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Colombian Emeralds and Evaporites: Tectono-


Stratigraphic Significance of a Regional
Emerald-bearing Evaporitic Breccia...

Conference Paper · September 2015

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Colombian Emeralds and Evaporites: Tectono-
Stratigraphic Significance of a Regional Emerald-bearing
Evaporitic Breccia Level
Yannick Branquet
ISTO, UMR 7327-CNRS/Université d’Orléans/BRGM,Orléans, France
Géosciences-Rennes UMR6881-CNRS/Université de Rennes I, 35042 Rennes Cedex, France

Gaston Giuliani
IRD-LMTG, 24, avenue Édouard-Belin, 31200 Toulouse, France
CRPG-CNRS, Nancy université, 15, rue Notre-Dame-des-Pauvres, 54501 Vandœuvre-lès-Nancy, France

Alain Cheilletz, Bernard Laumonier


GeoRessources UMR 7359-CNRS/Université de Lorraine/CREGU, Nancy, France

Abstract. In the eastern front of the Colombian Eastern 2 Geological and emerald deposits settings
Cordillera, all the emerald and evaporite deposits and
occurrences are hosted within a peculiar stratigraphic level The Eastern Cordillera (EC) of Colombia is a back-arc
at the Berriasian/Valanginian transition. This level contains basin inverted during the major Middle Miocene Andean
evidence of sabkha evaporitic sediment reworking and
destabilization on active sedimentary slopes. A main
tectonic event. As the result of inversion, thick Lower
stratiform breccia is interpreted as a residual breccia Cretaceous depocenters are at the core of large
resulting from salt ablation through dissolution during an anticlinoria flanking the eastern and western foothills of
emerald-related hydrothermal event and weathering. At 65 the EC. Localized in both anticlinoria, major Colombian
Ma, the emerald deposits formed in local extensional emerald deposits are hosted within Lower Cretaceous
structures related to the initiation of a foreland bulge and black shales, and are clustered into the western (e.g.
associated flexure. A kind of bedding-parallel fibrous Coscuez and Muzo deposits) and the eastern (e.g. Chivor
calcite and pyrite veins (called “beef” by reservoir and Gachala mining districts) emerald belts (Fig. 1). Here,
geologists implied in rock mechanics) attest to a supra- we only address the eastern emerald belt in the Chivor
lithostatic hydrothermal fluid pressure prevailing shortly
before emerald deposition. Significant migration of hot,
area. This area corresponds to the EC frontal fold and
deep (5-6 km) and overpressurized fluids occurred along thrust system onto the easternmost Llanos foothills. The
the eastern border around the K-T boundary. Finally, eastern emerald deposits of the Chivor district formed at
halokinesis during Lower Cretaceous rifting likely needs to 65 ± 3 Ma (Cheilletz et al. 1997) and are associated with
be re-evaluated, at least on the Chivor district scale. a strong hydrothermal alteration leading to albization,
pyritization and carbonatization, the last two being
Keywords: Colombian emerald, Eastern Cordillera, achieved through thermal sulfate reduction.
Chivor mining district, breccias, “beef” veins, evaporite
3 A regional Emerald-bearing Evaporitic
1 Introduction
Breccia Level (EEBL)
It is well established that Colombian emeralds formed
3.1 Litho-stratigraphy
from basinal brines which dissolved evaporites hosted
within the Lower Cretaceous sedimentary sequence of the Field structural and stratigraphic studies undertaken in the
Eastern Cordillera (Giuliani et al. 1995). These works Chivor mining district allow us to identify a peculiar
demonstrated the genetic relationship between emeralds stratigraphic level which hosts the emerald deposits and
and evaporites through mineralogy, fluid inclusion and gypsum occurrences (Figs. 1 and 2). This EEBL forms the
stable isotope studies. No evaporitic rocks were reported basal member of the upper part of the Tihonian-Berriasian
and described in the Colombian emerald deposits before Guavio formation.
Branquet et al. (1999a). However, old field studies dealing In emerald deposits and occurrences, the EEBL is
with salt core bodies in the central part of the Eastern characterized by: i) a main breccia stratiform level, which
Cordillera, reported emeralds mined within cap rock overlies the lower black shales and is mainly composed of
residual breccias called “rute” in Colombia (Scheibe dismembered and crushed black shales mixed with cm- to
1933). To our knowledge, since Branquet et al. (1999), no meter sized white albitite clasts (Fig. 3A, B, D). The lower
works dedicated to the tectono-stratigraphic controls on contact of the main breccia is broadly concordant with the
the Colombian emeralds and their relation with evaporites underlying bedding. A ubiquitous planar fabric within the
have been published. In this paper, we present detailed breccia indicates that bedding is locally preserved within
field, petrological and structural evidence highlighting the the main breccia. In contrast, the upper contact of the
role of evaporites in the formation of the eastern emerald breccia is irregular with caving structures and appears to
belt. be discordant with overlying bedding in some places (Fig.
3A, B); ii) hecto- to decametric stratoid bodies of white
albitites lying just above and/or below the main breccia
level (Fig. 2). Generally, albitites below the main breccia stratoid bodies made up of alternating
level show no peculiar textures and appear as alteration dolomicrite/gypsum layers (Fig. 3C). The gypsum-
halos in black shales. Upper albitites are different as they bearing bodies are embedded within a black shale breccia
show replaced and hydrothermalized nodules, tepee and similar to the main breccia level observed in the emerald
entherolitic structures which argue for the evaporitic deposits. The dolomicrite/gypsum alternations show
origin of the protolith (cf infra). In several emerald gypsum nodules which are more or less flattened,
deposits this EEBL is overlain by carbonated black shales entherolithic structures and numerous gypsum veinlets.
including limestones lenses and olistotroms (Figs. 2 & 3). At the Chivor area scale, the upper Guavio Fm. and
Hosted within the EEBL (Fig. 1), the gypsum specially the EEBL, is continuous but very heterogeneous
occurrences correspond to decametric white irregular with regard to lithologies and thicknesses (Fig. 2).

