RFT-6 Key+sol

JEE | MEDICAL-UG | BOARDS | KVPY | NTSE | OLYMPIADS
Date: 09-03-18 RAO FULL TEST - [6]

Max. Marks : 360
Batch: Target-18 Main Level
ANSWER KEY
PART-A: MATHEMATICS
1. (D) 2. (B) 3. (C) 4. (C) 5. (A)
6. (A) 7. (B) 8. (D) 9. (B) 10. (B)
11. (C) 12. (A) 13. (C) 14. (C) 15. (A)
16. (C) 17. (C) 18. (C) 19. (B) 20. (A)
21. (B) 22. (A) 23. (C) 24. (C) 25. (D)
26. (C) 27. (A) 28. (C) 29. (C) 30. (A)
PART-B: PHYSICS
31. (B) 32. (B) 33. (C) 34. (D) 35. (D)
36. (B) 37. (B) 38. (B) 39. (A) 40. (D)
41. (A) 42. (B) 43. (A) 44. (B) 45 (D)
46. (C) 47. (D) 48. (B) 49. (A) 50. (C)
51. (A) 52. (C) 53. (C) 54. (A) 55. (D)
56. (B) 57. (C) 58. (C) 59. (D) 60. (B)
PART-C: CHEMISTRY
61. (B) 62. (D) 63. (B) 64. (C) 65. (D)
66. (D) 67. (D) 68. (B) 69. (B) 70. (C)
71. (C) 72. (A) 73. (B) 74. (A) 75. (B)
76. (C) 77. (B) 78. (A) 79. (B) 80. (B)
81. (A) 82. (A) 83. (B) 84. (C) 85. (C)
86. (D) 87. (D) 88. (C) 89. (D) 90. (B)
Rao IIT Academy / JEE -Seniors Target-2018 / Rao Full Test - 6 / Main Level / Key + Solutions
PART-A: MATHEMATICS
====================================
1. (D)
2
 
c  c . a  b  ca b 
2

b  b . b  b c  a  bca 
2
 
a  a . a  a b  c   abc 
 a  b  c so  is equilateral.
or 2 = b  c  c  a  a  b
 a  b c
  ABC seems to be equilateral. But a , b , c represents the sides of a triangle, therefore they
must be coplanar and so  a , b , c = 0 i. e.,
| a |  | b |  | c | 0
Therefore, a , b , c cannot form a triangle.

Topic:- Vectors_L-1
2. (B)
x > 0, g (x) is bounded.
f  x  e nx  g  x 
 lim
n  1  e nx
f  x   g  x  / e nx
= lim = f (x) .
n  1  1/ e nx
Topic:- Limits_L-1
3. (C)
sec2 x  1
I  sec x dx
sec x sec x  1
sec x tan x
 dx
sec x sec x  1
Putting sec x – 1 = y2, sec x tan x dx = 2 ydy.
ydy
 I2  y  2 tan 1 y
2
 1 y
= 2 tan–1 sec x  1  c
 gx   sec x  1 and f(x) = tan–1 x

