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'l"l-. J g,',1
10. I lntroduction
Nuclear power iE the subject of this and the next chaPter. This one-
consideri the present situation, the background science and the types of
nuclearpower plant curently in use. Chapter 11then discusses possible
n"w and the issuos ttrat might determine the future for nuclear
"ysiems
\uclear power has led to controversy since itS inception. Beforc the gencral
public had evan heard of 'atomic enoaty', scientists in lhe 1940s lvere
aheady divided, with some talking of '€lect city too ch€ap to meter' and
others advocating no further developoent of the technology after lvorld
warIL In theevent, ihe post-wa-r period saw the emergence ofnew nuclear
rveapons and also tho frrst nucloar power slations supplying electricity
io the public. But the debate is by no mearls over. Supporters cite limited
fossil fuelresources and coDcems about climatechan8e, while oppo[ents
raise issues such as safety, proliferation of nuclear weapons and the
extent of the world's uranium Esource. These issues aJe also discuss€d
in Chapter ll.
Ukraine and the UK. In the laiter, nuclear power contributed 69TWh or
about a Iifth ofthe country's electricity production for tlc year (BP, 2010;
DECC,2oo9).
Ths fust few nuclear plarts started supplying power to nationalSrid systems
in the 1950s, but as FiSure 10.1(a) 6hows, th€ mpid Srora'th in nuclear
capacity begar over a decade later- From a mere 75TWh in 1970, world
anDual nuclear output incieased to over TOOTWh by 1980 - an average rise
of about 25% a year. One country was largely responsiblo for this change:
the USA. hometo theworld'sfirst nuclearreactor, had the technologv, and
with fluctuating oil prices andincreasing concern about resources nuclear
pla-Dts began to be s€en as worthwhile investm8nts.
30
25
20@
d
, tsm 5 ls
. t0@ & lo
' 500 5
0 0
I I t970 lt80 ?000
(b)
G)
Fi8urc I O. I Nuclqr cdributioni !o world .lectricit, g.ieBdon: (a) a.i6l nrclcar oulPuc (b) nuclear PeEsEre of tot:l
(i@rcq Bn 2010)
The worldwide incrcase received a fu:rther boosl in the 1980s wlth the
initiatioD of the French nuclear Plogralnme As discussed in earlier
chapters, France has only minimalios;il fuel resources' and in
the 1970s
a d;cision was asachod it government level to develop nuclear energy as
the dominant source fo. ui".tri.ity. Tbe reasoning may have ban rather
differenl, but the result was remarlably similar io the earlicr growlh in the
USA. Beiween 1975 and 1985 the annuat oulpul of French nucle'ir Planls
rcse fiom l8 to 224TWh, a twelvefold increase over the len_year Perrod
Continuin8 Srowth, although less rapid, has meant that over the past feiv
decades Fiich nuclear ouiputhas c;ntinued to meetabout three-quarters
of the country's eleclricity demand.
-197
0s and
World electicity consumPtion Srew very rapidly throughout the
1980s (see, for instance, Figurs 9 26), but nuclear outPut wasrising even
faster and bv 1990 accounied for about a slxlh of lolal world eleLlricil\,
Droduction iFisure l0 ltb)). Throu8hout the lggos, nu'lcar otrlpul lust
i.epl pace wilfthe ever-growing dimand for elect cily, bul in the hlst
de'cade oI the present ceitury iG perc*rtage cont bltior started
to fall'
ir"rir"rrv, i,"* pt""t startlups iould nolonger balance the shutdowos
"t lhe vear 2007 saw for the first tims an aclu'tl dPcrPa\e iD
(Figur€ 16.2),
world nuclear output.
CHAPTER IO NUCLEAR POWER l3l
F;"'"'"'""e
l
25
a 20
t5
0+
Figure I 0.2 wodd @ctor tnGup3 and shutdownt (source r€dnwn 1106 Sch.eider et rl.. 2009)
,/,/
.
