Beruflich Dokumente
Kultur Dokumente
TEST-II
CHEMISTRY
PART-I
SECTION–I
Single Correct Choice Type
3. (A)
Case I.
Calculation of pH of solution containing 1 mole of CH 3COONa + 1 mole of HCl per litre
CH 3COONa + HCl
→ CH 3COOH + NaCl
[ ]
∴ H+ = C
Ka
C
= K a C = K a = K1a/ 2
(
∵ C = 1 mol L−1 )
[ ] 1
∴ − log H + = − log K a
2
(pH )1 = − log K a
1
...(i)
2
Case II. Calculation of pH of solution containing 1 mole of CH 3COONa + 1 mole of
CH 3COOH per litre
Applying Henderson equation,
(pH )2 = pK a + log [Salt ] [salt] = [Acid] = 1 mol L−1 ]
[Acid]
= pK a = − log K a ...(ii)
(IV) Cl — C — CH
Cl O
H
Θ
6. (D) → C Cl 3 + H ⊕
CHCl3
Θ
→ C F3 + H ⊕
CHF3
Θ Θ
⇒ C Cl3 is more stable than C F3 due to pπ − dπ bonding.
Hence CHCl3 is more acidic, not CHF3 so, (I) is incorrect.
⇒ In chlorobenzene C – Cl bond length decreases due to resonance and hence its
dipolemoment is lesser than chlorocyclohexane. II is also incorrect.
⇒ Dipolemoment of fluoromethane is lesser than chloromethane due to very small
size of 'F' III is also incorrect.
⇒ Carbon and nitrogen atom containing organic compound gives positive test for
nitrogen in Lassaigne’s test.
SECTION–II
Integer Type
7. NaOH + HA → NaA + H 2O
HA + OH → A– + H2O
–
[A− ][H 2 O]
KC = −
= 1010 ...(1)
[HA] [OH ]
HA H+ + A– ,
weak acid
Ka =
[H ][A ]
+ −
... (2)
[HA]
Eq (1) Kc 1
=
Eq (2 ) Ka Kw
K a = K w × K c = 10 −4
A– + H2 O HA + OH–
[ ]
OH − = C.h = C
Kh
C
=
K w .C
Ka
[H ] = 10
+ −8
, pH = 8
Ans. 8
6−
8. CaMg3OSi4O11 → CaO + 3Mg2+ + Si 4 O11
Ans. 6
9. The isomers are
CH3 CH3 CH3 CH2Br CH2Br
H−C−Br H−C−Br Br−C−H H−C−Br and Br−C−H
H−C−Br Br−C−H H−C−Br CH2 CH2
CH3 CH3 CH3 CH3 CH3
∴ 5 isomers.
Ans. 5
11. The second nearest neighbour location of a Cs+ ion is body center of adjacent CsCl unit.
Ans. 6
O O O O
12. (B) 2−
OC2H5 + CO3 OEt
H Br
–Br–
Br
O O O O O O
2−
CO 3
OEt •• OEt OEt
–Br–
H CH2–CH2Br
Br
13. (C) In base catalysed mechanism, it is the enolate, which attacks the carbonyl group,
Base catalysed dehydration follows E1cB mechanism.
O O HO O
14. (A) •••O•
••
OH
+ •• •
H3O ••O• COOH
O
COOH
1.2 × 10 −24 cm 3
% occupied = × 100 = 3%
3.7 × 10 − 23 cm 3
SECTION –IV
Matrix Type
18. (A) – (p), (r), (t) ; (B) – (p), (s), (t) ; (C) – (q), (t) ; (D) – (s), (t)
Formic acid is oxidised to carbonic acid (H 2 CO 3 ) , which decomposes into CO2 and H2O.
It reduces Tollen's reagent.
