MTH-DPP-Y1718-W7

Assignment
Q121. The alkenes which are more CH3OH/H+
reactive than ethane for electrophilic (D) CH3-CH=CH-OCH3
addition reaction are H3C CH2 CH OCH3
(A) CH2=CH-Cl (B) CH3-O-CH=CH2 CH3

(C) CH3-CH=CH2 (D) CH2=CH-CHO

124. Three different alcohols (E), (F)
and (G) are synthesized from the
Q122: Which of the following same alkene (P) by using three
compounds will gave same major different reagents (I), (II), and (III)
product on acid catalysed hydration respectively as shown below. Identify
(A) (B) the reagents.
CH3 CH3
Ph C CH CH2 Ph CH C CH2
(I)
CH3 CH3 CH(OH)CH 2D (E)
(II)
CH CH3 OH (F)
(C) (D)
H3C Ph (III) CH2D
CH3
CHDCH2OH (G)
C C H3C C CH2
Ph CH3 CH
H3C
(A) (I) is D+/H2O;
(II) is 1. Hg(OAc)2, THF-H2O 2.
Q123: The correct products have been
NaBD4
reported in reactions.
(III) is 1. THF-B2D6; 2. H2O2, OH-
(HCl)g)(-100C)
(A) CH2=CH-CHO (B) (I) is 1. Hg(OAc)2, THF-H2O 2.
H2C CH2 CHO
NaBD4

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Cl (II) is D+/H2O
H2O/H2SO4 (III) is 1. THF- B2D6; 2. H2O2, OH-
(B) CH2=CH-COOH
H2C CH2 COOH (C) Products (E), (F) and (G) are formed
Cl
via free radical, carbocation and cyclic
CH3 carbonium ion intermediate
CH3OH respectively.
H3C C CH C CH3
H2SO4
(C) O (D) Products (E), (F) and (G) are formed
CH3 via mercury-bridged carbocation,
H3C CH CH C CH3 carbocation and fourcentre transition
OCH3 O
state respectively.

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MTH-DPP-Y1718-W7
Assignment
H , H2O FeCl3
125. Possible (A) +Br2-CCl4
products of the reaction will be
OH FeCl3
OH +Br2-CCl4
(B)
(B)
(A) FeCl3
OH OH +Br2-CCl4
(C)
(C) (D) FeCl3
CH3-CH=CH 2+Br2-CCl4
(D)
126. In which of the following
reaction(s), major product is formed 129. Consider the following addition
by the cyclic intermediate of reactive reaction on a pure enantiomer of the
intermediate? shown bromoalkene.
CH3
(A) + HCl H Br +HBr
CH=CH2
Product(s) What
+ Br 2 - H 2O
(B) is/are true regarding products of the
H2O NaBH4 above reaction?
+ (CF 3COO) 2Hg (A) Four stereoisomers of products of
(C)
the above reaction?
(B) A pair of enantiomers and a meso-
(D) +HBr
dibromide are formed
(C) Only a pair of diastereomers are
127. Which of the following is correct formed
statement about oxymercuration- (D) One of the product is meso-
Demercuration- dibromide
(A) In the Ist step oxymercuration 130. Identify the correct

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occurs i.e. water & Hg(OAc)2 add to
double bond
(B) In the IInd step demercuration
occurs i.e. NaBH4 reduces –HgOAc
group to hydrogen
(C) The net reaction is addition of
water according to Markonikoff rule
(D) Rearrangement takes place
128. In which of the following halogen
addition reaction, racemic mixture of
products is formed?
statement/statements :
(A) Alkynes are more reactive than
alkenes towards EAR.
(B) Alkynes are less reactive than
alkenes towards EAR.
(C) Alkynes decolourise Br2 water
(D) Addition of HBr to alkynes in
presence of peroxide proceeds via
Anti-Markownikoff’s rule
131. When But-2-yne is brominated, P
is formed. When But-2-yne is reacted

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MTH-DPP-Y1718-W7
Assignment
with HgSO4 + H2SO4, then Q is formed. HBr
Which statement is correct form. CH2=CH-CH=CH 2 H2 C CH CH CH3
(A) P will be 2,2,3,3- Br
Tetrabromobutane (I)
(B) Q will be Butan-2-one
(C) In the formation of P, Cyclic H2C CH CH CH3
intermediate is formed.
(D) In the formation of Q, Cyclic Br
intermediate is formed. (II)

Q132. What are the expected product(s) (A) At -800C, I is the major product
in the following reaction? (B) At room temperature, II is the
hv major product
+ NBS
CCl4 (C) Both of the products I and II are
always formed in comparable
(NBS=N-bromosuccinimide) amounts
Br (D) Product I isomerizes into II on
(A) Br heating above 400C
(B)
Br
135. The correct statement(s)
(D) Br regarding 1,2-butadiene(I) and 1,3-
(C) butadiene, (II) is/are
CH2=C=CH-CH3 CH2=C-CH=CH2
133. Predict product(s) in the reaction (I) (II)
(A) I has perpendicular pi planes
+ HBr while II has parallel pi planes
(B) Both gives the same product on
Br
adding 1.0 equivalent at HBr of -
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H
Br 800C
(B)
(A) Kinetically (C) I gives 2,2-dibromobutane while
Kinetically controlled II gives, 2,3-dibromobutane, when
controlled
reacted with excess of HBr at very
Br
low temperature
(D) Br (D) Both have same length of C=C
(C)
double bonds
Thermodynamically Thermodynamic
controlled -ally controlled 136. Addition of water over alkene
occur via
134. The correct statement(s)
regaring following reaction is/are

