Beruflich Dokumente
Kultur Dokumente
Stationary Point and Area Sources. AP42 is located on the EPA web site at www.epa.gov/ttn/
chief/ap42/
The file name refers to the reference number, the AP42 chapter and section. The file name
"ref02_c01s02.pdf" would mean the reference is from AP42 chapter 1 section 2. The reference
may be from a previous version of the section and no longer cited. The primary source should
always be checked.
AP42 Section: 7.1
Background Chapter 5
Reference: 8
January 1977
HYDROCARBON
EMISSIONS FROM
FLOATING ROOF
PETROLEUM TANKS
ENGINEERING-SCIENCE, INC.
HYDROCARBON E M I S S I O N S FROM
FLOATING-ROOF STORAGE TANKS
PREPARED FOR
THE WESTERN OIL AN0 GAS ASSOCIATION
609 SOUTH GRANO AVENUE
LOS ANGELES, CALIFORNIA 91107
JANUARY 1917
SUBMITTED BY
ENGINEER ING-SCI ENCE, I N C .
150 NORTH SANTA ANITA AVENUE
ARCAOIA. CALIFORNIA B l O O B
ENQINEERINQ-SCIENCE -
FOREWORD
i
ENOINEERINO-SCIENCE -
ACKNOWLEDGMENTS
Name Organization
P e t e r E. J o n k e r , Chairman Union Oil Company of C a l i f o r n i a
W i l l i a m J. P o r t e r Chevron U.S.A. Incorporated
D r . Robert L. R u s s e l l Union Oil Research
P e t e r L. Mehta A t l a n t i c R i c h f i e l d Company
E a r l K. Dewey, Jr. . C o n t i n e n t a l Oil Company
J e r r y Adams F l e t c h e r O i l R e f i n i n g Company
John A. Glaser Gulf Oil Company, U.S.
Richard A. O ' H a r e S h e l l Oil Company
Gordon J. Good Standard O i l Company of Ohio
Robert M. Stoneham Texaco, I n c o r p o r a t e d
Hayden H. J o n e s Union Oil Company of C a l i f o r n i a
ii
ENQINEERINQ-SCIENCE -
Environmental P r o t e c t i o n Agency
Research T r i a n g l e Park, North C a r o l i n a
Environmental P r o t e c t i o n Agency
Region I X , San F r a n c i s c o
C a l i f o r n i a A i r Resources Board
Sacramento, C a l i f o r n i a
Southern C a l i f o r n i a A i r P o l l u t i o n C o n t r o l D i s t r i c t
Los Angeles, C a l i f o r n i a
San Diego A i r P o l l u t i o n C o n t r o l D i s t r i c t
San Diego, C a l i f o r n i a
American Petroleum I n s t i t u t e
Committee on E v a p o r a t i v e L o s s Measurements
Washington, D.C.
Supporting Engineering-Science, I n c . in s p e c i a l t e c h n i c a l a r e a s
were:
A n a l y t i c a l Research L a b o r a t o r i e s
Monrovia, C a l i f o r n i a
iii
ENQINEERINQ-SCIENCE -
TABLE OF CONTENTS
FOREWORD i
ACKNOWLEDGMENT ii
CHAPTER I EXECUTIVE S W R Y 1-1
CHAPTER I1 CONCLUSIONS 11-1
CHAPTER I11 INTRODUCTION 111-1
Background 111-1
Objective 111-2
Scope 111-3
Methodology 111-5
CHAPTER I V STATIC STORAGE HYDROCARBON WISSION
MEASUREMENTS 1v-1
Sample C o l l e c t i o n Procedure 1v-2
Laboratory Procedure 1v-3
E v a l u a t i o n of P o t e n t i a l S t r a t i f i c a -
t i o n in t h e Tanks 1v-9
E f f e c t s of Water, Temperature and
Flashing Time 1v-14
Exclusion of C e r t a i n Tanks 1v-15
D e n s i t y Measurements 1v-15
CHAPTER V CORRELATION OF EMISSIONS WITH MEASURED
PARAMETERS v-1
General v-1
Comparisons w i t h API Equation v-3
C o r r e l a t i o n With Measured Parameters V-6
CHAPTER V I FURTHER DISCUSSION OF SIGNIFICANT
PARAMETERS v1-1
CHAPTER V I 1 BEST AVAILABLE SEAL TECHNOLOGY v11-1
General v11-1
Survey of A v a i l a b l e S e a l s v11-2
Primary S e a l s v11-2
Secondary S e a l s v11-8
S e a l and Tank A c c e s s o r i e s VII-12
Survey of I n s t a l l e d S e a l s w i t h
Respect t o Gap S i z e VII-19
D i s c u s s i o n of R e s u l t s VII-28
CHAPTER V I 1 1 RECOMMENDATIONS VIII-1
CHAPTER I X BIBLIOGRAPHY 1x-1
APPENDICES UNDER SEPARATE COVER
ENQINEERINQ-SCIENCE PI-
LIST OF FIGURES
-
No. Title
-
No. -
Title
EXECUTIVE SUMMARY
.. .
ENGINEERING-SCIENCE -
CHAPTER I
EXECUTIVE SUMMARY
T h i s i n v e s t i g a t i o n was i n i t i a t e d p r i m a r i l y t o p r o v i d e c u r r e n t
hydrocarbon emission d a t a on f u l l - s i z e s t o r a g e t a n k s in C a l i f o r n i a .
Seventeen t a n k s were o r i g i n a l l y made a v a i l a b l e b u t only 13 t a n k s con-
t a i n i n g d i s t i l l a t e p r o d u c t s were e v a l u a t e d f o r t h e d u r a t i o n of t h e
project. A p i c t o r i a l d e s c r i p t i o n of t h e s e 1 3 t a n k s and some of t h e
major parameters which a r e commonly a s s o c i a t e d w i t h hydrocarbon l o s s e s
from f l o a t i n g - r o o f t a n k s are i l l u s t r a t e d in F i g u r e 1-1. Work was
i n i t i a t e d i n J u l y 1976 and concluded i n January 1977.
A u x i l i a r y t a s k s a s s o c i a t e d w i t h t h i s p r o j e c t included l a b o r a t o r y
and p i l o t s c a l e t e s t i n g , s u r v e y s of seal technology, and review of t h e
I- 1
FIGURE I -
x
W x x x
oz x x x
3 x x x x
M x x
M x x x x x x
W
a
o
x X
~~
x x
x x x
x x x x
x x x x x x x x x x
x x x x x
0 0 0
Y ) O O O O
NY.-N'-J
0 0 0 0 0
c c c c c
0 - 0 0 0
N - 0 0
- N
x
x
x x
I x
x x x x
x x - x x x
x
x
Y X L m m m m m m m
3 m - N n - m w -
x x
r 0 0 0 0 0 0 0 0
X Y Y c c c c c c c c
P
0 - 0 0 0 0 0 0 0
x x f - N ' - J W V ) Y ) C
L
x
x
x
x X
I
x
. x
x
x
X I
x X I
x X X I
x x x x x X x
P a r t i c u l a r i n t e r e s t d u r i n g t h i s i n v e s t i g a t i o n was focussed on
d e t e r m i n i n g t h e b e s t a v a i l a b l e seal technology. Two s u r v e y s were
conducted. The f i r s t survey e v a l u a t e d commercially a v a i l a b l e s e a l s
through i n d i v i d u a l companies. The second survey addressed seal gap
s i z e a c t u a l l y measured a t d i f f e r e n t roof l e v e l s f o r some 200 t a n k s
i n Southern C a l i f o r n i a .