Figure 1. A. simplified geological map of the Colombian Eastern Cordillera. Inset is B location. B. Geological map of the Chivor
area. All emerald and gypsum deposits/occurrences are hosted within the upper Guavio Fm.

3.2 Hydrothermal alteration and weathering subsequent carbonate dissolution in the polygenic breccia.
In the evaporite occurrences, primary anhydrite nodules
The degree of hydrothermal alteration within the EEBL is replaced by gypsum are karstified, and veinlets and listric
highly variable. Only one hydrothermal event is cm-scale faults are filled with secondary fibrous gypsum.
recognized. It is responsible for emerald deposition
through carbonatization, ablitization and pyritization. In 3.3 Structures
the emerald deposits this alteration is at a maximum and
is particularly responsible for the transformation of Sedimentary and soft sediment deformation is widespread
dolomicrite/evaporite lenses into white albitites through in the EEBL. In particular, the basal contact of the EEBL
Na metasomatism. Emerald-bearing veins are mainly is marked by slumps, groove marks, hydro-plastic Riedel
filled with calcite, dolomite, albite and pyrite. This shears and meter-thick layers of intraformational breccias.
paragenesis also constitutes the hydrothermal cement of a During hydrothermal alteration leading to emerald
peculiar emerald-bearing polygenic breccia composed of deposition, sub-vertical veins that represent mineralized
black shale and white albitite clasts (Fig 3 D). This breccia listric normal faults attest to a small amount of horizontal
is sparsely found near the top of the main breccia level stretching of the bulk EEBL, the main breccia level acting
(Fig. 3B) and also fills polygenic breccia dykes (Fig. 3A). as a “detachment” plane (Fig 3A, Branquet et al. 1999).
In the gypsum occurrences, hydrothermal fluid/rock Polygenic breccia dykes crosscutting the upper albitites
interactions are weaker but isolated albite and pyrite are compatible with such horizontal stretching (Fig. 3A).
crystals are frequent in thin sections. Noteworthy, non- Within the main breccia level in the emerald mines,
cemented polygenic breccias (black shale and white albitites clasts are dragged and dismembered (Fig. 3B).
dolomicrite/gypsum clasts) occur locally in the Guali Such structures associated with scarce drag folds and
gypsum occurrences. Finally, with the exception of the La disharmonic folds demonstrate transport and
Guala emerald occurrence (Fig. 2), no hydrothermal displacement within and along the main breccia level.
alteration occurred in the Valanginian Macanal black Moreover, the albitites host numerous bedding-parallel
shales overlying the EEBL. fibrous calcite/pyrite veins i.e. “beef” (Fig. 3E) which are
The EEBL is strongly weathered. Present-day generally barren and pre-date the emerald deposition. The
meteoric waters flow through the main breccia level in the lack of strong hydrothermal alteration affecting the
emerald deposits, triggering pyrite oxidation and gypsum occurrences makes such deformation difficult to
identify at those places. Miocene Andean compression (Fig. 1, Branquet et al.
Finally, the weakness of the EEBL locally enhances its 2002). This thrusting is attested to by “dry” shear bands
reactivation as thrust and decollement during Middle and friction slickensides.

