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1. Consider the compound below: each of the gases in the mixture. (b) Calculate the
O total pressure of the mixture.
H H O H H
C8 8. (a) Place the following gasses inorder of increasing
H C1 C2 C3 C4 C7 H average molecular speed at 25°C: Ne, HBr, SO2,
NF3, CO. (b) Calculate the root mean square speed
H H H C5 C6 H
of NF3 molecules at 25°C.
H H
What is the hybridization of all the carbon atoms? 9. An unknown gas composed of homonuclear
What is the predicted bond angle at the carbon diatomic molecules effuses at a rate that is only
atoms? 0.355 times that of O2 at the same temperature.
Calculate the molar mass of the unknown, and
How many σ and π bonds are there?
identify it.
How many unshared electrons?
10. Cyanogen, a highly toxic gas, is composed of 46.2%
2. Choose which best exhibits the specified property.
C and 53.7% N by mass. At 25°C and 751 torr, 1.05
Stability: He2 or He2+ g of cyanogens occupies 0.500 L. (a) What is the
Paramagnetism: N2 or O2 molecular formula of cyanogen? (b) Predict its
Antibonding HOMO: F2+ or C2+ molecular structure. (c) Predict the polarity of the
Bonding LUMO: B2 or Ne2 compound.
Highest boiling point: H2O or H2S
H-bonding: NH2–NH2 or CH3F 11. Refer to the phase diagram below:
IMFA strength: H-bonding or ion-dipole
Doubly degenerate: π2p orbital or σ2p orbital
14. Given
H
H
C1 O
H C2
O3
H
a. What is the hybridization of C2 ?
b. What is the geometry with respect to O3?
c. What are the orbitals involved in overlap in
the C1 – C2 bond?
d. What is the bond angle along C1 – C2 – O3?
e. How many π bonds?
f. How many σ bonds?
g. Polarity of the molecule?