1-3
CHAPTER I 1
CONCLUS IONS
ENGINEERING-SCIENCE -
CHAPTER 11
CONCLUSIONS
11-1
CHAPTER 1 1 1
I NTROOUCT I ON
ENGINEERING-SCIENCE -
CHAPTER 111
INTRODUCTION
BACKGROUND
Use of t h e e q u a t i o n by t h e r e g u l a t o r y a g e n c i e s has r e c e n t l y r e s u l t e d
i n t h e conclusion t h a t floating-roof t a n k s were r e s p o n s i b l e f o r a
s i g n i f i c a n t p o r t i o n of t h e hydrocarbon emission i n v e n t o r i e s i n many
A i r Q u a l i t y C o n t r o l Regions and t h a t f u r t h e r c o n t r o l was r e q u i r e d .
Under t h e r e c e n t New Source Review r u l e s , estimates of hydrocarbon
e m i s s i o n s from proposed new tanks have caused c o n s t r u c t i o n of some
of t h e s e t a n k s t o be blocked.
111-1
ENGINEERING-SCIENCE Eq -
a p p l i e d t o f u r t h e r reduce f l o a t i n g - r o o f t a n k hydrocarbon emissions
r e g a r d l e s s of t h e i r r e l a t i v e magnitude.
OBJECTIVE
111-2
ENQINEERINQ-SCIENCE IES]-
-
SCOPE
Of t h e 17 f u l l - s i z e d t a n k s made a v a i l a b l e f o r t h i s f i e l d sampling
p r o j e c t , t h r e e of t h e t a n k s c o n t a i n e d c r u d e oil; t h e remaining 1 4 tanks
c o n t a i n e d a d i s t i l l a t e p r o d u c t r a n g i n g from naphtha t o j e t f u e l
(Table 111-1). A l l t a n k s m e t the f o l l o w i n g c o n d i t i o n s :
111-3
ENGINEERING-SCIENCE t%jd-
I n o u
h h I n
m m
d r l d
.
m
0
In
m
rl
m U Q
u m N
m m m
r l 4 r l
al
.
D
3
w
e
al Y
rl E
I
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H
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d d U
w
4w
5 5 5
al al al
U U Y
01 al
$ 2 2
d
d
d 2 d
m o u
o 4
m m
0
0
rl
111-4
ENQINEERINQ-SCIENCE -
METHODOLOGY
REPORT ORGANIZATION
The two c h a p t e r s p r e c e d i n g t h i s I n t r o d u c t i o n i n c l u d e Summary and
Conclusions o f t h e s t u d y . The n e x t f o u r c h a p t e r s d e s c r i b e f i e l d
test r e s u l t s , c o r r e l a t i o n s t u d i e s , c a l c u l a t i o n of hydrocarbon l o s s e s ,
and b e s t a v a i l a b l e seal technology. Recommendations and r e f e r e n c e s
conclude t h e r e p o r t . A s e p a r a t e r e p o r t of Appendices c o n t a i n s a l l
raw test d a t a .
111-5
._ .. . q
CHAPTER IV
S T A T I C STORAGE HYDROCARBON
EMlSS ION MEASUREMENTS
ENGINEERINQ-SCIENCE -
CHAPTER IV
IV-1
ENQINEERINGSCIENCE -
the specific stock's density-evaporation curve to calculate the weight
of stock loss.
IV-2
. . .
ENGINEERING-SCIENCE -
samples were s t o r e d on i c e and d e l i v e r e d t o t h e l a b o r a t o r y and then
. .
t r a n s f e r r e d t o o t h e r sample c o n t a i n e r s p r i o r t o d e n s i t y a n a l y s i s . These
procedures 'allowed an u n a c c e p t a b l e amount of f l a s h i n g and leakage. Sub-
s e q u e n t l y , 8-ounce narrow-mouth b o t t l e s were used and samples were n o t
t r a n s f e r r e d t o o t h e r sample c o n t a i n e r s p r i o r t o t h e d e n s i t y determination.
LABORATORY PROCEDURE
IV-3
ENQINEERINQ-SCIENCE -
TABLE I V - 1
SCOPE
\
DENSITY AND SPECIFIC GRAVITY OF LIQUIDS
BY BINGHAM PYCNOMETER
SCOPE
IV-4
ENGINEERING-SCIENCE (ESI-
2300 F t h a t can be handled i n a normal f a s h i o n a s a l i q u i d a t t h e s p e c i -
f i e d t e s t t e m p e r a t u r e s , " i s not c o n s i s t e n t w i t h t h e p a r t i c u l a r petroleum
s t o c k s u s e d i n t h i s s t u d y (mostly g a s o l i n e and crude o i l ) . The example
c a l c u l a t i o n and d e n s i t y e v a p o r a t i o n curves p r e s e n t e d i n API-2512
imply t h a t t h e method was s u c c e s s f u l l y a p p l i e d a t one t i m e . Therefore,
r a t h e r t h a n s t a t i n g t h a t t h e t e c h n i q u e suggested i n API-2512 is n o t
c o r r e c t , t h i s e x p e r i e n c e may only i n d i c a t e t h a t t h e r e q u i r e d s k i l l s could
n o t be gained w i t h i n a s h o r t t i m e frame t o a d e q u a t e l y perform t h e t e s t s .
Whatever t h e f i n a l r e s o l u t i o n may b e , t h e a p p l i c a t i o n of ASTM D-1217-54
t o g a s o l i n e and crude o i l s h o u l d b e c a r e f u l l y e v a l u a t e d b e f o r e being
used i n any o t h e r i n v e s t i g a t i o n r e q u i r i n g s t r i n g e n t accuracy.
I n t h e l a b o r a t o r y t h e sample b o t t l e i s r e t r i e v e d from c o l d s t o r a g e ,
t h e cap is removed and r e p l a c e d immediately by a cap w i t h a small h o l e .
The DMA-50 t e f l o n sample i n l e t t u b e i s immediately p l a c e d through t h e
h o l e mid-way i n t o t h e sample b o t t l e . Approximately 10 m l of sample i s
withdrawn and passed d i r e c t l y through t h e t u b u l a r o s c i l l a t o r . The
o s c i l l a t o r r e q u i r e s only 0.7 m l of sample, t h e r e f o r e , t h e 10 ml sample
IV-5
ENGINEERING-SCIENCE -
e n s u r e s t h a t a "mid-stream'' a l i q u o t is obtained. The frequency p e r i o d
i s determined and a n o t h e r sample a l i q u o t i s withdrawn a s a check. If
more t h a n a +0.00002 frequency d i f f e r e n c e i s observed, a n o t h e r a l i q u o t
i s measured.
