COMPONENETES HEPTANO Y OCTANO

COMP
No. SUSTANCIA FORMULA A B C
10 HEPTANO(A) C7H16 7 1264.37 216.636
107 OCTANO(B) C8H18 6.9094 1349.82 209.385

CALCULO DE LAS TEMPERATURAS DE EBULLICION POR LA SIGUIENTE ECUACION

�=𝐵/(𝐴−𝑙𝑜𝑔𝑃𝑡)−�
Pt[mmHg] 760

PARA (A) Teb[°C] 98.4296688706

para (B) Teb[°C] 125.6754562964

paso 2.7245787426

T[°C] Pvap (A)[mmhg] Pvap (B)[mmhg] XA YA CpAJ/Kmol*K]

98.4296689 760 334.3712030741 1 1 257088.4876846
101.154248 822.6581623368 365.3449018527 0.86298634 0.93413521 259087.445893
103.878826 889.2836087019 398.5731003221 0.73653793 0.8618304 261116.8636962
106.603405 960.0437237885 434.1711677742 0.61959657 0.78268395 263176.925817
109.327984 1035.108521617 472.2573823445 0.5112233 0.69627842 265267.8169786
112.052563 1114.650522127 512.9528714697 0.4105835 0.60218041 267389.721904
114.777141 1198.844625252 556.3815481974 0.31693409 0.49994044 269542.8253162
117.50172 1287.867982798 602.6700435623 0.22961242 0.38909274 271727.3119383
120.226299 1381.899868457 651.9476352532 0.14802662 0.26915523 273943.3664932
122.950878 1481.121546244 704.3461727925 0.07164726 0.13962934 276191.1737041
125.675456 1585.716137689 759.9999994558 6.5901E-10 1.375E-09 278470.9182939

XA VS YA
GRAF T
1.2 140

1 120

100
0.8
80
0.6
T[°C]
YA

60
0.4
40
0.2
20
0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4
XA
 0.2
20
0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4
XA

HL vs XA,YA H
9000 18000
8000 16000
7000 14000
6000 12000

Hv[Kcal/Kmol]
HL[Kcal/Kmol]

5000 10000
4000 8000
3000 6000
2000 4000
1000 2000
0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0
XA,YA
 COMPORTAMIENTO
IDEAL Pc[atm]
27
24.63
Tc (°K)
540
569.06

3.295836866

CpA[Kcal/Kmol°C] CpBJ/Kmol*K] CpB[Kcal/Kmol°C] HL[kcal/Kmol] λ A[kcal/Kmol]

61.4441485566 267405.3341507
61.9218995684 268133.0428983
62.4069304234 268832.8933225
62.8992852703 269503.7921205
63.3990082579 270144.6459898
63.9061435351 270754.3616277
64.4207352506 271331.8457315
64.9428275532 271876.0049988
65.4724645919 272385.7461268
66.0096905153 272859.9758129
66.5545494722 273297.6007545
63.909874862 6047.927196461 7797.383902143
64.0837972527 6293.626011416 7983.748880574
64.2510615041 6533.229109753 8176.345869475
64.4114063168 6766.59797524 8375.492780213
64.5645703916 6993.569859621 8581.529521541
64.710292429 7213.957666638 8794.819935675
64.8483111298 7427.549932745 9015.753942537
64.9783651947 7634.110876067 9244.74991871
65.1001933243 7833.380491439 9482.257341673
65.2135342193 8025.074674382 9728.759734464
65.3181265803 8208.885360824 9984.777951362

GRAFICAS T vs XA,YA PA VS
140 1800
1600
120
1400
100 1200
PA[mmHg]

80 1000
T[°C]

800
60
600
40
400
20 200
0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4

XA,YA
 400
20 200
0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4

XA,YA

Hv vs XA,YA
18000
16000
14000
12000
Hv[Kcal/Kmol]

10000
8000
6000
4000
2000
0
0 0.2 0.4 0.6 0.8 1 1.2
XA,YA
NTO

λ B[kcal/Kmol] Hv[kcal/Kmol]
6808.7393889306 13845.3110986
6954.5613338449 14194.02847
7104.5179540074 14537.479145
7258.7876319382 14873.1235621
7417.5591611674 15197.9951527
7581.0325170086 15508.644982
7749.4196968384 15801.0801184
7922.9456373058 16070.6950168
8101.8492168149 16312.1950981
8286.3843526773 16519.5115919
8476.8212035305 16685.7065665

PA VS XA,YA
1800
1600
1400
1200
PA[mmHg]

1000
800
600
400
200
0
0 0.2 0.4 0.6 0.8 1 1.2
XA,YA
400
200
0
0 0.2 0.4 0.6 0.8 1 1.2
XA,YA
 COMPORTA
COMPONENETES HEPTANO Y OCTANO
REA
No. SUSTANCIA FORMULA A B C Pc[atm]
10 HEPTANO(A) C7H16 7 1264.37 216.636 27
107 OCTANO(B) - C8H18 6.9094 1349.82 209.385 24.63

