Beruflich Dokumente
Kultur Dokumente
a r t i c l e i n f o a b s t r a c t
Article history: A multifunctional composite square honeycomb sandwich structure (MCHSS) is developed which provides both
Received 17 November 2015 high thermal conductivity and adequate mechanical property for a thermal management system. The out-of-
Received in revised form 12 April 2016 plane thermal conductivity of MCHSS is improved by a simple method of coating highly oriented graphite film
Accepted 15 April 2016
(HOGF), and investigated both theoretically and experimentally. There are two most efficient methods to further
Available online 19 April 2016
enhance the out-of-plane thermal conductivity of MCHSS: one is to increase the HOGF volume content, and the
Keywords:
other, to decrease the interface thermal resistance. The maximum improvement is up to approximately 26 times
Multifunctional sandwich structures for the measured out-of-plane thermal conductivity as compared with the traditional composite sandwich struc-
Composite square honeycomb tures. Results indicate that, except for high specific thermal conductivity for thermal management, MCHSS also
Highly oriented graphite film possess adequate mechanical properties for structural applications. Thus, MCHSS can be considered as a promis-
Thermal conductivity ing candidate for multifunctional structure material in the high-end heat dissipation field.
Mechanical properties © 2016 Elsevier Ltd. All rights reserved.
1. Introduction conductivity, which limits its application in the high-end heat dissipa-
tion fields such as satellite. Therefore, a multifunctional composite sand-
Periodic lattice materials are considered as the most promising wich structure, possessing both the superior mechanical properties and
multifunctional structure materials in the 21st century, and put forward high thermal conductivity, is urgently needed in these fields.
by Ashby, Evans, Fleck, Gibson, Hutchinson and Wadley, owing to their In this paper, MCHSS is devised and fabricated by the CFRP compos-
excellent mechanical properties (specific stiffness and specific strength) ite laminate coating HOGF [15,16]. Efforts are underway to determine
and multifunctional application potentials [1–5]. Carbon fiber rein- the out-of-plane thermal conductivity of MCHSS and to assess its out-
forced plastic (CFRP) composite sandwich structures are more remark- of-plane compressive and shear properties, both theoretically and ex-
able for building ultra-lightweight multifunctional structures, especially perimentally. Moreover, the detailed analysis is conducted to reveal
for spacecraft. Recently, a variety of composite lattice cores have been the main factors that affect the out-of-plane thermal conductivity.
fabricated and their performance evaluated [6–13]. The experimental
results have been added to the modified Ashby material property 2. Experimental
chart [14] as shown in Fig. 1. It can be obviously seen that composite
square honeycomb sandwich panels [11] have significantly higher 2.1. Materials and fabrication
compressive and shear modulus than the other sandwich panels, on
an equal mass basis. For core densities more than 100 kg/m3, composite The plain woven Toray T300-3 k carbon fiber epoxy prepreg with
square honeycomb sandwich panels [11] have superior out-of-plane 45% resin content (a density of 1.45 g/cm3, Liso Composite Material
compressive strength than most known materials. Only when the core Technology Co. Ltd., China) is used to fabricate the square honeycomb
densities are less than 100 kg/m3, pyramidal truss core sandwich panels core due to its high specific stiffness and strength. HOGF (the density
[6] exhibit greater out-of-plane compressive strengths. Moreover, 2.1 g/cm3, in-plane thermal conductivity is up to 1500 W/mK) with a
square honeycomb structures overcome the drawback of hexagonal thickness 20 μm is from Tanyuan Science and Technology Co., Ltd.,
honeycomb structures and show a high in-plane stretching strength China. The aluminum alloy (thermal conductivity of 208 W/mK) is
(at least for loadings along the directions of the cell walls). used as the facesheet with a thickness of 0.25 mm.
However, owing to vast inner space and low thermal conductivity of In this paper, multifunctional composite square honeycomb struc-
composite cores, composite sandwich structures show very low thermal tures are fabricated by a slotting and assembling procedure as follow.
⁎ Corresponding author. (i) Orthogonal symmetric composite prepregs are laid up on a base
E-mail address: wlz@hit.edu.cn (L.-Z. Wu). plate and then placed in a compressive molding for curing and
http://dx.doi.org/10.1016/j.matdes.2016.04.050
0264-1275/© 2016 Elsevier Ltd. All rights reserved.