W i t h d i l i g e n t a t t e n t i o n g i v e n t o sample c o l l e c t i o n , h a n d l i n g , s t o r a g e ,
i n s t r u m e n t c a l i b r a t i o n , and temperature c o n t r o l , i t was observed t h a t
t h e DMA-50 would a c c u r a t e l y r e p e a t t h e d e n s i t y measurements t o w i t h i n
-
+0.00002 g/ml. P u r e hydrocarbon compounds (hexane and benzene) were
used t o check t h e accuracy of t h e DMA-50 when u s i n g a i r and w a t e r as t h e
c a l i b r a t i o n mediums. The d e n s i t i e s of t h e pure compounds were determined
u s i n g t h e Bingham pycnometer method f o r f i v e r e p l i c a t e samples.
The DMA-50 c o n s i s t e n t l y gave d e n s i t y measurements t o w i t h i n +0.00002
g/ml o f t h e d e n s i t i e s o b t a i n e d u s i n g t h e 100 m l Bingham pycnometer.
T h e o c i g i n a l API method of d e t e r m i n i n g t h e s t o c k d e n s i t y by u s i n g
a pycnometer r e q u i r e s t h a t t h e s t o c k be t r a n s f e r r e d from t h e sample b o t t l e
t o t h e pycnometer w i t h a long n e e d l e s y r i n g e . Using t h e DMA-50 t o
d e t e r m i n e t h e d e n s i t y , where l i q u i d i s syphoned d i r e c t l y from t h e sample
b o t t l e i n t o t h e t u b u l a r o s c i l l a t o r , reduced t h e p o s s i b l e e r r o r s s i g n i f i -
cantly. Simple experiments w i t h t h e DMA-50 i n d i c a t e d t h a t some g a s o l i n e s
could n o t be t r a n s f e r r e d from t h e sample b o t t l e t o t h e pycnometer even
a t t e m p e r a t u r e s as low as 400 F w i t h o u t i n c r e a s i n g t h e d e n s i t y by
0.00100 g/ml o r more.
IV-6
FIGURE I V -
0.73300
0.73200
0.73100
-E 0.73000
\
M
*
-
I-
0.72800
0.72700
0.72600
0 1.0 2.0 3.0 4.0 5
WEIGHT LOSS, %
V a r i a t i o n s in s t o c k d e n s i t y o b t a i n e d from v a r i o u s g r a b s a m p l e s
were c o n s i d e r e d t o r e s u l t from " f l a s h i n g " of l i g h t ends r a t h e r t h a n
from random a n a l y s i s e r r o r . S i n c e f l a s h i n g would r e s u l t i n h i g h e r
d e n s i t y v a l u e s , t h e major random e r r o r i n each sample series should be
t o make c e r t a i n d e n s i t y v a l u e s h i g h e r t h a n t h e a c t u a l d e n s i t y . To o f f -
s e t t h i s p o s s i b l e random e r r o r , t h e t h r e e lowest d e n s i t y measurements
o b t a i n e d from t h e twelve s p a t i a l samples were always used as t h e b e s t
estimate of t h e average s t o c k d e n s i t y . The average d e n s i t y determined
by u s i n g t h e minimum t h r e e d e n s i t i e s u s u a l l y d i f f e r e d from t h e average
of t h e twelve samples by o n l y 0.00001 or 0.00002 g/ml.
ENQINEERINQ-SCIENCE -
EVALUATION OF POTENTIAL STRATIFICATION I N THE TANKS
N
PLANT U N I O N
TANK NO. 100514
04
84 OATE SEPT. 17. 1976
85 STOCK DEPTH 74.5'
O I A . OF TANK 137'
.82
+ 85
* A L L NUMBERS I N O I C A T E
THE LAST 110 OlGlIS
OF THE 5 t h PLACE
OENSITV A S .737._ E . m l .
STOCK TEMPERATURE ( O F )
NO. OF PORTS 13
NAXINUY SURFACE 89.9
N l N l N U N SURFACE 71.5
MAXIMUM M I D 6 8 . 5
M I N I N U N M I 0 68. I
*HAXlNUM NID-DEPTH D E N S I T Y
ENGINEERING-SCIENCE, INC
IV-10
FIGURE 1’4-3
U PLANT TEX A C O
TANK NO. 80210
DATE SEPT. 1 7 . 1976
STOCI( OEPTH 4 5 . I ”
011. OF TANK 120’
*ALL NUMBERS l N O l C A T E
THE L A S T 110 D I G I T S
OF THE 5 t h PLACE
DENSITY AS . 6 5 6 _ _ U m l .
STOCK TEMPERATURE ( O F )
NO. OF PORTS 13
MAXIMUM SURFACE 74. I
MINIMUM SURFACE , 73.0
MAXIMUM MI0 7 0 . 0
MINIMUM MI0 70.0
Spatial Depth V a r i a t i o n
Variation S u r f a c e Minus Bottom
Tank Date (10-5 g/ml) (10-5 g/ml)
IV-12
. .
I
ENQlNEERlNGSClENCE /ES( -
TABLE IV-3
1.V-13
ENQINEERING-SCIENCE IES]-
EFFECTS OF WATER, TEMPERATURE AND FLASHING TIME
IV-14
ENQINEERINQ-SCIENCE -
EXCLUSION OF CERTAIN TANKS
Three c r u d e o i l tanks (Standard 412, 497, and 2140) a r e shown in
Tables IV-12. 1 3 , and 1 4 b u t a r e n o t considered f u r t h e r in t h i s study
s i n c e v e r y u n r e l i a b l e r e s u l t s were o b t a i n e d . Inconsistent results f o r
t h e crude o i l may have been caused by handling problems in t h e l a b o r a t o r y
procedure or by t h e f a c t t h a t a r e s i d u e w a s formed in each tank between
t h e o i l and w a t e r i n t e r f a c e . Moreover, as s t o c k temperature decreased
d u r i n g t h e s t u d y , t h e crude oil became very v i s c o u s , and s t r a t i f i c a t i o n
may have occurred. Analyses of t h e hydrocarbon l o s s e s from t h e s e tanks
showed mostly methane and e t h a n e s o t h e i r importance may be less s i g n i f -
i c a n t from an a i r p o l l u t i o n p o i n t of view t h a n t h e g a s o l i n e s t o r a g e tanks.
DENSITY MEASUREMENTS
The a c t u a l f i e l d n o t e s h e e t s and l a b o r a t o r y a n a l y s i s s h e e t s are
l i s t e d in t h e appendices of Volume 2. T a b l e s I V - 4 through IV-20
( F i e l d Measurement Summary), a t t h e end of t h i s Chapter, summarize t h e
p e r t i n e n t d a t a f o r each f l o a t i n g - r o o f tank. The d e n s i t i e s l i s t e d in
t h e F i e l d Measurement Summary s h e e t s a r e f o r t h o s e samples t a k e n
h o r i z o n t a l l y throughout t h e t a n k a t mid-depth of t h e s t o c k . The column
l a b e l e d "MIN. 3 AVERAGE" r e p r e s e n t s t h e b e s t estimate of t h e t r u e average
stock density.
