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Definitions
Adhesive (DIN EN 923)
is a non-metallic material that functions as a
bonding material via surface adhesion (adhesion) and
internal strength (cohesion).
Main Purpose: Transmission of force
Introduction
3
Adhesives – Possible Classifications
There are many possibilities to classify adhesives, depending on…
Specific Application
Strength Class
Outward Form
Setting Mechanism
4
Specific Applications
Organic Adhesives
Inorganic Adhesives
Natural Basis Artificial Basis
Silicones
(Compound with organic and inorganic characteristics)
Semi-Structural Bonds
(i.e. 2-C-PUR)
Fixation Bonds
(i.e. Fast-Setting Adhesive)
Elastic Bonds
(i.e. 1-C-PUR)
Sealing Bonds
(i.e. Acrylate-Sealant)
Source: TC Kleben
Elasticity 8
Outward Forms
2 Components 3 Components
1 Component (1C)
(2C) (3C)
Chemically Reacting
Physically Bonding
Cold Setting Hot Setting
Introduction
● Polyaddition Adhesives
● Polymerisation Adhesives
● Polycondensation Adhesives
14
2C-Adhesives in General
Two-Component-Adhesives
Processing
Mixing Ratio
Rate of Dilution
Pot Life
Means the time in which the completed adhesive mixture can be used, i.e. the
processing time at room temperature
Begins with the first encounter of the adhesive monomers
Ends when the curing process has gone so far that hardness and viscosity
have increased measurably and further processing is no longer possible
Time
[min]
Example according to
20 data sheet: 10 min at
20°C
Rule:
An increase in temperature
10 of 10°C reduces the pot life
to half
5
0 10 20 30 40
Temperature [°C]
Source: Kleben, Habenicht, Springer Verlag 17
Curing of 2C-Adhesives
Curing time Period of time that an adhesive needs to reach at least handling strength or,
at the latest, its final strength.
100%
Festigkeit
Gelpunkt
Gel point
0% Time
Handling
Strength Final
Strength
Pot life
Source: Kleben, Habenicht, Springer Verlag 18
Influence of the Temperature on Chemical Reactions
Influence of the temperature on the speed of reaction during the curing
process of reactive adhesives
The higher the temperature, the quicker the curing process will be
The lower the temperature, the slower the curing process will be
Reaktionsgeschwindigkeit
Rule:
An increase in temperature of
10°C reduces the pot life to half
and therefor doubles the speed of
reaction
Temperature
Source: Kleben, Habenicht, Springer Verlag 19
Types of Adhesives
Chemically Curing
Adhesives
Methyl
Polyurethanes MS- Polymeres
Methacrylates
Anaerobic
Phenolic Resins
Adhesives
Polyurethane
● 1C-Polyurethane
Formed
polymer chains ● 2C-Polyurethane
21
Epoxy Resins
Are called so, because they are made out of compounds with epoxy-groups
O Epoxy-group
HO H2N
H C C Alcohol Amine
H H
React with copmpounds that have H-atoms at O or N, i.e. alcohols and amines
After the reaction, there are no more epoxy-groups
H O 1 H O H
2 R 1
R O H C C H C C R
H 2
H R O H
2
R
O
H H
H H N H
2 1 C C
R N H C C R H C C H
O 1 H H 1 O
H H H R R
23
Epoxy Resins – Starting Compound
Bisphenol A as most important basic element
Oligomeric Epoxy Resin
Cure: Hot-setting
Structural bonds
Fields of application: (Automobiles and wind power
stations)
Source: Kleben, Habenicht, Springer Verlag 26
Polyurethanes – Reaction Mechanism
Are called so because the adhesive molecules contain urethane-groups
Basic materials are isocyanates und alcohols
O
H
C
2
R O
N 1
Alkohol R
Isocyanat
O
2 1
R C R
O N
Urethan H
27
2C-Polyurethanes – Reaction Mechanism
