PHYSICAL/INORGANIC

TARGET CH E MI S T RY
DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2015

DPP
COURSE NAME : UDAY (UB) DATE : 23.09.2013 to 28.09.2013 DPP NO. 34

* Marked Questions are having more than one correct option.

DPP No. # 34
1. The correct order of basic strength of given oxides is
(A) Na2O > MgO > Al2O3 > Cs2O (B) MgO > Al2O3 > Cs2O > Na2O
(C) Al2O3 > MgO > Cs2O > Na2O (D) Cs2O > Na2O > MgO > Al2O3

2. Which has maximum covalent character ?

(A) NaCl (B) MgCl2 (C) ACl3 (D) CaCl2

3. Which is the correct order of covalent character

(A) LiF < LiCl < LiBr < Lil (B) LiCl < LiF < Lil < LiBr
(C) Lil < LiBr < LiCl < LiF (D) Lil < LiCl < LiBr < LiF

4. Which is the correct order of solubility in water

(A) CsF > CsCl CsBr > Cs (B) LiF > LiCl > LiBr > Li
(C) RbCO4 > KCO4 > NaCO4 > LiCO4 (D) LiF > NaF > KF > RbF

5. Which of the following is the right order of lattice energy

(A) Na2 O < Al2O3 < MgO (B) MgO < Al2O3 < Na2O
(C) Al2O3 < MgO < Na2O (D) Na2O < MgO < Al2O3

6. If it is known that on heating a ionic compound of a polyhalide with a cation it decomposese into more
stable halide of that cation due to high lattice energy, for example
Cs3 
 Cs+ 2
The complex compound Rb[IBrCl] after strong heating will
(A) RbI + BrCl (B) RbCl + IBr (C) RbBr + ICl (D) None

7. Which of the following combination of ion will have highest polarisation

(A) Fe2+, Br– (B) Ni4+, Br– (C) Ni2+, Br– (D) Fe, Br–

8. Which of the following cannot be explained on the basis of Fajan’s Rules.

(A) Ag2S is much less soluble than Ag2O (B) Fe(OH)3 is much less soluble than Fe(OH)2
(C) BaCO3 is much less soluble than MgCO3 (D) Melting point of AlCl3 is much less than that of NaCl

9. Which of the following species does not obey octet rule ?

(A) SiF4 (B) PCl5 (C) ICl (D) BF4–

ANSWER KEY
DPP No. # 34

1. (D) 2. (C) 3. (A) 4. (A) 5. (D) 6. (B) 7. (B)

8. (C) 9. (B)

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