IV-15
F.IGURE IV-'
73600
13500
-E
k 73400
ul
-
0
I
73300
r
-
I-
v)
z
Y 76500
0
Y
0
0
I- 76400
v)
16300
16200
DAY~ONTH
74000
73900
73800
73100
74100
74000
73900
13800
ST0 192
69100 I
^-I
74100
74000
73900
T X 20010
73800
OAY/MONTH
IV-18
ENGINEERING-SCIENCE, INC.
FIGURE IV-7
In
-
I
0
DAY/MONTH
DAY/’MONTH
IV-20
t , .
"1
ENGINEERING-SCIENCE ES
',
..
-2-
=I
Y
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c
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I
ENGINEERING-SCIENCE -
..
Y Y Y
O O Y O Y
0 0
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p:
A = w o w 0
a - 2 - 2
Y O W O Y 0
Y) Z S U E v
!
ENGINEERING-SCIENCE rEs]-
IV-23
ENGINEERING-SCIENCE -
A/
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!
!
' I
TV-24
ENGINEERING-SCIENCE -
-2-
zv-2s
ENGINEERING-SCIENCE PI-
L -
m VI-
IV-26
ENQINEERINQ-SCIENCE -
111-27
ENQINEERINQ-SCIENCE -
..
IV-28
Es
"1
ENGINEERING-SCIENCE
-2-
I IV-29
ENGINEERING-SCIENCE -
. .
-
Y
Q
4
*c
E
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YI
IV-30
1 ENGINEERING-SCIENCE -
I
!
e !
5 I
,
-
L
i 0 D
L L Y
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f
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f
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IV-31
ENGINEERING-SCIENCE -
Ee
Y
r
: .n
E 3
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5
5
:
a
I\'-32
h
ENQINEERING-SCIENCE -
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CHAPTER V
i
ENQINEERINQ-SCIENCE (ESI-
CHAPTER V
-
CORRELATION OF EMISSIONS WITH MFASUKED PARAMETERS
GENERAL
It should be s t r e s s e d t h a t w i t h o n l y t h i r t e e n t a n k s a s b a s i c d a t a
p o i n t s , and c o n s i d e r i n g t h e l a r g e number of p o s s i b l e parameters t h a t
may a f f e c t t h e emission r a t e s , o n l y g e n e r a l c o n c l u s i o n s r e g a r d i n g
trends a r e possible.
v- 1
m o m o o o o o U h 0 0 0
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v-2
ENGlNEERlNQ-SCIENCE -
COMPARISONS WITH API EQUATION
The American Petroleum Institute in their API Bulletin on Evaporation
Loss Prom Floating-Roof Tanks, API Bulletin 2517, February 1962, outlines a
suggested procedure for estimating standing-storage loss from floating-roof
tanks. The recommended equation is
where:
L - standing-storage evaporation loss, in barrels per year.
Kt
Y
- a tank-type factor which changes as follows:
Kt
Kt
-- double seal.
0.11 for riveted tank with pontoon roof, double seal.
0.13 for riveted tank with pontoon roof, single eeal..
-
Kt * 0.13 for riveted tank with pan roof, double seal.
Kt 0.14 for riveted tank with pan roof, single seal.
- -
C
v-3
ENQINEERINQ-SCIENCE -
The above e q u a t i o n was a p p l i e d t o a l l t h i r t e e n t a n k s i n t h i s s t u d y .
F i g u r e V-1 shows t h e c o r r e l a t i o n o f measured emissions and t h o s e calcu-
l a t e d u s i n g t h e API e q u a t i o n . T a b l e V-2 l i s t s t h e two emission rates f o r
each tank. Nine tanks e m i t less t h a n t h e API e s t i m a t e d emissions and
f o u r t a n k s emit more t h a n t h e API estimated emissions. The emission esti-
mate f o r Texaco 20010 is v e r y c l o s e t o t h e observed emission r a t e .
However, o v e r a l l t h e observed e m i s s i o n rates were approximately 58 p e r c e n t
of t h e c a l c u l a t e d emission r a t e s . I t would appear t h a t t h e API 2517
e q u a t i o n O v e r s t a t e s t h e magnitude of t h e emissions and does n o t adequately
r e p r e s e n t t h e i n f l u e n c e of s p e c i f i c parameters.
TABLE V-2
ARC0 510 55
Exxon 30 87
Gulf 131 - 0
Lion 128 175
Mobil 49 60
S h e l l 47 237 55
S h e l l 48 237 57
S t a n d a r d 192 362 445
S t a n d a r d 9464 35 56
T W c o 20010 34 33
TexAco 80210 145 43
Union 330 132 84
Union 100514 433 286
v- 4
~~
FIGURE V-1
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ENGINEER1 NG-SCIENCE, IN[
v- 5
ENQINEERINQ-SCIENCE IES]-
CORRELATION WITH MEASURED PARAMETERS
F f g u r e s V-2 through V-4 show t h e c o r r e l a t i o n of measured emission and
c e r t a i n measured parameters t h a t a r e thought t o be i m p o r t a n t t o t h e
p r o d u c t i o n of hydrocarbon e m i s s i o n s . Because of t h e many parameters
i n v o l v e d , c a u t i o n should b e used i n e v a l u a t i n g o n l y one parameter a t a
time; however, i t i s i n t e r e s t i n g t o g a i n i n s i g h t i n t o t h e p o s s i b l e e f f e c t
one v a r i a b l e may have on t h e emission r a t e s . As shown, t h r e e t a n k s have
emission r a t e s much h i g h e r than t h e o t h e r s . Standard 192, Union 100514
and Lion 428 emission r a t e s were from two t o f i v e times h i g h e r t h a n a l l
t h e o t h e r tanks. Measured parameters such as wind s p e e d , Reid vapor
p r e s s u r e , s t o c k temperature of s i z e of t h e seal gaps i n d i v i d u a l l y do n o t
appear t o t o t a l l y account f o r t h e t h r e e h i g h e r e m i s s i o n s . As mentioned
e a r l i e r , t h e r e c e n t C B I s t u d i e s have shown t h a t t h e t i g h t n e s s of t h e
vapor s p a c e under t h e f a b r i c s e a l on m e t a l l i c shoe seals i s a v e r y important
variable. No tears were v i s u a l l y observed f o r t h e Standard 192 tank.
A p r e s s u r e test may b e r e q u i r e d t o make t h e f i n a l judgment concerning t h i s
f a c t o r f o r Standard 192. I t is i n t e r e s t i n g t o n o t e t h a t t h e primary
seal on Standard 192 was i n s t a l l e d i n 1951 and r e p r e s e n t s t h e o l d e s t
primary s e a l i n t h i s s t u d y . The n e x t o l d e s t s e a l i s Union 100514 (1952).
F i g u r e V-5 shows t h e measured emission r a t e s v e r s u s t h e y e a r t h e primary
seal w a s i n s t a l l e d on each t a n k . A v i s u a l i n s p e c t i o n w a s made of t h e
f a b r i c apron of t h e o t h e r shoe seals and a l l had a p p a r e n t h o l e s i n t b e
fabric.