HCOOH + Ag 2 O
→ 2Ag + H 2 O + CO 2
⇒ HCOONa + NaOH CaO → Na 2 CO 3 + H 2 ↑
⇒ Fumaric acid is trans-but-2-en-1,4-dioic acid is HOOC–C –H
⇒ Cinnamic acid is trans-3-phenylprop-2-enoic acid H – C – COOH
Ph – C – H
H – C – COOH
19. (A) – (q) ; (B) – (s), (t); (C) – (p) ; (D) – (r)
21. Let the speed of the instrument package be v when it grazes the surface of the planet.
Conserving angular momentum of the package about the centre of the planet
mv0 × 5 R sin θ = mvR sin 90°
⇒ v = 5v0 sin θ … (1)
Conserving mechanical energy
GMm 1 2
− + mv0
5R 2
GMm 1 2
= − + mv
R 2
1
⇒ m(v 2 − v02 )
2
4GMm
=
5R
⇒ v 2 − v02
8GM
= … (2)
5R
Substituting the value of v from equation (1) in equation (2)
8GM
25v02 sin 2 θ − v02 =
5R
1 8GM
θ = sin −1 1 + 2
5 5v0 R
∴ (B)
P
R/2 5R/2
R
P Q R/2 R/2
R
R/2 5R/2
(i)
Q
(ii)
i
5R/2 R/2
i1 R i-i1
i2
i1-i2 i-i1+i2 V ≡ V
3 1 Req
R/2
R i R/2
2
i1 2 i-i1
5R/2 R/2
i
(iv)
(iii)
Now, let a battery is connected between point P and Q as shown in the figure (iii) and its
equivalent is shown in the figure (iv)
Applying KVL in loop 1
(i − i1 ) R + (i − i1 + i2 ) R + (i − i1 ) R = V … (i)
2 2 2
Applying KVL in loop 2
+ i2 R − (i − i1 ) = 0
5R R
i1 … (ii)
2 2
Applying KVL in loop 3
i2 R + (i − i1 + i2 ) + i2 R = (i1 − i2 )
R R
… (iii)
2 2
From (i), (ii) and (iii)
20V V 23R
i= = ⇒ Req =
23R Req 20
∴ (A)
dB
23. E 2πl = π.R 2
dt 20cm
q
C
R 2 dB
E= K
2l dt
(0, 0) (1m, 0)
qE + mg = Kx
q.R 2 dB mg
x= +
K 2l dt K
1 qR 2 dB
x= mg + = 3 mm
K 2l dt
So, l0 = 20 + 0.3 = 20.3 cm
∴ (D)
1 8g
24. f0 =
2π 3πR
f =
(
1 2 g 16 + 9π
2
)
2π 9πR
∴ f = 0.9 f 0
∴ (D)
SECTION – II
Integer Type
1
26. Least count of screw gauge = mm = 0.01mm
100
Diameter of the wire = (1 + 25 × 0.01) mm = 0.125 cm
4Tl
Since Y =
πd 2δl
∆Y ∆l 2∆d ∆ (δl )
∴ = + +
Y l d δl
0.01 2 × 0.001 0.001
= + + = 0.0242.