,|y'1 Nuclei a brief summary
4n ",oun, o, unnnnnucl.i in Chaplcr,l incluoed rhFtollusiug poinrs.
r The nucleus of any atom consists of two types of pa icls: protons and
nsutrons, collectivoly callgd nucleoDs. These ars the 'heavy' particles
in an atom, accounting for most ofits mass.
t The main differcnc€ between a proton and a neuton is that the proton
has positive olectric charge whilst a neutron is electrically neutal.
r The numberofplotons in thenucleus,the atomjc number, characterizes
a chemical element.
The unit lor eDergies on the atornic scale is the electron-volt (eV). defined as
the eneryy gained by an electrotr (or ploton) whcrl it 'fa]ls' through a Potential
difference of one volt.
In terms of the more familiar units for mass and energy, the values ofthose
units ar€ as follows:
one unified mass udt: 1u = 1.660 x 10at kg
otre electron-voltl 1eV = 1,602 x 10-10.)
or one million eloctron-volts: l MeV = 1.602 x 10-13 I
This means that 1 kg of hydr(8en contains about 6 x 1025 atoms
To give some i[dication oI the energy units' nole that:
a 1 million eleclron'volts) is the kinetic energy ofa higb-speed
Mev (1
. proton or noutron
bavelling at about 30 million miles per hour
a tho ener8ies of the outer elechons of an atom, those involved in the
chemical chalges described itr Section 4.4, are lrsually a few electron_volis
I the kjnelic enerSy of the avetage atom of a 8as at room temperdlure [seP
section { 3)' also call€d ils tb€r1trtl energj' isabout0025ev-onelorlrplh
of aE 6l6cbotr-volt.
l.l a$-.nc18,
ChaDter 4 exDlairsd tbat lrlass and onergy are now reSorded as essentiallv tr!o
enerS\
aspects oftie same quantirv, and thdi the msss_ener8y erpressed as an
ss a mass (m) inldlo8rams are
1Ei in loules and theiame mess-energy exprcssd
I
roiatei by Einstein's equation = mc2. Given that c = 3 x 1o3 m s-r this Bivesi
E(D=m(k8)xsx1016
At the nucl€ar level, it is useful to have this relatiotlshiP in lerms o[ unilied
mas6 units (u) and millions ofelectron'volts (MeV) instead olldlograms
aDd
joules, Usi[g the above values of the MeV and u, we find that the mass-energ]'
g31 times its mass-eaergy expressed in
of a parucle"expressod in Mev is
unifiod mass units (u):
E(MeV)=m(u)xs31
In other words, the mass of a single proton or neutron in ener8y terms
rs abn'_:
l.6Z Radioactivity
r\ r;ar0lul Lrok at lherelaliveatomicnrassrrsshrrr!ninl:iBul()'l'11) Ie\ 'r_ ''
thc nunlbcls ol Protorls and le.tlLons tenrl to lre lrlual lilr lllt l rlht'
r'
'l'he nuclcrrs ofcarb,rn, for lllslanc{r' his 6 l)mtorrs s(r i(s relirl:''' 1' :
, acq rrfrl,rrrr 12 nre.r)s tl).it it nrr!t lrir!a r, Drltlr.'rr! BLrt a! lrr' ir -''-
Itr:rrnre Ir,:aYi0r, .ttt ext:ess ol n{rLltrlrns i:all l)'] 5':rcn to tlclel'rr:' ) li _
(llgl lol itlstalrrr:e. \,\,ith atollli( Ilunlbcr llr), Ir'rs; Lrrl rtivr: il1'rrllic ll'
_
CHAPTER IO NUCLEAR POWER 185
.\ll isotopes of all the elcments beyond bismu r are ladioactive. 'lheir
nuclei sponta[eously emit high-energy, electrically cl,arged palticles -
rvhich moans of course that they change into nuclei of a different element
(Fi3rres 10.4 and 10.5 show cxamples). Ifthls is so. h.ru is it that we find
rLranium (atomic number g2) stilL existillg ir the Earth's .:rDst'? [he answel
is thal it is decaying. but only very slorvly indeed, as described later.