The C B I p i l o t t a n k s t u d y o f f e r s an e x c e l l e n t o p p o r t u n i t y t o e v a l u a t e
t h e i n f l u e n c e of one v a r i a b l e w h i l e h o l d i n g a l l o t h e r v a r i a b l e s c o n s t a n t .
The p i l o t scale s t u d i e s on a twenty-foot tank have shown t h a t t h e e m i s -
sions v a r y almost d i r e c t l y w i t h vapor p r e s s u r e which seems t o a g r e e w i t h
traditional theoretical considerations. However, s e v e r a l tests would
i n d i c a t e t h a t c e r t a i n v a r i a b l e s t h a t have p r e v i o u s l y been c o n s i d e r e d
t o d i r e c t l y impact t h e e m i s s i o n s may n o t be very important.
V- 6
FIGURE V-
275
250
225
zoo
175
150
125
IO0
75
50
25
0
0 2 6 8 10 12 I4 16 I8
R E I D VAPOR PRESSURE, p s i
TANK DIAMETER, f t .
75 I I
U M 330
50 UOBl L 7 EXXON
ARC0 w
STO 5464
25
smL 18 -01x 20010
0 GULF
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200
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v-9
FIGURE V-'
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ENGINEER ING-SCIENCE. INC
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I
ENQINEERINQ-SCIENCE -
s p a c e temperature w a s h e a t e d t o ZOO F above t h e b u l k l i q u i d temperature
and i n s t e a d of t h e emissions i n c r e a s i n g a s one might expect due t o t h e
i n c r e a s e i n vapor p r e s s u r e , t h e e m i s s i o n s tended t o d e c r e a s e or remain
t h e same. Perhaps t h i s i n d i c a t e s t h a t t h e "noise" l e v e l of t h e t e s t
procedure i s below t h e range of t h o s e two v a r i a b l e s . A significant
i n c r e a s e i n emissions was n o t i c e d when t h e gap a r e a was i n c r e a s e d by a
f a c t o r of e i g h t . The gap was 0 . 5 i n c h w i d e and t h i r t y f e e t long (halfway
around t h e circumference) i n t h e above example f o r t h e shoe seal.
Secondary s e a l s tended t o d e c r e a s e t h e emissions f o r t h e C B I tests. All
of t h e p r e l i m i n a r y p i l o t t e s t s on shoe s e a l s tended t o show t h a t t h e
e m i s s i o n s i n c r e a s e d w i t h t h e amount of d i l u t i o n a i r blown through t h e
test chamber. T h i s would i n d i c a t e t h a t wind speed c e r t a i n l y a f f e c t s t h e
e m i s s i o n s ; however, t h e e x a c t r e l a t i o n s h i p i s d i f f i c u l t t o determine due
t o r e l a t i n g t h e d i l u t i o n a i r f l o w r a t e t o wind speed. Similar r e s u l t s
were found w i t h t u b e s e a l s . In f a c t , i t would appear t h a t a t i g h t
f i t t i n g (no gap) t u b e s e a l would have h i g h e r emissions t h a n a t i g h t
f i t t i n g (no gap) shoe s e a l . Furthermore, t h e same gap s p a c e area f o r a
t u b e seal would y i e l d h i g h e r e m i s s i o n s t h a n f o r t h e same gap s p a c e a r e a
f o r a shoe s e a l .
v-11
EN~INCERIN~.S~IENCE -
t h e vapor p r e s s u r e f o r Gulf 80005 was a l s o one of t h e lowest i n t h e
study. -
I n g e n e r a l , i t does appear t h a t t h e f i e l d d a t a and t h e p i l o t t e s t
d a t a do a g r e e very w e l l i n t h a t t i g h t f i t t i n g shoe s e a l s and t i g h t f i t t i n g
tube seals would l o s e approximately t h e same amount of s t o c k . Further,
i t would appear t h a t t u b e seals, w h i l e d e c r e a s i n g t h e gap s i z e s i g n i f i -
c a n t l y under most c o n d i t i o n s , do n o t o f f e r a n advantage o v e r shoe seals
a s a p o l l u t i o n c o n t r o l device.
v-12
FIGURE V-l
- STANDARD 192
COMPARISON OF WIND SPEED AND STOCK TEMPERATURE
TO CHANGE I N D E N S I T Y
:I
4
6.0
5.0
4.0
0.69400
0.89300
0.69200
17 24 1 6 15 22 29 5 12 19 26 3 10 17 24 31
SEPTEMBER OCTOBER NOVEMBER DECEMBER
0 A Y /MONTH
ENGINEERING-SCIENCE. INC.
v- 13
ENGINEERING-SCIENCE -
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v-14
ENQINEERINQ-SCIENCE -
not. Only those tanks with tube s e a l s m e t t h e gap s i z e r u l e . Similar
tanks that d i d not meet the r u l e had emission r a t e s lower than the
f i v e i n compliance.
V-15
CHAPTER V I
FURTHER OlSCUSSlON
OF S I GNI F ICANT PARAMETERS
ENQINEERINQ-SCIENCE -
CHAPTER V I
Table V I - 1 p r e s e n t s f o r comparison a l i s t of v a r i a b l e s o r f a c t o r s
included in t h e API-2517 e q u a t i o n f o r emission l o s s from f l o a t i n g - r o o f
t a n k s and in t h e ES c o r r e l a t i o n stqidy of f i e l d t e s t d a t a . The API
e q u a t i o n is d e f i n e d i n Chapter V . There were no pan-type r o o f s i n
t h e ES f i e l d s t u d y , and t h e API s t u d y d i d n o t i n c l u d e double-deck t y p e
roofs. T h e r e f o r e , i t i s n o t known i f any e f f e c t on emission loss can
be a t t r i b u t e d t o d i f f e r e n c e s between pan, pontoon, o r double-deck
roofs.
VI-1
ENGINEERING-SCIENCE -
TABLE VI-1
VI-2
~
ENQINEERING-SCIENCE -
T h e r e f o r e , a l t h o u g h t h e measured emission l o s s f o r t h e 1 3 s t o r a g e
t a n k s can be compared t o t h e e m i s s i o n l o s s p r e d i c t e d by t h e AF'I
e q u a t i o n , i t i s n o t f e a s i b l e t o make a d i r e c t comparison of t h e q u a n t i -
t a t i v e e f f e c t of each v a r i a b l e o r f a c t o r o r t o a s s e s s t h e accuracy of
t h e v a l u e s a s s i g n e d t o exponents or k f a c t o r s i n t h e API e q u a t i o n .
I n g e n e r a l , however, t h e ES l a b o r a t o r y experiments on g a s o l i n e
e v a p o r a t i o n r a t e s , and t h e C B I j S O H I O p i l o t tank and o t h e r t a n k t e s t s
show t r e n d s of i n c r e a s i n g e m i s s i o n r a t e s a s wind speed and s e a l gap
area a r e increased.
