Reference Standard • ENVIRONMENTAL QUALITY (CLEAN AIR) REGULATIONS, 1978 • Malaysian Air Quality Guideline (Ambient Standard) Quantification of Emissions
• Emission levels from combustion system are
expressed in many different ways:- • Emission indices • Corrected concentrations • Emission factor Emission Indices
• The emission index for species i is the ratio of the
mass of species i to the mass of fuel burned by the combustion process 𝑚𝑖,𝑒𝑚𝑖𝑡𝑡𝑒𝑑 𝐸𝐼𝑖 = 𝑚𝐹,𝑏𝑢𝑟𝑛𝑒𝑑 • Dimensionless quantity • Measure of efficiency of a particular combustion process in producing a particular pollutant, uncoupled from specific application Emission Indices • For the combustion of a hydrocarbon fuel in air, the emission index can be determined from mole fraction measurements of the species of interest, together with those of all of the C-containing species. 𝑦𝑖 𝑥𝑀𝑊𝑖 𝐸𝐼𝑖 = (Equation 1) 𝑦𝐶𝑂 + 𝑦𝐶𝑂2 𝑀𝑊𝐹 • Where y are mole fractions, x is the number of moles of carbon in a mole of fuel CxHy, and MWi and MWF are the molecular weights of species i and the fuel, respectively • Assumed all of the fuel carbon appears as either CO2 or CO • Independent of any dilution of the sample stream by air Example 1 Example 1 Example 1 Various specific emission measures
• In the dynamometer testing of spark-ignition and
diesel engines, emissions are frequently expressed as: mass flow of pollutant • mass specific emission = brake power produced
• Mass emission factor: mass of pollutant emitted per
amount of fuel energy supplied mass of pollutant i Emission factor = Fuel energy supplied Example:
Determine the emission factor (i.e. kg of CO2 released per GJ of energy
produced) for the complete combustion of the following fuels at 298 K and 1 atm