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T H E present time, liquid nitrogen is being carried aboard several
aircraft for inerting fuel tanks, and it has recently been pro-
posed for inerting the fuel tanks on commercial transport aircraft. Be-
cause of the availability of large quantities for inerting, it has been further
proposed that a secondary use be made of the nitrogen for extinguishing
powerplant fires. Like carbon dioxide, the effectiveness of liquid nitrogen
in extinguishing fires is dependent upon cooling to reduce the temperature
of the combustible below its ignition temperature, or the point at which it
vaporizes, and upon oxygen dilution to the level that will no longer support
combustion. A comparison of the physical properties of liquid nitrogen,
carbon dioxide, and the two most common halogenated fire extinguishing
agents (dibromodifluoromethane and bromotrifluoromethane) currently in
use on United States military and commercial aircraft is made in Table 1.
NOTE: The author presented this paper at the 73rd Annual Meeting of the National
Fire Protection Association in New York City on May 13, 1969.
197
198 Fire Technology
overall effectiveness of liquid nitrogen as a fire extinguishing agent cannot
be expected to be as great as the highly effective halogenated agents, how-
ever, for these agents do not depend primarily on cooling and oxygen dilu-
tion, b u t on a chemical interference with the combustion process. This
lower effectiveness of nitrogen does not eliminate it from consideration as
a fire extinguishing agent on aircraft where large quantities can be made
available from the supply of liquid nitrogen stored for inerting fuel tanks.
A determination of just how large a quantity would be required for
extinguishment could not be made because of a lack of directly applicable
technical information. Work done by the U.S. Bureau of Mines 1 has shown
that diluting a mixture of JP-4 fuel vapor in air with gaseous nitrogen so
that the volumetric oxygen concentration is 12 per cent or less produces a
nonflammable mixture. This relationship is shown in Figure 1 for sea
level temperature and pressure. Inerting the mixture by reducing the
oxygen concentration to 11 per cent would require approximately 45 per
cent, by volume, of gaseous nitrogen added to a stoichiometric fuel-air
composkion. A comparison of this inerting data with results of an investi-
gation into the inhibition of diffusion flames by the National Bureau of
Standards 2 shows that, for most combustibles, the amount of nitrogen re-
quired to extinguish a flame is generally substantially lower, and the result-
ing oxygen concentration higher, than the requirements for inerting. Con-
sidering this difference in the requirements for inerting and extinguishment
together with the effects of cooling, it was theorized that liquid nitr: gen
could extinguish JP-4 jet fuel fires b y lowering the volumetric oxygen con-
centration from 21 per cent in air to some value above 11 per cent. In
order to demonstrate this and to provide design criteria for an aircraft
powerp|ant fire extinguishing system that would utilize a nitrogen supply
common to other aircraft systems, an investigation was initiated recently
by the Federal Aviation Administration. The work described here sum-
marizes the findings to date resulting from this effort and discusses current
and future areas of investigation.
DISCUSSION
The effectiveness of liquid nitrogen as a fire extinguishing agent is being
investigated at the Federal Aviation Administration's test facilities near
TABLE 1. Physical Properties of Several Extinguishants
Physical property LN2 C02 CBrF:~ CBr~.F~.
20
18 - ~ "-- Ls
12 :
~ ~N2~ ADDE n
10 _ _ ~ ~ _ Vo~u~
0 2 4 6 8 I0
J P-4 FUEL VAPOR, %VOLUME
Figure 1. Producing nonflammable mixtures by inerting with gaseous nitrogen.
LN z CONTAI NER
3
REGION FOR NOI~ 1/15 r .,,
EXTINGUISHMEN1 / ,,/
/ j..
!" i . : " :%:! ,,
/
/
/ i. : . :i ~..... :"!::~:::/ /
2 - ' : ::. : : .... ::: : - , / /10 %
I :.~::;~EGtbNi
:~:~ /
AIRFLOW, / / :..........................
/ / i:::.:':
'II}/"
9 .'" :"'"''"''" ......
; : :: ::;::::::~ii~:~i:;:~i::~!~i:-i:!;i:::;;::
,
./:;5 !.:;i::.~:;.~:!!i:i:!i!ii:i:!!:i:ii!i::i#!iii!iii:iii:ii:i!:i!:::
i:i~!::i!:::;~:~::ii:::~i!::i~i~i:;~::~
~i~:;::i:: ::!!:.:i:....9 /.- -
/ l l~" ": .:~i:i:i~;i~:~i:i~i:!:::~;i~i~::~i~i:i:.~::iii::::i!::::ii::. .
i: ': ~~::;:::~::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: 1
/ ~ ....~:::~:::~I~:~::I~::~::!~:::~L-~IMEJO~= 5
l/ i
j/ ...- =I
0 1 2 3
LN 2 D I S C H A R G E RATE, I b / s e c
Figure 3. The effect o[ airflow on liquid nitrogen requirements for extinguishment.
202 Fire Technology
are also shown in this figure for a time of 2 sec after initiation of nitrogen
discharge. The lower of the two lines shown for each percentage represents
the concentrations disregarding the oxygen consumption by the fire, and
the upper line represents the oxygen concentration with complete com-
bustion of the jet fuel. The results show that a dilution of the oxygen con-
centration to approximately 10 per cent was required at the low air flow,
while at the high air flow, the fires were extinguished with oxygen concen-
trations theoretically remaining well above 15 per cent. Further testing is
expected to better define this relationship.
Tests at the low air flows were conducted with nitrogen being throttled
to reduce the discharge rate. This resulted in large quantities of the
nitrogen being converted to a gas in the discharge line. It is theorized that
the required discharge rates would be somewhat lower if the nitrogen in
the line were maintained in the liquid state. The test fires at the higher air
flows are considered to have been burning lean, and it is expected that,
when the fuel is released at higher rates, the required nitrogen discharge
rates will increase producing lower oxygen concentrations.
Other items under investigation or under consideration for future
studies include the effects of line length and diameter, the type of discharge
nozzle, the amount of cooling and oxygen dilution, the effect of storage
pressure, the amount and effects of thermal shock to engine components,
and means of evaluating new powerplant installations that utilize liquid
nitrogen for extinguishing engine fires.
SUMMARY
Preliminary test results indicate that liquid nitrogen is effective in ex-
tinguishing fires in aircraft powerplant compartments; that the quantity of
liquid nitrogen expected to be available from a fuel tank inerting system
would be sufficient to extinguish this type of fire; and that, on aircraft
where a large quantity of liquid nitrogen is available, a liquid nitrogen fire
extinguishing system could provide greater in-flight powerplant fire pro-
tection than the limited quantity of agent available in a conventional high
rate of discharge system
REFERENCES
I Jones, G. W., Zabetakis, M. G. Scott, G. S., and Furno, A. L., "Research on the
Flammability Characteristics of Aircraft Fuels," W A D C Technical Report 52-35,
Supplement 1, January 1954.
2 Creitz, E. C., "Inhibition of Diffusion Flames by Methyl Bromide and Trifluo-
romethyl bromide Applied to the Fuel and Oxygen Sides of the Reaction Zone,"
Journal of Research (National Bureau of Standards), A. Physics and Chemistry, Vol.
65A, No. 4, July-August 1961.