I n t h e c a s e of t h e ES f i e l d t e s t s t u d y d a t a , m u l t i p l e l i n e a r
r e g r e s s i o n a n a l y s e s were conducted u s i n g s t a n d a r d computerized s t a t i s -
t i c a l programs (CORRE/STPRG) t o examine t h e r e l a t i o n s h i p of t h e
measured o r observed v a l u e s of t h e v a r i a b l e s l i s t e d i n Table V I - 1 to
t h e measured emission r a t e s . I n b r i e f , t h e s t a t i s t i c a l a n a l y s i s program
conducts a m u l t i p l e s t e p w i s e l i n e a r r e g r e s s i o n (STPRG) i n a f a s h i o n
t h a t o r d e r s t h e v a r i a b l e s from greatest t o l e a s t c o r r e l a t i o n . The
program was e x e r c i s e d i n t h e l o g a r i t h m i c mode t o produce a power
f a c t o r r e l a t i o n s h i p of t h e type:
Y = a x blx b2 b3--__
-
1 2 x3
where Y i s t h e dependent v a r i a b l e and x l , x2, e t c . , a r e indepen-
dent variables. T h i s form was s e l e c t e d s i n c e i n t h e MI-2517 e q u a t i o n ,
t h e emission r a t e (Ly) w a s a f u n c t i o n of P O a 7 , and Vw 0.7 .
The r e s u l t s of t h e r e g r e s s i o n a n a l y s e s were t h a t f o r t h e measured
f i e l d d a t a from t h e 1 3 g a s o l i n e s t o r a g e t a n k s , t h e emission rates
were more c o r r e l a t e d w i t h t h e v a l u e s of wind speed, RVP, ASTM
d i s t i l l a t i o n f a c t o r , gap a r e a (Ag), and s t o c k temperature t h a n w i t h
number of g a p s , t a n k d i a m e t e r , and t h e o t h e r v a r i a b l e s . I n o r d e r of
h i g h e r t o lower c o r r e l a t i o n f o r t h e f i r s t f i v e v a r i a b l e s :
VI-?
ENGINEERING-SCIENCE -
I t is c o n s i d e r e d t h a t i t might be a s a p p r o p r i a t e t o compute TVP
o r P f o r u s e i n t h e c o r r e l a t i o n a n a l y s i s i n s t e a d of RVP and t h e ASTM
d i s t i l l a t i o n factor. In t h a t c a s e , t h e c o r r e l a t i o n o r d e r of t h e most
s i g n i f i c a n t sets of t e s t v a r i a b l e v a l u e s i s :
The m u l t i p l e c o r r e l a t i o n c o e f f i c i e n t f o r t h i s s e t i s approximately
0.8. However, a n a c c u r a t e mathematical r e l a t i o n s h i p f o r t h e s e v a r i a b l e s
i n t h e form o f :
is n o t o b t a i n e d s i n c e t h e s t a n d a r d e r r o r of t h e r e g r e s s i o n c o e f f i c i e n t
( t h e b exponents in t h i s c a s e ) f o r each v a r i a b l e i s s i g n i f i c a n t (due
t o t h e d a t a s c a t t e r ) and due t o power f a c t o r format o f t h e r e l a t i o n s h i p ,
considerable uncertainty results. This uncertainty i s a r e s u l t not
o n l y of t h e d a t a s c a t t e r b u t of t h e r e l a t i v e l y s m a l l number of t e s t
t a n k s (13) compared t o t h e number of v a r i a b l e s (15).
I n a d d i t i o n , t h e r e s u l t i n g e x p r e s s i o n cannot be compared d i r e c t l y
t o t h e API e q u a t i o n s i n c e A h e r e i s a continuous v a r i a b l e expressed
g
i n an experimental r e l a t i o n s h i p t o L whereas i n t h e API e q u a t i o n ,
Y'
t h e gap f a c t o r i s i m p l i c i t l y assumed t o be a f i x e d l i n e a r v a l u e f o r
each t a n k l r o o f l s e a l combination.
VI-4
ENGINEERING-SCIENCE -
r a t e s t o t h o s e p r e d i c t e d by API-2517 was shown in F i g u r e V-1.
I g n o r i n g t h e c a s e of t h e Gulf O i l t a n k , t h e API e q u a t i o n p r e d i c t e d
l o s s e s r a n g i n g from o n e - t h i r d t o n i n e times t h e l o s s e s measured by ES.
In seven c a s e s , t h e API p r e d i c t i o n was s i g n i f i c a n t l y g r e a t e r , and i n
f o u r c a s e s , i t was s i g n i f i c a n t l y less. From t h i s r e s u l t , and without
a d d i t i o n a l d a t a , i t is c o n s i d e r e d t h a t t h e API e x p r e s s i o n i s n o t i n
t h e form t h a t w i l l produce r e a s o n a b l y r e p r e s e n t a t i v e e s t i m a t e s of
emission l o s s e s . A d d i t i o n a l l y , t h e i n c o n s i s t e n c y of t h e API p r e d i c t i o n s
compared t o t h e ES measured e m i s s i o n s make i t d i f f i c u l t t o i d e n t i f y
and e v a l u a t e p o t e n t i a l c a u s e s f o r t h e d i f f e r e n c e s . It remains u n c l e a r
whether a n e m i s s i o n l o s s r e l a t i o n s h i p can be expressed i n t h e form of
t h e API e q u a t i o n , or, i n view of t h e o r d e r of r e l a t i v e c o r r e l a t i o n
between t h e key f a c t o r s as i n d i c a t e d by t h e ES c o r r e l a t i o n a n a l y s e s ,
how t o develop w i t h less u n c e r t a i n t y t h e c o e f f i c i e n t s or exponents
f o r t h e v a r i a b l e s which should be i n c l u d e d in t h e emission l o s s e s t i -
mation e x p r e s s i o n . T h e r e f o r e , no f u r t h e r a t t e m p t s were made t o
develop a n emission l o s s e q u a t i o p by s t a t i s t i c a l c o r r e l a t i o n a n a l y s e s
or a n a l y t i c a l t e c h n i q u e s .
An e x p r e s s i o n f o r t h e e v a p o r a t i o n r a t e of v o l a t i l e l i q u i d s i n t o
a i r h a s been d e r i v e d in t h e form:
NA = e v a p o r a t i o n r a t e p e r u n i t l i q u i d s u r f a c e a r e a .
DAB = d i f f u s i v e l y c o n s t a n t f o r l i q u i d A.
z = stagnant a i r s p a c e h e i g h t .
PB2 = a i r p a r t i a l p r e s s u r e a t t o p o f c o n t a i n e r .
PB1 = a i r p a r t i a l p r e s s u r e a t s u r f a c e of l i q u i d .
VI-5
ENGINEERING-SCIENCE -
u s i n g n-pentane v e r s u s a r e p r e s e n t a t i v e petroleum l i q u i d :
2
Dm = 0.075 cm 2 / s e c = 6 . 2 9 f t I h r .
PAl = 6 . 8 p s i a (Pnl = 7 . 9 p s i a )
PB2 = 1 4 . 7 p i a
Then, NA =
4.65~10-~ lb
(.