Topic:- Integration_L-1
22
4. (C)
Since 1 + r + r2 + r3 + r4 + r5 + r6 = 0, r7 = 1
 +  = r + r2 + r4 + r3 + r5 + r6 = – 1
 = r4 +r6 +1 + r5 +1 + r +1 + r2 + r3
=3–1=2
2
 required equation is x + x +2 = 0
Topic:- Complex Number_(Roots of unity)_L-1
5. (A)
n n
r r n r n
  1
r0 r 1
C r    1 C r
0
r 1 n
  1 Cr
r 1
n
r 1 n 1
= 0    1 . C r1
0 n 1
1 1
=
n 1
0  n 1 C 0  
n 1
Topic:- Binomial Theorem_(Summation of series)_L-1
6. (A)
System of equations is
x+y+z=6
x +2y + 3z = 10
x +2y + z = 
1 1 1
A  1 2 3   3
1 2 
6 1 1
A x  10 2 3  2    16
 2 
System has infinitely many solutions if
A = Ax = Ay = Az = 0
  = 3, = 10. For these values of  and , it can be easily verified that for
 = 3, = 10
Ay = Az = 0
  = 3,  = 10
Topic:- System of equations_L-1
33
7. (B)
Let y = mx be one of the lines, then
dm3 + cm2 + bm + a = 0
Let two lines y = m1x & y = m2x make complementary angles with x-axis in anticlockwise sense,
then m1 = tan , m2 = tan (90o – ).
 m1m2 = tan  cot  = 1.
Then m1m2m3 = m3
a
 m3   which is a root.
d
a3 a2 a
 d 3
 c 2
b a 0
d d d
 a – ac + bd – d2 = 0
2
 a(a – c) = d(d – b)
Topic:- Straight Lines_L-1
8. (D)
Let OA = OB = OC = r
Then a  ri, c  r j
1
are AB  are BC
2
 BOA   / 6
y  b = r cos  / 6i
C
+ r sin  / 6 j
c B
b 3 1
= a c
/6 x 2 2
O a A
 c  2b  3 a
Topic:- Vectors_L-1
9. (B)
e1/ h  1 1  1/ e1/ h
f (0 + 0) = lim  lim  1.
h 0 e1/ h  1 h0 1  1/ e1/ h
e1/ h 1
f (0 – 0) = lim  1
h0e1/ h 1
f (0 – 0)  f (0 + 0)  f (x)
has non-removable discontinuity at x = 0.
Topic:- Continuity_L-1
44
10. (B)
1
 x  x  5 dx
2
I =
1
1
  (x  x  5)  [x 2  x  5] dx
2
=
1
1
 x  x  [x 2  x] dx  I1  I 2 .
2
=
1
1
 x  x  dx  2 / 3.
2
I1 =
1

1, 1  x  0

 5 1
– < x < 1  [x + x] = 0,
2 0x 
 2
 5 1
1,  x 1
5 1  2
0 1
 I =   1 dx    0  dx   511 dx
2
2 1 0
2
5 1
= –1+ 1–
2
2 5 1 1 3 5
 I = I1 – I2 =  
3 2 6
11. (C)
Let the rod AB rest with the end B on the wall and string AC, attached at A and to a point C on the
wall above B.
C
T
O R
B

G
M L A
W
Since the reaction at B which is perpendicular to the wall and the line of action of weight W at G,
meet at O, so the string AC will also pass through O.
Given AC = l, AB = a.
Since G is the middle point of AB, and OGL is parallel to CBM.
 O is middle point of AC and L is middle point of AM.
Now OL = BM = AB cos  = a cos 
1 1 1
AL = AM = AB sin  = a sin .
2 2 2
55
In right angles OLA, we get
OA2 = OL2 + AL2
1 2 2
or (l/2)2 = a2 cos2 + a sin 
4
or l2 = 4a2 cos2 + a2 ( 1 – cos2)
 cos2  = (l2 – a2) /3a2
Topic:- Vectors, Trigonometric ratios_L-1
12. (A)
In 17, 21, 25 ,........., 417, number of terms = 101.
and Tn = 17 + (n – 1) 4.
In 16, 21, 26,...., 466, number of terms = 91
and Tm = 16 + (m – 1) 5.
Tn = Tm  17 + (N – 1) 4 = 16 + (M – 1) 5, 1  n  101,
1  m  91 .
 5m – 4n = 2. n = m = 2 is a solution.
Then n = 2, 7,......,; 2 + (k – 1) 5  101  k  20
Also m = 2, 6, 10,.......
Hence, there are 20 common terms.
Topic:- Sequence and Series_L-1
13. (C)
Number of lines from 6pts. = 6C2 = 15. Points of intersection obtained from these lines.
= 15C2 = 105.
Now we find the number of times, the original 6 points come.
Consider one point say A1. Joining A1 to remaining 5 points, we get 5 lines, and any two lines from
these 5 lines give A1 as point of intersection.
 A1 appears 5C2 = 10 times in 105 points of intersections.
Similar is the case with other five points.
 6 original points come 6 × 10 = 60 times in the points of intersection.
Hence the number of distinct points of intersection
= 105 – 60 + 6 = 51
Topic:- Permutation and Combination_L-1
14. (C)
A is idempotent  A2 = A.
1 x  1 x  1 3x  1 x 
  0 2  0 2    0 4    0 2
      
