RECORD CODE Form/PES-15 ISSUE DATE 15/12/14 PAGE 1

Inadvertent Mixing of Hazardous Chemicals

South Plants

To: Operations North, HSE & Laboratory Teams

CC:
Rehman Hanif (Sr. DM T&P)
M. Riaz Chaudhry (PM North& South)
Asad Waheed (DM-QHSET)
Process Engineering File

PREPARED BY REVIEWED BY REVIEWED BY

UF MS AS

Sr. Process Engineer UM- Process South UM- HSE

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REV#
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DATE
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DESCRIPTION
"l J I
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00 15-12-2014
01 26-09-2017 After updating all plants data against CAMEO Chemicals (Software)
 withemlsslcmsofNOx& Notpcsslble Noxarese11erlycorrci;lvetoeyes,skin&upon MSDSofHF
Hf MSDSofN02
Annex-1.1
Produc.,HF&NOxbyructionwithRockPhosphate.
Elcothermicgaseous MSDS60%HN03
El<othermicgaseous bothermicgaseous Gaseouse:itothennic Gaseousexothermic HF&Noxare~erlycorrosivetoeyM,~ln&upon
Elcotl>ermicgaseow.. reaction(corrosivc& Elcothermicga:s.eous Elcothermkg:iscous Exothermic gaseous Explo:;iveoothcrmic Gaseous exothermic
reaction(corr~& (corrosive&twck). reaction{eicpiosive& reaction(explosive& reaction(cxp!Mive& Exothermic reaction (corrcsive&lOllicl.
reaction(explosive) tol<k).Unst;;iblewhen reaction(<'llplosive) reaction{<'llplosive) reaction{IOMic)
toxic) Unst;;iblewhenheated. co.rr0<i~) corr~) twcic) Unst<ib1ewhen h".ied. React with ammoniato form ammonium Nitrate MSDSofAN
whichisexploslveathightemperatur"s

8mthermlcgaseous Exothermicga.eous El<othermicgaseous

Exothermicga.eous Exothermic gaseous Eiiothermicga>COuS Exothermicreaction(
reaction(corrosive& re•ttion(corrosive& reaction(corroslve& veryexothermltreactionofnltricacid with water
reution(corr~) reaction(ccrrosivc) reaction(com>si~) corrosive)
toxic) tO>Cic) toxic)

incompatible with organic

Exolhermicg\aseous Gaseousreaction Gaseous reaction 1.l)MSDSAC

reactiDfl(CO<rosivc& Elcothermic.ga>COus Reactwithammoniumc;irbon•tetoproduce
(corrosive&toxic)
Unst<Jblewhenhea!ed.
incompatiblewith organic
chemicals
(corr0<ive&toxic).
Unsbble when heated.
{ccrrosive&toxic).
Unsbblc when heated.
. ....
toxk!.Unstablewhen (ei<plosivc)
(corrosive&toxicf.
Unstable when heated.
(corrosive&twclc).
Unst..blewhen heated.
ammoniumnitrateandca!clumcarbonate
1.2)MSDSofAN
1.3)MSDSofCC

Ammonia is reactlvewith HN03/NHN03/N204/NO. 1.l) MSDS HN03.

Exothermlcga.eous ExothermicreattiDfl ExactRe<ictlon/Reactioncondi1onsandhealthelfec:u l.2)MSDSofAN
Exothermic reaction
readion(explosive) (e:itp!osive) notexactly~nown. 1.3) N204 MSDS

Exothermic gaseous
reaction(corrosive&
lOllic).Unstabl<=whcn
Exothermic gaseous
rc~ction (corrosive]
Not known
GaseoltSreaction
(corrosive&tru<kJ.
Unstlblewhenhcated.
Gaseous reaction
(c0<rosive&to•ic).
Unst..blewhenhcated.
Exothermicgaseous
reaction(ccrrosivc&
twcic).Unstablc:wh.en
Exothennicgaseous bothermicgaseous
1uction(cor«1$.ive)
Exothermicgaseous
reaction{explosive}.
(nplosive)
Exothcrmicg•seous
reaction(corrosive&
toxic).Unstablewhen
Gaseousreaction(toJCit&
COlrosi~).Unst:iblewhcn Exothermic reaction jcONosive&t011k:).
UMtablewhcnheatcd.
._,
Explosi~•e~ctionwithnitrates.Reactiondetai!not Annex·l
1 .. l)MSDSofAN

Exothermicga.eous
Exothermicgas.c:ous Exothermicg.a.eoltS Elcothermicgaseous Exothermicgaseous Ga.eousreaction(IO!licl.
(corrosive&toxic). (corrosive&toxic). Noreactlon reaction {corrosive & (corrosive&toxlc).
reactlon(corrosive) reaction(corrosi~) Flammable !exploslv<!)
Unm1blewhenheated. Unstablewhen heated. toxic) Unstable when heated

1.l)MSDSAC
reaction with ammonia producingammonium
l.2)MSOSofAN
l.3)MSDSofCC

Exothermicg\aseous Exolhermicgaseous Ei<othermicg\aseous

Exothermicga.eou~
Exothermic gaseous Exothermicgase<>us reaction(corrosi~& reaction(corrosive& Exothermicgaseous EicothermicgaseoltS &o~hermic gaseous Ga.eous reaction {loxkl. Exothermicgaseous &othermicgaseous reaction(corroslve&
Not known reaction(corrosive&
rcactlon{explosive) reactlon(corrosive) lOKic).Unstilblewhen toxic).Unstablewhen reattion{corrosive) Flammable reaction(explcsive) tD><icl.Unstablewhen
toKlc)
heated. heated.