- molelhr
).
z 2
ft
T h i s r e s u l t i s w i t h i n a r e a s o n a b l e range of t h e v a l u e s of
measured e m i s s i o n s from t h e 1 3 t a n k s (20 t o 265 l b / d a y f o r t a n k diam-
e t e r s ranging from 55 t o 153 f e e t ) . T h e r e f o r e i t i s considered t h a t
f u r t h e r e v a l u a t i o n of t h e a p p l i c a t i o n of t h e t h e o r e t i c a l e v a p o r a t i o n
e q u a t i o n t o t h e r e a l t a n k s i t u a t i o n may prove t o be of v a l u e .
VI-6
CHAPTER V I I
.
.
.
ENGINEERING-SCIENCE -
CHAPTER V I 1
GENERAL
The o b j e c t i v e of t h i s t a s k w a s t o determine by s u r v e y s t h e b e s t
a v a i l a b l e s e a l technology f o r f l o a t i n g - r o o f tanks, particularly f o r
upgrading e x i s t i n g tankage where n e c e s s a r y . Major emphasis was placed
on seal technology (both primary and secondary) f o r pontoon-type and
double deck open f l o a t i n g - r o o f tanks. Both crude o i l and d i s t i l l a t e
t a n k s were s t u d i e d . Two types of s u r v e y s were conducted.-
Primary S e a l s
The t u b e seal i s a f l e x i b l e t u b e u s u a l l y f i l l e d w i t h l i q u i d o r a
compressible s o l i d foam. The t u b e s a r e h e l d between t h e r i m of t h e
roof and t h e t a n k s h e l l u s u a l l y a t o r above t h e l i q u i d l e v e l s o t h a t
they completely f i l l t h e a n n u l a r s p a c e . The weight of t h e l i q u i d of t h e
r e s i l i e n c e of t h e foam i s such t h a t t h e s e a l can adapt i t s e l f t o wide
changes i n t a n k dimensions and even f i l l i n t o some e x t e n t a t l e a s t ,
around p r o t r u d i n g r i v e t s and s h e l l i m p e r f e c t i o n s .
VII-2
. FIGURE V I I -
.. VII-3
ENGINEER ING-SCIENCE , I N C .
. ENQINEERINQ-SCIENCE m]-
S e a l s o f f e r e d by t h e major t a n k manufacturers vary c o n s i d e r a b l y
i n design d e t a i l . The s e a l i t s e l f i s u s u a l l y a r e i n f o r c e d f a b r i c
( e . g . , nylon) coated w i t h s y n t h e t i c e l a s t o m e r , r e s i s t a n t t o a b r a s i o n
and hydrocarbons. When a l i q u i d is used i n s i d e t h e t a n k t u b e i t is
commonly a petroleum d i s t i l l a t e or s i m i l a r m a t e r i a l t h a t w i l l not
contaminate t a n k c o n t e n t s i n c a s e of a puncture.
S e v e r a l o t h e r m a n u f a c t u r e r s o f f e r or have developed s p e c i a l d e s i g n s
of primary seals similar t o t u b e seals. Chiyoda Chemical Engineering
and C o n s t r u c t i o n Company, I n c . o f f e r s a vapor s e a l i n g d e v i c e b u i l t
i n t h e shape of a p a i r of l i p s and c a l l e d "Kisseal" ( F i g u r e VII-4).
The d e v i c e is made of p o l y u r e t h a n e foam bonded t o a cover s h e e t of
rubber-reinforced nylon w i t h a n a c r y l i c a d h e s i v e . The shape of t h e '
seal a l l o w s it t o a c t as a d o u b l e seal w i t h r e s p e c t t o small w a l l
deformations. The manufacturer claims t h a t whereas foam l o g s may
p a r t i a l l y f a i l by s p l i t t i n g when t h e a n n u l a r space narrows, t h e d e s i g n
of t h e "Kisseal" m i t i g a t e s such a c t i o n . The "Kisseal" has been in u s e
in welded t a n k s i n t h e O r i e n t f o r t e n y e a r s b u t h a s n o t been used on
r i v e t e d tanks. No i n s t a l l a t i o n s in t h e United S t a t e s are known.
During a n i n t e r v i e w w i t h r e p r e s e n t a t i v e s of Chiyoda, it w a s l e a r n e d
t h a t t h e c h i e f a t t r i b u t e of t h e s e a l , long l i f e , is due t o d e s i g n of
t h e s e a l which m i t i g a t e s compressive f o r c e s , and thereby promotes
VTT-L
FIGURE VII-2
WEATHER SHIELD-
HANGER BAR-
CURTAIN SEAL-
SEAL ENVELOPE -
SEAL SUPPORT-
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VII-7
ENQINEER~NQ-SCIENCE [ESI-
I
r e t e n t i o n of e l a s t i c i t y . However, i n s p e c t i o n of t e n t a n k s i n t h e
O r i e n t by company p e r s o n n e l i n d i c a t e d t h a t t h e s e a l d i d n o t meet t h e
C a l i f o r n i a A i r Resources Board c r i t e r i o n of no gaps g r e a t e r t h a n one-
e i g h t h i n c h on e i g h t of t h e 10 t a n k s examined. I n s t a l l a t i o n c o $ t of
t h e seal i n t a n k s i n t h e United S t a t e s is expected t o be two t o t h r e e
times t h a t of domestic t u b e s e a l s .
Secondary S e a l s
VII-8
FIGURE VII-
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ENGINEERING-SCIENCE, IN[
VII-11
ENQINEERINQ-SCIENCE -
Mini-Bag. There a r e s e v e r a l t y p e s of mini-bag s e a l s . All a r e
small v e r s i o n s of primary foam tube s e a l s . They may be a t t a c h e d
t o t h e t o p of t h e mechanical shoe or t o the r o o f . Foam l o g s a r e
3 t o 4 inches i n diameter. Examples a r e shown i n F i g u r e s V I I - 8 ,
9 , and 10.
S e a l and Tank A c c e s s o r i e s
VII-12
FIGURE V I I -
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VII-15
FIGURE VII-1
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S P R I N G A S S I S T E D MECHANISM
.. ENGINEERING-SCIENCE, IN[
VII-18
ENQINEERINQ-SCIENCE [asI -
t h e y have been considered by some as secondary s e a l s , b u t t h e i r e f f e c -
t i v e n e s s in reducing gap s i z e is poor.
VII-19
i
ENQINEERINQ-SCIENCE -
TABLZ V I I - 1
IAv. p e r Lev.)
Tank Diam. Primary Secondary Levels -l/a:'- 112" &
Iden. Service (feet; Seal Seal Tested i/2" Over
VII-20
ENGINEERING-SCIENCE [Es 1 -
TABLE V I I - 1
VII-21
ENGINEERING-SCIENCE IES]-
TABLE V I I - 1
Welded Tanks
Feet of Gap
(Av. per Lev.)
Tank Xam. Primary Secondfry Levels :/a”-. 1 / 2 “ 6
Ident. Service (feet) Seal Seal Tested 112‘‘ Over
VII-22
ENQINEERINQ-SCIENCE IES]-
TABLE V I I - 1
Welded Tanks
Feet of Gap
(Av. per Lev.)
