Beruflich Dokumente
Kultur Dokumente
Dossier –
TDS and July 22
MSDS for
Petronas
Lubricants
2017
for Gulf
Energy Intl.
Collated by
Hussam Adeni –
This dossier contains the TDS and MDSD of the Lubricants used at the Gulf
Energy Intl. units (Sadara Dev & Ivnstmnts) at Muscat, Nizwa, Nimr, at the
ex-Sadara
time of filing this dossier. Development &
This dossier is fulfillment of the ISO requirement of the Procurement
Department, that necessitates furnishing the product TDS and MSDS for each
Investments.
supply/invoice of Lubricants delivered. This dossier has been copied to This is
Purchase, Stores, Maintenance, & users at NIzwa, Nimr. Thus, the TDS/MSDS
requirement is met in “Full and in advance.” Updates would be required if Dossier Ver 6
new/additional Lubricants are procured. updated
For any additional Lubricant related info or query please contact
M Hussam Adeni, 22/7/2017
Lubricant Specialist,
email: lube.specialist@gmail.com
edited by
IMO and What’sApp Mob: +966542017250 removing all
Sadara contacts
details and logo
Useful Lubricant related information
Source of Lubricants
Viscosity and how is it classified
Typical Viscosity chart and different units
Useful specifications from API - for Engine Oils
Table of Contents
You may be surprised to know that a barrel of crude oil of 42 gallons, after fractional
distillation in a petroleum refinery, yields barely 1% fraction ( or cut) that, is called
Base Oil and which is useful for manufacture of lubricating oils. As the diagram below
shows, bulk of the crude oil after distillation, results in fuels like gasoline, diesel,
aviation fuel, kerosene and heavy residual fuels (used in Captive Power Plants,or in the
maritime industry). Typically fuels, have high calorific value, hence suitable for use as,
fuel.
Viscosity and how it is classified
ISO 3448 Viscosity classification
The ISO viscosity classification is recommended for industrial applications. The reference temperature of 40.C represents
the operating temperature in machinery. Each subsequent Viscosity grade (VG) within the classification has
approximately a 50% higher viscosity, whereas the minimum & maximum values of each grade ranges ±10% from the mid
point. For example, ISO VG 22 refers to a viscosity grade of 22 cSt = 10% at 40 C The viscosity at different temperatures
can be calculated using the viscosity at 40.c and the viscosity index (VI), which represents the temperature dependency of
the lubricant.
Diesel Engines
"C" Status Service Diesel Engines
Introduced in 2006 for high-speed four-stroke engines. Designed to meet 2007 on-highway exhaust
emission standards. CJ-4 oils are compounded for use in all applications with diesel fuels ranging in
sulphur content up to 500ppm (0.05% by weight). However, use of these oils with greater than
15ppm sulfur fuel may impact exhaust after treatment system durability and/or oil drain intervals.
CJ-4 oils are effective at sustaining emission control system durability where particulate filters and
other advanced after treatment systems are used. CJ-4 oils exceed the performance criteria of CF-
CJ-4 Current - 2006 4, C-4, AH-4 and C-4.
Used in conjunction with API C-4, the " CI-4 PLUS" designation identifies oils formulated to provide
a higher level of protection against soot-related viscosity increase and viscosity loss due to shear in
CI-4 diesel engines. Like Energy Conserving, CI-4 PLUS appears in the lower portion of the API Service
Plus Current - 2004 Symbol "Donut."
The CI-4 performance requirements describe oils for use in those high speed, four-stroke
cycle diesel engines designed to meet 2004 exhaust emission standards, to be implemented
October 2002. These oils are compounded for use in all applications with diesel fuels
ranging in sulfur content up to 0.05% by weight. These oils are especially effective at
sustaining engine durability where Exhaust Gas Recirculation (EGR) and other exhaust
emission componentry may be used. Optimum protection is provided for control of
corrosive wear tendencies, low and high temperature stability, soot handling properties,
Severe-Duty piston deposit control, valve train wear, oxidative thickening, foaming and viscosity loss due
Diesel Engine to shear. CI-4 oils are superior in performance to those meeting API CH-4, CG-4 and CF-4
CI-4 Service and can effectively lubricate engines calling for those API Service Categories.
This service oils are suitable for high speed, four-stroke diesel engines designed to meet
1998 exhaust emission standards and are specifically compounded for use with diesel fuels
Severe-Duty ranging in sulfur content up to 0.5% weight. CH-4 oils are superior in performance to those
Diesel Engine meeting API CF-4 and API CG-4 and can effectively lubricate engines calling for those API
CH-4 Service Service Categories.
This category describes oils for use in high speed four-stroke-cycle diesel engines used in both
heavy-duty on-highway (0.05% wt sulfur fuel) and off-highway (less than 0.5% wt sulfur fuel)
applications. CG-4 oils provide effective control over high temperature piston deposits, wear,
corrosion, foaming, oxidation stability, and soot accumulation. These oils are specially effective in
engines designed to meet 1994 exhaust emission standards and may also be used in engines
requiring API Service Categories CD, CE, and CF-4. Oils designed for this service have been in
CG-4 Obsolete existence since 1994.
Service typical of two-stroke cycle diesel engines requiring highly effective control over cylinder and
ring-face scuffing and deposits. Oils designed for this service have been in existence since 1994
and may be used when API Service Category CD-II is recommended. These oils do not necessarily
meet the requirements of API CF or CF-4 unless they pass the test requirements for these
CF-2 Obsolete categories.
Service typical of indirect-injection diesel engines and other diesel engines that use a broad range
of fuel types, including those using fuel with high sulfur content; for example, over 0.5% wt. Effective
control of piston deposits, wear and copper-containing bearing corrosion is essential for these
engines, which may be naturally aspirated, turbocharged or supercharged. Oils designated for this
service have been in existence since 1994 and may be used when API Service Category CD is
CF Obsolete recommended.
Service typical of high speed, four-stroke cycle diesel engines. API CF-4 oils exceed the
requirements for the API CE category, providing improved control of oil consumption and piston
deposits. These oils should be used in place of API CE oils. They are particularly suited for on-
highway, heavy-duty truck applications. When combined with the appropriate S category, they can
also be used in gasoline and diesel powered personal vehicles i.e., passenger cars, light trucks and
CF-4 Obsolete vans when recommended by the vehicle or engine manufacturer.
CE Obsolete Service typical of certain turbocharged or supercharged heavy-duty diesel engines, manufactured
since 1983 and operated under both low speed, high load and high speed, high load conditions.
Oils designed for this service may also be used when API Service Category CD is recommended.
Service typical of two-stroke cycle diesel engines requiring highly effective control of wear and
deposits. Oils designed for this service also meet all performance requirements of API Service
CD-II Obsolete Category CD.
Service typical of certain naturally aspirated, turbocharged or supercharged diesel engines where
highly effective control of wear and deposits is vital, or when using fuels with a wide quality range
(including high-sulfur fuels). Oils designed for this service were introduced in 1955 and provide
CD Obsolete protection from high temperature deposits and bearing corrosion in these diesel engines.
Service typical of certain naturally aspirated, turbocharged or supercharged diesel engines operated
in moderate to severe-duty service, and certain heavy-duty gasoline engines. Oils designed for this
service provide protection from bearing corrosion, rust, corrosion and from high to low temperature
CC Obsolete deposits in gasoline engines. They were introduced in 1961.
Service typical of diesel engines operated in mild to moderate duty, but with lower quality fuels,
which necessitate more protection from wear and deposits; occasionally has included gasoline
engines in mild service. Oils designed for this service were introduced in 1949. They provide
necessary protection from bearing corrosion and from high temperature deposits in naturally
CB Obsolete aspirated diesel engines with higher sulfur fuels.
Service typical of diesel engines operated in mild to moderate duty with high quality fuels;
occasionally has included gasoline engines in mild service. Oils designed for this service provide
protection from bearing corrosion and ring-belt deposits in some naturally aspirated diesel engines
when using fuels of such quality that they impose no unusual requirements for wear and deposits
protection. They were widely used in the 1940s and 1950s but should not be used in any engine
CA Obsolete unless specifically recommended by the equipment manufacturer.
API Engine Oil Service Category Charts
Gasoline Engines
"S" Status Service Gasoline Engines
Introduced in October 2010 for 2011 and older vehicles, designed to provide improved high
temperature deposit protection for pistons, more stringent sludge control, and seal compatibility. API
SN with Resource Conserving matches ILSAC GF-5 by combining API SN performance with
improved fuel economy, turbocharger protection, emission control system compatibility, and
protection of engines operating on ethanol-containing fuels up to E85.
Introduced in
SN October 2010 Further details about API SN...
Category SM oils are designed to provide improved oxidation resistance, improved deposit
Introduced on protection, better wear protection, and better low-temperature performance over the life of the oil.
30 November Some SM oils may also meet the latest ILSAC specification and/or qualify as Energy Conserving.
SM 2004 They may be used where API Service Category SJ and SL earlier categories are recommended.
Category SL was adopted to describe engine oils for use in 2001. It is for use in service typical of
gasoline engines in present and earlier passenger cars, sports utility vehicles, vans and light trucks
operating under vehicle manufacturers recommended maintenance procedures. Oils meeting API SL
requirements have been tested according to the American Chemistry Council (ACC) Product
Approval Code of Practice and may utilize the API Base Oil Interchange and Viscosity Grade Engine
2001 Gasoline Testing Guidelines. They may be used where API Service Category SJ and earlier categories are
SL Engine Service recommended.
Category SJ was adopted in 1996 to describe engine oil first mandated in 1997. It is for use in
service typical of gasoline engines in present and earlier passenger cars, vans, and light trucks
operating under manufacturers recommended maintenance procedures. Oils meeting API SH
requirements have been tested according to the American Chemistry Council (ACC) Product
Approval Code of Practice and may utilize the API Base Oil Interchange and Viscosity Grade Engine
1997 Gasoline Testing Guidelines. They may be used where API Service Category SH and earlier categories are
SJ Engine Service recommended.
SH Obsolete For model year 1996 and older engines.