G.-C. Yu et al. / Materials and Design 102 (2016) 238–246 239
Fig. 1. Modified Ashby material strength versus density map for engineering materials [9].
heated at 3 °C/min up to 80 °C, held for 30 min, then heated at (ASTM C117), the heat flow meter (ASTM C518) and the transient radi-
3 °C/min to 130 °C, for 120 min at 1.0 MPa before furnace natural- ant step heating method (ASTM E1461), respectively. The measured ef-
ly cooling to ambient temperature. fective thermal conductivities of the sandwich panel using the standard
(ii) Square honeycomb wall straps with the cross-slots are cut from steady-state techniques of the guarded hot plate and heat flow meter
the composite laminates by using the diamond wire cutting ma- are significantly higher than the reported radiant step heating data
chining into long strips of height H = 3l and length L = 6l + 2Δl, and are determined to be inaccurate [17]. Therefore, the flash method
where Δl is a small overhang length set at 2.0 mm, see Fig. 3A. is used to measure the effective out-of-plane thermal conductivity of
Cross-slots are of spacing l and of width d = c + 2t + e, where e MCHSS. With the measurement of the thermal diffusivity, heat capacity
is a clearance of 0.1 mm to provide a sufficiently tight fit during and density of the specimen, the thermal conductivity of MCHSS is
honeycomb assembly. calculated by the following equation:
(iii) After the surface grease is cleared, the rich resin layer of compos-
ite surfaces is gradually removed by the fine sandpaper, and then k ¼ αρC p ð1Þ
HOGF is adhered to the surface of square honeycomb wall straps.
(iv) The modified honeycomb wall straps are slot-fitted and assem- where k is the effective thermal conductivity (W/m K), α is the effec-
bled to build the honeycomb core topology. The sandwich panels tive thermal diffusivity (m2/s), ρ is the effective density (kg/m3); Cp
are fabricated by bonding the composite core to facesheets with a is the effective specific heat (J/kg K). The effective specific heat Cp is
high strength adhesive (J272-A, shear strength of 48 MPa, ther- given by:
mal conductivity of 0.3 W/mK) or a high thermal conductivity .X
X
adhesive (J-TC, thermal conductivity of 2.5 W/mK). C i mi mi
Cp ¼ ð2Þ
Fig. 2. Sketch of composite square honeycomb manufacturing technique and schematic of the series-parallel thermal conduction model.
where d is the thickness of the specimen, and t1/2 is the time re- 2.2.2. Mechanical properties
quired for the upper surface to reach half of the maximum temper- Composite square honeycomb sandwich structures are tested in
ature rise. out-of-plane compression and shear at a nominal strain rate of
The measurement procedure of thermal conductivity is as follows. 10−3 s−1 in accordance with ASTM standards C365 and C273. Accord-
ing to the Ref. [11], the out-of-plane compressive tests are conducted on
(i) Square test specimen with size 10 mm× 10 mm× 6 mm is cut the reference specimen geometry comprising 6 × 6 cells with a cell as-
from the center of a composite square honeycomb sandwich pect ratio H/L = 3. Square honeycomb cores are fabricated into the
panel. cube of 64 × 64 × 30 mm3. Specimens with three relative densities are
(ii) A thin layer of the pyrolysis graphite is sprayed on the specimen compressed along the out-of-plane direction, and three repeated tests
surface to ensure uniform emissivity on the surface for measure- are performed to gauge the variability in each case. The damage mor-
ment accuracy. phologies are recorded using a Nikon COOLPIX P7700 camera.
(iii) The specimen is placed within the laser flash diffusivity instru- Shear property is one of the most important factors characterizing
ment (LFA447, Netzsch) under an air atmosphere, where a sandwich panel. Shear tests of composite square honeycomb structures
Xenon flash lamp is used to provide energy (up to 10 J) of a are conducted with a cell aspect ratio H/L = 1, according to the reference
short heat pulse to the front surface of the sample. The tempera- [11]. The shear tests are performed by a single-lap shear set-up in accor-
ture rise on the back surface of the disk is recorded as a function dance with ASTM standard C273. The standard demands a specimen as-
of time using an infra-red detector. pect ratio ℓ/H ≥ 12, where ℓ is the length of the specimen. The shear
(iv) The out-of-plane thermal diffusivity is determined from the response is also dependent upon the direction of loading. The load is
temperature rise data based on the Cowen model [18]. measured by the load cell of the test machine and used to define the
(v) With the measurement of the thermal diffusivity, heat capacity nominal shear stress, while a clip gauge mounted on the single-lap
and density of the specimen, the thermal conductivity of MCHSS shear test fixture is employed to measure the relative displacement
is calculated by Eq. (1). and thereby gives the applied shear strain.
Fig. 3. The out-of-plane thermal conductivity of MCHSS vs. (a) the relative density of composite honeycomb cores and (b) the HOGF volume content.