Figure 2. Litho-stratigraphic synthesis and correlations between the emerald deposits/occurrences in the Chivor district. Logs are
located on Fig. 1. The main breccia level and albitites are hydrothermalized facies hosting most of the emerald deposits at the top of
the Guavio Fm.

Figure 3. A. Cross-section through the Chivor emerald deposit. B. Upper contact of the main breccia level with albitites (1), Chivor
Klein pit. Drag of albitite clasts within the breccia (2) is marked by tails. C. Evaporites at the Paez Gypsum mine (northeast of Fig.
1B) showing alternation of dolomicritic limestones and gypsum beds. D. Polygenic breccia cemented by pyrite, carbonates and albite,
Oriente deposit. E. “Beef” vein composed of fibrous calcite in albitites, Chivor Klein pit.

4 Interpretation emerald-related hydrothermalism at 65 Ma.


The EEBL is a complex and polyphased breccia.
Using our structural works which depict Andean Dolomicritic thin layering, nodules, entherolitic and tepee
deformation patterns, we established that emerald structures are diagnostic of evaporite deposition in a
deposits and evaporites of the Chivor area are hosted in sabkha environment. Soft-sediment deformation,
the same stratigraphic level at the top of the Berriasian intraformational breccia and discontinuous albitites and
Guavio Fm. In the emerald deposit, ancient evaporites evaporite bodies argue for reworking of the sabkha
made of alternating dolomicrite/anhydrite or gypsum beds environment through slope instabilities, block break-off
have been massively metasomatized into albitites. This and slide down-slope. Overlying the EEBL, black shales
albitite protolith is exposed in gypsum occurrences which with ammonites and olistotroms indicate more open
appear to be EEBL segments partly “preserved” from the marine conditions coeval with slope instabilities.
Therefore, we propose that the EEBL corresponds to simple shearing (Warren, 2006). However, several lines of
sabkhas reworked and partly dismembered during the evidence argue for halokinesis: (i) weathering and
Early Cretaceous major transgression, which is coeval hydrothermal alteration may have obliterated shear
with the important rifting event which affected the eastern criteria; (ii) cut-off of albitites lenses above the main
border of the EC back-arc basin at that time. breccia level is evidence of block rotation in roll-over;
In this context, the main stratiform breccia level in the (iii) cm-scale disharmonic folding has been observed in
emerald mines and the similar breccias embedding one location; (iv) a panel of EEBL is found above the
dolomicritic gypsum lenses in the evaporite occurrences normal fault plane cutting the Paleozoic basement (Fig. 1,
are likely vanished salt-bearing sediments. Halite was Branquet et al. 2002), suggesting evaporite-lubricated
removed through various dissolution events from emerald draping structures. During the Cretaceous rifting, no thin-
related hydrothermalism at 65 Ma to present-day meteoric skinned extensional tectonics implying evaporites at the
weathering. This interpretation is strengthened by the basin scale has been reported in the EC to date.
close resemblance existing between the main breccia level Contractional salt bodies of the central part of the EC (Fig.
and the “rute” (cf supra.). 1) have a Lower Cretaceous mother salt rock but no
At 65 Ma, large flows of hydrothermal fluids extension-related diapiric origin has been reported to date.
responsible for emerald deposition occurred through the Therefore, we cannot exclude that the main breccia level
EEBL level and dissolved halite. Structures coeval with behaved as a salt weld prior to emerald deposition at 65
those fluids flows are connected to the main breccia level Ma. Further studies are required to ensure this point.
which acted as a major fluid drain. Detachment within the Finally, the EEBL is a major metallotect in the Chivor
main breccia level and associated extensional mineralized mining district. On a larger scale, the emerald exploration
structures described in Branquet et al. (1999a) do not strategy on the eastern edge of the EC has to focus on
correspond to large extensional strain at the eastern border lateral stratigraphic equivalents of evaporite and black
of the EC around the KT limit. The observed structures shale breccia occurrences.
are rather diagnostic of hydraulic fracturing associated
with evaporite solution within the salt-bearing main Acknowledgements
breccia level. Barren calcite beefs observed in albitites
indicate that high fluid pressures prevailed at least during P. R. Cobbold is greatly thanked for recent discussion.
the incipient stage of hydrothermalism. As no horizontal
shortening is reported (Branquet et al. 1999), mechanical References
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