Beruflich Dokumente
Kultur Dokumente
June 2014
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Summer 2014
Publications Code UA038324
All the material in this publication is copyright
© Pearson Education Ltd 2014
PMT
Examiners should look for qualities to reward rather than faults to penalise.
This does NOT mean giving credit for incorrect or inadequate answers, but it
does mean allowing candidates to be rewarded for answers showing correct
application of principles and knowledge. Examiners should therefore read
carefully and consider every response: even if it is not what is expected it may
be worthy of credit.
/ means that the responses are alternatives and either answer should receive
full credit.
( ) means that a phrase/word is not essential for the award of the mark, but
helps the examiner to get the sense of the expected answer.
Phrases/words in bold indicate that the meaning of the phrase or the actual
word is essential to the answer.
ecf/TE/cq (error carried forward) means that a wrong answer given in an
earlier part of a question is used correctly in answer to a later part of the
same question.
Candidates must make their meaning clear to the examiner to gain the mark.
Make sure that the answer makes sense. Do not give credit for correct
words/phrases which are put together in a meaningless manner. Answers
must be in the correct context.
6CH04_01
1406
PMT
6 (a) B 1
6CH04_01
1406
PMT
Section B
6CH04_01
1406
PMT
OR
OR
OR
Number of mol(es)/molecules
decreases
OR
‘(Positive) Answer
is as expected...’
(0)
6CH04_01
1406
PMT
OR
= +2152 + (-108.1)
= (+)2043.9
3SF
6CH04_01
1406
PMT
OR
= −641.296
ALLOW
Note
6CH04_01
1406
PMT
ALLOW
4.725 kJ
(−)4725 ÷ 0.0300
OR
(−)4725 ÷ 0.0500
ALLOW
Value (1)
Sign (1)
6CH04_01
1406
PMT
First mark
For example,
(−1920) = −763.5
OR
(−1920) = −700.5
ALLOW
Third mark
OR
6CH04_01
1406
PMT
ALLOW
TE from (d)(ii)
6CH04_01
1406
PMT
Cl-.H2O
OR
6CH04_01
1406
PMT
First mark
OR
OR
OR
OR
OR
ALLOW
6CH04_01
1406
PMT
OR
ALLOW
Reflux/distil
ALLOW
OR
6CH04_01
1406
PMT
ALLOW
(1)
CH3C=O reaction with iodine in
alkali/NaOH/KOH/OH-
ALLOW
Iodoform/tri-iodomethane/haloform
AND
reaction/test
(1)
Note
Examples:
6CH04_01
1406
PMT
ALLOW
Note
6CH04_01
1406
PMT
OR C=O is planar
Carbonyl bond is
Carbonyl group/reaction site is planar
(trigonal) planar
Intermediate is
OR planar
OR
6CH04_01
1406
PMT
ALLOW
OH absorptions similar/the same.
ALLOW
Correct number followed by ,
eg 3
ALLOW
No adjacent/neighbouring
hydrogens/protons
6CH04_01
1406
PMT
ALLOW
6CH04_01
1406
PMT
ALLOW multiples
OR
ALLOW
…quicker
ALLOW
OR
6CH04_01
1406
PMT
First mark
Correct graph of rate v concentration,
Note
Linear scales
6CH04_01
1406
PMT
OR
Just ‘as
As concentration increases by (factor of) concentration
2 rate increases by 2 (or any other increases rate
numbers, including ‘x’) increases’
OR
OR
TE from (c)(ii)
ALLOW
6CH04_01
1406
PMT
First mark
Gradient = − Ea/R
OR
Ea = − R x gradient (1)
Second mark
(Gradient =) -3.0-(-3.69)
(3.30-3.41) x 10−3
OR
= -6272.7 (K)
Method 2
First mark
OR
Two negative signs clearly cancel in method
and no sign given (1)
6CH04_01
1406
PMT
OR
Repeat at the same two temperatures
ALLOW
6CH04_01
1406
PMT
Section C
ALLOW
OR
6CH04_01
1406
PMT
OR
To maintain a closed system
OR
To maintain a closed environment
ALLOW
To prevent:
OR
Due to volatility (of chemicals)
IGNORE
…gas escaping
…HCl escaping
6CH04_01
1406
PMT
Third mark
Sodium ethanoate is (slightly) alkaline
OR
Ethanoic acid is a weak acid
OR
Phenolphthalein pH range coincides with
vertical section of the pH/titration curve
OR
Titration of weak acid with strong base
OR
Neutralisation/equivalence point is at 8-
10/ any number between 8 and 10.
OR
pKin +/-1 lies within vertical region
(1)
Third mark is independent
6CH04_01
1406
PMT
ALLOW
Single arrow
-CO2H
-C2H5
Displayed formulae
Ignore SF except 1
TE same as (ii)
6CH04_01
1406
PMT
= 0.02692 x 0.02692
0.01308 x 0.01308
= 4.23579 = 4.24
(1)
Ignore SF except one
6CH04_01
1406
PMT
OR
addition/elimination
ALLOW
Condensation (1)
OR
ALLOW
OR
OR
IGNORE
Dynamic equilibrium
OR
6CH04_01
1406
PMT
OR
Protonates... Protates
OR
Protonating agent...
OR
Donates protons
OR
Increases H+ concentration
6CH04_01
1406
PMT
6CH04_01
1406