Exothermicgaseous Exothermicg;Jseous Exothermicgaseous Exothermicgaseous Exothermicgaseous Elcothermicgaseous Exothermicgaseous Exothermicgaseous Exothermicgirs.eous

rnctiDfl(cxplosive)

No reaction

Eiiothermicg.;iseous Exothermicgaseous Exothermicg.aseous

Exothermicgaseous Exothermicgaseous Exothermicgneous
reattiDfl(cxplos.ive& reaction{corrosivc& reactiDfl{corrosivc& ~reaction
ruction{corros.ive) ruction(CO<rosive) reaction{corrosive) {corrosive)
corrosive\ toKic).Explosivc toxic)

Exothermicgaseous Exothermic reaction reactivl'withorganicmaterialbut ..xactreattlonls

Exothermicgaseous Exothermicreaction Gaseousreaction(toxic). Gaseousreaction(toxic). Exothermicgaseous
Exothermic reaction reaction(explosive). Exothermic reaction
lexplosive) Flammable fbmmabi.. reaclionj""plosive) (explosive) l.l)UreaMSDS
flammable

Exothermicgaseous Exothermicgaseous Exothermicgaseous Exothermicgaseous Decomposesoncontactwithwatertoproducenitric

Exothermicreaction Gaseous reaction Exothermicgaseous Exothermicgaseous Gaseous<'l!othermic
reaction(corrosive& reaction{corroslve& reaction(explosive). reaction{toxic& NO reaction l.l)N02MSDS
(nplosivc) (nplO"..;....,) (oplosive) reaclion(e><plosMo) reaclion(e><plosive)
toxic) toxic).El<plosive corrosive} N02isincompatiblewithhyd1ocarbonsandfuel

Exothennicgaseous
Gas.eousexothermlc
re;iction(exploslve).
reaction(toxic)

Exothermicgaseous
Gaseouse><othermic Exothermicgaseous Gaseousreaction Exothermicgaseous Exothermicgaseous Exothermicgaseous Exothermicgaseous Exothermicgaseous Exothermic gaseous GaseousreactK>n
reaction(corrosive& Exothermic.gaseous Exothennicgaseous
reaction(e><plosive& reaction(corrosivc& (corrosive&toKic). reaction(corrosive& reaction(corrosive& reaction(corrosive& reaction{toxic & reaction(corrosive& rl'aclion{corrosive& {corrosive&IOl!icj.
toxic).Unstablewhen
corrosive) toxic) Unstable when heated. toxic) =•"""'") toxic) toxic) Unstable when heated.
"""''
toxic}

Gaseousreaction(toxic& Exothermicgaseous
Exothermic reaction( Exothermicgaseous Exothermic gaseous
reaction [explosive & lcorrosive&toxic) corrosive).Unstablewhen reaction(corrosi~& (corrosive&toxic).
corrosive) (corrosive) 1.1IN02MSDS
to>!lc] Unstilblewhenheated. heated toxic) Unstable when heated.

Exothermicgaseous silicadlssolveinhydroflouricaddformingcorrosive Annex-l

Exothermic reaction reaction(corrosive& s•IJtontetrafluoridewhichiscorrosivetoeves,skln&l.l)SiF4MSDS
toxic) U?Qninhalation

Ellothennicg\a:s.eous
Gaseous1eaction Gaseous reaction Gaseous reaction
reaction(corrosive& Exothermicgaseous Exothermicreaction reacti.,.,withreduclngagent,ammonia&organic
(corrosivc&toxic). (corrosive&toxic). {c0<rosive&toxic). (CO<rosive&toxic). (ccrros.ive&to>cic}.
toxic).Ulllibblcwhcn {ttplosive) meterials l.l)MSDSofCN
Unstable when heated. Unstablewhen heated. Unst;iblewhenheated. Unstablewhen heated. Unstablewh"" beated.
 React with Nitric acid to form calcium nitrate
CC is reactive with Lime reactive with 1.1) MSDS CN.
No reaction No reaction No reaction not known & Carbon dioxide.
oxidizing agent, acids oxidizing agent 1.2) MSDS of C02
React with AN to form CAN fertilizer
1.3 MSDS of CAN
react violently with
CC is reactive with NA react violently with CAN is incompatible with Annex-1
No reaction reducing agents, strong not known Reaction with CAN is not known
oxidizing agent, acids reducing agents;ammonia strong acid 1.1) MSDS HN03.
base, organic material

NA react violently with ammonium nitrate is React with Nitric acid to form Ammonium Annex-1
CAN is incompatible with
No reaction reducing agents, strong reactive with reducing No reaction not known nitrate which is highly explosive. 1.1) MSDS HN03.
strong base
base, organic material agent;ammonia Reaction details with CAN is not known 1.2)NH4N03 MSDS

CAN is incompatible with CAN is incompatible with

No reaction No reaction Not possible not known Reaction with NA & Ammonia is not known
strong acid strong base

ammonium nitrate is
Lime reactive with Annex-1
No reaction reactive with reducing No reaction No reaction not known
oxidizing agent 1.1) MSDS NH3N03
agent;ammonia

react violently with

No reaction reducing agents, strong No reaction Not possible No reaction not known
base, organic material

not known not known not known not known not known not known