SG Obsolete For model year 1993 and older engines.
SF Obsolete For model year 1988 and older engines.
SE Obsolete For model year 1979 and older engines.
SD Obsolete For model year 1971 and older engines.
SC Obsolete For model year 1967 and older engines.
SB Obsolete For older engines. Use only when specifically recommended by the manufacturer.
For older engines; no performance requirement. Use only when specifically recommended by the
SA Obsolete manufacturer.
PETRONAS ATF-D3
Premium Quality Automatic Transmission Fluid (ATF)
Petronas ATF-D3 is a new generation premium quality transmission fluid primarily
intended for use in power transmission and hydraulic system of passenger car and truck
automatic transmissions, powershift transmissions in off-highway construction
equipment, power steering and other hydraulic systems requiring Dexron-III or Allison C-4
fluids.
It is formulated from highly refined very high viscosity index mineral oils and advanced
additives system to provide excellent antiwear, corrosion resistance, friction retention,
and thermal and oxidation stability at high temperatures as well as excellent low
temperature characteristics (below -40oC), thereby providing excellent protection under
the widest extremes of operating conditions. Its friction-modifying properties ensure
consistent, smooth shifts in all driving conditions. Superior protection against wear and
improved transmission cleanliness contribute to extended transmission life.
Customer Advice
For further assistance on product MSDS, recommendation or technical queries, please liaise with the regional technical
services engineer or contact HQ technical engineers.
ATF-D3/ver3/2004.06.03
ATF-D3 Page 1 of 5
ATF-D3
PETRONAS SAP No: 50539301
3. Hazards Identification
Emergency Response Data: Pale amber liquid. Combustible, flash point 210 °C
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
.
5. Fire-Fighting Measures
Procedures:
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Acute Toxicology
Oral Toxicity (Rats):
Practically non-toxic (LD50) greater than 2000 mg/kg. - calculated from testing of
alternative products.
Dermal Toxicity (Rabbits):
Practically non-toxic (LD50) greater than 2000 mg/kg. - calculated from testing of
alternative products.
Inhalation Toxicity (Rats):
Negligible hazard. At ambient temperature and with reasonable handling,
vapours will not be inhaled into the lungs.
Eye Irritation (Rabbits):
Practically non-irritating. (Draize score : 0 or greater but 6 or less ) - calculated
from testing of alternative products.
Skin Irritation (Rabbits):
Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than
3) - calculated from testing of alternative products.
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in
this product, showed no evidence of carcinogenic activities. Dermal applications,
at doses significantly higher than those expected during normal industrial
exposure were applied to rats. No adverse effects were detected in the internal
organs or the body fluids.
Hydraulic oils, with formulations similar to this product, have not caused skin
sensitization in guinea pigs. Dermal exposure of pregnant rats had no adverse
effects on the mother and offspring.
It is formulated from specially selected premium quality base oils for their oxidation
stability and water separating characteristics, and further fortified with selected sulphur-
phosphorous additives system to provide outstanding extreme pressure and wear
protection, enhanced oxidation stability and resistance to rusting and foaming. It is
available in ISO 32 through ISO 680* viscosity grades.
Specifications
AIST 224
AGMA 9005-E02
DIN 51517 part 3 CLP
David Brown S1.53.101
Product Typicals
* available upon special request only and the packaging sizes are 200 Lt drum & 20 Lt pail
Customer Advice
For further assistance on product MSDS, recommendation or technical queries, please liaise with the regional technical
services engineer or contact HQ technical engineers.
GEAR MEP 100 Page 1 of 5
__ _ _ _ _ _ _
1. Product and Company Identification
3. Hazards Identification
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray
may be used to cool fire-exposed containers and flush spills away from
exposure. Prevent any runoffs from polluting drinking water supply and the
environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be
used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
o
Flash Point C: 222 (ASTM D-92)
NFPA Hazard ID: Health: 1, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide. Elemental and
metallic oxides.
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water
supply and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Eye Protection: Chemical type goggles or face shields are optional depending
on working conditions.
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in
this product, showed no evidence of carcinogenic activities. Do not ingest this
product.
Not regulated.
It is designed and manufactured from premium quality base oils and carefully selected
additives system to provide high level of protection for hypoid gears and other heavily
loaded gears, in general, where API GL-4 performance is required.
Applications
Recommended for the lubrication of manual Superior thermal and oxidation stability – the
transmissions and transaxles (particularly where the highly refined base oil and special inhibitor system
manufacturer specifically advises against the use of provide superior oxidation stability to high
API GL-5 lubricants), hypoid, spur, bevel, helical, temperature oil degradation and oil thickening to
spiral-bevel and worm gears in differentials, transfer ensure deposit do not form around seal and helps
cases and steering mechanisms. It is also suitable for maintain clean bearing surfaces to minimize wear.
use in gearboxes, final-drives and power take-offs on
farm and earth-moving machinery. Non-corrosive to steel – the special mild-extreme
pressure additives and corrosion inhibitor system is
non-corrosive towards sensitive copper alloy
components and protects ferrous metals against
rusting in the presence of moisture.
Customer Benefits
High load carrying ability – the special high Specifications
performance EP additives system provide high
level of protection against gear tooth wear and API GL-4
scoring. MIL-L-2105
Product Typicals
Customer Advice
For further assistance on product MSDS, recommendation or technical queries, please liaise with the regional technical
services engineer or contact HQ technical engineers.
GL-4 90 Page 1 of 5
GL-4 90
PETRONAS SAP No: 50539335
3. Hazards Identification
Effects of Overexposure: No significant effect.
Emergency Response Data: Brown, viscous liquid. Combustible, flash point 210°C
5. Fire-Fighting Measures
Extinguishing Media: Water fog, alcohol stable foam, dry chemical powder or CO2
Fire Fighting Procedures: Water may cause frothing. However, water spray may be used
to cool fire-exposed containers and flush spills away from exposure. Prevent any runoffs
from polluting drinking water supply and the environment.
Special Protective Equipment: Full bunker gear (Helmet with face shield, bunker coats,
gloves, rubber boots) and positive pressure NIOSH approved Self-Contained Breathing
Apparatus must be used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
Flash Point °C: 210 (ASTM D-92)
NFPA Hazard ID: Health: 0, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide. Elemental and metallic
oxides.
Land Spills: Contain and adsorb on sawdust or sand/earth. Shovel up and dispose of at a
waste disposal facility conforming to local disposal regulations.
Water Spills: Notify port or relevant authority to warn other shipping. Confine the spill with
booms and remove from the surface by skimming or with suitable absorbents. Dispose the
residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water supply
and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong oxidizing
agents or combustible material.
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in this
product, showed no evidence of carcinogenic activities. Dermal applications, at doses
significantly higher than those expected during normal industrial exposure were applied to
rats. No adverse effects were detected in the internal organs or the body fluids.
It is designed and manufactured from selected premium quality base oils and specially
selected additives system to provide excellent protection for heavy-duty manual
transmission of heavily loaded equipment and passenger vehicles.
Applications
Recommended for the lubrication of hypoid, spur, • Superior thermal and oxidation stability – the
bevel, helical, spiral-bevel and worm gears in highly refined base oil and special inhibitor system
differentials, manual transmissions, final drives, provide excellent resistance toward high
transfer cases and steering mechanisms where this temperature oil degradation and oil thickening to
type of fluid is recommended. ensure deposit do not form around seal and helps
maintain clean bearing surfaces to minimize wear.
Product Typicals
Customer Advice
For further assistance on product MSDS, recommendation or technical queries, please liaise with the regional technical
services engineer or contact HQ technical engineers.
GL-5 80W-90 Page 1 of 5
GL-5 80W-90
PETRONAS SAP No: 50539337
3. Hazards Identification
Effects of Overexposure: No significant effect.
Emergency Response Data: Pale amber liquid. Combustible, flash point 210 °C
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray may be used
to cool fire-exposed containers and flush spills away from exposure. Prevent any runoffs
from polluting drinking water supply and the environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be used for
fires in enclosed areas..
Unusual Fire and Explosion Hazards: None.
Flash Point °C: 210 (ASTM D-92)
NFPA Hazard ID: Health: 0, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide. Elemental and metallic oxides.
Land Spills: Contain and adsorb on sawdust or sand/earth. Shovel up and dispose of at a
waste disposal facility conforming to local disposal regulations.
Water Spills: Notify port or relevant authority to warn other shipping. Confine the spill with
booms and remove from the surface by skimming or with suitable absorbents. Dispose the
residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water supply
and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong oxidizing
agents or combustible material.
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in this
product, showed no evidence of carcinogenic activities. Dermal applications, at doses
significantly higher than those expected during normal industrial exposure were applied to
rats. No adverse effects were detected in the internal organs or the body fluids.
Gear oils, with formulations similar to this product, have not caused skin sensitization in
guinea pigs. Dermal exposure of pregnant rats had no adverse effects on the mother and
offspring.
GRIS EPI 2
__ _ _ _ _ _ _
1. Product and Company Identification
3. Hazards Identification
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray
may be used to cool fire-exposed containers and flush spills away from
exposure. Prevent any runoffs from polluting drinking water supply and the
environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be
used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
o
Flash Point C: 205 (ASTM D-92)
NFPA Hazard ID: Health: 1, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide, Carbon Dioxide,
Lithium
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water
supply and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Eye Protection: Chemical type goggles or face shields are optional depending
on working conditions.
NGLI Grade: 2
Appearance: Yellowish brown paste
Odour: Slight Odor
o
Melting Point (Dropping Point) C: 207
Solubility in water: Negligible
o
Work penetration @ 25 C: 282
o
Flash point, C: 205
o
Viscosity @ 100 C, cSt: 10.5
Not regulated.
assumed by the user and we expressly disclaim all warranties of every kind and
nature, including warranties of merchantability and fitness for a particular
purpose in respect to the use or suitability of the product. Nothing is intended as
a recommendation for uses which infringe valid patents or as extending license
under valid patents. Appropriate warnings and safe-handling procedures should
be provided to handlers and users.
