𝑁2 + 3𝐻2 → 2𝑁𝐻3

∆𝐻𝑅𝑜𝑥 (𝑇𝑅 ) = 2𝐻𝑁𝐻

𝑜 (𝑇 )
3
𝑜 𝑜
𝑅 − 3𝐻𝐻2 (𝑇𝑅 ) − 𝐻𝑁2 (𝑇𝑅 ) (E8-3.1)

∆𝐻𝑅𝑜𝑥 (𝑇𝑅 ) = 2𝐻𝑁𝐻

𝑜 (𝑇 )
3
𝑜
𝑅 − 3(0) − 0 = 2𝐻𝑁𝐻3

𝑐𝑎𝑙
= 2(−11,020) 𝑚𝑜𝑙 𝑁
2

𝑐𝑎𝑙
= −22,040 𝑚𝑜𝑙 𝑁2 𝑟𝑒𝑎𝑐𝑡𝑒𝑑

∆𝐻𝑅𝑜𝑥 (298 𝐾) = −22,04 𝑘𝑐𝑎𝑙/𝑚𝑜𝑙 𝑁2 𝑟𝑒𝑎𝑐𝑡𝑒𝑑

= −92,22 𝑘𝐿/𝑚𝑜𝑙 𝑁2 . 𝐾 𝑟𝑎𝑒𝑐𝑡𝑒𝑑

𝐶̂𝑃𝐻2 = 6,992 𝑐𝑎𝑙/𝑚𝑜𝑙 𝐻2 . 𝐾

𝐶̂𝑃𝑁2 = 6,984 𝑐𝑎𝑙/𝑚𝑜𝑙 𝑁2 . 𝐾

𝐶̂𝑃𝑁𝐻 = 8,92 𝑐𝑎𝑙/𝑚𝑜𝑙 𝑁𝐻3 . 𝐾

3

∆𝐶̂𝑃 = 2𝐶̂𝑃𝑁𝐻3 − 3𝐶̂𝑃𝐻2 − 𝐶̂𝑃𝑁2 (E8-3.2)

= 2(8,92) − 3(6,992) − 6,984

= −10,12 𝑐𝑎𝑙/𝑔 𝑚𝑜𝑙 𝑁2 𝑟𝑒𝑎𝑐𝑡𝑒𝑑 . 𝐾

∆𝐻𝑅𝑥 (𝑇) = ∆𝐻𝑅𝑜𝑥 (𝑇𝑅 ) + ∆𝐶̂𝑃 (𝑇 − 𝑇𝑅 ) (8-27)

∆𝐻𝑅𝑥 (423 𝐾) = −22,040 + (−10,12)(423 − 298)

= −23,310 𝑐𝑎𝑙/𝑚𝑜𝑙 𝑁2 = −23,31 𝑘𝑐𝑎𝑙/𝑚𝑜𝑙 𝑁2

= −97,530 𝐽/𝑚𝑜𝑙 𝑁2
 1 𝑔 𝑚𝑜𝑙 𝑁2 𝑘𝐽
∆𝐻𝑅𝑥 (423 𝐾) = (−97,53 )
3 𝑔 𝑚𝑜𝑙 𝐻2 𝑚𝑜𝑙 𝑁2
𝑘𝐽
= −32,51 𝑚𝑜𝑙 𝐻 𝑝𝑎𝑑𝑎 423 𝐾
2