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MTH-DPP-Y1718-W7
Assignment
140. In which case rearrange product
(A) H2O/H+ will be major one,
(B) Hydroboration-axidation
HBr
(C) Oxymercuration-demercuration (A) H2O/H+
(D) Alkoxymercuration- (B)
demercuration Ph
CH3OH/H+ Br2
(C) (D)
137. Which statement is/are correct
for hydroboration oxidation.
(A) It is the addition of water over 141. Addition of HCl to 3,3-dimethyl-
alkene 1-butene yields two products, one of
(B) It proceeds via formation of 4 which has a rearranged carbon
membered cyclic TS skeleton. Among the following
(C) It follows Markowniff rule carbocations, select the possible
(D) Hydroboration oxidation over intermediates in that reactions?
propene leads to propan-1-ol as (A) (CH3)3CCHCH2Cl (B) (CH3)3CCHCH3
major product. (CH3)2CC(CH3)2
(D) (CH3)2CCH(CH3)2
138. In which case carbocation is not (C) Cl
formed as a reaction intermediate on
reaction over alkene.. 142. In the addition oh HBr to 1,3-
(A) Halogenation butadiene, one product is called the
(B) Acid hydration kinetic product & the other is called
(C) Oxymercuration-demercuration the thermodynamic product. Which of
(D) Hydroboration-oxidation the following descriptors applies to
the kinetic product?
139. In which case product is correct, (A) 1,2 product

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Cl (B) least stable wit less substituted
alkene
HOCl (C) formed fastest at low temperature
(A) OH
(D) bromide attack at more
NO
substituted site
NOCl
(B) Cl 143. Which of the following alkenes
I yield(s) 3-bromo-3-methylpentane as
the major product upon addition of
I-Cl
Cl
HBr?
(C)
CH3OH

H+ OCH3
(D)
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MTH-DPP-Y1718-W7
Assignment
The correct statements with respect
(B) to the above pair of reactions are that
(A) (A) The reactions are stereospecific
(B) (X) is meso and (Y) is racemic
(C) (D)
mixture
(C) (X) is racemic mixture and (Y) is
144.
CH3CHCH=CH2 CH3CH-CHCH3
meso
(D) each of (P) and (Q) gives a
A OH
mixture if (X) and (Y)
;
Reagent A may not be:
OH Br2 MeOH
(A) H2O/H+ (Q)
HBr + (P)
(B) BH3.THF/H2O2-OH- 147. Cl
(C) Hg(OAc) 2.H2O/NaBH4 product P,Q will be
(D) BH3. THF/H2O2-AcOH O O
Cl
(A) Br CH3
(B)
145. Which series of reactions will not P P
achieve the following transformation? O O
OCH3
Br (C) Br OCH3
1 2
(D)
Cl Q Q
Cl
(i)Cl2/CCl4 (i) HBr 148. Select the reaction(s) that would
result in the formation of 2-
(ii) Br2 (ii) Cl2/CCl4 bromopropane.
(A) (B)
peroxide
(i) Cl2/CCl4 (i) NBS (A) CH3CH=CH2+HBr
(ii) Cl2/CCl4 CCl4

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(ii) NBS
(C) (D) (B) CH3CH=CH2 + HBr
hv
146.
146. (C) CH3CH2CH3 + Br2
COOH Br
2 CCl4
HOOCCH(Br)CH(Br)COOH
HOOC CCl4 (D) CH3CH=CH2 + Br2

149. The major product of the

(P) (X)
reaction given below is:
Br2
Br2
OH
HOOC COOH HOOCCH(Br)CH(Br)COOH
CCl4 H2O
?
OH
(Q) (Y) (A) Br OH

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MTH-DPP-Y1718-W7
Assignment
Br
(B) HO OH
H
O
CH2-Br
(C)
CH2-Br
O
(D) H

150. Which of the following

compounds gives the same
carbocation on ionization?
Br

(A) Br (B)
Br CH2
(D) Br
(C)

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MTH-DPP-Y1718-W7
Assignment

(A) (B) 135° (C) 75° (D) 225°

60°

(A)
(B)
(C)
(D)

(A) (B) (C) (D)

(A) (B)
(C) (D)

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MTH-DPP-Y1718-W7
Assignment
hours. If the cars travel towards
each other, they meet in 1 hour.
What are the speeds of the two
cars?

Q2: Find the number of solution in

positive integers of 2x + 3y = 763 .

Q3: A reduction of 10% in the price

1
of sugar enables me to get 1
2
kg more for Rs.225. Find
the reduction price per kg.

Q4: If Joseph gets 71 on his next

test, his average will be 83. If
he gets 99, his average will be
87. How many tests has Joseph
taken so for.

Q5: Of 28 students taking atleast one

of Mathematics. English or
History, those students taking
only one subject are all taking
Mathematics. Of those students
taking exactlytwo of the three
subjects. it is known that the
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number

Q1: X is a two-digit number. Y is the

Q1: Points A and B are 100 km
apart on a highway. One car
starts from A and another from
B the same time. If the cars
travel in the same direction at a
constant speed they meet in 5
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number obtained by reversing the
digits of X. Which of the following is
true?
(A) X+Y is divisible by 10
(B) X-Y is divisible by 6
(C) X-Y is divisible by 9
(D) X+Y is divisible by 8
P-8
MTH-DPP-Y1718-W7
Assignment
Q2:
Q2: In what time will ₹ 1000 amount to
₹ 1331 at 10% per annum
compounded annually?
(A) 1 years (B) 2 years
(C) 3 years (D) 4 years

Q3: A quadrilateral has three acute

angles, each measuring 75° , find
the measure of the fourth angle.
(A) 60° (B) 135° (C) 75° (D) 225°

(A)
(B)
(C)
(D)

(A) (B) (C) (D)

(A) (B)
(C) (D)

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