n HO – (CH2)X – OH + n O = C = N – (CH2)Y – N = C = O
Diol Diisocyanate
Addition Reaction
28
1C-Polyurethanes – Reaction Mechanism
Addition reaction
R N C O + H OH R N C OH
water
Isocyanate
(from the air or the
surface of the bonding H O
elements) Derivative of carbamide acid
decomposition (unstable)
reaction
R N C OH R NH2 + CO2
Amine Carbon dioxide
H O
Addition reaction
R NH2 + O C N R R N C N R
Amine Isocyanate
H O H
Substituted urea
29
1C-Polyurethanes – Characteristics
Monomer
Radical/Ion Monomer Monomer Monomer
P o l y m e r
32
Polymerization
A CC-double bond must be in the monomer molecule
Polyethylene Polypropylene
Radical Anion
PE PP
H N
H 2C CH2 C CH2 CH3 C
H CH2
H 3C C H 2C C H 2C C
C O C O
F F H O O
C C C CH2 CH3 CH3
F F Cl
Polytetrafluor- Polyvinyl chloride Polystyrene Polymethyl methyacrylate
Polymethyl cyanacrylate
ethylene (Teflon) PVC PS PMMA
33
Radical Polymerization
Start reaction
● Initiator molecule is split into two radicals
● Radical breaks open a multiple bond growable primary radical
Growth Reaction
● Radical reacts with monomer, takes electron from the double
● Repititious linkage of monomer to molecule chain
Termination Reaction
● Growth of polymer chain is disrupted, recombination of radicals
35
Radical Polymerization
Termination Reaction * + I* I
*+ *
36
Radical Polymerization
Growth:
37
Methyl Methacrylates – Characteristics
Strengtht: High
Gap bridging
Fields of Application:
(not by No-Mix)
H C≡N H C≡N
-
A–C–C C=C
H COOR H COOR
n
Polyalkylcyanacrylate
Room temperature,
Cure:
reacts quickly
Strength: High
Sensitive to humididty,not
Disadvantages:
temperature stable, brittle
Joining Element 1
Monomer + Accelerator
Joining Element 1
Joining Element 2
Advantages:
low thickness of adhesive layer (0,3 - 0,4 mm)
long pot life
Source: Kleben, Habenicht , Springer Verlag 45
Direct Addition of Hardener
The hardener is added to the monomer-accelerator mixture
shortly before application („mix-system“), comparable with 2C-
systems
Harder than paste or powder
Low degree of strength (1-3%) needs a good intermixture
Not suitable for monomers that react quickly
Monomer A Monomer B
P o l y m e r
+
Elimination
Products
47
Polycondensation Adhesives
Polyester
Phenolharze
Silicone
48
Polyester – Reaction Mechanism
Polyethylen
terephthalate
49
Polyester Resin
Disadvantages: Brittle
Bakelite
51
Phenolic Resins - Characteristics
2C, Duromere
Type of Polymer:
H 3C CH3 H 3C CH3
O CH3 O O CH3 O
H 3C Si O Si O Si CH3 H 3C Si O Si O Si CH3
O CH3 O CH3
H 3C n CH3 n
H 2O H 2O O O
H 3C CH3
O CH3 O CH3
H 3C Si O Si O Si CH3 H 3C Si O Si O Si CH3
O CH3 O O CH3 O
H 3C n CH3 H 3C n CH3
+ 4 H 3C O H
53
Silicones – Characteristics
Introduction
● Through Solidification
● Through Evaporisation
● Permanently Adhesive
● Through Gelling
Dispersion
Butyle rubber
Adhesives
Contact Adhesives
57
Physically Bonding Adhesives
Characteristics Hotmelts
Solvent-based
Adhesives
Dispersion
Sensitive
Adhesive
Butyle Rubber
Plastisols
Adhesives
Contact
Adhesives
Adhesive
Contact
Adhesive
Ingredients Effect on Characteristics
Adhesive
Contact
Adhesive
• no Solvents
• no mixing of components
Advantages • very short bonding periods
• thermically disconnectable and rebondable adhesion
Adhesive
Contact
Adhesive
Hotmelt is applied
joining elements
to joining elements are fixated
61
Physically Bonding Adhesives
Adhesive
Cotact
Adhesive
Pressure
Influence of temperature on the evaporization of solvent Hotmelts Solvent-Based Sensitive