Radioactivity was discovered by Henri Bocquerel in 1896, as an invisible
ra(liation'that could fog photographic plates. This was fii'tee!t years before
eren the idea of the nuclear atonr, but several imporlant lcaturcs r,vere
: -Jrrully re, ognized:
In maDy cases the 'radiatioh' decreases witll time. over.periods varying
liom seconds to years. In others it seems to show no detectable chatrge
dLrring many years of observation.
'l irc tvpc oi 'radiation' and its inteDsity
are cham(;tc sticofthecmitting
elorneut. Physical or chemical changes - heating, compressil]g, even
r.rnbining into rliflp-en, chemrcal rompoLrnds havp ncl et'[eet ot ull
on the radioactivity.
.\ftru Ruther-ford developed tlie idea of the ouclear atom, he was able to
ihor.v that radioactivity is a nuc,ledr process, and that there arc three main
l!pes of radioactiv0 emissioDs, easily distinguishcd bv their penetratlng
r)or! ers (Figure 10.3)
q
I
p ..............................i
Figure 10.3 PenerndnS powers of differem rypes of radiarion. Norc rhar neurrcns a.€
not ehirred in narural radioactivib/, but are rhowh here Ior.omparison because free
neufo.s pla), a maior rote in nu.tear reacto.s
ENERGY SYSTEttS AND SUSTAINABILITY
Alpha particles
Aloba Daflioles (o-particles) at'e lhe ieasl pcnotldling being stopped Lr 'r
.Li", urn"t. , ao,iple of r nr h"' of arr'. or hrrmJn skrn ' 'l lrcv can' h' 'w cver'
"i
,,."orrij.irio,rr t *ith haza-r'lradioa'.rivDsrrhsldnrjeentersthebodr -
ilth,
ly inhalation or Ly ingestiorr in i.on'amirlal(d lootl or dr ink'
two protol'ts
Rutherford tdentified a-partickrs as helirun nuoler" consisting of
u,',Jit,ln n.uttont. ,nd Figur. t 0.n shon r thc prut e;s ol alpha emissiglhgrn
the DU!.leus of Rn_222 an isotoPe ol the rddioaclivc 8'rs radon'
whlclr nas
86 nr'otons. The loss of lwo protorts mcan s a redurtion ')[ lwoin the atonlic
uhir:h
,r,r-ber,sotheresultisanuil'usoIthemetallicelem"nt polonium
ir.r'"ri, to protons, two places lower rn the Periodic lable lFiSure 4 1s)'
,qi ,rr" ii.", tt e mass numher is reduced bv /our' which determines
"'"r"
tf,"-ir".ii""tu. i.ntope ofthe new element, Po'2'18 in this examPle
Beta particles
lhrr) u Parlicles' but
Beta Darticles (F'particles) are more penctraling
il;'ffi;;";id;eJbvathi" of'neral or a few mjllinretro' of 'rlrrrost
'hecrqujcLly idcnlilied as elcctrons' ex'rcll)
were
rn.i.r,"1 tlisloiically thcv
"u, a few years ear)ier (s* s*]l:I.:,-o.l
i#.;;;;t those alreaiy dit"uu"'"'iNormal lrom ra(llodcrl\e
but with a qreat deal more energy B_patticles
but' like
H":;iil;#;ilt" inro tt'" iiln' causing tLnpleasant burns
*if f produce internal damage if lhe source is inhalo(l
^i"i"'""ttl"f"tl tlic'very encrgelrc p-parlrcle' proouceo
ll"t.,iJri"ilirci*"r"r,"nly rn. ntrr'rcar
.""at"o, aun d"ngerously penetraling'Y_rays os they deceleratc'
"rnit had lo wail some twenlY year s
An understancling ofthe origins ofp-emission wilh s'T,"-'-',11:
iu ir,rr"ri"ra'. ii.,,rre of in "tom as a positivn nucieus\{ere comrnB Irorn
B,,t ili"" tho discovcr! thsl thesc narticlcs
"j;;,;;;.