G.-C. Yu et al. / Materials and Design 102 (2016) 238–246 241
Fig. 4. The out-of-plane thermal conductivity of MCHSS vs. HOGF volume content and interface thermal resistance.
Fig. 5. The out-of-plane thermal conductivity of MCHSS vs. (a) the interface thermal resistance and (b) the thickness of the sandwich structure.
242 G.-C. Yu et al. / Materials and Design 102 (2016) 238–246
3.1.2. Interface
The measured out-of-plane thermal conductivities of MCHSS are Fig. 4 shows the surface plots of the out-of-plane thermal conductivity
plotted against the relative densities of composite honeycomb cores in of MCHSS versus the HOGF volume content together with the interface
Fig. 3(a). As expected, the out-of-plane thermal conductivities increase thermal resistance. Obviously, the out-of-plane thermal conductivity is
with the relative densities of honeycomb cores as seen in Fig. 3(a). At influenced not only by the HOGF volume content but also by the interface
the density of 7.7%, the mean thermal conductivity of composite square thermal resistance in Fig. 4. It can be clearly seen that the thermal conduc-
honeycomb structures is only 0.45 W/mK, which limits its application in tivities increase rapidly with increasing HOGF volume content and de-
the heat dissipation fields. creasing interface thermal resistance due to reducing effective thermal
The relative density of the composite honeycomb core is fixed at resistance of cores.
7.7%. The out-of-plane thermal conductivity as a function of the HOGF Fig. 5(a) plots the thermal conductivity against the interface thermal
volume content is shown in Fig. 3(b). It can be observed that the ther- resistance for different HOGF volume contents, to intuitively show the
mal conductivities obviously increase with the HOGF volume content. effect of the interface thermal resistance. It is obvious that the out-of-
The maximum mean thermal conductivity of MCHSS is up to 13.53 W/ plane thermal conductivities of MCHSS decrease rapidly with increasing
mK corresponding to HOGF volume content of 6.14%. Compared with the interface thermal resistance at the same HOGF volume content. This
traditional composite sandwich structures, the maximum improvement indicates that an effective method to enhance the out-of-plane thermal
on the measured thermal conductivity attains to more than 26 times. It conductivity is to reduce the interface thermal resistance between the
indicates that HOGF vastly improves the out-of-plane thermal conduc- facesheet and the core as much as possible.
tivity of MCHSS. Nevertheless, the thermal conductivity does not in- Meanwhile, according to Eq. (6), increasing the thickness H of the
crease linearly with the HOGF volume content. It implies that there sandwich structure can indirectly decrease the interface thermal resis-
may exist another factor that affects the out-of-plane thermal conduc- tance phase 2RH , and then improves the out-of-plane thermal conductiv-
i
tivity of MCHSS. ity of the sandwich structure. Fig. 5(b) shows the variation of the out-of-
Fig. 7. The out-of-plane thermal conductivity of MCHSS vs. the HOGF volume content and the thermal conductivity of facesheet materials.
G.-C. Yu et al. / Materials and Design 102 (2016) 238–246 243
Fig. 10. Measured failure mode and modified predicted model of composite square honeycomb structures under a compressive load.
244 G.-C. Yu et al. / Materials and Design 102 (2016) 238–246
Fig. 11. Comparison of the predicted and measured values of the out-of-plane compressive strengths of composite square honeycombs.
Under out-of-plane compressive load, the composite square honey- mode shown in Fig. 10A, the theoretical model is modified as shown
comb core shows two possible failure modes: elastic bucking and plastic in Fig. 10B. The elastic buckling strength σpk of a square honeycomb
microbuckling of the cell wall. The minimum value of ultimate strengths core is modified as
predicted by different failure modes will be the effective out-of-plane
compressive strength. For different failure modes, the corresponding Kπ2 E1 t3
out-of-plane compressive strengths of square honeycomb cores are σ buck ¼ ðElastic buckingÞ: ð9Þ
6 ðH=2Þ2 L
given by [10]
pffiffiffiffiffiffiffiffiffiffi 3 The buckling coefficient K lies in a range from 1.0 to 2.0. The predict-
Kπ 2 E1 E3 t
σ buck ¼ ðElastic buckingÞ ð7Þ ed and measured values of the compressive strengths are included in
6ð1−υ13 υ31 Þ L
Fig. 11. It can be found that K is close to 1.5.
