Problema

Si 100 Mol/h de una mezcla son vaporizados instantaneamente

de 150° F y 50 Psia encuentra los moles de vapor de liquido
formados por hora.

Modelo matematico
Ecuaciones flas isotermico
1) Balance por componente 2) Balance general
�_𝑧𝑖= 𝐿_𝑥𝑖+𝑉_𝑦𝑖 �=𝐿+𝑉

3) Balance de energia 4) Relacion de equilibrio

�+�𝐻_�=𝑉𝐻_𝑉+𝐿𝐻_𝐿 �_𝑖=𝐾_𝑖 𝑋_𝑖

5) Fraccion vaporizada
𝑋_𝑖= 𝑍_𝑖/(Θ (𝐾_(𝑖 )−1)+1) �_𝑖= (𝐾_𝑖 𝑍_𝑖)/(Θ (𝐾_𝑖 −1)+1)

∑24_(𝑖=1)^(𝑛. 𝐶)▒ 〖 ((𝐾_𝑖 −1) 𝑍_𝑖)/(Θ (𝐾_𝑖 −1)+1)=0 〗

Ecuacion derivada Metodo de N-R

− ∑24_(𝑖=1)^(𝑛.𝐶)▒ 〖 (𝑍_𝑖 (𝐾_𝑖 −1)^2)/[1+ Θ(𝐾_𝑖 −1) ]^2 =0 〗 Θ= Θ/Θ^´

 V

T=
T= 65.55°C P=

Zi Alimentacion F = 100 Mol

0.0079 C6H6 P = 344.73
KPa
0.1321 C3H8 F
0.0849 i-C4H10
0.269 n-C4H10
0.0589 i-C5H12
0.1321 n-C5H12
0.3151 n-C6H14 L
HL Xi
Componente Yi Hv
C6H6
C3H8
i-C4H10
n-C4H10
i-C5H12
n-C5H12
n-C6H14

65.55
344.73

Componente
C6H6
C3H8
i-C4H10
n-C4H10
i-C5H12
n-C5H12
n-C6H14
 parametros de Antoine
componente A B C temperatura presion kPa
C6H6 13.7819 2726.81 217.572 65.55 3.4473 344.73
C3H8 - - - 65.55 3.4473 344.73
i-C4H10 13.8254 2181.79 248.87 65.55 3.4473 344.73
n-C4H10 13.6608 2154.7 238.789 65.55 3.4473 344.73
i-C5H12 - - - 65.55 3.4473 344.73
n-C5H12 13.7667 2451.88 232.014 65.55 3.4473 344.73
n-C6H14 13.8193 2696.04 224.317 65.55 3.4473 344.73
°C bar

psat
63.4772103627 kPa k1 0.184136021 C6H6
1592.4927675 kPa k2 4.619536355 C3H8
978.7789200348 kPa k3 2.839262379 i-C4H10
721.1636662531 kPa k4 2.091966659 n-C4H10
91.7 kPa k5 0.266005279 i-C5H12
251.3532094834 kPa k6 0.729130651 n-C5H12
91.6837114046 kPa k7 0.265958029 n-C6H14

fraccion vaporizada Xi Yi
-0.0219134904 -0.004035063
0.0187753461 0.086733394
0.0208748517 0.0592691811
Zi
0.0079 0.5
0.1321
0.0849
0.269
0.0589
0.1321
0.3151

teta sup ƒ(teta sup) ƒ´(teta sup) teta cal error

0.5 0.2406302758 -0.3121545 1.2708691 -0.6065685
1.2708691 0.3070480615 -3.9521096 1.34856129 -0.0576112
1.34856129 0.1904646471 -0.5970556 1.66756782 -0.1913005
1.66756782 0.1242308048 -0.0927842 3.00648974 -0.4453439
 interpolacion de compuesto Pa
Xo 80 YO 1765197
X 65.55 Y=? 1592492.77
X1 40 Y1 1287123

Y=�_𝑜+ (�_1 − �_0)/(𝑋_1 − 𝑋_0 ) ∗ (𝑋 −𝑋_0 )

Pascal Kpa
1 0.001
1592492.77 1592.49277