Beruflich Dokumente
Kultur Dokumente
NIM : 1710246298
TUGAS : SAPTK
(CH3)2CHOH CH3COCH3 + H2
Isopropanol Acetone Hydrogen
The effluent from the reactor enters a phase separator that separates vapor from liquid. The
liquid contains the bulk of the product, and the vapor is a waste stream. The vapor stream is at
a temperature of 30 oC and an absolute pressure of 1.1 bar.
The component flowrates in the vapor stream are given in table 2.13, together with their raw
material values and fuel values. Three options are to be considered :
a. Burn the vapor in a furnace
b. Recover the acetone by absorption in water recycled from elsewhere in the process with
the tail gas being burnt in a furnace. it is expected that 99% will be recovered by this
method at a cost of 1.8 $/kmol acetone recovered
c. recover the acetone by condensation using refrigerated coolant with the tail gas being
burnt in a furnace. It is anticipated that a temperature of -10 oC will need to be achieved in
the condenser. It can be assumed that the hydrogen is an inert that will not dissolve in the
liquid acetone. The vapor pressure of acetone is given by
2940.5
𝐿𝑛 𝑃 = 10.031 − ( )
𝑇 − 35.93
The cost of refrigerant is $11.5 / GJ, the mean molal heat capacity of the vapor is 40
kJ/kmol.K and the latent heat of acetone is 29,100 kJ/kmol. Calculate the economic
potential of each option given the data in Table 2.13.
reactor Phase
isopropanol separator
acetone
hydrogen
liquid vapor
Fuel value
Flow rate in vapor Raw Material Fuel value cost
Component
(kmol/hour) Value ($/kmol) ($/kmol) ($/hour)
Fuel value Hydrogen cost = Flow rate Hydrogen in vapor (kmol/hour) * Fuel value Hydrogen ($/kmol)
= 51,1 kmol/hour * 0,99 $/kmol
= 50,589 $/hour
Fuel value Acetone cost = Flow rate Acetone in vapor (kmol/hour) * Fuel value Acetone ($/kmol)
= 13,5 kmol/hour * 6,85 $/kmol
= 92,475 $/hour
Total cost/hour = Fuel value Hydrogen cost + Fuel value Acetone cost
= 50,589 $/hour + 92,475 $/hour
= 143,064 $/hour
(b) OPTION B : Recover the acetone by absorption in water recycled with expected 99%
recover rate (1,8 $/kmol)
So :
absorption cost
Absorpsion cost Hydrogen = Flow rate Hydrogen in vapor (kmol/hour) * absorption cost ($/kmol)
= 51,1 kmol/hour * 1,8 $/kmol
= 91,98 $/hour
Absorpsion cost Acetone = Flow rate Acetone in vapor (kmol/hour) * absorption cost ($/kmol)
= 13,5 kmol/hour * 1,8 $/kmol
= 24,3 $/hour
acetone recovered
acetone recovered = Flow rate Acetone in vapor (kmol/hour) * absorption rate
= 13,5 kmol/hour * 99%
= 13,365 kmol/hour
Fuel value Acetone cost = (Flow rate Acetone in vapor (kmol/hour) – Acetone recovered ) *
Fuel value Acetone ($/kmol)
= (13,5 kmol/hour – 13,65 kmol/hour) * 6,85 $/kmol
= 0,92 $/hour
Fuel value cost/hour = Fuel value Hydrogen cost + Fuel value Acetone cost
= 50,589 $/hour + 0.92 $/hour
= 51,51 $/hour
Acetone product value
Acetone product value = Raw Material Value ($/kmol) * Acetone recovered
= 34,8 $/kmol * 13,365 kmol/hour
= 465,10 $/hour
(c) OPTION C : recover acetone by condensation using refrigerated coolant with the tail gas
being burnt in a furnace
Data :
Feed temperature = 30 oC = 303,15 K
Coolant temperature = - 10 oC = 263,15 K
cost of refrigerant = $11.5 / GJ
mean molal heat of vapor = 40 KJ/kmol.K
latent heat acetone = 29100 KJ/kmol
𝑃 = 0,05 𝑏𝑎𝑟
Coolant energy Acetone = Flow rate Acetone in vapor (kmol/hour) * mean molal heat of vapor *
(Feed temperature – coolant temperature)
= 13,5 kmol/hr * 40 KJ/kmol.K * (303,15 K – 263,15 K)
= 21.600 KJ/hr
Latent energy needed
Latent energy needed = Flow rate Acetone in vapor (kmol/hour) * latent heat acetone
= 13,5 kmol/hr * 29100 KJ/kmol
= 392,85 KJ/hr
Total Coolant energy acetone = Coolant energy acetone (KJ/hr) + latent energy needed (KJ/hr)
= 21.600 KJ/hr + 392,85 KJ/hr
= 414.450 KJ/hr
Total coolant energy needed (KJ/h) = Total Coolant energy hydrogen + Total Coolant energy acetone
= 81.760 KJ/hr + 414.450 KJ/hr
= 496.210 KJ/hr
Cost of refrigerant Acetone ($/h) = Total Coolant energy Acetone * cost of refrigerant
= 414.450 KJ/hr *11,5 $/GJ*10-6 GJ/KJ
= 4,77 $/hr
Cost of refrigerant ($/h) = Cost of refrigerant hydrogen ($/h) + Cost of refrigerant Acetone
($/h)
= 0,94 $/hr + 4,77 $/hr
= 5,71 $/hr
Fuel Value Cost Acetone ($/h) = ( Flow rate Acetone in vapor (kmol/hour) – Acetone recovered ) *
Fuel value ($/kmol)
= ( 13,5 kmol/hr – 13,5 kmol/hr ) * 0,99 $/kmol
= 0
Fuel Value Cost ($/h) = Fuel Value Cost hydrogen ($/h) + Fuel Value Cost Acetone ($/h)
= 50,59 $/hr
SUMMARY
From of three options above (option A, B dan C), it can be concluded that option C
is the most economic by recover the acetone by condensation using refrigerated coolant with
the tail gas being burnt in the furnace