Which is not possible for any x.
Topic:- Matrices_L-1
66
15. (A)
f (x) = [x] + x
f (1) = 1 + 0 = 1.
f 1  0   lim 1  h   1  h  lim1  h 1.
h0 h0
f 1  0   lim 1  h   1  h  lim 0 1 h  1
h 0 h 0
 f (x) is continuous at x = 1.
1  h   1  h  f 1
Lf ' 1  lim
h 0 h
0  1 h 1
=  lim
h0 h
=  lim
1  h   1 1

h 0
h  1  h 1  2
1  h   1  h  f 1
Rf ' 1  lim
h0 h
1  h 1
= lim   .
h 0 h
 At x = 1, f (x) is continuous but not differentiable.
Topic:- Limits, Continuity, Differentiability_L-1
16. (C)
In CAL and CME
k2 + a2 / 4 = h2 + b2 / 4 = r2
Y
 4 (h2 – k2) = a2 – b2
 Locus of (h, k) is
D
M h C (h, k)
b/2 r
E r' k
OA a/2 L X
B
4(x2 – y2) = a2 – b2
Topic:- Circle_(Power of point)_L-1
17. (C)
Let l1, m1,n1 and l2, m2, n2 be the d. r. ‘s of the lines in which the planes
3x – 7y – 5z = 1 and 5x – 13y + 3z + 2 = 0 cut the plane 8x – 11y + 2z = 0, then
77
3l1 – 7m1 – 5n1 = 0
8l1 – 11m1 + 2n1 = 0
 l1  m1  n1
69 46 23
and 5l2 – 13m2 + 3n2 = 0
8l2 – 11m2 + 2n2 = 0
l2 m2 n2
  
7 14 49
If  is the angle between the two lines, then
l1l2 + m1m 2 + n1n 2
cosθ = =0
 l12 + m12 + n12   l22 + m22 + n 22 
  =  /2
Topic:- 3-D Geometry_L-1
18. (C)
x 1
f x 
x 1 x 1
 1 2 1
2  x 1  x 1
f x  f    
 x  1  x  1  1 2x x
x 1
 1 
  1 x  1
3  1   x 
f x  f    
 x   1   1 1  x
 
 x 
x 1
 1 2x
f 4 x  1 x  x
x 1 2
1
x 1
 f4 = I (identity function)
 f1998 (x) = (f4)499 (x) . f(2) (x) = – 1/x
1 1
  f 1998  x dx    1/ x  dx
1/ e 1/ e
1
 log  x  1/ e   0  log 1/ e   1
Topic:- Function/ Integration_L-1
88
19. (B)
arg (z2 – z1) – arg (z – z1) z2
= arg (z – z1) – arg (z3 – z1)

z1
 z 2  z1   z  z1  z
 arg  z  z   arg  z  z 
 1   3 1
z3
 z lies on the angle bisector of 
z1z 2
and 
z1z3
 locus of z is a straight line.

