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SOLUTIONS s-1
1 (c) 21 (b) 41 (a) 61 (b) 81 (b) 101 (d) 121 (b) 141 (c) 161 (d)
2 (b) 22 (d) 42 (a) 62 (a) 82 (d) 102 (c) 122 (d) 142 (c) 162 (c)
3 (c) 23 (a) 43 (d) 63 (c) 83 (a) 103 (d) 123 (a) 143 (C) 163 (C)
4 (c) 24 (b) 44 (a) 64 (C) 84 (d) 104 (c) 124 (a) 164 (b)
5 (b) 45 (c) 65 (d) 85 (c) 105 (c) 125 (d) 145 (a) 165 (a)
6 (c) 26 (b) 46 (d) 66 (d) 86 (c) 106 (d) 126 (b) 146 (a) 166
7 (a) 27 (c) 47 (b) 87 (b) 107 (a) 127 (b) 147 (c) 167 (b)
8 (a) 28 (d) 48 (b) 68 (d) 88 (d) 108 (d) 128 (d) 148 (c) 168 (b)
9 (c) 29 (c) 49 (d) 69 (c) 89 (c) 109 (a) 129 (a) 149 (b) 169 (a)
10 (c) 30 (C) 50 (c) 70 (b) 90 (b) 110 (a) 130 (c) 150 (b) 170 (c)
11 (d) 31 (C) 51 (c) 71 (b) 91 (d) 111 (b) 131 (d) 151 (d) 171 (a)
12 (a) 32 (C) 52 (d) 72 (c) 92 (b) 112 (b) 132 (d) 152 (b) 172 (b)
13 (c) 33 (c) 53 (a) 73 (c) 93 (d) 113 (a) 133 (d) 153 (c) 173 (c)
14 (a) 34 (a) 54 (d) 74 (d) 94 (a) 114 (b) 134 (b) 154 (c) 174 (C)
15 (b) 35 (b) 55 (a) 75 (a) 95 (d) 115 (a) 135 (a) 155 (a) 175 (d)
16 (d) 36 (a) 56 (b) 76 (a) 96 (c) 116 (b) 136 (c) 156 (d) 176 (c)
17 (b) 37 (a) 57 (b) 77 (b> 97 (d) 117 (c) 137 (d) 157 (b) 177 Id)
18 (c) 38 (c) 58 (c) 78 (b) 98 (a) 118 (a) 138 (a) 158 (a) 178 (c)
19 (C) 39 (a) 59 (c) 79 (b) 99 (a) 119 (b) 139 (a) 159 (b) 179 (d)
20 (a) 40 (a) 60 (d) 80 (a) 100 (b) 120 (b) 140 (b) 160 (d) 180 (b)
I Total distance = - X 10 X (6 + 2) = 40 m.
I ime to complete ~ th vibration from 2
O
(c) Work function of aluminium is 4.2 eV. The
extreme position is obtained from energy of two photons can not be added
a 2 7i T at the moment photons collide with
y = - = a cos cot = a cos-1 or t = -s
"
electron all its energy will be dissipated or
2 T 6
wasted as this energy is not sufficient to
So time to complete 3/8th oscillation knock it out
Hence emmission of electron is not
T T 5T
possible.
7+ 6 ~ 12
_
-
a AT =10ÿx100 = 10
9. (c) Since Range on horizontal plane is
„ i/ 2 sin 20 -.
'
-
X 100% =10 3 X 100
(
ÿ
= 10 ' =0 1% .
zero.
the fixed axis. 17. (b) From the figure, il is clear that angle of
mass = density * volume {v p = density} incidence on the reflecting surface is 45°.
So, critical angle for glass air interface
2 °
pnr t should be 45
Ma= pre r2t; 1
.
p = = 1.4
64p7i/- 41 18. (c) For a single negative point charge, electric
lines of force are radial and inwards.
y
V 32
not follow Ohm's law. Thev are also called
non-ohmic devices
j 3RT
140 32 C 700- 160 "
rms
20. (a) or .- < V M
9 5
orC 60 V
5R 400
21. (b) The bullets are tired at the same initial speed '
II so v,, - 2230.59 m/sec
2
// m2 sin2 60" 2 sin 60° -
'
(c) For the observation of interference
H 2ÿ u~ Sin2 30° sin2 30° phenomenon, the two source must be
coherent & must have same frequency.
