SAFETY DATA SHEET

Issue date 26-Dec-2014 Revision Date 28-Apr-2016 Version 3

Section 1: PRODUCT AND COMPANY IDENTIFICATION

Product identifier
Product name ThreeBond 2706

Recommended use of the chemical and restrictions on use

Recommended use Cleaner

Details of the supplier of the safety data sheet

Manufacturer Department in charge & Address
ThreeBond Fine Chemical Co., Ltd. Production Engineering Division
1-1 Oyama-cho, Midori-ku
Sagamihara-shi, Kanagawa, Japan

Emergency telephone number

+81-42-774-1333

Section 2: HAZARDS IDENTIFICATION

Classification of the substance or mixture
Flammable Aerosols Category 1
Flammable liquids Category 2
Skin corrosion/irritation Category 2
Germ cell mutagenicity Category 1B
Carcinogenicity Category 1A
Reproductive Toxicity Category 1A
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Category 2 liver.
Aspiration toxicity Category 1
Acute aquatic toxicity Category 3
Chronic aquatic toxicity Category 2

Label elements

Signal word Danger

Hazard statements

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H222 - Extremely flammable aerosol

H229 - Pressurized container: May burst if heated
H225 - Highly flammable liquid and vapor
H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H340 - May cause genetic defects
H350 - May cause cancer
H360 - May damage fertility or the unborn child
H373 - May cause damage to organs through prolonged or repeated exposure
H402 - Harmful to aquatic life
H411 - Toxic to aquatic life with long lasting effects
H335 - May cause respiratory irritation
H336 - May cause drowsiness or dizziness
May cause damage to the following organs through prolonged or repeated exposure: liver.

Precautionary Statements - Prevention

•Obt ainspeci alinst ructionsbef oreuse
•Donothandl eunt ilallsaf etypr ecautionshav ebeenr eadandunder stood
•Useper sonalpr otect iv
eequi pmentasr equi r
ed
•Washf ace,handsandanyex posedski nt horoughl yaft
erhandli
ng
•Donotbr eathedust /f
ume/ gas/ mi st/
vapor s/spray
•Useonl yout door sori nawel l-vent i
l
atedar ea
•Av oidr eleaset ot heenv ironment .
•Keepawayf rom heat /
spar ks/ openf lames/ hotsur faces.— Nosmoki ng
•Donotspr ayonanopenf l
ameorot herigni t
ionsour ce
•Pressur izedcont ainer :Donotpi erceorbur n,ev enaf t
eruse
Precautionary Statements - Response
•IFex posedorconcer ned:Getmedi caladv i
ce/att
ent i
on
•Forf irstai dpr ocedur e,refert ot hisSDS.
•IFONSKI N:Washwi t
hpl ent yofsoapandwat er
•Ifskini rrit
ationoccur s:Getmedi caladv ice/attent
ion
•Takeof fcont ami nat edcl othingandwashbef orer euse
•IFI NHALED:Remov ev i
ct i
mt of reshai randkeepatr estinaposit
ioncomf ort
abl
eforbr
eat
hing
•IFSWALLOWED:I mmedi at elycal laPOI SONCENTERordoct or/
physi ci
an
•DoNOTi nducev omi ti
ng
•Col l
ectspi l
lage
Precautionary Statements - Storage
•Stor el ockedup
•Stor ei nawel l-vent i
latedpl ace.Keepcont ainertightl
yclosed
•Prot ectf rom sunl ight .Donotex poset otemper aturesexceeding50° C/122°F
Precautionary Statements - Disposal
•Disposeofcont ent s/cont ainert oanappr ovedwast edisposalpl
ant

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Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Effective June 1, 2016, regarding Japan’s Industrial Safety and Health Law’s
Single substance or mixture Mixture “Notifiable Dangerous and Harmful ”, target substances will be subjected to risk
assessment in accordance with Japan’s Industrial Safety and Health Law’s “Harmful
Substances Whose Names Are to be Indicated on the Label.”
Chemical name Weight-% ENCS ISHL No. CAS No.
Ethyl alcohol 1-10 (2)-202 - 64-17-5
Hexane 3.0 (2)-6 - 110-54-3
Carbon dioxide 1-10 (1)-169 - 124-38-9
Acetone <5 (2)-542 - 67-64-1
Isohexane 55-65 - - -
Butane 15-25 - - -

Pollution Release and Transfer Registry

Class Chemical Name in Regulation (Metal Name) Ordinance Number
First Class Designated Chemical n-Hexane - 392
Substances (Law Art. 2-2,
Enforcement Order Art. 1 Attached
Table No.1)