Topic:- Complex Numbers_L-1
20. (A)
(a, a)  R, (a, a)  S  (a, a)  R  Sa  A
 R  S is reflexive.
Let (a, b)  R  S  (a, b)  R, (a, b)  S
 (b, a)  R, (b, a)  S
 (b, a)  R  S .
 R  S is symmetric.
(a, b), (b, c)  R  S  (a, b) (b, c)  R ,
(a, b), (b, c)  S   a, c   R , (a, c)  S
 (a, c)  R  S
 R  S is transitive.
Hence, R, S are equivalence relations
 R  S is also equivalence.
 Choice (a) is true.
Let on set A = {1, 2, 3}, R = {(1, 1), (2, 2), (3, 3), (1, 2), (2, 1) },
and S = {(1, 1), (2, 2), (3, 3), (1, 3), (3, 1) }.
Then both R and S are equivalence relations. Also,
R  S = { (1, 1), (2,2), (3, 3), (1, 2), (2, 1), (1, 3), (3, 1) }.
Then R  S is reflexive and symmetric but not transitive since (2, 1), (1, 3)
 R  S but (2, 3) 
 R S .
Therefore , R  S is not transitive.
Topic:- Relations_L-1
99
21. (B)
S.D. between the lines
x   y  z  
 
l m n
x  ' y ' z   '
and   is given by
l' m' n'
   '   '    '
S. D. =
l m n     mn ' m 'n  2
l' m' n'

Here lines are
x 1 y  2 z  3
   r  say 
2 3 4
x 2 y4 z5
and    s  say 
3 4 5
2 2 2 2
   mn ' m 'n    1   2   1   6
 
1 2 2
1
S.D.  2 3 4  6 
 6
3 4 5
i j k
Aliter : n  2 3 4  i  2j  k.
3 4 5
 1
 n
6

i  2 j  k 
A = (1, 2, 3), B = (2, 4, 5)  AB  i  2 j  2k.
1 1
S.D. = AB . n  1  4  2 
6 6
Topic:- 3-D Geometry_L-1
22. (A)
m

y  x  1 x2 
m 1  2x 

 y1  m x  1  x
2
 . 1 
2
 2 1 x 

m
 
1  x 2 y1  m x  1  x 2   my
2x m2 y
 1  x 2 y 2  y1   my1 
1  x2 1  x2
 (1 + x2) y2 + 2xy1 = m2y
Topic:- Differentiation_L-1
110
0
23. (C)
3 normals can be drawn to a parabola through any point.
Topic:- Parabola_L-1
24. (C)
The curve y  x is
Y
2
1
y2 y2
X
O 1
y 2  x,  y  0  . .......(1)
Points of inersection of the curves (1) and curve
y = x3 ........(2)
are (0, 0) and (1, 1).
 Required area
1 1
=  y
0
1  y 2  dx 
0
 
x  x 3 dx  5 /12
25. (D)
Graph of the function is strictly above x-axis if
16x2 + 8(a + 5)x – 7a – 5 > 0  x,  R
 64 (a + 5)2 + 64 (7a + 5) < 0
 a2 + 17a + 30 < 0
 – 15 < a < – 2.
But a   20, 0 
 Probability = 13 /20
Topic:- Quadratic Equation, Probability_L-1
26. (C)
x 2 y2 dy xb2
  1  dx  
a 2 b2 a2y
x 2 y2 dy xm 2
 1  
l 2 m2 dx l 2 y
Curves cut orthogonally.
111
1
x 2 b2 m2
  y 2l 2a 2  1
x 2 l 2a 2
or 2  2 2 .
y bm
From the equation of the curves, we get
1 1  1 1 
x 2  2  2   y2  2  2   0
a l  b m 
x2  m 2  b 2  a 2l 2 l 2 a 2
 y2   m2b2 l 2  a 2  b2m2
 
 m2 + b2 = – l2 + a2
or a2 – b2 = l2 + m2
Topic:- Ellipse, Hyperbola_L-1
27. (A)
x2 + y2 – 2y – 3 = 0
C
D B
 x2 + (y – 1)2 = 22  2
x  1:x  0 A (0, 1)
y= | x | + 1 y=  .
 x  1:x  0 O
 CAB   / 4

 Required area = .4  
4
Topic:- Circles_L-1
28. (C)
Using the weighted H.M. formula
n
1 1 fi

