DIAGRAMA ENTALPÍA-CONCENTRACIÓN

40000.00
38000.00
36000.00
34000.00
32000.00
30000.00
28000.00
26000.00
24000.00
22000.00
H (cal/mol)

20000.00
18000.00
16000.00
14000.00
12000.00
10000.00
8000.00
6000.00
4000.00
2000.00
0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

X oY
A-CONCENTRACIÓN

0.5 0.6 0.7 0.8 0.9 1

oY
 DIAGRAMA ENTALPÍA-CONCENTRACIÓN PARA SISTEMA BENCENO-TOLUENO

ECUACIÓN DE ANTOINE:
COMPONENTE A B C RANGO T(°C) T(°C) P (kPa)
BENCENO 13.7819 2726.81 217.572 6-104 80.1 41826.1825
TOLUENO 13.932 3056.96 217.625 13-136 110.8 42078.5332

T(°C) PA* (kPa) PB* (kPa) Xa Ya

110.8 300519.64 42078.5332 1.044613E-10 7.460497E-10 PT ( kPa)
108 254950.675 34996.3727 0.032198327 0.195087246
106 226301.54 30620.0156 0.058556972 0.314923834
104 200574.126 26746.4549 0.088202748 0.420432649
102 177503.235 23323.4045 0.121644502 0.513142713
100 156844.468 20303.3955 0.159476832 0.59443752
98 138372.887 17643.3959 0.202395762 0.665567066
96 121881.734 15304.4545 0.251217508 0.727659052
94 107181.223 13251.3685 0.306900982 0.78172931
92 94097.3823 11452.3718 0.370574838 0.828691487
90 82470.9602 9878.84604 0.443570043 0.869366029
88 72156.3903 8505.0504 0.527459169 0.904488506
86 63020.808 7307.8708 0.624103918 0.934717306
84 54943.1233 6266.58712 0.735712705 0.960640754
82 47813.1449 5362.65747 0.864910581 0.982783661
80.1 41826.1825 4616.04158 1.006781774 1.000743965

CÁLCULO DE LAS CAPACIDADES CALORIFICAS LÍQUIDO

COMPONENTE A B C D R (J/mol*K)
BENCENO(A) -0.747 6.80E-02 -3.78E-05 0
TOLUENO(B) 15.133 6.79E-03 1.64E-05 0

CALORES LATENTES DE VAPORIZACION

COMPONENTE C1 C2 C3 C4 C5 Tc (K)
BENCENO(A) 4.53E+07 0.39053 0 0 0 562.05
TOLUENO(B) 4.95E+07 0.37742 0 0 0 591.75

CÁLCULO DE LAS CAPACIDADES CALORIFICAS VAPOR

COMPONENTE A B C D
BENCENO(A) -0.206 3.91E-02 -1.33E-05 0
TOLUENO(B) 0.29 4.71E-02 -1.57E-05 0
 CALCULO DE h (LÍQUIDO)
T(°C) T(K) XA CpLA (J/mol*K) CpLB (J/mol*K) h (cal/mol) Tref (K)
110.8 383.95 1.0446E-10 1.64E+02 1.68E+02 5143.16
108 381.15 0.03219833 1.64E+02 1.67E+02 4658.34
106 379.15 0.05855697 1.63E+02 1.67E+02 4313.19
104 377.15 0.08820275 1.62E+02 1.66E+02 3969.04
102 375.15 0.1216445 1.62E+02 1.66E+02 3625.95
100 373.15 0.15947683 1.61E+02 1.66E+02 3283.98
98 371.15 0.20239576 1.60E+02 1.65E+02 2943.25
96 369.15 0.25121751 1.60E+02 1.65E+02 2603.91
94 367.15 0.30690098 1.59E+02 1.65E+02 2266.17
92 365.15 0.37057484 1.58E+02 1.65E+02 1930.28
90 363.15 0.44357004 1.58E+02 1.64E+02 1596.63
88 361.15 0.52745917 1.57E+02 1.64E+02 1265.67
86 359.15 0.62410392 1.56E+02 1.64E+02 938.05
84 357.15 0.73571271 1.56E+02 1.63E+02 614.57
82 355.15 0.86491058 1.55E+02 1.63E+02 296.29
80.1 353.25 1.00678177 1.54E+02 1.63E+02 0.00

