any saturation history the relative the trapped hydrocarbon saturation, and the trapped gas
permeabilities are written as functions of a flowing saturation saturation. The residual hydrocarbon saturation Shr is found
Sf, where it is assumed that using this functionality gives from:
relative permeabilities that are independent of saturation
path.25 The overall saturation is the sum of flowing and S hmax
S hr = ……………………………………..(19)
trapped fractions: S = Sf + St. 1 + C h S hmax
First consider a water-wet medium. Gas is trapped by both
oil and water. Land24 proposed that the amount of gas that can where Shmax is the largest hydrocarbon saturation reached
be trapped is related to the maximum gas saturation reached during the displacement – Shmax = Max(So + Sg). Ch, the Land
during the displacement. trapping constant = Min(Co, Cg), where Co is the trapping
constant for oil. For strongly water-wet media, you can
S gmax assume that Ch = Cg = Co.
S gr = ……………………………………..(16) The flowing hydrocarbon saturation is:
1 + C g S gmax
1
(S h − S hr ) + (S h − S hr )2 + (S h − S hr ) .(20)
4
where Sgr is the amount of gas that can be trapped, Sgmax is the S hf =
maximum gas saturation, and Cg is the Land trapping constant. 2 Ch
Cg is normally found from the residual gas saturation to
waterflooding, Sgrw. At the beginning of waterflooding the gas The flowing oil saturation is Shf minus the flowing gas
saturation is some high value, Sgmax and from Eq. (16) we find: saturation, and the contribution due to oil layers. This is the
bulk flowing oil:
Cg =
1
−
1
……………………………………(17) ( ( ))
S ofb = Min S o − S ol , Max S hf − S gf − S ol ,0 …...……(21)
S grw S gmax
where Sgf is found from Eq. (18) and Sol from Eq. (13).
The flowing gas saturation is:24 kro(w) and kro(g) are recorded as functions of Sofb. If kro(w)(So)
is measured for primary drainage, then for this experiment Sofb
1
S gf =
2
(
S g − S gr + ) (S g − S gr )2 + C4 (S g − S gr ) (18) = So. For a secondary displacement, Eqs (19)-(21) with Sol =
g Sgf = 0 are used to find Sof. This model assumes that gas does
not trap oil, and thus if kro(g)(So) is measured for gas invasion
During primary drainage the gas saturation is the same as into oil and irreducible water, Sofb = So - Sol.
the flowing saturation, and thus we can find krg(w)(Sgf) from gas Conceptually the oil saturation has three components. The
injection into water and krg(o)(Sgf) for gas invasion into oil (and first is trapped oil that does not flow. The second is oil in
irreducible water). However, for displacements where the layers. Its contribution to the relative permeability is given by
water and/or oil saturations are increasing, gas may be trapped Eq. (14). At low oil saturations, all the oil is flowing in layers
and Eqs. (16) and (18) can be used to find the flowing gas (we call this the layer drainage regime). At higher saturations,
saturation, against which the relative permeabilities are the amount of oil in layers is some fraction of the gas
tabulated. saturation, Eq. (13). The third component is flowing, bulk oil
To predict relative permeability in a three-phase that occupies the centers of the pore space. The three-phase
displacement, the largest gas saturation saturation, Sgmax ever kro is found from saturation-weighted interpolation between
reached is recorded. Eq. (16) is used to find Sgr, and Eq. (18) kro(w)(Sofb) and kro(g)(Sofb), Eq. (8), and then kol is added to the
gives the flowing gas saturation, and hence the relative result.
permeabilities can be found. If a new maximum gas saturation This model predicts that the sum of trapped oil and gas
is reached, then Eq. (16) is used to recompute Sgr. saturations is constant, and depends only on the maximum
SPE 56474 AN EMPIRICAL MODEL FOR THREE-PHASE RELATIVE PERMEABILITY 9
oil+gas saturation reached during the displacement. However, permeability is the same for gas/water and oil/water
for systems that are not strongly water-wet, this may not be the displacements.