H N
x
i 1 i
or H  1
n
1 fi
N
x
i 1 i
 Average speed
400
=  192mph
 1 1 1 1 
100     
 100 200 300 400 
Topic:- Mean, Averages_L-1
112
2
29. (C)
Sine rule gives
a b c
   R.
sin A sin B sin C
 da = R cos A dA, db = R cos B dB
and dc = R cos C dC.
da db dc
  
cos A cos B cos C
= R(dA + dB + dC) ....(1)
Also A + B + C =  (constant)
so dA + dB + dC = 0 ....(2)
From (1) and (2) we have
da db dc
  0
cos A cos B cos C
Topic:- Solution of Triangle_L-1
30. (A)
dy x 2  y 2
 , put y = x. Then
dx 2xy
d 1   2
x 
dx 2
2 dx
 2
d 
1  x
2
 – log (1 –  ) = log x + log c
 x 1  y / x   c  0
2 2
x 2  y2
 c 0
x
x = 2, y = 1  c = – 3/2
 Equation of the curve is
3
x2 – y2  x  0
2
 (x – 3/4)2 – y2 = 9/16
This hyperbola is rectangular, therefore its eccentricity 2 .
Topic:- Differential Equation_L-1
113
3
PART-B: PHYSICS
====================================
31. (B)
q +
C – 2R
O i
2
q
V0  2  2iR   V0
C
 q
i 
R 2 RC
dq
also i 
dt
q t
dq
   dt
 q 
C
   0
 R 2 RC 
q
 q 
ln   
 R 2 RC  C
t
 1 
  2 RC 
 
 2 C  q  t
ln  
 C  2 RC
q  2 C   Ce t / 2 RC
q   C  2  e  t / 2 RC 
Topic:- Current Electricity_L-1
32. (B)
ay = –3 m/s2 & ax = 2 m/s2
It has maximum y-coordinate, when
vy = 0 = 6 – 3(t)
 t = 2 sec
1
at that instant, y = × 3 × 22 = 6 m
2
1
&x= × 2 × 22 = 4 m
2
Topic:- Kinematics _L-1
114
4
33. (C)
Acceleration of all blocks :
mg g
a 
4m 4
So, acceleration of block m on top of 2m is caused only due to friction between them,
f  ma
mg

4
Topic:- Friction_L-1
34. (D)
Topic:- Circular Motion_L-2
35. (D)
M
Mass of the chain hanging over the edge 
3
L
height of centre of mass 
6
M L
 W done to pull hanging part  g
3 6
mgL

18
Topic:- Work Power Energy_L-1
36. (B)
As there is no friction, net force acting on the yo-yo is only F. So it accelerates to the right. Also the
only force produce rollings torque about centre of mass is also F.
Since this torque is anticlockwise, the yo-yo rotates anticlockwise.
Topic:- Rotational Motion_L-2
37. (B)
1
hcE = 10cos(2 × 50 ×
600
) = 53 V]
Topic:- AC_L-1
115
5
38. (B)
Fthrust
mg
Fthrust – mg = ma
m = 5000 kg
a = 20 m/s2
 Fthrust = 150000 N
dm dm
Fthrust = Urel ×  (–800) × = 150000
dt dt
dm
  –187.5 kg/s
dt
Topic:- Impulse Momentum_L-1
39. (A)
By using Paralell axis theorem with the diagonal axis paralell to the specified axis:
2
Ma 2  a  7
I= + M  = Ma2
12  2 12
Topic:- Rotational Motion_L-2
40. (D)
Heat required to melt 10 gm ice at 0°C = 10 × 80 = 800 cal
800 cal heat have to be absorbed from m gm water at 50°C
Then, 800 = m × 1 × 50, m = 16 gm
m = 16 gm
Topic:- Heat Calorimetry_L-1
41. (A)
 + 90° +  = 180°
  = 90 – 
 1 sin  = 3 sin (90 – )
 = 60°
Topic:- Geometric Optics_L-2
116
6
42. (B)
l  2R  2r 
Strain = = 
l  2r 
R r
Strain =  
 r 
F/A l
Y= l , Y l A = F
l
R r
F = AY   Ans.
 r 
Topic:- Properties of Matter/ Elasticity_L-2
43. (A)
Area under the curve W1 > W2 > W3