CALCULO DE H (VAPOR)
T(°C) T(K) YA CpVA (J/mol*K)CpVB (J/mol*K) Tra Trb lab (J/mol)
110.8 383.95 7.4605E-10 1.07E+02 1.33E+02 0.68312428 0.64883819 28948.1725
108 381.15 0.19508725 1.06E+02 1.33E+02 0.67814251 0.64410646 29125.0618
106 379.15 0.31492383 1.06E+02 1.32E+02 0.67458411 0.64072666 29250.392
104 377.15 0.42043265 1.05E+02 1.31E+02 0.67102571 0.63734685 29374.8896
102 375.15 0.51314271 1.05E+02 1.31E+02 0.66746731 0.63396705 29498.5692
100 373.15 0.59443752 1.04E+02 1.30E+02 0.6639089 0.63058724 29621.4448
98 371.15 0.66556707 1.04E+02 1.30E+02 0.6603505 0.62720744 29743.5301
96 369.15 0.72765905 1.03E+02 1.29E+02 0.6567921 0.62382763 29864.8382
94 367.15 0.78172931 1.03E+02 1.28E+02 0.6532337 0.62044782 29985.3822
92 365.15 0.82869149 1.02E+02 1.28E+02 0.6496753 0.61706802 30105.1747
90 363.15 0.86936603 1.02E+02 1.27E+02 0.64611689 0.61368821 30224.2278
88 361.15 0.90448851 1.01E+02 1.27E+02 0.64255849 0.61030841 30342.5535
86 359.15 0.93471731 1.01E+02 1.26E+02 0.63900009 0.6069286 30460.1635
84 357.15 0.96064075 1.00E+02 1.25E+02 0.63544169 0.6035488 30577.069
82 355.15 0.98278366 9.97E+01 1.25E+02 0.63188328 0.60016899 30693.281
80.1 353.25 1.00074396 9.92E+01 1.24E+02 0.6285028 0.59695817 30803.0501

XA YA x y
1.0446E-10 7.4605E-10 0 0 Diagra
0.03219833 0.19508725 0.1 0.1 1
0.05855697 0.31492383 0.2 0.2
0.9
0.08820275 0.42043265 0.3 0.3
0.8
0.1216445 0.51314271 0.4 0.4
0.7
0.15947683 0.59443752 0.5 0.5
0.6
0.5
Y

0.4
0.3
 0.9
0.8
0.7
0.6
0.20239576 0.66556707 0.6 0.6
0.25121751 0.72765905 0.7 0.7 0.5

Y
0.30690098 0.78172931 0.8 0.8 0.4
0.37057484 0.82869149 0.9 0.9 0.3
0.44357004 0.86936603 1 1 0.2
0.52745917 0.90448851 0.1
0.62410392 0.93471731 0
0.73571271 0.96064075 0 0.1 0.2 0.3 0.4

0.86491058 0.98278366 Datos generados para

1.00678177 1.00074396 la línea de 45°
A BENCENO-TOLUENO

Ecuación de Antoine

42078.5332 Dia
120

Ecuaciones de composiciones
tomadas de la ley de Dalton para 90
XA y ley de Raoult para YA

T (°C)
60

30

0
0 0.1 0.2 0.3 0.

8.314
Ecuación de capacidad calorífica
para líquidos

Ecuación del calor latente de

vaporización

Ecuación de capacidad calorífica

para gases
 353.25

Ecuación para líneas de

entalpía en fase líquida

lbb (J/mol) lb' (J/mol) H (cal/mol)

33352.7744 3.44E+04 37446.51
33521.6851 36408.63
33641.4814 35751.77
33760.578 35155.93
33878.9856 34613.85
33996.7145 34119.05
34113.7747 33665.81
34230.1759 33249.06 Ecuación para líneas de
entalpía en fase vapor
34345.9279 32864.32
34461.0399 32507.63
34575.5211 32175.53
34689.3805 31864.96
34802.6266 31573.22
34915.2682 31297.97
35027.3134 31037.17
35133.2116 30801.15

Diagrama x, y
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X
 Diagrama T-x,y

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x oy
 DIAGRAMA ENTALPÍA-CONCENTRACIÓN
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H (cal/mol)

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XoY
ALPÍA-CONCENTRACIÓN

H l i qui do
H vapor
110.8°C
108°C
102°C
96°C
88°C
80.1°C

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oY
 Diagrama T-x,y
120

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90

80

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60

T (°C)
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10

0
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Diagrama T-x,y

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xoy