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
RECOMMENDED USE:
Identified uses : Lubricating grease
2. HAZARD IDENTIFICATION
Precautionary statement(s)
Storage None
Page 1 of 6
SAFETY DATA SHEET
PRODUCT NAME:
GRIS EPI 2
Revision Date 20/01/2015
4.2 Most important symptoms and effects, both acute and delayed: Headache,
dizziness, nausea, respiratory irritation. Mildly irritating to skin.
4.3 Indication of any immediate medical attention and special treatment needed: Treat
symptomatically.
Page 2 of 6
SAFETY DATA SHEET
PRODUCT NAME:
GRIS EPI 2
Revision Date 20/01/2015
3
ACGIH TLV-TWA 5 mg/m
8.3 PPE
Eye/face protection: Goggle with face shields are recommended.
Skin and body protection: Wear gloves made from nitrile rubber. Chemical / oil resistant
clothing
Respiratory protection: Wear organic vapor respirator
Page 3 of 6
SAFETY DATA SHEET
PRODUCT NAME:
GRIS EPI 2
Revision Date 20/01/2015
11.3 DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE; IMMEDIATE EFFECTS
May cause respiratory irritation, headache and nausea. Mildly irritating to skin and eyes.
Chronic effects:
Prolonged and repeated contact with skin can cause deflating and drying of the skin
resulting in skin irritation and dermatitis.
12.5 OTHER ADVERSE EFFECTS Long term effect to the aquatic environment.
13 DISPOSAL INFORMATION
13.1 WASTE TREATMENT METHODS
Disposal as an industrial waste in a manner acceptable to good waste management practice
and in compliance with applicable local, state and federal regulations.
14 TRANSPORT INFORMATION
14.1 UN number No data available
Page 5 of 6
SAFETY DATA SHEET
PRODUCT NAME:
GRIS EPI 2
Revision Date 20/01/2015
15 REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE
(DSL/
(TSCA) (EINECS) (AICS) (ENCS) (ELCI) (IECSC) (PICCS) (NZIOC)
NDSL)
Distillates Yes Yes Yes Yes Yes Yes Yes Yes Yes
solvent-dewaxed
(petroleum),
heavy paraffinic
16 OTHER INFORMATION
Page 6 of 6
PETRONAS GRIS MPI
Multipurpose Industrial Grease
Petronas Gris MPI is a high quality medium-fibre multipurpose, NLGI 2 and NLGI 3 grades,
lithium hydroxystearate grease specially formulated to provide added protection against
rusting and water washout in general purpose industrial applications at moderate
temperature and load.
Petronas Gris MPI is manufactured from high viscosity index premium quality base oils,
lithium soap thickener and compounded with rust, corrosion and oxidation inhibitors to
provide high mechanical and chemical stability, to resist rapid deterioration due to
intense mechanical and thermal stresses.
The recommended operating temperature range • High mechanical and chemical stability
o o
of Petronas Gris MPI is –20 C to 130 C. In
applications where heavy or shock loading is a • High resistance to oil separation in storage and in
factor, extreme pressure greases are preferred. use.
Product Typicals
Customer Advice
For further assistance on product MSDS, recommendation or technical queries, please liaise with the regional technical
services engineer or contact HQ technical engineers.
GRIS MPI 2 Page 1 of 4
GRIS MPI 2
__ _ _ _ _ _ _
1. Product and Company Identification
3. Hazards Identification
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray
may be used to cool fire-exposed containers and flush spills away from
exposure. Prevent any runoffs from polluting drinking water supply and the
environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be
used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
o
Flash Point C: 220 (ASTM D-92)
NFPA Hazard ID: Health: 1, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide, Carbon Dioxide,
Lithium
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water
supply and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Eye Protection: Chemical type goggles or face shields are optional depending
on working conditions.
NGLI Grade: 2
Appearance: Yellowish Brown paste
Odor: Slight Odor
o
Melting Point (Dropping Point) C: 210
Solubility in water: Negligible
o
Work penetration @ 25 C: 280
o
Flash point, C: 220
Skin Irritation (Rabbits): Prolonged and repeated skin contact may cause
irritation
Carcinogenic Effect: Not listed IARC, NTP, ACGIH
They are formulated from premium quality base oils and selected additives system
to provide excellent protection against wear and corrosion, enhanced thermal and
oxidation stability, and resistance to rusting and foaming. They are available in ISO
10 through ISO 150 viscosity grades.
Product Typicals
ISO Viscosity Grade
Characteristics
10 22 32 37* 46 68 100 150
Density @ 15 °C, kg/l 0.865 0.860 0.891 0.892 0.893 0.897 0.898 0.899
Pour Point, °C -30 -30 -9 -9 -9 -9 -9 -9
Flash Point, °C 145 204 222 228 228 246 252 270
Kinematic V iscosity, cSt
@ 40 °C 10.7 22 32 37 46 68 100 150
@ 100 °C 2.8 4.4 5.3 5.8 6.6 8.5 11.1 14.6
Viscosity Index 98 98 95 95 95 95 95 90
* not and ISO Viscosity Grade. ISO 10 & 37 only available on special request
Customer Advice
For further assistance on product MSDS, recommendation or technical queries, please liaise with the regional technical
services engineer or contact HQ technical engineers.
Hid.EP/rev2/20070215
Material Safety Data Sheet
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
EP HYDRAULIC OIL 32
MOTOR OIL, INC.
1490 Jarvis Avenue
Elk Grove Village, IL 60007
Phone (847) 956-7550 Fax (847) 956-0399
Eye Flush eye(s) with water for at least 15 minutes or until irritation subsides. Get medical attention if eye irritation
develops or persists
Skin Wash with soap and water. Immediately remove contaminated clothing. Get medical attention if irritation
develops. Launder contaminated clothing before re-use. If product is injected into or under the skin, or into
any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated
immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure
injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce
the ultimate extent of injury.
Inhalation Vapor pressure is very low. Vapor inhalation under ambient conditions is normally not a problem. If adverse
effects are observed, remove exposed person to fresh air. If breathing is labored, administer oxygen. If
breathing has stopped, apply artificial respiration. If overexposed to oil mist, remove from further exposure
until excessive oil mist subsides.
SECTION 5 FIRE FIGHTING MEASURES
Extinguishing Media Carbon Dioxide, dry chemical, water spray (fog) and foam. Note: water, water
fog and foam may cause frothing and spattering.
Special Firefighting Procedures Wear self-contained breathing apparatus. Avoid breathing fumes and vapors.
Use water spray (fog) to cool containers exposed to high heat or open flames.
Unusual Fire and Empty containers contain residue and/or vapors. DO NOT WELD, CUT,
Explosion Hazards PRESSURIZE, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, SPARKS, FLAME, STATIC ELECTRICITY OR
OTHER SUCH SOURCES OF IGNITION. Keep empty containers closed and
dispose of in an environmentally safe manner and in accordance with all
government regulations.
Autoignition Temperature Not Determined
Spill Procedures Evacuate all non-essential personal. Personal Protective Equipment must be worn
(see Personal Protection Section for PPE recommendations). Remove sources of
ignition. Ventilate spill area. Prevent entry into sewers and waterways. Pick up free
liquid for recycle and/or disposal. Residual liquid can be absorbed on inert
material. Assure conformity with applicable Federal, state and local regulations.
Handling Procedures Keep away from potential sources of ignition. Avoid breathing vapors if present.
Keep containers closed when not in use. Wash thoroughly after handling. Make
sure that proper warning labels are affixed in accordance with 29 CFR 1910.1200.
Use good personal hygiene around product. Do not smoke or eat around product.
Storage Procedures Do not store near potential sources of ignition. Store in a well ventilated area.
Store in a dry area. Do not store around food or eating areas.
Ventilation Procedures Use material in well ventilated areas only. Additional ventilation or exhaust may
be required to maintain air concentrations below recommended exposure limits.
Glove Protection Use chemical resistant gloves, if needed, to avoid prolonged or repeated skin
contact.
Eye Protection Safety glasses recommended. Use splash goggles or face shield when eye
contact may occur.
Respiratory Protection Under normal conditions, respirator is not usually required. Use NIOSH/MSHA
approved disposable dust/mist mask if the recommended exposure limit is
exceeded.
Clothing Recommendation Use a chemical resistant apron or other impervious clothing, if needed, to avoid
contaminating regular clothing, which could result in prolonged or repeated skin
contact.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Stability Material is normally stable at room temperature and pressure. See the Handling
and Storage Section for further details.
Thermal Decomposition Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other
decomposition products, in the case of incomplete combustion.
Skin Irritation May cause skin irritation. Prolonged or repeated contact may cause dermatitis.
Symptoms may include redness, edema, drying, defatting and cracking of skin.
Dermal Toxicity Not Determined.
Respiratory Irritation If material is misted or if vapors are generated from heating, exposure may cause
irritation of mucous membranes and the upper respiratory tract.
Dermal Sensitivity No data available to indicate product or components may be skin sensitizer.
Inhalation Sensitivity No data given to indicate product or components may be respiratory sensitizer.
Carcinogenciity The components of this product has not been found to be a carcinogen under either
NTP, IARC Monographs or current OSHA regulations.
Other Under conditions which may generate mists, observe the OSHA PEL 5 mg/m³.
SECTION 12 ECOLOGICAL INFORMATION
No Data Given.
WASTE DISPOSAL This product is not considered a hazardous waste under RCRA regulations. After use, it is the
responsibility of the user to determine the products status for disposal. This product can be
incinerated, if practical, or recycled.
U. S. TSCA Inventory All components of this product are listed on the TSCA Inventory.
SARA 302 Threshold No RQ for product or any constituent greater than 1.0% or 0.1% (carcinogen).
Planning Quantity
SARA 304 Reportable Qty No RQ for product or any constituent greater than 1.0% or 0.1% (carcinogen).
SARA 311 Categories EPA Hazard Classification Code
No No No No No
SARA 313 Supplier This product does not contain greater than 1.0% (greater than 0.1% for carcinogenic
Notification substances) of any chemical substances listed under SARA Section 313.
CERCLA Hazardous No chemicals in this product are subject to the reporting requirements of CERCLA.