50 0.125 0.125
∆Y
Percentage error = × 100 = 2.42
Y
∴ n=5
Ans.: 5
u Mu 3Mu N
27. ∫ Ndt = M + = v
2 2 2 2 2
v'
Mu ω' ω u/ 2
∫ − µ' Ndt = Mv'− µ' N µ' N
2 u/ 2
k
A v' ' B
∫ µ' Ndt = M A v' '
µ = 0.2
3Mu
µ' = M A v' '
2 2
v' ' = 2.5 m/s
1 1
M A v' '2 = kx 2 ⇒ x = 1m
2 2
300
kx = N = 18.75 N
16
µM B g = 20 N
Since kx < µMB g, the block must be at rest (i.e.,) vB = 0
∴ vB = 0 m/s
Ans.: 0
q12 ε AV
28. For middle plate Q, + kx = Mg ; q1 = 0
2ε 0 A l
P
Let lower plate R move upwards by y
q2
+ k ( x − y ) = Mg
2ε 0 A Q
l V
ε AV R
q= 0
l−x− y
−2 k
ε 0 AV 2 x + y
1 − + k ( x − y ) = Mg
2l 2 l
vc sin φ − v sin 30 0
t=
g
(vc cos φ)t + x = L sin φ u
vc cos φ v cos φ v
vc sin φ − c = L sin φ − x v = c , sin 30 0 = cos 60 0 = cos φ
g 3 3
gL cos φ
g sin φ cos φ −
cos 2 φ
(
= L sin φ − x vc = gL cos φ )
3
L cos 3 φ
x− = L sin 3 φ
3
30. V0 = Al = 5 ×10 −3 m 3 A
P0 , V0 , T 0 P0 , V0 , T 0
P0 = 2 × 10 5 N/m 2
m 28
n1 = = =1
M 28 k = 2 × 103 N/m
1 2 4 n1 n2
n2 = 2 × + = (n1 & n2 are the number of moles)
3 3 3 l l
5 7
Cv1 = R, C p1 = R
2 2
2 3 2 5
× R+ × R
Cv2 = 3 2 3 2 = 2R
2 2
+
3 3
C p2 = C v2 + R = 3R
C p2 3
γ2 = = = 1. 5
Cv2 2
7l 7 A
V1 = A × = 10 −2 × × 0.5 P1 , V1 , T 1 P2 , V2 , T 2
4 4
−3
V1 = 8.75 × 10 m 3
P2 = 8P0
P V − P0V0
∆W = 2 2
1− γ
∆W = −1414 J
∴ n=2
Ans.: 2
h1 + h
35. = h0
2
⇒ h = 1m
∴ (B)
−1 10
43. (C) Then z lies on the circle with centre of , 2 and radius = , then maximum
3 3
1 10 25
area of ∆PAB = × × 5 =
2 3 3
44. (C) B = ( I − A) ( I + A) −1 ⇒ B T = ( I + AT ) −1 ( I − AT )
= ( I − A) −1 ( I + A),
BB T = ( I − A) ( I + A) −1 ( I − A) −1 ( I + A)
= ( I − A) ( I − A) −1 ( I + A) −1 ( I + A) = I
(As ( I − A).( I + A) = ( I + A)( I − A))
46. ∴ f ( x + λ ) = f ( x)
5( x + λ ) 5x
⇒ cos n( x + λ ) sin = cos(nx) sin
n n
at x = 0
5λ
cos nλ sin = 0
n
if cos nλ = 0
π
nλ = r π + , r ∈ I
2
π
n(3π ) = rπ + (∵ λ = 3π )
2
1
(3n − r ) = (not possible)
2
5λ
∴ cos nλ ≠ 0 ∴ sin = 0
n
5λ 15
⇒ = pπ( p ∈ I ) ⇒ n =
n p
for p = ±1, ± 3, ± 5, ± 15
n = ±15, ± 5, ± 3, ± 1
Ans. 8
47. In radius of ∆ABC is 4
We have to find
abc
2(a + b + c)
∆
r=
S
S = a + b + c, ∆ = abc(a + b + c)
A a c B
b
C
Ans. 8
SECTION – III
Paragraph Type
Paragraph for Question Nos. 50 to 52
2
53. (A) equation of tangent at P 2t , is
t
2
x + yt = 4t
A ≡ (4t, 0),
4
B ≡ 0, ,
t
Hence area = 8 sq. unit. (constant)
1 1
55. (B) Shortest distance exist along common normal t 2 = ⇒ t=
2 2
Hence foot of common normal ( 2, 2 2 )
Hence shortest distance =
(
4 2 −1 )
5
SECTION - IV
Matrix Type
4 4 1
So, z = (c − b ) and x = a − y − z = a + 4c + (b − c ) = [3a + 4b + 8c ]
3 3 3
So, 3 x + 2 y + 3 z = 3a + 4b + 8c − 8c + 4c − 4b = 3a + 4c .