case. Jerauld22 found that the residual oil saturation was However, Eqs. (22)-(26) do not ensure that the oil and gas
approximately independent of trapped gas, and that the sum of relative permeabilities have the correct form as miscibility is
trapped oil and gas increased linearly with Sorw. In such cases, approached. At miscibility, the oil and gas flow as a single
oil trapping could be treated independently from gas, using a phase, with no trapping, and the hydrocarbon relative
Land-type treatment (Eqs. (16)-(18) with the subscript ‘g’ permeabilities are:22
replaced by ‘o’), or a generalization that matches the data.22
Si
Water trapping, in oil-wet systems, could also be treated k ri = k rh( w) ( S hf ) ………………….……………...(27)
using the methodology here. The water relative permeabiliites Sh
could be recorded as functions of the flowing water saturation.
Shf is the flowing hydrocarbon (oil+gas) saturation (given by
If it is assumed that both gas and oil can trap water, then a
Eq. (20) for a water-wet system). krh is a hydrocarbon/water
Land treatment for water could be attempted, using Eqs. (16)-
relative permeability that is the same whether oil or gas is
(18) with the subscript ‘g’ replaced by ‘w’ for water.
being considered. Eq. (27) is only valid in a small region near
the critical point – typically for capillary numbers higher than
Capillary Number Dependence and Compositional
approximately 10-4, or gas/oil interfacial tensions around 10-5 –
Consistency. The properties of the oil and gas phases can
10-4 N/m.4,20
vary continually as the pressure and composition of the
A possible formulation for near-miscible flow that obeys
hydrocarbon varies in the reservoir. The relative
Eq. (27) as the gas/oil interfacial tension tends to zero is:
permeabilities should also vary smoothly from oil-like to gas-
like with composition. To ensure this, hydrocarbon relative Si c
permeabilities are computed as a compositionally weighted k rim( w) = αk ric ( w) ( S i ) + β k ri ( w) ( S h ) ………..…….…(28)
Sh
average of the oil and gas values. Jerauld22 suggested using a
parachor weighted molar density to interpolate hydrocarbon
Si c
properties. We propose here a simpler approach that uses k rim( j ) = αk ric ( j ) ( S i ) + β k ri ( w) ( S h ) ………………...(29)
phase densities. Sh
Define ρo0 as the oil density at some reference pressure, The subscript m implies both compositional consistency and a
temperature and composition (for instance the values when the
two-phase relative permeability measurements were taken). correction for near-miscible flow. k ric ( w) and k ric ( j ) are found
ρg0 is the reference gas density and ∆ρ0 is the reference density from Eqs. (24) and (26) respectively. The weighting factors α
difference between oil and gas. In a compositional simulation and β are:
imagine that we have a hydrocarbon phase of density ρi, where
γ go
i labels either an oil or a gas phase. We define the less dense
phase as gas, and the denser phase as oil. The degree of “oil- α = Max Min crit ,1,0 …………………………….(30)
γ go
ness” of the phase is defined as:
ρi − ρ g0
a i = Max Min ,1,0 ……………………....(22) γ go
crit
− γ go
∆ρ 0 β = Max Min ,1,0 ………………….….(31)
γ go crit
while the “gas-ness” is:
An appropriate critical gas/oil interfacial tension, γgocrit is
ρ − ρi typically around 10-5 to 10-4 N/m.
bi = Max Min o 0 ,1,0 ……...…………….….(23)
∆ρ 0 k rim( w) and k rim( j ) are used in saturation-weighted
The hydrocarbon and water relative permeabilities are: interpolation – Eqs. (8) and (10) – to find the three-phase
c
relative permeabilities for oil and gas. k rw (i ) in Eq. (25) is
k ric ( w) = a i k ro ( w) + bi k rg ( w) ………..…………...…...….(24)
used in Eq. (9) to find the three-phase water relative
permeability.
