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for sulfur.
5. C Melting point 3540 °C Carbon
Carbon is the most important and influential alloying element in
steel. In addition to carbon however, any unalloyed steel will
contain silicon, manganese, phosphorus and sulfur, which occur
unintentionally during manufacture. The addition of further alloying
elements to achieve special effects and intentional increase in the
manganese and silicon contents result in alloy steel. With
increasing C content, the strength and hardenability of the steel
increase, but its ductility, forge ability, weldability and machinability
(using cutting machine tools) are reduced. Corrosion resistance to
water, acids and hot gases are practically unaffected by the
carbon.
Carbon
This is usually present in solid solution or as carbides. Free carbon is not
normally found in steels ( but is often present as graphite in cast irons and
pig irons )
The terms FERRITE ( α ) and AUSTENITE ( γ ) refer to the solid
solutions of carbon in the body – centered and face – centered cubic
forms of iron respectively the solubility of carbon in austenite is much
greater than in ferrite . if austenite is cooled rapidly the precipitation of
carbide as it transforms to ferrite can be prevented . the excess carbon in
the ferrite results in a distortion of the body – centered cubic structure
which produces a phase termed MARTENSITE.
By suitable alloying additions , austenite can be stabilized at room
temperature ( this forms the basis of the austenitic stainless steels ) in the
absence of alloying elements the carbide formed in steels is
CEMENTITE Fe3c , the form of which can vary greatly depending on the
amount of carbon present and the heat treatment received by the steel
(characteristic structures are referred to as : pearlitic , bainitic ,
spheroidised , etc ).
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Silicon
Can be added to steel for deoxidation purposes , but in certain cases it is
added as an alloying element to obtain specific properties .
Silicon addition will improve the tensile strength of iron and amounts as
high as 4% are added to certain steels to give increased electrical
resistivity .
Adding 0.5% - 4% silicon to stainless steels increases the resistance to
oxidation at high temperatures.
Silicon is present in steels mainly in solid solution. Small amount may
occur in inclusions but there are not plentiful (except in wrought
irons,where significant amounts of entrapped slag are present ).
Material type Amount of silicon %
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MANGANESE
Is nearly always present in ferrous materials. It is added to steel as an
alloying element and also as a deoxidizing agent. Manganese has an
affinity for sulphur , forming manganese sulfide , thus preventing the
formation of an inter-crystalline film of brittle , low melting-point iron
sulfide which would significantly spoil the properties of the steel.
In plain and low-alloy steels it is usually less than 1%
Sulfur
Is almost always present in steel as an undesirable residual impurity
rather than as an intentional addition. In general , sulfur has a detrimental
effect on the steels properties and is kept to levels less than 0.035%.
tighter limits than this may be imposed, however (eg steels for aircraft
construction are 0.01 % max. ) .
In the absence of manganese , the sulfur combines with the iron to give
an embrittlement effect on the steel in both the hot and the cold condition
. at room temperature iron sulfide is very brittle and at steel hot working
temperatures it is molten , allowing inter granular fissures to open up
inside the steel.
Manganese sulfide is much more plastic than iron sulfide and it forms as
globules in the steel rather than around the grains.
Phosphorus
Is generally present as a lift-over impurity from iron making.
It is undesirable in that it is prone to segregation (which is then difficult
to remove by heat treatment or working ) and tends t lead to stratified
macrostructures with poor directional properties.
It is usually present in solid solution but might form phosphides.
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Chromium
Is added as an alloying element , often in conjunction with other
elements, to give improved mechanical and metallurgical properties eg
hardness , magnetic characteristics , wear – and corrosion resistance.
It exists in steels in solid solution and also as carbides .
Molybdenum
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Nickel
Is used extensively as an alloying addition. It promotes hardenability in
the low alloy steels and in particular it improves toughness .
The nickel – chromium, nickel-molybdenum, chromium-nickel-
molybdenum steels of the low alloy type (containing 0.2 to 0.4 % carbon
) find many application as forgings , stampings , gears , crank shafts ,
rotors, etc…
Nickel levels of 2 to 5% are used for case hardening where a tough metal
core is needed as well as a wear resisting surface.
nickel tends to stabilized the high – temperature form of iron , austenite ,
and is added to stainless steels up to about 20% for this purpose.
It rarely enters the carbides and is usually found dissolved in the iron.
Copper
This element can have a serious deleterious effect on the hot working of
steel unlees nickel is also present … copper is more resistant to oxidation
than iron and most other alloying elements which can lead to a copper-
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rich layer forming on the steel surface underneath the scale; this layer can
melt at hot working temperatures causing surface cracking (called "red
hot shrtness" and accentuated by some elements such as tin and antimony
).
On the other hand, a useful precipitation-hardening effect can be obtained
with copper in steel , producing an increase in strength and hardness
although with a corresponding decrease in ductility also copper increases
resistance to atmospheric corrosion.
Copper is usually present in most steels as a residual element , being
introduced with the scrap. It does not form carbides and is nearly always
present as a solid solution in the matrix.
Niobium ( columbium )
This is sometimes used for grain refinement , accomplished by a finely
dispersed precipitation of Fe3nb2 without the undesirable oxide inclusions
which are obtained with other grain refiners which are also strong
deoxidizers . in controlled rolled steels , the finishing temperature is
carefully controlled to achieve the right amount and type of precipitate to
ensure a fine grain size counteracting softening.