(v;3/2) 3
(c) The direction of oscillations of £ and B
(1 / 2)J I fields are perpendicular to each other as
r> (d) Total resistance of the circuit well as to the direction of propagation. So,
<1000 400 1400 Q electromagnetic waves are transverse in
r 440 nature.
Current flowing / - 0 1 amp.
R 4400
.
f 10 spherical shell!
r
(d) Phase difference .*= (|)
As the shell is shrinking, r decreases.
A
Path diff = - X phase diff.
.
'
71 ?T 35. (b) v
e = 42m0 where v and v are the escape
velocity and orbital velocity respectively.
26. (b) E' Rhc 36.
ni n2
" (a) The kinetic energy is directly proportional
to temperature.
E will be maximum for the transition for
37.
(a) GÿISQ, ig = 4mA. i = 6A
Required shunt,
which ismaximuin. Here n->
2 2 '
I
Clearly, is maximum for the 4xl0~3
2
<15™° "1f
"I "2
j 5.9% '
AM YA YA
28. (d) Velocity after the collision
10x10 + 5x0 "
_
100 _ 20 m i sec
ÿ
-
39. (a) ÿ = 9 , fn =9f,
15 15 " 3
29, (c) The centre of mass remains at rest because Also f(l + f -20 (.. i
f nal image is at infinity)
force of attraction is mutual. No external
9 f + f =20, f
r1 P
.
-2 cm,
,
.
. . fn = 18 cm
(1
force is acting.
SECTION 2 -CHEMISTRY
2T
P, (in
'
smaller bubble ) = Po + - 46. (d) BFj is planar triangular while PF3 is
r
pyramidal.
2T 47. (b) Let the wt. of each gas mixed = x g
P2 (in bigger bubble) = Pq + R
( R > r) x
mole of SO,
64
Pi > P2 x
64 16 32 64
If A is the amplitude, then Partial pressure exerted by a gas in the
2A = 50cm => A = 25 cm. mixture of non-reacting gases (p) is given
(a) Width of central maximum by
X
y2 sin 0 = a 48. (b) Cb/FcCI-
y,Ki" 0 = ~
ir
49. (d) Decomposition of carbonates and hydrated
o sin 0 = 0 oxides.
V X
yi ÿm 9o -- 50. (c) Chiorination of methane proceeds via free
25xl0"&m =31%5> 10 cm.
radical mechanism. Conversion of methyl
Intensity x. . „
-
*
>/
Yi sin 0 =- -y-" chloride to methyl alcohol proceeds via
-
»D<-
< nucleophilic substitution. Formation of
ethylene from ethyl alcohol proceeds via
dehydration reaction. Nitration of benzene
Screen position of various minima for is electrophilic substitution reaction.
51. (c) Benzene is non-polar and hence dissolves
Fraunhoffer diffraction pattern of a single
non-polar compounds (like dissolves like).
slit of width a.
Among the given compounds, only (c) is
(d) In a p-type semic-onductor germanium is non-polar hence it dissolves in benzene.
doped with trivalerit element. All the 52. (d) Ozone hole is reduction in ozone layer in
elements, like aluminium, boron & gallium stratosphere.
are trivalent. So, the correct alternative is 53. (a) In a period on moving from left to right ionic
(d). radii decreases.
(c) The size (or length) of collector is large in (a) So order of cationic radii is
comparison to emitter (base is very small in Cr2+ > Mn2" > Fe2+ > Ni2t and
comarison to both collector & emitter) to (b) Sc>Ti>Cr> Mn
dissipate the heat. (correct order of atomic radii)
mole, lit V,
(d) For unpaired electrons
[mole, lit j [mole, lit " |
Fe2+ (Four) > Co;+ (Three) -
ÿ mo le . lit .. s 1
( I wo) > Cirt (One) 61. (b) As the molecular weight of noble gas atoms
-
> Ni"
54. (d) The reaction is an example of SN1 reaction increases down the group its polarity
increases due to which van-der-waal-s force
CH3 ch3 between them increases. Due to increased
1 i -i-
-
Br"
CH , -
OCH, h
Av
.