sistema van laar van laar

POR VAN LA 0 0
A12 A21 1 1
HEPTANO(A)-OCTANO(B) 2.7 2.463

T[°C] T[F] P[psia] XA YA gama1 gama 2

125.4017 257.723 14.7 0 0 14.88 1
99.1272 210.429 14.7 0.05 0.56752 11.173 1.007
91.0206 195.837 14.7 0.1 0.68143 8.546 1.029
87.8294 190.093 14.7 0.15 0.72116 6.657 1.067
86.6844 188.032 14.7 0.2 0.7353 5.277 1.121
86.5211 187.738 14.7 0.25 0.73739 4.256 1.093
86.8328 188.299 14.7 0.3 0.73279 3.49 1.286
87.3461 189.223 14.7 0.35 0.72415 2.908 1.404
87.9006 190.221 14.7 0.4 0.71306 2.463 1.551
88.4011 191.122 14.7 0.45 0.7007 2.118 1.734
88.7956 191.832 14.7 0.5 0.68802 1.849 1.961
89.0606 192.309 14.7 0.55 0.67594 1.637 2.243
89.2011 192.562 14.7 0.6 0.66543 1.471 2.592
89.2422 192.636 14.7 0.65 0.65759 1.34 3.027
89.2350 192.623 14.7 0.7 0.6538 1.238 3.572
89.2594 192.667 14.7 0.75 0.65594 1.158 4.256
89.4383 192.989 14.7 0.8 0.66678 1.098 5.12
89.9611 193.93 14.7 0.85 0.69094 1.053 6.612
 91.1428 196.057 14.7 0.9 0.73695 1.023 7.618
93.5728 200.431 14.7 0.95 0.82328 1.006 9.417
98.5861 209.455 14.7 1 1 1 11.74

YA vs XA
1.2 300

1 250

0.8 200

0.6 150

T[°F]
YA

0.4 100

0.2 50

0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2
XA

Hl vs XA,YA
9000 16000

8000
14000
7000
12000
6000
10000
HL[Kcal/Kmol]

5000
8000
Hv

4000
6000
3000

2000 4000

1000 2000

0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2
XA,YA
PORTAMIENTO
REAL
Tc (°K)
540
569.06

AN LAAR
Phi1 CpAJ/Kmol*K] CpA[Kcal/Kmol°CCpBJ/Kmol*K] CpB[Kcal/Kmol°C]HL[kcal/Kmol]
1 278240.38082 66.499451017 273255.310009 65.3080190921 8189.734440842
1 257597.37521 61.5657726763 267594.236561 63.9550225382 6327.841746268
1 251805.16754 60.1814350421 265294.245566 63.4053246902 5741.843855803
1 249597.68795 59.6538474209 264329.505217 63.174751747 5502.217488218
1 248815.52329 59.4669100658 263975.72798 63.0901989873 5406.12229166
1 248704.37274 59.4403450852 263924.942647 63.0780612927 5378.899137734
1 248916.55792 59.4910573434 264021.780694 63.1012055858 5385.209202119
1 249266.88069 59.5747844842 264180.647154 63.1391746699 5405.993898761
1 249646.43691 59.6654984223 264351.346538 63.1799718227 5429.984957448
1 249990.15383 59.7476467647 264504.653425 63.2166121685 5450.421578129
1 250261.71099 59.8125489272 264624.920893 63.2453560934 5463.497520905
1 250444.50014 59.8562355332 264705.450974 63.2646027829 5467.427576407
1 250541.56498 59.8794340313 264748.07573 63.2747900995 5462.459861859
1 250569.97041 59.8862229272 264760.531456 63.2777670179 5450.313740514
1 250564.97978 59.8850301665 264758.343668 63.2772441366 5434.651930995
1 250581.87198 59.8890674036 264765.747833 63.2790137321 5421.311066239
1 250705.56487 59.9186300044 264819.876251 63.2919504241 5419.363234437
1 251067.77319 60.0051977919 264977.485713 63.3296190855 5442.994560807
 1 251890.52605 60.2018357255 265330.558166 63.4140034018 5516.239123811
1 253600.07053 60.610416856 266042.430639 63.5841409227 5685.398048552
1 257202.44458 61.4713842552 267447.853083 63.9200368867 6060.22471834

T vs X, Y
300

250

200

150

100

50

0
0 0.2 0.4 0.6 0.8 1 1.2
XA , YA

Hv vs XA, YA
16000

14000

12000

10000

8000

6000

4000

2000

0
0 0.2 0.4 0.6 0.8 1 1.2
XA,YA
λ A[kcal/Kmol] λ B[kcal/Kmol] Hv[kcal/Kmol]
9958.60518318 8457.40961683 0
7844.52081763 6845.688807 11151.64017315
7319.8014291 6431.79524529 11369.69594824
7126.28711734 6277.70972469 11295.74581218
7058.52367212 6223.56740857 11256.25632904
7048.92740979 6215.89227415 11250.61267283
7067.25373484 6230.54806668 11257.12249334
7097.5770115 6254.78243504 11259.00206984
7130.52422155 6281.09191986 11245.66081697
7160.44501811 6304.96494294 11212.5265089
7184.1415316 6323.85843734 11159.82057119
7200.12063884 6336.59210954 11092.35362381
7208.61528065 6343.35926926 11019.91930714
7211.10242107 6345.34033523 10956.63037402
7210.66540762 6344.9922531 10922.3672593
7212.14467351 6346.17047534 10944.10290831
7222.98261871 6354.80140512 11059.09255967
7254.78064609 6380.10996221 11321.41756261
 7327.35296697 6437.7922733 11811.93358763
7479.70289299 6558.52693484 12646.93898296
7807.92143011 6817.00343117 13868.14614845

1.2

1.2