PUNJAB GROUP OF COLLEGES

ALI PUR CHATHA

Class: 2nd year Half Book Test Marks: 17 Time: 20 min

Subject: Chemistry Syllabus: Chapter 7-15

(Objective Type)

Q1: Encircle the correct option. (1 x 17 = 17)

1. Linear shape is associated with which set of hybrid orbitals.

(a). sp (b). sp2 (c). sp3 (d). dsp2

2. Which gas is used for artificial ripening of fruits?

(a). Ethane (b). Ethyne (c). Methane (d). Propane.

3. Halogenation of alkanes in the presence of sunlight undergoes:

(a). SN1 mechanism ( b). SN2 mechanism

(c). Free radical mechanism (d). Acid –base catalysed mechanism

4. Benzene cannot undergo

(a). Substitution reactions (b). Addition reactions (c). Oxidation reactions (d). Elimination
reactions.

5. Ortho, para derivatives are obtained by halogenation of:

(a). Nitrobenzene (b). Toluene (c). Benzaldehyde (d). Benzene

6. SN2 reactions are given by:

(a). Primary alkyl halides (b). Secondary alkyl halides (c). Secondary alcohols (d). Primary alcohols.

7. For which mechanisms the first step involved is the same:

(a). E1 and E2 (b). E1 and SN1 (c). E1 and SN2 (d). E2 and SN2

8. Which woody raw material is used for the manufacture of paper pulp?
(a). Cotton (b). Bagasse (c). Poplar (d). Rice straw.

9. Which compound is universal solvent:

(a). H2O (b). CH3OH (c). C2H5OH (d). CH3 – O – CH3

10. Cannizzaro’s reaction is not given by:

(a). Formaldehyde (b). Acetaldehyde (c). Benzaldehyde (d). Trimethyl acetaldehyde

11. Methanol can be prepared from hydrogenation of:

(a). CH3CN (b). CH3Br (c). HCHO (d). CH3CHO

12. Which compound is polyprotic acid

(a). CH3COOH (b). C6H4(OH)COOH (c). (COOH)2 (d). C6H5OH

13. Amino acids are prepared by
(a). Williamson’s synthesis (b). Strecker’s synthesis (c). Wurtz’s synthesis (d). Perkin’s reaction.

14. One of the following does not react with NaHSO3

(a). Methanal (b). Propanone (c). Butanone (d). 3 – pentanone

15. Ketones are prepared by oxidation of:

(a). Primary alcohols (b). Secondary alcohols (c). Tertiary alcohols (d). None of these.

16. Which of the following is a condensation polymer?

(a). Benzene (b). Bakelite (c). PVC (d). Polystyrene

17. Which is a synthetic polymer?

(a). animal fat (b).cellulose (c). starch (d). polyester
 PUNJAB GROUP OF COLLEGES
ALI PUR CHATHA
Class: 2nd year Half Book Test Marks: 68 Time: 2 hr 10 min

Subject: Chemistry Syllabus: Chapter 7-15

(Subjective Type)

(SECTION I)
Q2: Write answers of any eight (8) questions (2 x 8 = 16)

1. What is vital force theory? How was it rejected?

2. Differentiate between alicyclic and aromatic compounds.
3. Define tautomerism with example.
4. What is catalytic cracking? Give an example.
5. 2 – Butyne does not show geometric isomerism but 2 – butene does. Give reason.
6. Why alkenes are called olefins?
7. What is Baeyer’s Test?
8. Convert ethene to 1 – butanol.
9. Explain why alkanes are less reactive than alkenes.
10. Describe catalytic oxidation of methane.
11. Convert: (a). CH4 into CH3NO2
(SECTION II)
Q3: Write answers of any eight (8) questions (2 x 8 = 16)
1. What is the difference between rectified spirit and absolute alcohol?
2. Why phenoxide is more stable than the ethoxide ion?
3. Define fermentation. Give one example.
4. Alcohols react with conc.H2SO4 and give different products at different conditions, give reactions
5. How does ethyl alcohol reacts with the following reagents?(a)Conc.H 2SO4(b)PCl5
6. How acetone is prepared from propyne.
7. How can you prepare (i)Formalddehyde (ii)Ethylene glycol from ethene.
8. What is condensation reaction? Give an example.
9. Discuss oxidation of aliphatic aldehdye with Fehling‘s solution.
10. What is haloform reaction?
11. Write method to prepare formaldehyde and acetaldehyde.
(SECTION III)
Q4: Write answers of any six (6) questions (2 x 6 = 12)

1. What are polyamide resins? Explain it with an example.

2. Define saponification number and iodine number.
3. What is the hardening of oil? Give an example.
4. What are Steroids? Give their general structure.
5. Define lipids and give their types.
6. What is clinker?
7. What are the four main non – woody raw materials used in the production pulp and paper?
8. Give reactions taking place in first 24 hours in setting of cement.
9. What are macronutrients?
Q: Write answers of any three (3) question. (3 x 8 = 24)

Q5: (a) What is meant by Reforming of Petroleum? Explain knocking and octane number in that regard. 4

(b) Give mechanism of Alkylation and Acylation of benzene. 4

Q6: Complete the following reaction in balanced form: 8

(i) Ethene + Alkaline KMnO4

(ii) Ethene + Sulphur monochloride
(iii) Ethyne + Ammonical silver nitrate
(iv) Methane + HNO3

Q7: (a) Explain the structure of benzene on the basis of atomic orbital treatment. 4

(b) Define hybridization. Discuss the structure of ethyne on its basis. 4

Q8: (a) How Grignard reagent reacts with the followings? 3

║ (b). H2C – CH2 (c). C2H5 – OH

(a). CH3 – C – CH3 O

(b) What is Aldol Condensation? Give two examples and mechanism of the reaction. 5

Q9: (a) What is haloform reaction? Give two examples. 4

(b) What are the factors affecting the enzyme activity? 4