Topic:- Thermodynamics_L-2
44. (B)
a = Atan
9 = Atan37°
A = 12 m/s2
Nsin37° = 10 × 12
N = 200 N
Topic:- Newton’s Law of Motion_L-2
45 (D)
x1 = (8 + 3sint) x2 = (4cost)
x1 = x2 for collision
8 + 3sint = 4cost
8 = 4cost – 3sint
8 >max values hence will not collide
Topic:- SHM_L-2
46. (C)
Characteristic X-ray may be produced or not depending on whether the electrons are incident with
sufficient energy to create vacancy in lower energy levels or not.]
Topic:- Modern Physics_(X-ray)_L-1
117
7
47. (D)
3  340 1
= (2n+1) ; = = m
8 4 680 2
n=1
next overtone  n = 2
 1
x = = m = 25 cm
2 4
Topic:- Waves and Sound_L-2
48. (B)
As object approaches C, the ray passing through F hits the line AB closer to C.
Topic:- Ray Optics_L-2
49. (A)
The ratio of wavelength in glass to water
g 4

w 5
1
as  

g w

w  g
4 4/3

5 g
5
g 
3
Topic:- Wave Optics_L-1
50. (C)
+q
–q
q
k (q )(q ) kqq kq( q) k ( q ) 2 kq 2

u= + + + +
a b b 2a 2b
kq 2 kq 2
u= –
2b 2a
Topic:- Electrostatics_L-2
118
8
51. (A)
A = 2,  = 8M, v = 4m/s,
2  2
k= = = ×4=
8 4 8
y = –A sin ( t – kx)
y = A sin (kx – t) = 2 sin [/4x – t]
y = 2 sin (/4x – t )Ans.
Topic:- Waves String_L-2
52. (C)
When the monkey jumps from ball A with a relative velocity v, then both monkey and ball A will hence
v
a speed in opposite directions.
2
When monkey catches on to ball B, by conservation of linear momentum, their combined velocity will
v
be .
4
Now if B has to complete a vertical circle, minimum velocity at the bottom  5gL
v
or  5gL
4
so, v  4 5gL
Topic:- Momentum Collision_L-2
53. (C)
ve = 2gR
2gR gR
v= =
4 2 2
1 GMm GMm
mv2 – =0–
2 R Rh
1 gR gR 2 m
m – mg R = –
2 8 Rh
1 R
=1–
16 R h
1 h
=
16 R h
R + h = 16 h
R = 15 h
R
h=
15
Topic:- Gravitation_L-1
119
9
54. (A)
 1 1 
He+ being a hydrogen like atom, E = 13.6 z2  2  2  , n1 = 1, n2 =  ]
 n1 n 2 
Topic:- Modern Physics_(Bohr’s Model)_L-1
55. (D)
 
   E ·ds  qin
0
(A) is ture, if E = 0  qin = 0
(B) is true, if  = 0  qin = 0
(C) is ture, if E = 0   = 0
 
(D) is false, if  = 0 then  E ·ds is zero E may not be zero everywhere.
Topic:- Electrostatics_L-1
56. (B)
Here S  13.8  0.2  cm; t   4.0  0.3 s
13.8
 V  3.45 ms 1
4.0
V  S t   0.2 0.3 
Also          0.0895
V  S t   13.8 4.0 
V  0.3 (rounding off to one place of decimal)
Topic:- Measurement_(Error)_L-1
57. (C)
Since in parallel combination, equivalent resistance is less than each individual resistance.
Topic:- Current Electricity_(Ohm’s law)_L-1
58. (C)
V0 L2
I0  divide the current in L1 and L2 like reistors I1  I 0
R L1  L2
Topic:- EMI_(LR Circuit)_L-2
59. (D)
B
HV i
i  = Bvl
l l
v LV 
i
i
220
0
i X F
      
