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Appendices

Appendix 1. Thermodynamic Data for Lead Compounds. H. Bode,


LeadeAcid Batteries, John Wiles & Sons, Inc., New York, USA, 1977,
p. 366, 367

Material DH (103 J/mol) DG (103 J/mol) S (103 J/mol) Cp (103 J/mol)
3PbO$PbSO4 1626.7 1427.5 340.6
PbO$PbSO4 1152.7 1016.3 217.4 150.2
2PbO$PbSO4 1358.5 1202.6 318.6 196.2
4PbO$PbSO4 1882.1 1595.3 435.6 287.9
3PbO$PbSO4$H2O 1668.5
5PbO$2H2O 1407.5
PbO$0$4H2O 281.5
Pb(OH)2 514.63 420.91 87.86
PbSO4 rhombic 919.94 813.20 148.57 103.21
PbO tet 218.99 188.95 66.52 45.82
PbO orthorhomb 217.32 187.90 68.70 45.77
H2O fluid 285.83 237.18 69.92 75.29
H2SO4 fluid 813.99 690.10 156.90 138.91
Pb2þ aq. 1.67 24.39 10.46
HPbO2 aq.
338.48

Appendix 2. X-ray Powder Diffraction Data for Battery Phases Pb


R.J. Hill, J. Power Sources 9 (1983) 55

2q d-Spacing I/I0 h k l
31.27 2.858 100.0 1 1 1
36.26 2.475 50.3 0 0 2
52.22 1.750 34.6 0 2 2

a-PbO

2q d-Spacing I/I0 h k l
17.64 5.024 2.6 0 0 1
28.62 3.117 100.0 0 1 1
(Continued)

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