>(. 11; ~ C CI I ;
i 4rtm
och3 h
Av
55. (a) According to the (n + I) rule the higher the 4 ran
value of (n + 1) the higher is the energy.
,
5
'
5 +24 + : 51
(ii) Optical isomers
4
Ml,
Hybridisation = sp-,
Similarly, for BF4 . it is spJ. a\ a
Cll2OII
)
,
72
65 (d) (J .
CI 1,011 [A j[B
IABI
66. (d) An ion exchange resin containing R--COOH
group exchange cations like Ca-\ Mg-
'
,
Salt will precipitate if ionic conc. > K
Na , l c" with H' when-hard water is [A |[B 10"
suggests that the enthalpy of formation is structures. Thus, statement (a) is correct.
the heat evolved or absorbed when one
Mg2C3 + 4H20-->
mole of substance is formed from its
2Mg(OH)2 + CH3C = CH
constituent atoms. Propym.,
1
"
J
i e., statement (b) is also correct.
sp sp sp' .
C = NH-
71. (b) Complex Co(en)(NH3),CI,JCl will have four ®
different isomers.
76. (a) Given vapour pressure of pure solute
(i) Geometrical isomers
(P°) = 121.8 mm; Weight of solute (w) = 15 g
Weight of solvent (W) = 250 g; Vapour
pressure of pure solvent (P) = 120.2 mm
and Molecular weight of solvent (M) = 78
ci
. mw/v-fbrm
PU P vv M 12 LX 12 (U 15 78 '
250 1.6
C,H, --C-011
77. (b) With the decrease in the electronegativity
of central atom the bond angle decreases 82. (d) Penicillin is an antibiotic which was first
78. (b) When the concentration of reactant is obtained from a fungus, penicillium
reduced to half its initial value, the rate is notatum by the scientist, Flemming.
2 4
83. (a) Slow step is rate determining step
reduced by - 4 times : Rate law = k |NOBr2] [NO], [NOBr2] is
06
.
the intermediate
It means, rate x [ reactantj-
So. order of reaction ; 2
| NOBi.2 J
For the fast reaction, K - -
79. (b) p-p overlap between B and F is maximum [NO][Br2j
due to identical size and energy of p- [NOBr2] K [NO] [Br2J
orbitals, so electron deficiency in boron of Rate law - Is. k [NO]2 [Br-,J
BI-. is neutralized partially to the maximum = K
,
|N0j'[Br2f
extent by back donation. 84. (d) Various products are formed when
Hence BF3 is least acidic. nitroarenes are reduced. These are given
80. (a) Following generalization can be easily below for C6i 15N09.
derived for various types of lattice Medium Main product
arrangements in cubic cells between the In acidic medium Aniline (C6HSNH,)
edge length (a) of the cell and r the radius (metal/11CI)
of the sphere. In neutral medium Phenyl hydroxylamine.
(Zrv'NHjCl) NIIOII
a -
or r
V3 4 O )--nh-( O
Ilydrir/obi1nzene
For face centred cubic :
Thus, Aniline will be main product in case
of(d).
a = 2V2r or r - - -7= a
2V2 85. (c) Reaction used in fuel cell is
ion
81 (b> Recall that presence of electron-
withdrawing group increases while ,
87. (b) /' remains unchanged when number of ions
presence of electron-releasing group before and after complex ion remains
constant.
decreases the acidity of carboxvlic acids.
,,, ,
C
Where, 97. (d) a-amyiase enzyme stimulates the
k = specific conductance - Unit ohm 1
_
cm
_
, germination of barley seed.
C normality of the solution unit gm e<] 'cm3 98. (a; DNA ligase is the enzyme which helps in
joining two r f agments of DNA. The enzyme
Hence, the unit of Aet] is Ohtrr,.cm2 (gm is used in DNA replication as it joints the
equivalent)
Okazaki segments (also in proof reading).
