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Metals-Ceramics
Ashraf Bastawros
www.public.iastate.edu\~bastaw\courses\Mate271.html
6 0.414-0.732 Octahedron
rcation /r anion
Material Sciences and Engineering MatE271 Week 3 6
FCC
BCC
BCC FCC
Graphite hexagonal
Material Sciences and Engineering MatE271 Week 3 10
Cs
Cr
Cl
Ca2+
_
F
Lattice: FCC
Chemical formula: MX2 _
Ion/ Unit Cell: 4 Ca2++ 8 F = 12
Typical Ceramics: UO2 , ThO2 , and TeO2
Lattice: hexagonal
Chemical formula: M2X3 _
Ion/ Unit Cell: 12 Al3++ 18 O2
= 30
Typical Ceramics:
Al2O3 , Cr2O3 , α Fe2O3
Lattice: SC
Chemical formula: M’ M’’ X3
Atoms per lattice point = Ferroelectric
Piezoelectric
Ion/ Unit Cell =
Carbon - Graphite
not
hcp
Buckyball
C60
Glass Structure
¬ The basic structural unit of a silicate glass is
the SiO4 tetrahedron
¬ Link together sharing corners to form a 3-D
network
Atomic Densities
- Why do we care?
- Properties, in general, depend on linear and planar
density.
- Examples:
- Speed of sound along directions
- Slip (deformation in metals) depends on linear & planar
density
- Slip occurs on planes that have the greatest density
of atoms in direction with highest density
(we would say along closest packed directions on the closest packed
planes)
Material Sciences and Engineering MatE271 Week 3 26
Linear Densities
fraction of line length in a particular direction
that passes through atom centers
Planar Densities
fraction of total crystallographic plane area that
is occupied by atoms (plane must pass
through center of atom)
LD = LC/LL linear
density
LC = 2R circle length
LL = a line length
LD = 2R/(2R√2) = 0.71
C A B C
B
A
D E F
F
E • Compute planar area
• Compute total “circle” area
D
Semiconductor Structures
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