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Titanium
Because of its strong affinities , titanium is found in steels in the form of
carbides , carbonitrides and carbosulfides ( as well as within the
inclusions ) .
Vanadium
This strong carbide former tends to promote secondary hardening and
grain refinement but it also goes into solution in low alloy steels
producing a stronger tougher metal matrix.
Medium carbon steels containing manganese or chromium together with
0.1 to 0.15% vanadium are used for forgings requiring a good
combination of strength and toughness.
Vanadium improve wear resistance in the low alloy steels and aids creep
resistance in the chromium –molybdenum steels .
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Aluminum
Dissolved gases
Abstract:
Very important elements for alloy steels are manganese,
nickel, chromium, molybdenum, vanadium, tungsten,
silicon, copper, cobalt and boron. All commercial steels
contain 0,3-0,8% manganese, to reduce oxides and to
counteract the harmful influence of iron sulphide. There is
a tendency nowadays to increase the manganese content
and reduce the carbon content in order to get a steel with
an equal tensile strength but improved ductility. Nickel
and manganese are very similar in behaviour and both
lower the eutectoid temperature. Nickel steels are noted
for their strength, ductility and toughness, while
chromium steels are characterized by their hardness and
resistance to wear. Chromium can dissolve in either
alpha- or gama-iron, but, in the presence of carbon, the
carbides formed are cementite (FeCr)3C in which
chromium may rise to more than 15%; chromium
carbides (CrFe)3C2 (CrFe)7C3 (CrFe)4C, in which
chromium may be replaced by a few per cent, by a
maximum of 55% and by 25% respectively. The chrome
steels are used wherever extreme hardness is required,
such as in dies, ball bearings, plates for safes, rolls, files
and tools. The combination of nickel and chromium
produces steels having all these properties, some
intensified, without the disadvantages associated with the
simple alloys. Molybdenum dissolves in both alpha- or
gama-iron and in the presence of carbon forms complex
carbides (FeMo)6C, Fe21Mo2C6, Mo2C. Molybdenum is
also a constituent in some high-speed steels, magnet
alloys, heat-resisting and corrosion-resisting steels.
Manganese
Nickel
Chromium
Molybdenum
Molybdenum dissolves in both alpha- and gama-iron and
in the presence of carbon forms complex carbides
(FeMo)6C, Fe21Mo2C6, Mo2C.
Molybdenum is similar to chromium in its effect on the
shape of the TTT-curve but up to 0,5% appears to be
more effective in retarding pearlite and increasing bainite
formation. Additions of 0,5% molybdenum have been
made to plain carbon steels to give increased strength at
boiler temperatures of 400°C, but the element is mainly
used in combination with other alloying elements.
Ni-Cr-Mo steels are widely used for ordnance, turbine
rotors and other large articles, since molybdenum tends to
minimize temper brittleness and reduces mass effect.
Molybdenum is also a constituent in some high-speed
steels, magnet alloys, heat-resisting and corrosion-
resisting steels.
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Vanadium
Tungsten
Silicon
C Si Mn
1. Silico-manganese 0,5 1,5 0,8
2. Silicon steel 0,07 4,3 0,09
3. Silichrome 0,4 3,5 8
Other elements
Copper
Cobalt
Boron.
Abstract:
Austenite-forming elements
The elements C, Ni and Mn are the most important ones in
this group. Sufficiently large amounts of Ni or Mn render a
steel austenitic even at room temperature. An example of
this is the so-called Hadfield steel which contains 13% Mn,
1,2% Cr and l% C. In this steel both the Mn and C take
part in stabilizing the austenite. Another example is
austenitic stainless steel containing 18% Cr and 8% Ni.
Ferrite-forming elements
The most important elements in this group are Cr, Si, Mo,
W and Al. The range of stability of ferrite in iron-chromium
alloys is shown in Figure 2. Fe-Cr alloys in the solid state
containing more than 13% Cr are ferritic at all temperatures
up to incipient melting. Another instance of ferritic steel is
one that is used as transformer sheet material. This is a
low-carbon steel containing about 3% Si.
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Carbide-forming elements
Several ferrite formers also function as carbide formers. The
majority of carbide formers are also ferrite formers with
respect to Fe. The affinity of the elements in the line below
for carbon increases from left to right.
Carbide stabilizers
The stability of the carbides is dependent on the presence of
other elements in the steel. How stable the carbides are
depends on how the element is partitioned between the
cementite and the matrix. The ratio of the percentage, by
weight, of the element contained in each of the two phases
is called the partition coefficient K. The following values are
given for K:
Al Cu P Si Co Ni W Mo Mn Cr Ti Nb Ta
0 0 0 0 0,2 0,3 2 8 11,4 28 Increasing
Malleable cast iron (i.e. white cast iron that is rendered soft
by a graphitizing heat treatment called malleablizing) must
not contain any Cr. Steel containing only Si or Ni is
susceptible to graphitization, but this is most simply
prevented by alloying with Cr.
Nitride-forming elements
All carbide formers are also nitride formers. Nitrogen may
be introduced into the surface of the steel by nitriding.
precipitation hardening.