(i ) = a i k rw (o ) + bi k rw( g ) ……………………….....…(25)
c
k rw In compositional simulations near the critical point, the oil
and gas saturations can change rapidly due to mass transfer
k ric ( j ) = a i k ro ( g ) + bi k rg ( o ) ………………………......…(26) between phases. The predicted amount of oil and gas trapping
is based on saturation changes due to displacement. As a
The superscript c implies compositional consistency, while j consequence, the estimated amounts of oil and gas trapped
labels the other hydrocarbon phase. This formulation ensures may be inaccurate.
that the relative permeabilities vary smoothly with Before showing the final forms of the equations for three-
composition. At miscibility (ρi = ρg = ρo), the oil and gas phase relative permeability, we will review the procedure.
relative permeabilities are the same, and the water relative
10 M.J. BLUNT SPE 56474
[ )]
for gas invasion into oil
(
+ bo (S o − S oi ) + b g S g − S gr k rw( g ) ( S wf )
and irreducible water.
=
( )
k rw ...(32) So* Oil saturation for layer From gas/oil displacement.
(S o − S oi ) + S g − S gr drainage regime.
Sg* Gas saturation when So From gas/oil displacement.
= So*.
kro(g)* Oil relative permeability From gas/oil displacement.
when So = So*.
[ ]
krg(o)* Gas relative permeability From gas/oil displacement.
(S w − S wi ) a o k ro ( w) ( S ofb ) + bo k rg ( w) ( S ofb ) when Sg = Sg*.
( )[
+ S g − S gr a o k ob ( S ofb ) + bo k rg ( o ) ( S ofb )
] Cg Land trapping constant Waterflood residual gas.
=α
for gas.
k ro
(S w − S wi ) + S g − S gr( ) Ch Land trapping constant
for hydrocarbon.
Waterflood residual oil or
gas.
+ αk ol ( S ol ) (33) γgocrit Critical gas/oil interfacial Estimated from capillary
tension for near-miscible desaturation experiments.
+β
So
So + S g
(
a o k ro ( w) ( S hf ) + bo k rg ( w) ( S hf ) ) ρo0
flow.
Reference oil density. From phase behavior
calculations or core
measurements.
ρg0 Reference gas density. From phase behavior
calculations or core
measurements.
All the features of the model do not always have to be The predictions ignoring layers are the same as saturation-
used. For instance, for a black-oil simulation of an oil-wet weighted interpolation, Eq. (8), with no corrections and lie
system, layer drainage may be ignored, and compositional between the two-phase curves kro(w) and kro(g). kro(w) is 2 to 200
effects neglected, so that in Eqs. (32)-(34) α = 1, β = 0, ao = bg times larger than kro(g) at the same oil saturation. This means
= 1, ag = bo = 0 and kol = 0. that unless Sw is very close to Swi, saturation-weighted
interpolation will tend to predict kro close to kro(w), since kro(w)
Test Problem dominates the weighted sum of the relative permeabilities. In
We will now test the model against the three-phase data from contrast, the experimental points, albeit with considerable
Oak and co-workers.4,5 They performed a series of scatter, seem lie around the kro(g), and some points, at low oil
experiments on three water-wet Berea cores. We will predict saturations, lie below kro(g). Thus saturation-weighted
the three-phase oil relative permeability. Using the procedure interpolation alone systematically over-estimates kro. Stone’s
in the previous section, the steps are: models I and II make even poorer predictions for this data.5
1. kro(w) is found from a primary drainage displacement of
water by oil – Fig. 4 of Ref. 5. kro(g) comes from a gas/oil
primary drainage displacement at connate water saturation 1
Swi = 0.2, also plotted in Fig. 4 of Ref. 5.
2. To assess the effect of including layer drainage, we make
predictions both including and ignoring layers. If we
account for layers, Fig. 2 indicates So* = 0.2, where Sg* =
While layer drainage does indeed allow oil to drain to zero and layer drainage improved the predictions over using
saturation, the corresponding relative permeabilities are very saturation-weighted interpolation alone.
small. In fact, the most significant effect of layers is to take
saturation away from the bulk oil, and thus reduce the
predicted kro at low to moderate oil saturations. While the 1
experimental data appears to support the layer model, there are
some problems. First, the model does not capture the full
range of the experimental points. Second, the huge scatter in
the data makes definitive conclusions difficult. Third, the
krg(w) = two-phase gas relative permeability for gas and the Department of Trade and Industry) for financial
injection into water. support.
kro(w) = two-phase oil relative permeability for oil/water
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