Substances
Although the information and recommendations set forth herein are presented in good faith and believed to be correct
as of the date hereof, MOTOR OIL, INC. makes no representations as to the completeness or accuracy thereof.
MOTOR OIL, INC. makes no warranty whatsoever, expressed or implied, of MERCHANTABILITY OR FITNESS FOR
THE PARTICULAR PURPOSE since the conditions of use are beyond our control. MOTOR OIL, INC. assumes no
responsibility for injury to recipient or to third persons for any damage to any property and recipient.
HIDRAULIK EP 46 Page 1 of 5
HIDRAULIK EP 46
3. Hazards Identification
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray
may be used to cool fire-exposed containers and flush spills away from
exposure. Prevent any runoffs from polluting drinking water supply and the
environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be
used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
o
Flash Point C: 228 (ASTM D-92)
NFPA Hazard ID: Health: 1, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water
supply and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Eye Protection: Chemical type goggles or face shields are optional depending
on working conditions.
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in
this product, showed no evidence of carcinogenic activities. Do not ingest this
product.
Not regulated.
HIDRAULIK EP 68
3. Hazards Identification
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray
may be used to cool fire-exposed containers and flush spills away from
exposure. Prevent any runoffs from polluting drinking water supply and the
environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be
used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
o
Flash Point C: 246 (ASTM D-92)
NFPA Hazard ID: Health: 0, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide. Elemental and
metallic oxides
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water
supply and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Eye Protection: Chemical type goggles or face shields are optional depending
on working conditions.
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in
this product, showed no evidence of carcinogenic activities. Dermal applications,
at doses significantly higher than those expected during normal industrial
exposure were applied to rats. No adverse effects were detected in the internal
organs or the body fluids
Not regulated.
Applications
PETRONAS MECAFLUID SM 95/P is an emulsifying fluid that is used in the machining of ferrous and non-ferrous
metals. It contains effective biocides to combat bacterial growth, rancidity and odors in machine sumps. MECAFLUID
SM 95/P exhibits excellent cooling ability, balanced lubricity and extreme pressure characteristics needed for superior
machining operations.
Typical Properties
For further assistance on product MSDS, recommendation or technical queries, please liaise with the regional technical services engineer or
contact HQ technical engineers.
2016/06
www.petronas.com
Petronas Mecafluid SM 95/P
2. HAZARDS IDENTIFICATION
Emergency response data : Brown Liquid. DOT ERG No. - Not applicable.
GHS Classification:
Health
Acute inhalation toxicity Hazard category 4. May be harmful if inhaled. Warning
Acute oral toxicity Hazard category 5. May be harmful if swallowed. Warning
Skin irritation Hazard category 3. May cause mild skin irritation. Warning
Eye irritation Hazard category 2B. May cause mild eye irritation. Warning
Environmental
Aquatic toxicity : Hazard category 2. May have harmful effects on the aquatic Warning
environment.
Physical
Flammability : Not classified.
GHS Labels/Pictograms:
Hazard Statements
Precautionary Statements
Response
IN CASE OF FIRE: Use carbon dioxide, foam or dry chemical for extinction. IF IN EYES: Rinse cautiously with
water for several minutes. IF SWALLOWED: Immediately call a POISON CENTRE or doctor. IF INHALED:
Remove to fresh air and keep at rest in a position comfortable for breath.
Disposal
Do not discharge into lakes, streams, ponds and ground water supply.
3. COMPOSITION/INFORMATION ON INGREDIENTS
1
Petronas Mecafluid SM 95/P
Skin contact : Remove contaminated clothing. Dry wipe exposed skin and cleanse with
hand cleaner, soap and water. Launder contaminated clothing before
reuse. (See Section 16 - Injection Injury)
Eye contact : Flush thoroughly with water. If irritation occurs call a doctor.
5. FIRE-FIGHTING MEASURES
Extinguishing media : Carbon dioxide, foam, dry chemical and water fog.
Special fire fighting : Water or foam may cause frothing. Use water to keep fire exposed
procedure containers cool. Water spray may be used to flush spills away from
exposure. Prevent runoff from fire control or dilution from entering
streams, municipal sewers, or drinking water supply.
Special protective : For fires in enclosed areas, fire fighters must use Self-Contained
equipment for firefighters Breathing Apparatus.
Products of decomposition : Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes and other
decomposition products, in the case of incomplete combustion.
Methods for cleaning up : LAND SPILL: Shut off source taking normal safety precautions. Take
measures to minimize the effects on ground water. Recover by pumping
using explosion-proof equipment or contain spilled liquid with sand or
other suitable absorbent and remove mechanically into containers. If
necessary, dispose of absorbed residues as directed in Section 13.
WATER SPILL: Notify port and relevant authorities. Confine with booms
if skimming equipment is available to recover the spill for later recycling
or disposal.
Warn other ships in the vicinity. If allowed by regulatory authorities the
use of suitable dispersants should be considered where recommended in
local oil spill procedures.
2
Petronas Mecafluid SM 95/P
Environmental precautions : Prevent spill from entering municipal sewers, water sources or low lying
areas. Advise the relevant authorities if contaminations have occurred.
Safe handling advice : No special precautions are necessary beyond normal good hygiene
practices.
Storage information : Keep containers closed when not in use. Do not store in open or
unlabelled containers. Do not store near heat sources, sparks, flames,
strong oxidizing agents and combustible materials.
Storage and handling : Prevent small spills and leakages to avoid slip hazard.
procedures
LTEL: Long Term Exposure Limits - Time Weight Average (TWA) over 8 hours.
STEL: Short Term Exposure Limits - Time Weight Average (TWA) over 15 Minutes
Engineering controls : If mists are generated, use ventilation, local exhaust or enclosures to
control below exposure limits.
Respiratory protection : Approved respiratory equipment must be used when mist concentrations
exceed the recommended exposure limits.
Eye protection : If splash with liquid is possible, chemical type goggles should be worn.
Appearance : Liquid.
Colour : Brown
Odour : Mild
Solubility : Emulsifiable
Flash Point : 150 °C
Upper Explosion Limit (UEL) : 7.0 %(V)
Lower Explosion Limit (LEL) : 0.9 %(V)
Vapour pressure : < 0.1 hPa
Density : 0.895 g/cm3 @ 15 °C
Pour point : -6 °C
Viscosity, kinematic : 29 mm2/s @ 40 °C (ASTM D-4052)
Stability : Stable.
Conditions to avoid : Extreme heat and high energy sources of ignition, such as sparks and
3
Petronas Mecafluid SM 95/P
static electricity.
Hazardous decomposition : Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes and other
products decomposition products, in the case of incomplete combustion.
Acute oral toxicity : (Rats): Practically non-toxic (LD50: Greater than 2000 mg/kg). Based
on testing of similar products and/or components. Warning Hazard
category 5. May be harmful if swallowed.
Acute dermal toxicity : (Rabbits): Practically non-toxic (LD50: greater than 2000 mg/kg).
Based on testing of similar products and/or the components. Warning
Hazard category 5. May be harmful in contact with skin.
Acute inhalation toxicity : (Rats): Harmful (LC50: greater than 10 but less than 20mg/l) 4 hours.
Based on testing of similar products and/or the components. Warning
Hazard category 4. May be harmful if inhaled.
Skin irritation : (Rabbits): Mild irritant. (Primary Irritation Index: greater than 0.5 but
less than 3). Based on testing of similar products and/or the
components. Warning Hazard category 3. Causes mild skin irritation.
Eye irritation : (Rabbits): Mild irritant. (Draize score: greater than 6 but 15 or less).
Based on testing of similar products and/or the components. Warning
Hazard category 2B. May cause mild eye irritation.
Respiratory and skin : Not expected to be sensitizing based on tests of this product,
sensitization components, or similar products.
Germ cell mutagenicity : This product tested negative in a series of mutagenic tests.
Carcinogenicity : Chronic mouse skin painting studies of severely solvent refined mineral
base oils showed no evidence of carcinogenic effects. Synthetic base oils
have been tested in the Ames assay and other tests of mutagenicity with
negative results. These base oils are not expected to be carcinogenic
with chronic dermal exposures.
Reproductive toxicity : No teratogenic effects would be expected from dermal exposure, based
(Teratogenicity) on laboratory developmental toxicity studies of major components in this
formulation and/or materials of similar composition.
Specific target organ toxicity : Although an acute inhalation study was not performed with this product,
(STOT) - single exposure a variety of mineral and synthetic oils, such as those in this product,
have been tested. These samples had virtually no effect other than a
nonspecific inflammatory response in the lung to the aerosolized mineral
oil. The presence of additives in other tested formulations (in
approximately the same amounts as in the present formulation) did not
alter the observed effects.
Specific target organ toxicity : No significant adverse effects were found in studies using repeated
(STOT) - repeated exposure dermal applications of similar formulations to the skin of laboratory
animals for 13 weeks at doses significantly higher than those expected
during normal industrial exposure. The animals were evaluated
extensively for effects of exposure (haematology, serum chemistry,
urinalysis, organ weights, microscopic examination of tissues etc.).
Repeated and/or prolonged exposure may cause irritation to the skin,
eyes or respiratory tract.
Aspiration hazard : Overexposure to oil mist may result in oil droplet deposition and/or
granuloma formation.
4
Petronas Mecafluid SM 95/P
Ecotoxicity effects
Toxicity to fish : (Salmon) LC/EC50: 8.1 mg/l at 96 hours. Warning Hazard category 2.
Remarks : In the absence of specific environmental data for this product, this
assessment is based on information for representative substances.
Waste disposal : Product is suitable for burning in an enclosed, controlled burner for fuel
value or disposal by supervised incineration. Such burning may be
limited pursuant to the Resource Conservation and Recovery Act. In
addition, the product is suitable for processing by an approved recycling
facility or can be disposed of at any government approved waste disposal
facility. Use of these methods is subject to user compliance with
applicable laws and regulations and considerations of product
characteristics at time of disposal.