F = i (l  B)   
i.e. F  l & F  B 
Topic:- EMI_(Faraday’s Law)_L-2
60. (B)
Photons per area per second at a distance r are 5.00 × 1018/4r2. Photons per second entering the eye,
radius R is then this times R2. Set this product equal to 500 per second and solve for r.
5  1018
Photons per second entering the eye  2
  (4  103 )2  500
4 r
r  2  105 m
Topic:- Modern Physics_L-2
221
1
PART-C: CHEMISTRY
====================================
61. (B)
Ca 2  Cl  S2 size
20 17 16
Z/e ratio as the Z/e ratio increases size of Ion decreases.
18 18 18
Topic:- Periodic table_(Ionic radii)_L-1
62. (D)
For steam distillation compn must be insoluble in water with lower b.p. than water.
Topic: Basic concepts in O.C._L-1
63. (B)
aA  bB  cC  dD
1  d  A 1 d  B 
  
a dt b dt
d  B  b d  B 
  
dt a dt
Topic: Chemical kinetics_(Rate of reaction)_L-1
64. (C)

CN– and N O both have same number of electrons so bond order will be same 3.
While O2 and CN+ have bond order 1.5 and 1.0 respectively..
Topic:- Chemical bonding_(Molecular Orbital theory)_L-2
65. (D)
for C4H10 are postional
& OH
OH
OH O are functional
O are metomars
O
Topic: Isomerism_L-1
66. (D)
For a first order reaction t 1 is constant

2
0.693 n2
& t1   where K is rate constant.
2 K K
Topic: Chemical kinetics_(Order of reactions)_L-1
222
2
67. (D)
Bond strength  electronegativity difference between atoms.
Topic:- Chemical Bonding_L-2
68. (B)
Cl
has 3 stereoisomers in that two are optically active one is meso.

Cl
Topic: Stereoisomerism_L-1
69. (B)
Milk is a liquid - liquid colloid known as Emulsion
Topic: Surface Chemistry_(Colloids)_L-2
70. (C)
Molecule which has one lone pair of electron always show permanent dipole moment.
NO2 and O3 has odd electron and one lone pair of electrons respectively.
Topic:- Chemical Bonding_(Dipolemoment)_L-1
71. (C)
Lewisite is formed by addn of AsCl3 to Acetylene.
ASCl2
ASCl3
H  C  C  H  CH  CH
Cl  ASCl2
 Cl
Topic: Alkynes_L-1
72. (A)
pr  nRT (Ideal gas equation)
d
p RT
M
p RT p
   Temperature
d M d
Topic: Gaseous State_(Gas laws)_L-1
73. (B)
OH
+
–
+ – Br OH Br
Br OH
 
Topic: Alkenes_L-1
223
3
74. (A)
Element those forms volatile iodide, purify by Van-Arkel method.
Ti, Zr, Hf are purify by this method.
Topic:- Metallurgy_(Purification of Metals)_L-2
75. (B)
NO2 NO2
H
+
+ 
H
HNO3  H 2 SO4 
 NO2  
  
RDS
Topic: Aromatics_L-1
76. (C)
Let the weight of CH 4 of O2 is x.
x x
Moles  nCH 4  , nO2 
16 32
 PO2  Mole frcation × Total pressure
PO2 nO2 x
32 1
   
PT nO2  nCH 4 x x 3
16 32
Topic: Gaseous State_(Gas laws)_L-1
77. (B)
SO2 Na2CO3 
Na2CO3 NaHSO3 Na2SO3 Na2S2O3
(aq) (A) (B) (C)
AgNO3
SO3 + Ag2S Ag2S2O3
(D)
Topic:- s-block Elements_(Sodium Carbonate)_L-2
78. (A)
X Nu
NO2 NO2
–
Nu
( ArSN )
NO2 NO2
is fastest when –X is strong electron withdrawing group.
Topic: Arylhalides_L-1_IIT-JEE-2015_Grand Test-1_(Main level)_NGch sir.
224
4
79. (B)
Z
Vnth orbit  V0 
n
 velocity of electron is innersely proportional to principle quautum number n.
Topic: Atomic Structure_(Shapes of orbitals)_L-2
80. (B)
6
SiO 2  2XeF6 
 2 Xe OF4  SiF4
X
Oxidation state of Xe is +6 inXeOF4 (X)