ii" ,,t.i*. deepened the mystcr\" How rould a
neBalive nlectrun
""r,
;:".:i;t"'.";; i;;'p.',,i"' l-"";'c"d the dev'lopnnnt o[ tlrc morc
' "'
CHAPTER iO NUCLEAR POWER l8
Dr. B r..
stl te
Figu re I 0.S Emission ol a b€ri panicte (an €tecrron) from an iodtne- I3 I nucl€ur resurB
in a xenon- l3lnucleus
Gamma radiation
Camma rays (1'rays) woro discovered a feu: r'ears alier lhe otller t\'!olypes
nf.uaion.tivity, .ulnl-v ber;ause thcl' are Duch morc pcnetrating and thrrs
aitfi.rtt tn cle,iotr. When thel rrr:re identifiecl as verv short l\'avelength
1vuues, the,Y werc also called 1.radialion whilstthephoton
"l""t"or,rogn"ti.
view ofraiiation led to d lhirll lerm: I'particles' lAll lhrcc of lht'se rranrcs
ar. currentiy aeceptable.) Canrrra radiation ic cssenliallv the samc as higlt'
.,r..n, X-ruv. (sec Fieure q 15l and has similar effe(ts on li\il'8 mallcr'
C^,ri-a oarii, les are itopperl ,'nlv bv several ccntimelros of lead or sleel'
or a lew feet of concrete ond logelher wilh neulrons thev a1s the chief
racliation hazard associated with nuclear technology'
Gamma emission doesn't change the numbers of protons or neutloos-
in
the nucleus. It is a settling-down process by which a nucleus loses surplus
f"11"*ing crl or p-emission, oi fission The nuclei before and
"""rgy-
afte;diffe"ft""ng only in their energy, are called nuclear isomers'
uiil+, *r,y.""
half-ltvp< i< thai i Prpc' o' "rAn'urr' *ir'ifi$'Jij$:T,?:TI,:
oi these"',pl*,
*-'-;;;;-u-r;; 11,1'il^,::i,l::,1,* *"" "':',) - r'-'":
-.--^..
would ha''e irad eqrro] anlounts of lhese two isolopes
-.L^..' .n^^,-lll:^- .,^."",d^
,PTER IO NUCLEAB POWER
0000,
9000
8000
7000
5000
5000
4000
1000
2000
t000
0 t5 20 25 30 t5
days
ilcsl|ring radioactivity
lioactive soulce can be characterized by the an activity of 100008q per cubic metre (uDdesimbl!
rer of particles it emils per second. This is its high for contiDuous exposur'e) requires no morc
gllr, measued j11 becquerels (Bq). A piece ol thaD two parts per thousand-millior1 million of
rial lvith an aciivity of l MBq is therefore emittinA iodine-131 in air
nillion particles a se.ond, and so on.
tic encapsulatod sources considercri safe lor school
x:cqut:rcl rephtced the eotlia unt fot lhe iaboMtories have activities of perhaps 100(10 Bq.
cth a'n so.tt'.c. thc (,t,ip tO. A on"-nn.
So is 10 000 Bq a safe ievel oI ra.lioactivity or not? Tho
:e $ould emit 3.7 x 1A10 particles o second, jsn
first answer is tbat it t a']eve]'but the strcngth ol
e canersion is very tau9hly 1Ci 40GBq or
= apa icular sourco. And scconrlly, salcty depcnds orr
| 30 ci.