Contaminated packaging : Empty containers retain residue (liquid and/or vapour) and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or
clean container since residue is difficult to remove. Empty drums should
be completely drained, properly bunged and promptly returned to a
drum reconditioner. All containers should be disposed of in an
environmentally safe manner and in accordance with governmental
regulations.
Other regulations : The unused product, in our opinion, is not specifically listed by the EPA
as a hazardous waste (40 CFR, Part 261D), nor is it formulated to
contain materials which are listed hazardous wastes. It does not exhibit
the hazardous characteristics of ignitability, corrosivity, or reactivity and
is not formulated with contaminants as determined by the Toxicity
Characteristic Leaching Procedure (TCLP). However, used product may
be regulated.
Note : This product is not regulated by the following: U.S. DOT (CFR), ADR,
IATA and IMDG.
5
Petronas Mecafluid SM 95/P
US OSHA Hazard : When used for its intended purposes, this product is not classified as
Communication Standard hazardous in accordance with OSHA 29 CFR 1910.1200.
Governmental Inventory : All components comply with TSCA, EINECS/ELINCS, AICS, METI, DSL,
Status KECI, ENCS, PICCS and IECSC.
SARA
INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body,
regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a
doctor as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal
or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of
injury.
Note: No significant changes have been made to this Safety Data Sheet since the previous date.
Disclaimer
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and
suitability of the product for particular uses are beyond our control; all risks of use of the product are
therefore assumed by the user and we expressly disclaim all warranties of every kind and nature, including
warranties of merchantability and fitness for a particular purpose in respect to the use or suitability of the
product. Nothing is intended as a recommendation for uses which infringe valid patents or as extending
license under valid patents. Appropriate warnings and safe handling procedures should be provided to
handlers and users.
6
Technical Data Sheet
Revised: 2016/05/30 (version 1.0)
PETRONAS COOLANT
33%
APPLICATIONS FEATURES & BENEFITS
Premium performance pre mixed mono ethylene glycol based fluid with anti-
rust, anti-corrosion additive components developed to meet the requirements Excellent cooling system
of modern gasoline and light duty diesel engines. It provides corrosion protection
protection for all engine and cooling system metals. It minimizes the engine Protect against rust and
damage by raising the boiling point of diluted coolant. corrosion
Provides excellent heat
Note: Always consult your owner’s manual to check recommended viscosity grade and specifications for your
particular vehicle.
transfer characteristics
Compatible with rubber
hoses used in cooling
systems
Good solubility and
TYPICAL PHYSICAL DATA** stability in both soft and
hard water
Typical Outstanding anti-freeze
Parameters Method Unit
Value property
Density at 15°C ASTM D4052 g/cm3 1.04
Equilibrium Boiling
ASTM D1120 °C 110
Point (undiluted)
Freezing point 50%
ASTM D3321 °C -30
in water
Reserve alkalinity ASTM D1121 Ml 8.0
pH ASTM D 664 8.0
** These characteristics are typical of current production. Whilst future production will conform to PLI’s
specification, variations in these characteristics may occur.
www.pli-petronas..com
Health, Safety and Environment
This product is unlikely to present any significant health and safety hazards when
used in the recommended application. Avoid contact with skin. Wash immediately
with soap and water after skin contact. Do not discharge into drains, soil or water.
For further detail regarding storage, safe handling, and disposal of product, please
refers to product SDS or contact us at: www.pli-petronas.com
Important Note
The word PETRONAS, the PETRONAS logo and such other related trademarks
and/or marks used herein are trademarks or registered trademarks of PETRONAS
Lubricants International Sdn. Bhd. (“PLISB”), or its subsidiaries or related Holding
Corporation under license unless indicated otherwise. The PLI Documents and the
information contains herein is believed to be accurate as of the date of printing.
PLISB makes no express or implied representation or warranties as to its accuracy
or completeness or information in or any transaction performed. The PLI Documents
information provided is based on standard tests under laboratory conditions and is
given only as a guide. Users are advised to ensure that they refer to the latest version
of these PLI Documents. It is the responsibility of the users to evaluate and use
products safely, to assess suitability for the intended application and to comply with
all applicable laws and regulations imposed by the respective local authorities.
Safety Data Sheets are available for all our products and should be only be consulted
for appropriate information regarding storage, safe handling and disposal of the
product. No responsibility shall be taken by either PLISB or its subsidiaries and
related holding corporation for any loss or injury or any direct, indirect, special,
exemplary, consequential damages or any damages whatsoever, whether in action
of contract, negligence or other tortuous action, in connection or resulting from
abnormal use of the materials and/or information, from any failure to adhere to
recommendations, or from hazards inherent in the nature of the materials and/or
information. All products, services and information supplied are under our standard
conditions of sale. Please consult with any of our local representative in the event
you require any further information.
www.pli-PETRONAS.com
PETRONAS Coolant 33
2. HAZARDS IDENTIFICATION
GHS Classification:
Health
Acute oral toxicity Hazard category 4. Harmful if swallowed. Warning
STOT - single exposure Hazard category 2. May cause damage to organs. Warning
Environmental
Aquatic toxicity : Not classified.
Physical
Flammability : Not classified.
GHS Labels/Pictograms:
Hazard Statements
Precautionary Statements
General
Keep locked up and out of reach of children.
Prevention
Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when
using this product.
Response
IN CASE OF FIRE: Use carbon dioxide, foam or dry chemical for extinction. IF SWALLOWED: Immediately call
a POISON CENTRE or doctor. IF INHALED: Call a POISON CENTRE or doctor immediately. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: get medical attention.
Storage
Store in a well-ventilated place and keep the container cool and tightly closed.
Disposal
Do not discharge into lakes, streams, ponds and ground water supply.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Skin contact : Remove contaminated clothing. Dry wipe exposed skin and cleanse with
hand cleaner, soap and water. Launder contaminated clothing before
reuse. (See Section 16 - Injection Injury)
Eye contact : Flush thoroughly with water for at least 15 minutes. Get medical
assistance.
5. FIRE-FIGHTING MEASURES
Extinguishing media : Carbon dioxide, foam, dry chemical and water fog.
Special fire fighting : Water or foam may cause frothing. Use water to keep fire exposed
procedure containers cool. Water spray may be used to flush spills away from
exposure. Prevent runoff from fire control or dilution from entering
streams, municipal sewers, or drinking water supply.
Methods for cleaning up : Absorb on fire-retardant treated sawdust, diatomaceous earth, etc.
Shovel up with spark-resistant utensils for later disposal at an approved
facility, in accordance with current laws and regulations.
Environmental precautions : Prevent spill from entering municipal sewers, water sources or low lying
areas. Advise the relevant authorities if contaminations have occurred.
Safe handling advice : Avoid prolonged repeated skin contact. Avoid inhalation of vapours or
mists. Avoid ingestion.
Storage information : Do not store in unlabelled containers. Do not store near strong oxidizing
agents and combustible materials.
LTEL: Long Term Exposure Limits - Time Weight Average (TWA) over 8 hours.
STEL: Short Term Exposure Limits - Time Weight Average (TWA) over 15 Minutes
Eye protection : If splash with liquid is possible, chemical type goggles should be worn.
Appearance : Liquid.
Colour : Yellow
Odour : Characteristic
Solubility : Miscible
Boiling point : 140 °C
Density : 1.065 g/cm3 @ 20 °C (ASTM D-4052)
Stability : Stable.
Acute oral toxicity : (Rats): Toxic (LD50: Less than 250 mg/kg). Based on testing of similar
products and/or components. May be fatal if swallowed and enters
airways. Hazard category 3. Danger
Acute dermal toxicity : (Rabbits): Practically non-toxic (LD50: greater than 2000 mg/kg).
Based on single dose testing at 2 000mg/kg. May be harmful in contact
with skin. Hazard category 5. Warning
PETRONAS Coolant 33
Acute inhalation toxicity : (Rats): Toxic (LC50: greater than 2 but 10mg/l or less) 4 hours. Based
on testing products and/or components.
Skin irritation : (Rabbits): Practically non-irritating. Causes mild skin irritation. Hazard
category 3. Warning
Eye irritation : (Rabbits): Irritant. (Draize score: greater than 15 but less than 35).
Based on testing of similar products and/or the components. Causes eye
irritation. Hazard category 2A. Warning
Respiratory and skin : This product was not a skin sensitizer when tested in a Modified Buehler
sensitization Guinea Pig Sensitization Assay.
Carcinogenicity : No carcinogenic effects were observed when this product was applied to
the skin of mice for two years.
Reproductive toxicity : Ethylene glycol, when administered orally to pregnant rats at 2250
(Teratogenicity) mg/kg/day caused some malformations of the offspring. The NOEL was
1250 mg/kg/day. No developmental or teratological effects were
observed in rabbits administered 2000 mg/kg/day orally. Aerosols of
2500 mg/m3 during organogenesis resulted in teratogenic effects in mice
but not rats. Nose-only exposure of mice to aerosols of 1000 mg/m3
resulted in developmental effects but minimal teratogenic effects. The
NOEL based on maternal toxicity was 500 mg/m3. When applied to the
skin of rats during organogenesis no teratogenic effects were observed.
Although these effects are not known to occur in humans, precautionary
measures should be taken to avoid exposure during pregnancy,
particularly in the early stages.
Specific target organ toxicity : Ingestion of ethylene glycol may result in nausea, vomiting, abdominal
(STOT) - single exposure cramps, convulsions, oedema of the lung, cardiopulmonary effects
(metabolic acidosis), pneumonia and kidney failure which could result in
death. The single lethal dose for humans is about 100 ml.
Specific target organ toxicity : Small quantities of ethylene glycol ingested, inhaled or absorbed through
(STOT) - repeated exposure the skin repeatedly over a prolonged period of time may result in
systemic toxic effects. Rats fed 1-2 percent ethylene glycol for two years
suffered severe kidney damage, liver damage and bladder stones.
Inhalation studies for two years at 100 ppm with 7 species of animals did
not result in any adverse effects other than respiratory irritation. Danger
Hazard category 2.
Aspiration hazard : Material if aspirated into the lungs may cause chemical pneumonitis.