Tank Ciam. Primary Secondary Levels l/P- i:2" &
Iden. Service (feet) Seal Seal Tes:ed 1/2" Cver
-
T-17 Gas 120 Tube None 1 2.2 0
T-18 Gas 120 Shoe Weather 1 1.4 0
Shield
T-19 Recov. O i l 52 Shoe Wiper 1 1.7 0.2
T-20 Av. Gas 60 Tube None 3 7.1 2.5
T-21 Av. Gas 60 Tube None . 2 .9 0
T-22 Ga s 120 Tube None 3 1.2 0
T-23 Recov. O i l 60 Tube None 3 1.4 0
T-24 Gas 90 Tube None 2 5.3 17.2-
T-25 Gas 70 Shoe None 2 28 1.3
T-26 Gas 150 Tube Weather 4 3.5 0
Shield
T-27 Reformate 120 Tube Weather 1 0 0
Shield
Y-l* JP-4 60 Foam None 7 4.1 30.4
Log
y-2* JP-4 60 Foam None 2 0 0
Log
Y-3 JP-4 90 Foam None 5 0 2.9
Log
Y-4" Gas O i l 86 Foam None 6 12.3 56.8
Log
Y-5 C.O. 150 Liquid- None 4 0 8
Filled
Fabric
VII-23
CNOlNtERINO-SCIENCE PI-
TABLE UII-2
Riveted Tanks
Feet of Gap
(Av. p e r Lev.)
Tank Diam. Primary Secondary Levels 113"- 112" &
Iden. Service (Feet) Seal Seal Tested 112" Cver
VII-24
(E61-
c
LNQINEERINQ-SCIENCE
TABLE V I I - 2
Riveted Tanks
Feet of Gap
(Av. p e r Lev.)
Tank Diam. Primary Secondary Levels 118"- 112" &
Iden. Service (Feet) Seal Seal Tested 112'' Over
Riveted Tanks
Feet of Ga?
(Av. p e r Lev.)
Tank Diam. Frimary Secondary Levels 1:8"-' li2" &
Iden. Service (feet) Seal Seal Tested 1:2" Over
VII-26
CNGINLERINQBCILNCL -
of "no gap g r e a t e r than 1/8-in." T h i s was Tank 15 and i t had been
i n s p e c t e d o n l y a t one roof l e v e l . A f t e r an e x t e r n a l s p r i n g was a t t a c h e d
t o T-16. It met t h e c r i t e r i o n , b u t a g a i n , only a one-level i n s p e c t i o n
was made. S e v e r a l o t h e r t a n k s came c l o s e , b u t even t h e s e had gaps in
excess of 1/2-inch.
T h i s d i s c u s s i o n of f a c t o r s a f f e c t i n g s e a l performance i s based
p a r t l y on t h e t e s t d a t a p r e s e n t e d in Tables V I I - 1 and V I I - 2 , and
p a r t l y on t h e experience of f l o a t i n g - r o o f tank m a n u f a c t u r e r s , e r e c t o r s ,
and u s e r s . The d i s c u s s i o n i s d i r e c t e d s o l e l y t o t h e minimization of
seal gaps and c a r r i e s no c o n n o t a t i o n a s t o hydrocarbon l o s s by evapor-
ation.
D e s p i t e good d e s i g n , t h e r e a r e a v a r i e t y of c o n d i t i o n s t h a t may
develop a s f i e l d c o n d i t i o n s v a r y and time p a s s e s . For i n s t a n c e , i f
t h e t a n k becomes out-of-round (e.g., t e n d i n g toward egg-shape) even
t e m p o r a r i l y , or becomes bulged o r d e n t e d , t h e shoe must have t h e
c a p a b i l i t y of conforming t o t h e new contour i f l a r g e r gaps a r e t o be
avoided. Tank "out-of-roundness'' may r e s u l t from d i f f e r e n t i a l s e t t l i n g
of t h e f o u n d a t i o n o r t h e ground under t h e f o u n d a t i o n , from thermal
stresses ( d i f f e r e n t i a l h e a t i n g by t h e sun), or from wind p r e s s u r e .
Bulges may r e s u l t from thermal o r p h y s i c a l stresses d u r i n g e r e c t i o n .
Tanks of l a r g e diameter a r e more prone t o t h e s e v a r i a t i o n s than smaller
tanks. Tanks up t o 260 f e e t in d i a m e t e r were i n v e s t i g a t e d d u r i n g t h e
c u r r e n t study.
VII-28
ENQINEERINQ-SCIENCE -
If the roof shifts to one side of the tank or another, the shoe
seal must be capable of accommodating the large gap that forms on one
side of the tank, and must do this fairly uniformly. Roof shifting
often results from twisted roof poles or roof drains with stack swivel
joints that tend to pull the roof off-center, particularly at lower
levels. Even if the tank is perfectly round and the roof doesn't
shift, any imperfection in the tank wall such as rivet heads, butt-
straps, beaded welds, guide bars, or a build-up of corrosion products,
carbon, or heavy wax will hold the shoe sufficiently away from the
wall to produce gaps. Bulges or dents in addition to surface imper-
fections accentuate gap development.
To cover up any gaps that occur in the primary seal, one may
install a secondary seal, hoping the gap in the two seals may not
line up vertically. A good secondary seal should be either softer or
harder than the primary seal with the hope that the different type of
closure will add to the overall effectiveness of the dual seals. The
secondary seal should also have the potential to reach out further than
the primary seal and thus cover up large gaps.
VII-29
ENQINEERINQ-SCIENCE -
The most common types of secondary seals are the foam or liquid
filledtube seals, the solid "high pressure" seal, and the clinging
wiper seal-. The secondary tube seal is usually considerably smaller
(less diameter) than the primary Lube seal, and may have a softer
envelope. The smaller diameter, the greater softness and the greater
!,throw" (potential to extend further than the primary seal) make it
effective when used in conjunction with either a shoe or tube seal as
the primary one. It is, of course, subject to the same tearing, and the
potential to wrinkle and form gaps as the primary tube seal.
The wiper seal has the advantage of long "throw" and some of the
softness properties of the tube seal. It probably is somewhat
cheaper.
VII-30
ENQINEERING-SCIENCE -
sufficiently to eliminate gaps has not been demonstrated. The best
methodology for minimizing seal gaps in riveted tanks appears to be a
primary shoe seal plus a secondary tube ( o r similar) seal. In order
to meet gap minimization regulations even with this "best" methodology,
exemptions for protrusions inherent in tank construction (rivet heads,
etc.) are required.
VII-3 1
CHAPTER V I I I
RECOMMENDAT IONS
?
?
-,
. .
, . .
..
. . . '.
.
i
.
:
ENQINEERINQ-SCIENCE -
CHAPTER V I 1 1
RECOMMENDATIONS
VIII-1
CHAPTER IX
B I EL IOGRAPHY
LNOINEERINQ-SCIENCE -
CHAPTER IX
BIBLIOGRAPHY
IX-1