Industrial Safety and Health Law

Law Name Chemical Name in Regulation Ordinance Number
Harmful Substances Whose Names Are to be Acetone 1-3
Indicated on the Label (Law Art.57, Para.1,
Enforcement Order Art.18)
Harmful Substances Whose Names Are to be n-Hexane 27
Indicated on the Label (Law Art.57, Para.1,
Enforcement Order Art.18)
Notifiable Substances (Law Art.57-2, Acetone 17
Enforcement Oder Art.18-2 Attached Table No.9)
Notifiable Substances (Law Art.57-2, Ethanol 61
Enforcement Oder Art.18-2 Attached Table No.9)
Notifiable Substances (Law Art.57-2, Butane 482
Enforcement Oder Art.18-2 Attached Table No.9)
Notifiable Substances (Law Art.57-2, Hexane 520
Enforcement Oder Art.18-2 Attached Table No.9)

Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc
Law Name Chemical Name in Regulation Ordinance Number
Priority Assessment Chemical Substances (Law n-hexane 3
Article 2, Para.5)
Priority Assessment Chemical Substances (Law Acetone 114
Article 2, Para.5)

Section 4: FIRST AID MEASURES

INHALATION Move victim to fresh air If breathing is irregular or stopped, administer artificial respiration
Administer oxygen if breathing is difficult

Skin contact In case of contact with liquefied gas, thaw frosted parts with lukewarm water

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing Seek immediate medical attention/advice.

INGESTION Do NOT induce vomiting

Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.

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Note to physicians Keep victim warm and quiet.

Section 5: FIRE FIGHTING MEASURES

Flammable properties Containers may explode when heated.

Suitable extinguishing media Use extinguishing agent suitable for type of surrounding fire Dry chemical or CO2 Water
spray, fog or regular foam Move containers from fire area if you can do it without risk
Damaged cylinders should be handled only by specialists

Specific hazards arising from the Some may burn but none ignite readily Ruptured cylinders may rocket
chemical

Special extinguishing media Keep container away from fire.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions Do not touch or walk through spilled material Stop leak if you can do it without risk

Environmental precautions Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to
contact spilled material Prevent entry into waterways, sewers, basements or confined areas

Methods for containment If possible, turn leaking containers so that gas escapes rather than liquid Allow substance
to evaporate

Methods for cleaning up Do not direct water at spill or source of leak.

Prevention of secondary hazards Keep ignition source away from spill.

Section 7: HANDLING AND STORAGE

Handling
Precautions for safe handling
Advice on safe handling Take equipment measures listed in Section 8. Wear protection gear.

Local and general ventilation Take equipment measures listed in Section 8. Wear protection gear.

Storage
Storage conditions Avoid direct sun light. Keep at 40C or below. avoid humid and/or rusty places. Fire
prohibited

Material of vessels and Keep this product in original container. Do not put it back in the container.
packaging

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Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure guidelines

Chemical name Japan ISHL Working Environmental ACGIH TLV

Evaluation Standards -
Administrative Control Levels
Ethyl alcohol - - STEL: 1000 ppm
Hexane TWA: 40 ppm ISHL/ACL: 40 ppm TWA: 50 ppm
TWA: 140 mg/m3 Skin
Skin
ISHL/ACL: 40 ppm
Carbon dioxide TWA: 5000 ppm - STEL: 30000 ppm
TWA: 9000 mg/m3 TWA: 5000 ppm
Acetone TWA: 200 ppm ISHL/ACL: 500 ppm STEL: 750 ppm
TWA: 470 mg/m3 TWA: 500 ppm
ISHL/ACL: 500 ppm

Engineering controls Install local ventilation or seal source of substances. Install safety shower, hand wash, and
eye wash station. Clearly indicate the location.

Personal protective equipment

O Respiratory protection In case of inadequate ventilation wear respiratory protection

O Hand protection Wear appropriate protection glove (Made from non-permeable material such as
polyethylene, rubber)
O Eye/face protection Wear safety glasses with side shields (or goggles)
O Skin and body protection Wear protection apron, protection boots. Wear long sleeve cloth.

Other information Wash hands thoroughly after handling. When using do not eat, drink or smoke.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid
Odor Solvent odor
Color Transparent clear

Property Values Remarks

pH No data available
Melting point/freezing point No data available
Boiling point / boiling range No data available
Flash point -20 °C Seta closed cup
Evaporation rate No data available
Flammability (solid,
gas)
Flammability limit in air
Upper flammability limit: No data available
Lower flammability limit: No data available
Specific gravity 0.66
Water solubility
Autoignition temperature No data available
Decomposition temperature No data available
Dynamic viscosity No data available

Section 10: STABILITY AND REACTIVITY

Stability Stable under normal conditions.

Possibility of hazardous reactions React with strong acid. Could cause fire.