Ecotoxicity effects
Contaminated packaging : Empty containers retain residue (liquid and/or vapour) and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or
clean container since residue is difficult to remove. Empty drums should
be completely drained, properly bunged and promptly returned to a
drum reconditioner. All containers should be disposed of in an
environmentally safe manner and in accordance with governmental
regulations.
Other regulations : Disposal of unused product may be subject to RCRA regulations (40 CFR
261). Disposal of the used product may also be regulated due to
ignitability, corrosivity, reactivity, or toxicity as determined by the
Toxicity Characteristic Leaching Procedure (TCLP).
Note : This product is not regulated by the following: CFR and IATA.
US OSHA Hazard : Product assessed in accordance with OSHA 29 CFR 1910.1200 and
Communication Standard determined to be hazardous.
Governmental Inventory : All components comply with TSCA, EINECS/ELINCS, AICS, METI, DSL,
Status KECI, ENCS, PICCS and IECSC.
Symbols : Xn
Harmful
S-Phrase(s) : S2
Keep out of the reach of children.
SARA
SARA (313) Toxic Release : Ethylene Glycol (107-21-1) - Conc > 90%
Chemicals:
Health studies have shown that many hydrocarbons pose potential human health risks which may vary from
person to person. Information provided on this MSDS reflects intended use. This product should not be used
for any other applications. In any case, the following advice should be considered:
INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body,
regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a
doctor as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal
or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of
injury.
Empty container may contain product residue, including flammable or explosive vapours. Do not cut,
puncture, or weld on or near container. All label warnings and precautions must be observed until container
has been thoroughly cleaned or destroyed.
Disclaimer
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and
suitability of the product for particular uses are beyond our control; all risks of use of the product are
therefore assumed by the user and we expressly disclaim all warranties of every kind and nature, including
warranties of merchantability and fitness for a particular purpose in respect to the use or suitability of the
product. Nothing is intended as a recommendation for uses which infringe valid patents or as extending
license under valid patents. Appropriate warnings and safe handling procedures should be provided to
handlers and users.
Technical Data Sheet
Revised: 2016/05/30 (version 1.0)
PETRONAS COOLANT
FEATURES & BENEFITS
50 %
Excellent cooling system
APPLICATIONS protection
Protect against rust and
Premium performance pre mixed mono ethylene glycol based fluid with anti- corrosion
rust, anti-corrosion additive components developed to meet the requirements Provides excellent heat
of modern gasoline and light duty diesel engines. It provides corrosion transfer characteristics
protection for all engine and cooling system metals. It minimizes the engine Compatible with rubber
damage by raising the boiling point of diluted coolant. hoses used in cooling
systems
Note: Always consult your owner’s manual to check recommended viscosity grade and specifications for your
particular vehicle. Good solubility and
stability in both soft and
hard water
Outstanding anti-freeze
property
TYPICAL PHYSICAL DATA**
Typical
Parameters Method Unit
Value
Density at 15°C ASTM D4052 g/cm3 1.065
Equilibrium Boiling
ASTM D1120 °C 120
Point (undiluted)
Freezing point 50%
ASTM D3321 °C -36
in water
Reserve alkalinity ASTM D1121 Ml 8.0
pH ASTM D 664 8.0
** These characteristics are typical of current production. Whilst future production will conform to PLI’s
specification, variations in these characteristics may occur.
www.pli-petronas..com
Health, Safety and Environment
This product is unlikely to present any significant health and safety hazards when
used in the recommended application. Avoid contact with skin. Wash immediately
with soap and water after skin contact. Do not discharge into drains, soil or water.
For further detail regarding storage, safe handling, and disposal of product, please
refers to product SDS or contact us at: www.pli-petronas.com
Important Note
The word PETRONAS, the PETRONAS logo and such other related trademarks
and/or marks used herein are trademarks or registered trademarks of PETRONAS
Lubricants International Sdn. Bhd. (“PLISB”), or its subsidiaries or related Holding
Corporation under license unless indicated otherwise. The PLI Documents and the
information contains herein is believed to be accurate as of the date of printing.
PLISB makes no express or implied representation or warranties as to its accuracy
or completeness or information in or any transaction performed. The PLI Documents
information provided is based on standard tests under laboratory conditions and is
given only as a guide. Users are advised to ensure that they refer to the latest version
of these PLI Documents. It is the responsibility of the users to evaluate and use
products safely, to assess suitability for the intended application and to comply with
all applicable laws and regulations imposed by the respective local authorities.
Safety Data Sheets are available for all our products and should be only be consulted
for appropriate information regarding storage, safe handling and disposal of the
product. No responsibility shall be taken by either PLISB or its subsidiaries and
related holding corporation for any loss or injury or any direct, indirect, special,
exemplary, consequential damages or any damages whatsoever, whether in action
of contract, negligence or other tortuous action, in connection or resulting from
abnormal use of the materials and/or information, from any failure to adhere to
recommendations, or from hazards inherent in the nature of the materials and/or
information. All products, services and information supplied are under our standard
conditions of sale. Please consult with any of our local representative in the event
you require any further information.
www.pli-PETRONAS.com
PETRONAS Coolant 50
2. HAZARDS IDENTIFICATION
GHS Classification:
Health
Acute oral toxicity Hazard category 4. Harmful if swallowed. Warning
STOT - single exposure Hazard category 2. May cause damage to organs. Warning
Environmental
Aquatic toxicity : Not classified.
Physical
Flammability : Not classified.
GHS Labels/Pictograms:
Hazard Statements
Precautionary Statements
General
Keep locked up and out of reach of children.
Prevention
Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when
using this product.
Response
IN CASE OF FIRE: Use carbon dioxide, foam or dry chemical for extinction. IF SWALLOWED: Immediately call
a POISON CENTRE or doctor. IF INHALED: Call a POISON CENTRE or doctor immediately. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: get medical attention.
Storage
Store in a well-ventilated place and keep the container cool and tightly closed.
Disposal
Do not discharge into lakes, streams, ponds and ground water supply.
PETRONAS Coolant 50
3. COMPOSITION/INFORMATION ON INGREDIENTS
Skin contact : Remove contaminated clothing. Dry wipe exposed skin and cleanse with
hand cleaner, soap and water. Launder contaminated clothing before
reuse. (See Section 16 - Injection Injury)
Eye contact : Flush thoroughly with water for at least 15 minutes. Get medical
assistance.
5. FIRE-FIGHTING MEASURES
Extinguishing media : Carbon dioxide, foam, dry chemical and water fog.
Special fire fighting : Water or foam may cause frothing. Use water to keep fire exposed
procedure containers cool. Water spray may be used to flush spills away from
exposure. Prevent runoff from fire control or dilution from entering
streams, municipal sewers, or drinking water supply.
Methods for cleaning up : Absorb on fire-retardant treated sawdust, diatomaceous earth, etc.
Shovel up with spark-resistant utensils for later disposal at an approved
facility, in accordance with current laws and regulations.
Environmental precautions : Prevent spill from entering municipal sewers, water sources or low lying
PETRONAS Coolant 50
Safe handling advice : Avoid prolonged repeated skin contact. Avoid inhalation of vapours or
mists. Avoid ingestion.
Storage information : Do not store in unlabelled containers. Do not store near strong oxidizing
agents and combustible materials.
LTEL: Long Term Exposure Limits - Time Weight Average (TWA) over 8 hours.
STEL: Short Term Exposure Limits - Time Weight Average (TWA) over 15 Minutes
Eye protection : If splash with liquid is possible, chemical type goggles should be worn.
Appearance : Liquid.
Colour : Yellow
Odour : Characteristic
Solubility : Miscible
Boiling point : 140 °C
Density : 1.065 g/cm3 @ 20 °C (ASTM D-4052)
Stability : Stable.
Acute oral toxicity : (Rats): Toxic (LD50: Less than 250 mg/kg). Based on testing of similar
products and/or components. May be fatal if swallowed and enters
airways. Hazard category 3. Danger
PETRONAS Coolant 50
Acute dermal toxicity : (Rabbits): Practically non-toxic (LD50: greater than 2000 mg/kg).
Based on single dose testing at 2 000mg/kg. May be harmful in contact
with skin. Hazard category 5. Warning
Acute inhalation toxicity : (Rats): Toxic (LC50: greater than 2 but 10mg/l or less) 4 hours. Based
on testing products and/or components.
Skin irritation : (Rabbits): Practically non-irritating. Causes mild skin irritation. Hazard
category 3. Warning
Eye irritation : (Rabbits): Irritant. (Draize score: greater than 15 but less than 35).
Based on testing of similar products and/or the components. Causes eye
irritation. Hazard category 2A. Warning
Respiratory and skin : This product was not a skin sensitizer when tested in a Modified Buehler
sensitization Guinea Pig Sensitization Assay.
Carcinogenicity : No carcinogenic effects were observed when this product was applied to
the skin of mice for two years.
Reproductive toxicity : Ethylene glycol, when administered orally to pregnant rats at 2250
(Teratogenicity) mg/kg/day caused some malformations of the offspring. The NOEL was
1250 mg/kg/day. No developmental or teratological effects were
observed in rabbits administered 2000 mg/kg/day orally. Aerosols of
2500 mg/m3 during organogenesis resulted in teratogenic effects in mice
but not rats. Nose-only exposure of mice to aerosols of 1000 mg/m3
resulted in developmental effects but minimal teratogenic effects. The
NOEL based on maternal toxicity was 500 mg/m3. When applied to the
skin of rats during organogenesis no teratogenic effects were observed.
Although these effects are not known to occur in humans, precautionary
measures should be taken to avoid exposure during pregnancy,
particularly in the early stages.
Specific target organ toxicity : Ingestion of ethylene glycol may result in nausea, vomiting, abdominal
(STOT) - single exposure cramps, convulsions, oedema of the lung, cardiopulmonary effects
(metabolic acidosis), pneumonia and kidney failure which could result in
death. The single lethal dose for humans is about 100 ml.
Specific target organ toxicity : Small quantities of ethylene glycol ingested, inhaled or absorbed through
(STOT) - repeated exposure the skin repeatedly over a prolonged period of time may result in
systemic toxic effects. Rats fed 1-2 percent ethylene glycol for two years
suffered severe kidney damage, liver damage and bladder stones.
