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Historical, current and
The rst production route for acetic acid was aerobic fermentation of ethanol forecast prices, together with
(http://www.icis.com/V2/chemicals/9075284/ethanol.html?redirect=english). The commentaries, to help you
ethanol (/energy/ethanol/) is catalytically dehydrogenated or oxidised to track price uctuation and
acetaldehyde, which in turn is oxidised to acetic acid. While this technology is understand price drivers and
old, in 2001 Perkebunan Nusantara X built a 30,000 tonnes/year molasses- trends. Make fast and
based acetic acid plant in Jakarta, Indonesia. In addition, Celanese con dent decisions and
(http://www.icis.com/v2/companies/9145158/celanese.html?redirect=english) gauge the best time to buy or
announced that it was exploring a biocatalytic route to acetic acid in sell.
collaboration with Diversa.
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Methanol (/chemicals/methanol/) carbonylation
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technology for acetic acid and claimed signi cantly lower production costs. The demand-service/?
Cativa process uses a catalyst system based on iridium, in conjunction with intcmp=CHEM-free-
several novel promoters, such as rhenium, ruthenium and osmium. articles-pages-promo-
sndd)
The iridium catalyst system has a higher activity compared with the rhodium
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process, produces fewer byproducts, and is able to operate at reduced water
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levels (less than 5% for Cativa versus 14-15% with the Monsanto process). All of
keeps you fully informed of
these factors combine to allow plants to increase their capacity at relatively low
key events in your
capital cost.
marketplace as they happen –
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In the 1980s, Celanese developed its proprietary AO Plus (Acid Optimisation
Plus) technology, greatly improving the Monsanto process. The AO Plus Request a FREE trial
technology was achieved in part by increasing the rhodium catalyst stability by (/contact/request-free-trial-icis-
adding inorganic iodide (primarily lithium iodide) in high concentrations, news/?
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in the reactor while maintaining a high carbonylation rate. This subsequently
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Showa Denko (http://www.icis.com/v2/companies/9146251/showa-denko.html? Special Publications
redirect=english)has developed a one-step, vapour phase process for the
production of acetic acid by direct oxidation of ethylene
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(http://www.icis.com/V2/chemicals/9075774/ethylene.html?redirect=english).
(/resources/energy/?
Owing to relatively reduced capital outlays needed, the Showa Denko ethylene
intcmp=ENER-free-articles-
based process is claimed to be economical for 50 000-100 000 tonne/year acetic
acid plants. pages-free-resources)
Alkane oxidation
The principal products are acetic acid and methylethylketone. Other organic
products, however, such as ethanol, methanol, formic, propionic and butyric
acids are also produced. It is unlikely that any new acetic acid plants using non-
selective alkane oxidation will be built in the future.
The new Sabic catalyst system, which is a calcined mixture of oxides of Mo, V,
Nb and Pd, allows selectivities to acetic acid as high as 71%. Combining this
technology with low cost ethane may result in production economics
competitive with methanol carbonylation technology.
(Source: Extracts from Spoilt for choice, by Je rey Plotkin and Larry Song of
Nexant, ECN 7 April 2003)
Related articles:
01 November 2007 10:51 Acetic Acid Prices and Pricing Information
(/resources/news/2007/11/01/9074786/acetic-acid-prices-and-pricing-information/)
31 October 2007 14:25 Acetic Acid Uses and Market Data
(/resources/news/2007/10/31/9074779/acetic-acid-uses-and-market-data/)
31 October 2007 11:56 Acetic Acid CAS No: 64-19-7
(/resources/news/2007/10/31/9074417/acetic-acid-cas-no-64-19-7/)
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