Topic:- P-block Elements_(Zero group elements)_L-2
81. (A)
PBr3
R  CH 2  CH 2  OH   R  CH 2  CH 2  Br
KCN

H
R  CH 2  CH 2  COOH 
H2 O
 R  CH 2  CH 2  CN
Topic: Alcohols_L-1_IIT-JEE-2015_Grand Test-1_(Main level)_NGch sir.
82. (A)
For Lyman Series n1  1, Uisng Rydberg’s Equation
1 2  1 1
v  R 1  2  2 
 1 4 
16 16
  m  969.7 Å
15 R 15  1.097  107
 96.97 nm.
Topic: Atomic Structure_(H-spectrum)_L-1
83. (B)
K3[Co +3(CO3)3]
27 CO   Ar  3d 6 4s2
Co+3 = [Ar] 3d64s°
3d 4s 4p 4d
3 2
sp d hydridisation
Since n = 4 so dipolemoment  n  n  2 
 4  6
= 4.9 B.M
Topic:- Co-ordination_(Valence Bond Theory)_L-2
225
5
84. (C)
Aqueous ions are having entropy than a crystalline solid substance.
Topic: Thermodynamics_(IInd law)_L-1
85. (C)
 Mg  NH 4  PO4  Na 2SO4  H2 O
MgSO4  NH 4OH  Na 2 HPO4 
 White precipitate
Topic:- Qualitative Analysis_(Basic Radicals)_L-2
86. (D)
To get
O
CH 3  C  NH 2 
 CH 3  NH 2
Br2 and aq NaOH (or) aq KOH should be added together..

Topic: Amines_L-1
87. (D)
H  0 for an isothermal process as T  0 .
Topic: Thermodynamics_(IInd law)_L-1
88. (C)
Topic: Chemistry in everyday life_L-1_IIT-JEE-2015_Grand Test-1_(Main level)_NGch sir.
89. (D)
( x ) C6 H10  H 2  C6 H12 cyclohexene heat of hydrogenation.
(3 x) C6 H 6  3H 2  C6 H12 Benzene heat of hydrogenation.
H Hydrogenation of benzene   H observal  H Calculated
  119.5  3  150.4
 208.1 kJ/mol
Topic: Thermodynamics_(Ist law)_L-1
90. (B)
HN3 Hydrozonic Acid, its conjugate base is Azide ion N3 .

Topic: Ionic equilibrium_(Theories of acids)_L-1
226
6

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JEE | MEDICAL-UG | BOARDS | KVPY | NTSE | OLYMPIADS

Date: 09-03-18 RAO FULL TEST - [6]

must be coplanar and so  a , b , c = 0 i. e.,

Therefore, a , b , c cannot form a triangle.

 gx   sec x  1 and f(x) = tan–1 x

= arg (z – z1) – arg (z3 – z1)

 locus of z is a straight line.

l' m' n'

Points of inersection of the curves (1) and curve

Topic:- Circular Motion_L-2

Area under the curve W1 > W2 > W3

k (q )(q ) kqq kq( q) k ( q ) 2 kq 2

For a first order reaction t 1 is constant

has 3 stereoisomers in that two are optically active one is meso.

 PO2  Mole frcation × Total pressure

Oxidation state of Xe is +6 inXeOF4 (X)

Br2 and aq NaOH (or) aq KOH should be added together..

Topic: Chemistry in everyday life_L-1_IIT-JEE-2015_Grand Test-1_(Main level)_NGch sir.

( x ) C6 H10  H 2  C6 H12 cyclohexene heat of hydrogenation.

(3 x) C6 H 6  3H 2  C6 H12 Benzene heat of hydrogenation.

H Hydrogenation of benzene   H observal  H Calculated

HN3 Hydrozonic Acid, its conjugate base is Azide ion N3 .

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