σ pk ¼ σ c ρ ðPlastic microbucklingÞ ð8Þ
3.2.2. Shear
The peak shear strength of composite square honeycombs is again
where K is the buckling coefficient, E1 and E3 are the Young's modulus of
governed either by the elastic buckling of the cell walls, by the interfa-
the orthotropic faces along the x1 and x3 directions in Fig. 2, respective-
cial debonding or by the shear strength τs of the composite sheet
ly; υ13 and υ31 are the Poisson's ratio of honeycomb core walls, and σc
material when subjected to a shear stress. We consider each of these
the strength of the plastic microbuckling of honeycomb core walls.
mechanisms in turn.
The measured compressive stress-strain responses of honeycomb
Consider the elastic buckling of the cell walls that lie along the x1 di-
structures are plotted in Fig. 9. An initial linear response is observed in
rection. The principal bending rigidities of this cell wall are given as [11]
all cases. The subsequent softening after the peak stress is rather dra-
matic for the case of ρ ¼ 0:17. By contrast, the stress falls more gradually
for the lower density honeycomb cores. For the specimens with the E1 t 3 E3 t 3
D1 ¼ D3 ¼ : ð10Þ
relative densities of 0.039, 0.077 and 0.17, the mean strengths are 12ð1−υ13 υ31 Þ 12ð1−υ31 υ13 Þ
0.52 MPa, 4.55 MPa and 45.16 MPa, respectively.
According to Ref. [10,13], the buckling coefficient K should be equal The elastic shear buckling stress of a plate is given in terms of the
to 7.86. The predictive strengths of the specimens with three relative above rigidities as
densities are 7.67 MPa, 43.2 MPa and 92.7 MPa, respectively. Obviously,
the predictive values are much greater than the measurements. It shows qffiffiffiffiffiffiffiffiffiffiffiffi
that the previous analytical model is not suitable for forecasting the π2
D1 D33 :
4
τb ¼ K 2
ð11Þ
compressive strengths of MCHSS in this paper. According to the failure t ðH=2Þ
Fig. 12. The measured out-of-plane shear stress versus shear strain responses of composite square honeycomb structures for α=0° and α=45°.
G.-C. Yu et al. / Materials and Design 102 (2016) 238–246 245
cos α þ sin α
τbpk ¼ τb ρ : ð12Þ
2
cos α þ sin α
τcpk ¼ τc ρ ð13Þ
2
cos α þ sin α
τspk ¼ τs ρ : ð14Þ
2
The measured shear responses of composite square honeycomb specific strength and specific modulus of MCHSS is very small due to it-
structures for α = 0° and α = 45° are plotted in Fig. 12. Samples with self weak mechanical property. According to the predicted formulas,
three relative densities ρ ¼ 0:039, 0.077 and 0.125 are investigated in HOGF decrease the specific compressive strength and specific compres-
shear. For test orientations with α = 0°, the cell walls in the plane nor- sive modulus of MCHSS. Still, MCHSS possesses both a high specific ther-
mal to x2 of square honeycombs undergo shear strain, while the walls mal conductivity and adequate mechanical properties, which satisfies
in the plane normal to x1 deform by bending and carry a negligible frac- the multifunctional design requirement of sandwich structures and
tion of the load. Thus neglecting the contribution of the cell walls in the shows good potential in the high-end heat dissipation field.
plane normal to x1, a half of square honeycomb core is undergoing loads
in shear. Whereas, in the case of shear loading for α =45°, each cell wall
4. Conclusions
of the square honeycomb core carries loads in shear. The α =0° and α =
45° specimens display both a stiff linear response up to their peak
Multifunctional composite square honeycomb sandwich structures
strength; a strongly post-peak softening response is observed. The mea-
are made from the plain woven carbon fiber composite laminates coat-
sured peak shear strengths for both α = 0° and α = 45° are plotted
ed by HOGF. The analytical results reveal that the out-of-plane thermal
against the relative density ρ in Fig. 13. The model predictions are also
conductivity of MCHSS increases with increasing the HOGF volume con-
plotted on this figure. The theoretical results are in good agreement
tent ρ f , the relative density of composite cores ρcomp , the thickness of
with the experimental data. The shear strengths of both α = 0°and
α = 45° specimens increase with the relative density ρ, with the α = sandwich structures H and the thermal conductivity of facesheet mate-
45° honeycomb specimens stronger than the α = 0° honeycomb rials kupper, together with decreasing the interface thermal resistance
specimens. Ri. Among them, increasing the HOGF volume content and decreasing
the interface thermal resistance are the most efficient methods. The
3.3. Multifunctional characteristic experimental results show that the maximum out-of-plane thermal
conductivity of MCHSS attains to 13.53 W/mK, which is more than 26 [7] J. Xiong, L. Ma, L.Z. Wu, B. Wang, A. Vaziri, Fabrication and crushing behavior of low
density carbon fiber composite pyramidal truss structures, Compos. Struct. 92 (11)
times that of traditional composite honeycomb sandwich structures. (2010) 2695–2702.