9 (c) Nylon-6 is also called as perlon. It is a
It also finds its use in genetic engineering
.
fNi kch2)s -c-n i i--(c 112 )5-c v 101. (d) DDT residues are rapidly passed through
Polvmerise
Nvion-6 food chain causing biomagnification
because DDT is lipo soluble. Biomagni-
SECTION 3-BOTANY
fication, also known as bioamplification or
91. (d) The hormone, which controls cell division biological magnifiea-tion, is the increase in
and cell differentiation, is cytokinin. Both concentration of a substance, such as the
the auxin and gibberellins cause elongation pesticide DDT, that occurs in a food chain
of cell and plants. as a consequence of:
92. (b) During aerobic respiration oxygen is Persistence (slow to be broken down by
consumed and CO, is released. R.Q. is environmental processes)
defined as ratio of volume of C01 released Food chain energetics
and consumed by the respiratory Low (or non-existent) rate of internal
substrate. degradation/excretion of the substance
VolumeofCOÿ (often due to water-insolubility).
_
R.Q. = ---
102. (c) Deep black soil has high content of clay
Volumeof 02 and humus, which makes it more fertile and
93. (d) Long-day plants usually flower in the spring so productive. Humus is amorphous and
or early summer; they flower only if the light colloidal mixture of complex organic
periods are longer than a critical length, substances. It provides fertility to the soil.
which is usually 9-16 hours. For example, 104. (c) Embryo sac is 7-celled structure. There is a
wheat plants flower only when light periods large central cell with two polar nuclei, egg
exceed fourteen hours. apparatus with egg ceil and 2 synergids
95. (d) The end product of glycolysis is pyruvate. present at micropylar end and its chalazal
It enters mitochondria and is oxidatively end, 3 antipodal cells are present.
107. (a) AaBB * aaBB on crossing gives 50% 113. (a) Food chain is the transfer of energy from
individuals having genotype AaBB and green plants (Primary producers), through
50% individuals having genotype aaBB. a sequence of organisms occupies in a food
chain is known as its trophic level.
AaliB | | jjBB | Therefore, statements (ii) and (iii) are
Ci;mick's
© © j© 115. (a)
correct.
112. (b) The rate at which organic molecules are elongated dead cells with tapering ends
formed in a green plant is called gross having lignified walls and large or wide
lumen. Their main function is conduction
productivity.
of water and minerals rom root to leaf.
123. (a) The linking of antibiotic resistance gene 131. (d) The factors which affect the rate of
with the plasmid vector became possible transpiration are Light -stomatal opening,
with DNA ligase. DNA ligase is an enzyme femperature - increases rate of
that is able to join together two pot
r ions of transpiration. Humidity - low humidity
DNA and therefore plays an important role increases the rate of transpiration whereas
in DNA repair. DNA ligase is also used in high humidity exerts an opposite effect i.e.
recombinant DNA technology as it ensures decreases the rate. Wind -- High wind
that the foreign DNA is bound to the causes stomatal closure, thereby, reducing
plasmid into which it is incorporated. the rate of transpiration in plants.
124. (a) , hi situ means keeping endangered species 132. (d) Turgor pressure is the pressure that
develops in a cell due to osmotic diffusion
of animals or plants into natural
environment and not in the environment of water inside it and is responsible for
that looks like natural but man made, like
pushing the membrane against cell wall.
Stomata open under conditions of
zoological & botanical gardens. In situ
increased turgor pressure of guard cells and
includes, national parks, sanctuaries and
stomata get closed under conditions of
biosphere reserve.
decreased turgor pressure of guard cells.
125. (d) Monascus purpareus is a yeast used in the When turgid, they swell and bend outward.
production of statins which are used in As a result, the stomatal aperture opens.
lowering blood cholestrol. When they are flaccid, the tension from the
126. (b) Gel electrophoresis is a technique to wall is released and stomatal aperture
separation of DNA fragments according to closes.
their size. DNA is negatively charged so in 133. (d) Heterotrophic plants are less dependent on
gel tank when electric passed, DNA move nitrogen obtained from nitrification since
towards positive electrode. they receive some nitrite and nitrate through
127: (b) DNA or RNA segment tagged with a their parasitic or carnivorous nutritional
radioactive molecule is called Probe. They modes.
are used to detect the presence of 134. (b) Grana are present inside the chloroplasts.
complementary sequences in nucleic acid Each granum may contain 10 - 100
samples. Probes are used for identification thylakoids. Thylakoids or baggy trousers
and isolation of DNA and RNA. are membrane lined flattened sacs.