Adhesive
Plastisols
100 [%]
Amount of solvent in the adhesive
layer
Room temperature
Higher temperature
Time t
Source: Kleben, Habenicht, Springer Verlag 63
Physically Bonding Adhesives
Characteristics Hotmelts
Solvent-Based
Adhesive
Dispersion
Sensitive
Adhesive
Butyle Rubber
Plastisols
Adhesive
Contact
Adhesive
Polymers (PVA, Acrylate, PU) are, as solid particles, in a watery dispersion agent
Bonding via the evaporization of the water, or rather the intrusion into the joining
elements
Not suitable for materials with even or non-permeable surfaces
Hardening period increases with the degree of humididty of the joining elements, as
this prolongs the evaporization of the water from the dispersion
Mainly used for wooden materials
Advantage: Water used as solvent cheap and non-toxic
Disadvantage: Sensitive to frost, cannot be used after defrosting
Adhesives
Contact
Adhesives
Formation of film (adhesive layer) Polymer particles flow into each other
Adhesive
Contact
Adhesive
Permanently
Dispersion Adhesives –
Solidification Evaporization Gelling
Adhesive
Pressure
Hotmelts Solvent-Based Sensitive Plastisols
Selected basic polymers and there appplication Adhesives
Dispersion
Adhesive
Butyle Rubber
Adhesives
Contact
Adhesives
Adhesives
Contact
Adhesives
Polymers such as rubber and polyurethane are suitable for contact adhesives
Adhesive is contained within an adhesive
Solvent needs to evaporate completely before the joining elements can be fixated
seemingly dry adhesive films on the surfaces of the joining elements
Joining elements bonded through high pressure which leeds to a bond with high strength
Processing of contact adhesives:
● One-sided joining (wet bonding): Adhesive is applied only to one joining element (only possible
with materials that are permeable for solvents)
● Two-sided-joining (contact adhesion): Adhesive is applied to both joining elements, airing of the
joint area, pieces are pressed together within the processing time
Consist of polymers that are permanently adhesive and that are applied onto support
materials
Elements of adhesive tapes
Polymers like rubber plus waxes and resins
Exemplary support materials: Glass fabric, synthetic materials /metal foil, paper
Adhesion achieved through pressure formation of adhesion forces
Appliance to support material through
● Radiation hardening of reactive solvent-free systems
● Appliance with organic solvents
● Application as melt
Characteristics
High adhesiveness
Good sealing qualities and therefore low gas permeability
Absorbs vibrations and shocks
Resistance to acids and bases
Good resistance to weather and ozone
High electrical insulation properties
Can be bought as sealant, adhesive tape or injectable material
Is used in air pipes, inner sides of tyres, bladders, seals
Plastisols – Sol-Gel-Process
Pressure
Solvent-Based Sensitive Plastisols
Hotmelts
Adhesive Adhesive
Dispersion Butyle Rubber
Adhesive
Two-phase system (Sol) is changed into an Contact
Adhesive
one-phase system (Gel) through the
absorbtion of softeners
Sol-Gel-Process at
160 to 180 °C:
Pre-gelling at 100 to
Transformation of
120°C
fluid sol into hard,
irreversible gel
Source: Kleben, Habenicht, Springer Verlag 72
Agenda
Introduction
73
Procedure
1. Defining of requirements
2. Systematic search for types of adhesives
3. Evaluation of the considered adhesives
4. Search for specific products (producer of the adhesive)
5. Possibly verification of the adhesive with the specification sheet