Inhalation studies for two years at 100 ppm with 7 species of animals did
not result in any adverse effects other than respiratory irritation. Danger
Hazard category 2.
Aspiration hazard : Material if aspirated into the lungs may cause chemical pneumonitis.
Ecotoxicity effects
Contaminated packaging : Empty containers retain residue (liquid and/or vapour) and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or
clean container since residue is difficult to remove. Empty drums should
be completely drained, properly bunged and promptly returned to a
drum reconditioner. All containers should be disposed of in an
environmentally safe manner and in accordance with governmental
regulations.
Other regulations : Disposal of unused product may be subject to RCRA regulations (40 CFR
261). Disposal of the used product may also be regulated due to
ignitability, corrosivity, reactivity, or toxicity as determined by the
Toxicity Characteristic Leaching Procedure (TCLP).
Note : This product is not regulated by the following: CFR and IATA.
US OSHA Hazard : Product assessed in accordance with OSHA 29 CFR 1910.1200 and
Communication Standard determined to be hazardous.
Governmental Inventory : All components comply with TSCA, EINECS/ELINCS, AICS, METI, DSL,
Status KECI, ENCS, PICCS and IECSC.
Symbols : Xn
Harmful
S-Phrase(s) : S2
Keep out of the reach of children.
SARA
SARA (313) Toxic Release : Ethylene Glycol (107-21-1) - Conc > 90%
Chemicals:
Health studies have shown that many hydrocarbons pose potential human health risks which may vary from
person to person. Information provided on this MSDS reflects intended use. This product should not be used
for any other applications. In any case, the following advice should be considered:
INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body,
regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a
doctor as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal
or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of
injury.
Empty container may contain product residue, including flammable or explosive vapours. Do not cut,
puncture, or weld on or near container. All label warnings and precautions must be observed until container
has been thoroughly cleaned or destroyed.
Disclaimer
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and
suitability of the product for particular uses are beyond our control; all risks of use of the product are
therefore assumed by the user and we expressly disclaim all warranties of every kind and nature, including
warranties of merchantability and fitness for a particular purpose in respect to the use or suitability of the
product. Nothing is intended as a recommendation for uses which infringe valid patents or as extending
license under valid patents. Appropriate warnings and safe handling procedures should be provided to
handlers and users.
Creation Date: 25/09/2003
Revision Date: 28/10/2011
Pag. 1 /12
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE:
Lubricant for transmission system (U.T.T.O.).
2. HAZARDS IDENTIFICATION
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
Directives 67/548/EEC or 1999/45/EC:
This product is not considered hazardous for people or for environment according to EC directives (see
INDICATIONS OF DANGER
Not applicable.
CONTAINS:
RISK PHRASES
Not applicable.
SAFETY PHASES
Not applicable.
OTHER INDICATIONS:
Contains monothiophosphate amine salt. May produce an allergic reaction.
It contains skin sensitizer components, but their quantity is insufficient to classify it.
The product is not readily biodegradable. In case of large accidental spills, it is a potential source of soil,
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2 MIXTURES
Additive package containing nitrogen, sulphur, phosphorus, antioxidants and polymers.
Directive 67/548/EEC:
EYE CONTACT:
Rinse thoroughly with plenty of water for at least 10 minutes keeping eyelids open. Obtain medical
SKIN CONTACT:
Remove contaminated clothes and shoes and rinse thoroughly with plenty of water and soap.
Creation Date: 25/09/2003
Revision Date: 28/10/2011
Pag. 4 /12
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Refer to section 11.
5. FIREFIGHTING MEASURES
FLASH POINT: 210°C (ASTM D 92)
water mist.
Avoid high pressure water jet. Use water jet only to cool down surfaces exposed to fire.
COMBUSTION PRODUCTS:
Oxides of carbon, compounds of sulphur, phosphorus, nitrogen and products of incomplete combustion.
Surfaces on which the product has been spilled may become slippery.
necessary.
absorbent material. Put dirty material in suitable container. Dispose of dirty material in accordance with
store in the open air. Assure a correct ventilation of premises and the control of possible leak.
other required precautions. If necessary, adopt all required precaution to avoid product immission in
RESPIRATORY PROTECTION:
None required under normal conditions of use. Use approved full face respirator with organic vapour filter
show wear. The kind of gloves and the term of use must be decided from employer with regard to
processing and to allow for legislation on personal protection equipment and glove producer's indications.
Wear suitable protective clothing (for further information, refer to CEN-EN 14605); change it immediately
EYE PROTECTION:
Chemical goggles and face shield in case of oil splashes.
Creation Date: 25/09/2003
Revision Date: 28/10/2011
Pag. 7 /12
INHALATION:
Inhalation of mists and vapours generated at elevated temperatures may cause respiratory irritation.
EYE CONTACT:
Contact may cause slight irritations.
SKIN CONTACT:
The product contains sensitizing substances, but is not classified in this way. Product is not an irritant,
biodegradable.
The product is not soluble in water. In case of large spills, it is a potential source of soil, watercourse and
groundwater pollution.
evaporation, little mobility in the ground and it can be adsorbed from soil.
Do not discharge in sewers, tunnels or water courses. Dispose in accordance with local or national
Regulation (EC) No 790/2009 amending, for the purposes of its adaptation to technical and scientific
progress, Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and
mixtures
Directive 1999/45/EC and all following updates, together with its national realization, about classification,
Regulation (EC) No 1907/2006, with all National and European related legislations - concerning the
Regulation (EU) No 453/2010 amending Regulation (EC) No 1907/2006 on the Registration, Evaluation,
and all following updates, togeher with its national realization, about improvement of worker safety and
health
Creation Date: 25/09/2003
Revision Date: 28/10/2011
Pag. 11 /12
Directives 98/24/EC and all following updates, together with its national realization, about protection of
Directive 1991/156/EC and all following updates, together with national waste legislation
EC directives and national environment protection legislation (air, water and soil)
extract according to IP 346 method, and are therefore not classified as carcinogen according to
Sheet complies with the criteria of Annex I of Regulation (EU) No. 453/2010 as well as with Regulation
This product must not be used in applications other than recommended without first seeking the advice of
As regard as the previous version this sheet has been changed at following headings:
This product must be stored, handled and used according to correct industrial hygienic practices and in
The information contained herein is based on the present state of our knowledge and is intended to
describe our products from the point of view of safety requirements. It should not therefore be considered
3. Hazards Identification
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray
may be used to cool fire-exposed containers and flush spills away from
exposure. Prevent any runoffs from polluting drinking water supply and the
environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be
used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
o
Flash Point C: 242(ASTM D-92)
NFPA Hazard ID: Health: 1, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water
supply and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Eye Protection: Chemical type goggles or face shields are optional depending
on working conditions.
Appearance: Liquid
Colour: Dark Brown
Odour: Mild petroleum characteristic
Solubility in water: Insoluble
o
Density at 15 C, kg/l: 0.876
o
Flash point, C: 232
o
Viscosity @ 40 C, cSt: 109.5
o
Viscosity @ 100 C, cSt: 14.7
Viscosity Index: 139
Total Base Number, mgKOH/gm: 10
o
Pour point, C: -30
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in
this product, showed no evidence of carcinogenic activities. Do not ingest this
product.
Not regulated.
Its advanced additive system ensure excellent control over soot induced wear, high
temperature piston deposits, corrosion, foaming and oxidation stability. It also provide
excellent resistance to bore polishing, a high level of wear protection and ensure superior
engine cleanliness at extended drain intervals.
3. Hazards Identification
Eye Contact: Rinse immediately with plenty of water until irritation stops. If
irritation continues, contact nearest medical centre.
Skin Contact: Wash contact areas with soap and water.
Inhalation: Problem unlikely to occur.
Ingestion: Do not induce vomiting. Give at least one glass of water and consult
nearest medical centre.
5. Fire-Fighting Measures
Extinguishing Media: Carbon dioxide, foam, and dry chemical powder.
Fire Fighting Procedures: Water may cause frothing. However, water spray
may be used to cool fire-exposed containers and flush spills away from
exposure. Prevent any runoffs from polluting drinking water supply and the
environment.
Special Protective Equipment: Self-Contained Breathing Apparatus must be
used for fires in enclosed areas.
Unusual Fire and Explosion Hazards: None.
o
Flash Point C: 228 (ASTM D-92)
NFPA Hazard ID: Health: 1, Flammability: 1, Reactivity: 0
Hazardous Decomposition Products: Carbon monoxide
Water Spills: Notify port or relevant authority to warn other shipping. Confine the
spill with booms and remove from the surface by skimming or with suitable
absorbents. Dispose the residue according to local disposal regulations.
Packages and Containers: Plug the leak and return containers to source.
Environment Precautions: Prevent spillage from further polluting drinking water
supply and the environment.
Storage: Do not store in open or unlabelled containers. Store away from strong
oxidizing agents or combustible material.
Eye Protection: Chemical type goggles or face shields are optional depending
on working conditions.
Appearance: Liquid
Colour: Brown
Odour: Mild petroleum characteristic
Solubility in water: Insoluble
o
Density at 15 C, kg/l: 0.869
o
Flash point, C: 228
o
Viscosity @ 40 C, cSt: 102
o
Viscosity @ 100 C, cSt: 14.2
Viscosity Index: 142
Total Base Number, mgKOH/gm: 10.0
o
Pour point, C: -36
Chronic Toxicology
Long term, mouse skin painting studies of the severely treated base oils used in
this product, showed no evidence of carcinogenic activities. Do not ingest this
product.
Not regulated.