128. (d) Hot spots are those areas which were rich Thylakoids (or granna) contain chloroplast
in biodiversity but now under threat due to proteins, photosynthetic pigements and
direct or indirect interference of human other factors required for photosynthesis.
activites. These regions are on the edge to SECTION 4 -ZOOLOGY _
_
get some of their species extinct due to 136. (c) Movement of Ca~ out in sarcoplasmic
humans. Western Ghats in India are under reticulum controls the making and
threat due to continuous developmental breaking of actin and myosin complex
activities and Doon valley is under threat actoniyosin due to which muscle
due to continuous mining activities. contraction and relaxation takes place.
129. (a) Kaziranga National Park in Assam is famous Albert Szent Gyorgyi worked out
biochemical events of muscle contraction.
as a protection environmental park for
rhinoceros. 137 (d) Brain is the most vital organ. It stops
functioning in the absence of 07.
130. (c) Osmosis is the movement of solvent
138. (a) Elbow joint is an example of hinge joint.
particles from a region of low solute
The elbow is a hinge joint; it can open
concentration to a region of high solute
and close like a door. Hinge joint is a form
concentration through a selectively
of diarthrosis (freely movable joint) that
permeable membrane.
allows angular movement in one plane
only, increasing or decreasing the angle 153. (c) Catla catla and Labeo rohitu are the two
between the bones e.g. elbow joint, knee Indian major carps whereas I leleropneustes
joint etc. is a catfish. Cyprinus is the exotic breed.
140. (b) Posterior pituitary releases vasopressin 154. (c) Chimpanzees and gorillas are our closest
which stimulates reabsorption of water in relatives among the living primates.
the distal tubules in nephron. 155. (a) Adaptive radiation refers to evolution of
141. (c) The transmission of nerve impulse different species from a common ancestor.
through synapse requires a chemical The mammals are adapted for different
neurotransmitter. The most common mode of life i.e. they show adaptive
,
142. (c) Melanin is the pigment which gives colour (whale and dolphins), burrowing or fossorial
to the skin. Retinol is the other name for (rati, cursorial ( horse), scantorial (squirrel)
vitamin A. Sclerotin is the component of or arboreal (monkey). The adaptive
the carapace in crustaceans. radiation, the term by Osborn, is also known
143. (c) The smooth muscles of bronchioles show as Divergent evolution.
spasmic contraction during expiration in 156. (d) The most significant trend in evolution of
asthma. modern man (Homo sapiens) from his
144 (a) Egg is liberated from the ovary (ovulation) ancestors is development of brain capacity.
at secondary oocyte stage when the 159. (b) The terms Porifera was given by Grant, the
meiosis II is arrested in secondary oocyte. phylum includes animals with pores in their
It will be induced by the sperm. body. Its classification based on skeleton
145. (a) Stenohaline : Steno meaning narrow and or spicules.
haline meaning salt. A fish cannot handle a 160. (d) Squamous epithelium is formed of thin
wide fluctuation in salt content in water. discoidal and polygonal cells that fit like
Many fresh water fish tend to be tiles in a floor, so is also called pavement
stenohaline and die in environments of high epithelium. It is found in the walls of blood
salinity such as the ocean. Fish living in vessels, in the alveoli of lungs for exchange
,
coastal estuaries and tide pools are often of gas, and in Bowman s capsule of
euryhaline (tolerant to changes in salinity) nephron for ultra filtration.
as are many species which have life cycle 161. (d) Myoglobin is a single-chain globular
requiring tolerance to both fresh water and protein of 153 amino acids, containing
sea water environments such as Salmon. a heme (iron-containing porphyrin)
148. (c) Reproductive health in society can be prosthetic group in the center around which
improved by creating awareness among the remaining apoprotein folds. It has a
people about various reproduction related molecular weight of 16.700 daltons, and is
aspects and providing facilities and support the primary oxygen-carrying pigment of
for building up a reproductively healthy muscle tissues. Unlike the blood-borne
society. hemoglobin, to which it is structurally
149. (b) Foetal ejection reflex in human female is related, this protein does not exhibit
induced by fully developed foetus and cooperative binding of oxygen, since
placenta. When a woman is in a lithotomy positive cooperativity is a property of
or semi-sitting position, the foetal ejection multimeric/oligomeric proteins only.
reflex is impaired and the increased pain 164. (b) Malaria is caused by Plasmodium. Asexual
cycle of Plasmodium takes place in man
,