Moreover, MCHSS exhibit adequate mechanical properties, although [8] S. Yin, L. Wu, S. Nutt, Stretch–bend-hybrid hierarchical composite pyramidal lattice
the added weight of HOGF decreases the specific compressive proper- cores, Compos. Struct. 98 (2013) 153–159.
[9] T. George, V.S. Deshpande, H. Wadley, Mechanical response of carbon fiber compos-
ties (strength and modulus) of MCHSS due to the weak mechanical ite sandwich panels with pyramidal truss cores, Compos. Part A 47 (2013) 31–40.
property of HOGF. Above all, the multifunctional composite square [10] L. Dong, H. Wadley, Mechanical properties of carbon fiber composite octet-truss lat-
honeycomb sandwich structures appear to be a promising candidate tice structures, Compos. Sci. Technol. 119 (2015) 26–33.
[11] B.P. Russell, V.S. Deshpande, H.N.G. Wadley, Quasistatic deformation and failure
for the high-end heat dissipation applications. modes of composite square honeycombs, J. Mech. Mater. Struct. 3 (7) (2008)
1315–1340.
Acknowledgments [12] F. Cote, B.P. Russell, V.S. Deshpande, N.A. Fleck, The through thickness compressive
sandwich panel with a hierarchical square honeycomb sandwich core, J. Appl.
Mech. 76 (6) (2009) 061004.1–061004.8.
The present work is supported by the Major State Basic Research [13] H.L. Fan, F.H. Meng, W. Yang, Sandwich panels with Kagome lattice cores reinforced
Development Program of China (973 Program) under Grant No. 2011 by carbon fibers, Compos. Struct. 81 (4) (2007) 533–539.
CB610303. [14] M.F. Ashby, Y.J.M. Brechet, Designing hybrid materials, Acta Mater. 51 (19) (2003)
5801–5821.
[15] Y. Hishiyama, M. Nakamura, Y. Nagata, et al., Graphitization behavior of carbon film
References prepared from high modulus polyimide film: synthesis of high-quality graphite film,
Carbon 32 (4) (1994) 645–650.
[1] M.F. Ashby, A.G. Evans, N.A. Fleck, L.J. Gibson, J.W. Hutchinson, H.N.G. Wadley, Metal [16] G.C. Yu, L.Z. Wu, L.J. Feng, Enhancing the thermal conductivity of carbon fiber rein-
foams: a design guide, Butterworth Heinemann, Boston, 2000. forced polymer composite laminates by coating highly oriented graphite films,
[2] A.G. Evans, J.W. Hutchinson, M.F. Ashby, Multifunctionality of cellular metal Mater. Des. 88 (2015) 1063–1070.
systems, Prog. Mater. Sci. 43 (3) (1999) 171–221. [17] K. Daryabeigi, Heat transfer in adhesively bonded honeycomb core panels, AIAA
[3] L.J. Gibson, Mechanical behavior of metallic foams, Annu. Rev. Mater. Sci. 30 (1) 2001, pp. 2001–2825.
(2000) 191–227. [18] R.D. Cowan, Pulse method of measuring thermal diffusivity at high temperatures,
[4] H. Zhang, N. Kuang, F. Sun, H. Fan, X. Wang, Ultra-light CRH wind deflector fabricated J. Appl. Phys. 34 (1963) 926–927.
by woven lattice sandwich composites, Compos. Sci. Technol. 102 (2014) 145–151. [19] W.J. Parker, R.J. Jenkins, C.P. Butler, G.L. Abbott, Flash method of determining
[5] J.S. Yang, J. Xiong, L. Ma, L.N. Feng, S.Y. Wang, L.Z. Wu, Modal response of all- thermal diffusivity, heat capacity, and thermal conductivity, J. Appl. Phys. 32
composite corrugated sandwich cylindrical shells, Compos. Sci. Technol. 115 (1961) 1679–1684.
(2015) 9–20. [20] S. Sihn, S. Ganguli, D.P. Anderson, A.K. Roy, Enhancement of out-of-plane thermal
[6] K. Finnegan, G. Kooistra, H.N.G. Wadley, V.S. Deshpande, The compressive response conductivity of sandwich construction using carbon foam, Compos. Sci. Technol.
of carbon fiber composite pyramidal truss sandwich cores, Int. J. Mater. Res. 98 (12) 72 (2012) 767–773.
(2007) 1264–1272.