Synthetic API CI4 10w/40 Grp-III,IV Delvac 1 5w40 Rubia TIR 7800
Mineral API CI4 10w/40, 15w/40 Group-II Delvac MX Superfleet LE Max Rybia TIR 7400
Mineral API CH4 15w/40 Group-II Delvac Super 1400 Superduty VLE
Mineral – Mono grades API CF SAE 10 W, 30, 40, 50 - Group-I Delvac 1340 SDMO Rubia S
Gear Oils
GL - 4 SAE 90, 140, 80w/90, 85w/140 Group-I Mobilube GX Gear EP GL 4 Dynatrans MP for LS
GL - 5 SAE 90, 140, 80w/90, 85w/140 Group-I Mobilube GX 85w140 Gear MP GL 5 Dynatrans MDL NA
ATF Dexron II D, III Group-II Mobil ATF 220 ATF DX II Dexron VI ATF
Transmission T O 4 Fluids
Brake Fluids
DOT 3, 4 Brake Fld DOT 3, 4 Brake Fld DOT 3 HD Brake Fluid DOT 3
Hydraulic Oils R & O Type
DIN 51524-I,II HL, HLP ISO VG 10, 15, 22, 32, 46, 68, 100, 150 Group-I DTE 20 Harmony Azolla ZS, AF (AF- Zn free)
Hydraulic Oils HVI Type
DIN 51524-III, HVLP ISO VG 10, 15, 22, 32, 46, 68, 100, 150 Group-II DTE 10 Excel Harmony HVI Equivis ZS
Industrial Gear Oils
ISO VG 68, 100, 150, 220, 320, 320,
AGMA EP, DIN 51517-3 CLP 460, 680 Group-I Mobilgear 600 XP EP Lubricant HD Carter EP
Compressor Oils
DIN 51506 VDL ISO VG 46, 68, 100, 150 Group-II Rarus 400 Dacnis
Circulating Oils
ISO VG 68, 100, 150, 220, 320, 320,
Straight Min 460, 680, Group-I Vacuoline 100 Security
Turbine Oils
Mineral DIN 51515-1 (No AW) ISO VG 32, 46, for Steam Turbines Group-II DTE 732 Crest Preslia
AW for Geared Turbines ISO VG 32, 46, 68, 100 Group-II DTE 800 Crest EP Preslia GT
Greases
Synthetic API SN 5w/30, 5w/40 Grp-III,IV Voyager Gold Titan Super Synth Syntium 3000
Semi Synthetic API SM 10w/40 Group-II Voyager Silver Titan Syn F Eco Syntium 800 SM
Synthetic API CI4 10w/40 Grp-III,IV Voyager Ultra Syn Titan Unimax ultra MC Motolub C3 S CI4
Mineral API CI4 10w/40, 15w/40 Group-II Voyager Ultra Titan Truck Plus Urania Supermo CI 4
Mineral API CH4 15w/40 Group-II Voyager HPSD Titan Truck 15w40 Urania Supermo CH4
Mineral – Mono grades API CF SAE 10 W, 30, 40, 50 - Group-I Voyager HD Titan TXE Monograde Urania CF
Gear Oils
GL - 4 SAE 90, 140, 80w/90, 85w/140 Group-I Gear Oil GP Titan Gear MP Gear Oil SAE 90 GL4
GL - 5 SAE 90, 140, 80w/90, 85w/140 Group-I Gear Oil GX Titan Gear XP Gear Oil 80w90 GL5
ATF Dexron II D, III Group-II ATF D II Titan ATF 5005 ATF Synth Asia
Transmission T O 4 Fluids
TO - 4-30, 4-40, 4-50 Group-I Tranmission Oil TO4 Titan ATF 3000, 4000 ATF
Radiator Coolants
Brake Fluids
Tutela Plus 3, Tutela
DOT 3, 4 Brake Fluid DOT 3, 4 Universal Br & Clt Fld Extreme HT DOT 4
Hydraulic Oils R & O Type
ISO VG 10, 15, 22, 32, 46, 68, 100,
DIN 51524-I,II HL, HLP 150 Group-I Hydraulic Oil H Renolin B Hidraulik EP
Hydraulic Oils HVI Type
ISO VG 10, 15, 22, 32, 46, 68, 100,
DIN 51524-III, HVLP 150 Group-II Hydraulic Oil E HP Renolin B HVI Hidraulik HVI
Industrial Gear Oils
ISO VG 68, 100, 150, 220, 320, 320, Industrial Gear Oil
AGMA EP, DIN 51517-3 CLP 460, 680 Group-I EP Renolin AWD, CLP Gear MEP
Compressor Oils
DIN 51506 VDL ISO VG 46, 68, 100, 150 Group-II Compressor Oil Renolin 500 Pressol
Circulating Oils
ISO VG 68, 100, 150, 220, 320, 320,
Straight Min 460, 680, Group-I Circulating Oil Renolin 200 Circula
Turbine Oils
Mineral DIN 51515-1 (No AW) ISO VG 32, 46, for Steam Turbines Group-II Turbine oil E Tyro Jenteram HC
AW for Geared Turbines ISO VG 32, 46, 68, 100 Group-II Turbine Oil E T 77 Renolin Eterna Jenteram HC Extra
Greases
Synthetic API SN 5w/30, 5w/40 Grp-III,IV Genesis Advanced Havoline ProDS Syn LE Visco 7000 C
Semi Synthetic API SM 10w/40 Group-II Luxe Synthetic SM Havoline Formula Visco 2000
Mineral API SL 20w/50 Group-I Luxe SL/CF Havoline Premium Visco 2000
Mineral API CH4 15w/40 Group-II Avantgarde Extra Delo Gold Multigrade Vanellus Multi CG 4
Mineral – Mono grades API CF SAE 10 W, 30, 40, 50 - Group-I Delo Silver Vanellus Mono
Gear Oils
GL - 4 SAE 90, 140, 80w/90, 85w/140 Group-I Transmission TM 4 Delo Gear EP 4 Energear
GL - 5 SAE 90, 140, 80w/90, 85w/140 Group-I Transmission TM 5 Delo Ger EP 5 Energear HPA
ATF Dexron II D, III Group-II ATF Synth Asia Havoline ATF Autotrans DX II
Transmission T O 4 Fluids
Anti freeze Ready to use Antifreeze Ultra G 12 Havoline EL Antifreeze Diesel Coolant HD 50
Antifreeze G11 Blue
Brake Fluids
DOT 3, 4 Lukoil DOT 3, DOT 4 Br & Clt Fld DOT 3, 4 Brake Fld DOT 3, 4
Hydraulic Oils R & O Type
ISO VG 10, 15, 22, 32, 46, 68, 100,
DIN 51524-I,II HL, HLP 150 Group-I Ind Hyd Oil IGS Hydraulic Oil AW Energol HLP HM
Hydraulic Oils HVI Type
ISO VG 10, 15, 22, 32, 46, 68, 100,
DIN 51524-III, HVLP 150 Group-II Geyser LTD 46 Rando HD2 Bartan HV
Industrial Gear Oils
ISO VG 68, 100, 150, 220, 320, 320,
AGMA EP, DIN 51517-3 CLP 460, 680 Group-I I T D Gear Oils Meropa XL Energol GR XP
Compressor Oils
DIN 51506 VDL ISO VG 46, 68, 100, 150 Group-II Stabio Compressor oil EP VDL Energol RC R
Circulating Oils
ISO VG 68, 100, 150, 220, 320, 320,
Straight Min 460, 680, Group-I Canopus, Rando Energol EM
Turbine Oils
Mineral DIN 51515-1 (No AW) ISO VG 32, 46, for Steam Turbines Group-II Turbine oil TP 30 Regal R&O, GST Premium Turbinol X
AW for Geared Turbines ISO VG 32, 46, 68, 100 Group-II Turbine oil Tornado T Regal EP, Regal GST EP Turbinol X EP
Greases
Lithium NLGI EP 0,1,2,3 Renolit MP EP Delo Grease Hy Duty EP Energrease LS EP, L21m
Lithium Complex Li Complex Grease Renolit LX PEP Delo Starplex EP Ind. Energrease LC
*Lukoil endorses Fuchs -
Marine/Ind applications
Profile of
an ExCastrol
Lubricant Specialist
Hussam Adeni
Chemical Engineer by education
Lubricant Specialist by
Certification - MLA 1 – www.icml.com, Lube Council
Experience – Castrol, BPCastrol
Membership – www.stle.org
GHG mitigation and Fuel Conservation Evangelist by Philosophy
https://www.linkedin.com/in/hussamadeni/
https://twitter.com/hussamadeni
hussam_adeni@yahoo.com Lubricant Specialist & Tribologist
hussam.adeni@gmail.com What’s App: +966542017250
Profile - Lubricant Specialist
Edu. Qualification B Tech. Chemical Engineer – Andhra University School of Chemical Engineering,
Visakapatnam, Andhra Pradesh.
Memberships Society of Tribologists and Lubrication Engineers – STLE (www.stle.org) since 2005
International Council for Machinery Lubrication (ICML) – (www.lubecouncil.com)
Life member ( # 5235) – Tribology Society of India (TSI) – (www.tribologyindia.org)
Work Experience Indrol, Castrol India, BPCastrol, Castrol Industrial Lubricants - ILS – 1983 to 2001
Sr. Business Manager – Castrol SBU Cement Bricks and Glass Ind. - 1999-2001
Tech Manager & Tribologist –Mackay Group and PG group, Singapore & Manila - 2009/10
Distributor for Boron CLS Bond – (http://www.themackaygroup.com.ph/mge-boron.html)
Lubricant Specialist & Business Head. Malaysian Base Oil Trader, Petro Nuhr Trading Co., Ltd.,
Chennai - Jan 2012 to March 2013.
Lubricant Specialist Reza Group. (ProOne Div.) Jeddah, Saudi Arabia – Oct 2014 – Oct 2015
http://www.rezagroup.com/1/Companies/Energy/RezaEnergyProductsServices.aspx
Business Development Manager – Petronas Distributor, Muscat Oman Jun 2016 – Oct 2016
Slideshare Analytics Combined performance summary of all uploads – 54K ++ Views, 5300++ Downloads
Networking – Memberships and Certificates Professional:
www.stle.org
www.lubecouncil.com
For details of my prowess on the net, please feel free to browse the web links.
http://www.slideshare.net/hussam57/basic-of-lubricants-amp-lubrication
Invite you to Google search for "Hussam Adeni" for blogs & posts of my web activity.