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Conditions to avoid Heat

Incompatible materials Strong oxidizing agents.

Hazardous decomposition products May generate harmful gas by incineration

Section 11: TOXICOLOGICAL INFORMATION

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document
Inhalation LC50 No data available as this product.

Numerical measures of toxicity - Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

Ethyl alcohol = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h
Hexane = 25 g/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h
Acetone = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation No data available as this product.

Serious eye damage/eye irritation No data available as this product.

Sensitization No data available as this product.

Germ cell mutagenicity No data available as this product.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen

Chemical name Japan IARC

Ethyl alcohol Group 1

Reproductive toxicity No data available as this product.

STOT - single exposure No data available as this product.

STOT - repeated exposure No data available as this product.

Aspiration hazard No data available as this product.

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity
Acute aquatic hazard No data available as this product.

Chronic aquatic hazard No data available as this product.

Ecotoxicity Harmful to aquatic life Toxic to aquatic life with long lasting effects

Chemical name Algae/aquatic plants Fish Crustacea

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Ethyl alcohol - 100: 96 h Pimephales promelas 2: 48 h Daphnia magna mg/L

mg/L LC50 static 12.0 - 16.0: 96 EC50 Static 10800: 24 h
h Oncorhynchus mykiss mL/L Daphnia magna mg/L EC50
LC50 static 13400 - 15100: 96 h 9268 - 14221: 48 h Daphnia
Pimephales promelas mg/L magna mg/L LC50
LC50 flow-through
Hexane - 2.1 - 2.98: 96 h Pimephales >1000: 24 h Daphnia magna
promelas mg/L LC50 mg/L EC50
flow-through
Acetone - 6210 - 8120: 96 h Pimephales 10294 - 17704: 48 h Daphnia
promelas mg/L LC50 static 4.74 magna mg/L EC50 Static 12600
- 6.33: 96 h Oncorhynchus - 12700: 48 h Daphnia magna
mykiss mL/L LC50 8300: 96 h mg/L EC50
Lepomis macrochirus mg/L
LC50

Persistence and degradability No data available as this product.

Bioaccumulation No data available as this product.

Mobility in soil No data available as this product.

Endocrine disruptor information No data available as this product.

Section 13: DISPOSAL CONSIDERATIONS

Waste from residues / unused Dispose of in accordance with national, state and local regulations. Consult industrial waste
products managent companies for waste. Do not release this product to natural environment nor
reclaim.

Contaminated packaging Dispose containers as same as residual of this product.

Section 14: TRANSPORT INFORMATION

IMDG
UN/ID No. UN1950
Proper shipping name Aerosols
Hazard class 2.1
EmS-No F-D, S-U
Marine pollutant P

ICAO/IATA (air)
UN/ID No. UN1950
Proper shipping name Aerosols
Hazard class 2.1

ADR
UN/ID No. UN1950
Proper shipping name Aerosols
Hazard class 2.1
ERG code 10C

Japanese regulations
UN Number UN1950
Proper shipping name Aerosols
Hazard class 2.1
Subsidiary hazard class SP63
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Marine Transportation Safety High Pressure Gases (Ministry of Transportation Ordinance Regarding Transport by Ship
Act and Storage, Ordinance Art.3, Attached Table 1)
Civil Aeronautics Act Comply with aviation regulations.

Section 15: REGULATORY INFORMATION

Effective June 1, 2016, regarding Japan’s Industrial Safety and Health Law’s “Notifiable Dangerous and Harmful ”, target
substances will be subjected to risk assessment in accordance with Japan’s Industrial Safety and Health Law’s “Harmful
Substances Whose Names Are to be Indicated on the Label.”
Fire protection law criteria Group 4 - Petroleums - 1st Class(not Water solubility)

Act on the Evaluation of Chemical Priority Assessment Chemical Substances (Law Article 2, Para.5)
Substances and Regulation of Their
Manufacture, etc

Industrial Safety and Health Law Harmful Substances Whose Names Are to be Indicated on the Label (Law Art.57, Para.1,
Enforcement Order Art.18)
Notifiable Substances (Law Art.57-2, Enforcement Oder Art.18-2 Attached Table No.9)

Act on Confirmation, etc. of Release First Class Designated Chemical Substances (Law Art. 2-2, Enforcement Order Art. 1
Amounts of Specific Chemical Attached Table No.1)
Substances in the Environment and
Promotion of Improvements to the
Management Thereof

Section 16: OTHER INFORMATION

Issue date 26-Dec-2014

Other information Please contact to local sales offices for further information.

Disclaimer
Handle with care. The data in this document is not guaranteed. This information may be revised based on new findings or test
results. This data sheet is authored in accordance with Japanese regulations.

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