= lvhol the source is and wlere it is. An encapsulate.i
10.1 shows the half-lives and activities of a few source used corecdy in the laboratory adds a negligibip
isotopes (mdioactive isotopes). Compa son oI the amount to the natural radioactiviiv that we all receive
raniun) isotopcs shows, as one would expect, that continuously: but 100008q ofplutonirun in a solub,e
r activitr leads to a shorter half-lile. To put the form entc ng thc bloodstream \^.ould be a !u'y dilierprt
D.O:rtext, note thati mdller. In assessin8 sdlcry - or Uorert.al J.Igpr s" i
need data of thc type in Table 10.1, but \{e also n.rx
e Sram is the mass of half a (drv) tea bag, and one informaiion oD tho resultinB doses a]ld thci efleds
crograrn is a rnillio th oI ihis
a speck oI dust These topics are discusscd in more dctail in Chapifr l.l.
. ir:n
i s e\peliDtents rvero soon repeatcd b-v others, including Ottcr Halur .utcl
UL-.itnor jn llerlin (Figuros 10.8 and 10.9). lclonlifi i[g the linv ant)unTs
,r llrrL\'lnaterials llroduced bl rleutroD itradiatiorl of rttanium '.r,ts nol
Lut e\'enlrLail."-. in 193u, a brilliant chemical ana lysis establishecl that
rn rT as ce|tainh one protluct (Hal-in irnd Strassnral)n, 1!)39). Hoil co'.ild
tg a lieutron lo uraniunl resLllt in this much sntrrl/er rruclerLs? llahli
Figure 10.7
Ennco Fermi (1901-1954) and his brother G ulio were science prodigies,
inseparablo until Grulio d ed at the age of 15. Enrico took refuge ln study'
teaching himsell from books found in lhe lobal flea maftet in Rome. At 17 he
won a fellowship at P sa, and by 1927 had made a majo. contribution: Fermr
statislics - the basis for modem theories of metals and semiconductors.
Turning to nuclear physics. he carried out lhe experimenls lhat led ultimately
to fission. Allwho knew hrm said Fermiwas truly unique. His leclures were
dazzling, a slream of new insights rather than slandard approaches.
Figur€ ,|0.8
Olto Hahn (1879-1968) sludied chemistry ln Germany, and worked with
Rutherford in Montrealbefore returning to Berlin. He disianced himselffrom
the German nuclear weapons programme, and in the poslwar yeaas
concenlrated on the peaceiul applications of radiolsolopes and fission -
including, in 1950, an analysis of the safety measures lhat would be needed
if nLclear power stations were ever bLilt
Figur€'10.9
Lise [/eitner (1878-1968) studied physics rn Vienna bul moved to Berlin in
1907. Barred as a woman frorn the main Deparlment, she was aLlowed (as a
special concess on to Otlo Hahn!) to use a spare room on lhe ground floor
By the 1930s she was Head of Physics. BeLng an Auslrian citizen- she was
allowed lo continue desprte her Jewsh background, but the Anschluss
changed lhat, and in 1938 she left, travelling illegally and escorled by a
Dutch ,riend of Niels Bohr (Figure 10.'11 ). Declining to join the N4anhatten
Project, she stayed in Sweden until retir ng in 1960 to Cambrldge (UK).
ENERGY SYSTEMS AND SUSTAINABILITY
Meitner was reading Hahn's letter when her DephelY Otto Frisch arrived
from Copenhagen to speDd Christmas, and in the next couple of dar s,
sitting in a small hotel, they found an explanation (Pais, 1991. p. '15{.
citing Frisch and Wheeler, 1967), The resulting paper lMeitncr ar]d
Frisch, 193s) proposed a mechanism by which a heavy mrcleus absorbing
a relatively sLow-moving neutron might become unstable and split il1to
two lighter nuclei (Fi8ure 10.10). They called thc process kernspaltrtngr
nucleir lission, and remarked that it should release a great deal oI energv
(Box 10.4).
elo'loFlssionofUranium.2]5whcnarelativelyslow.movinSneutronisabsorbedb/aU-235nUc]eu''there'Uldn8
)eU.236nuclelrcantake!padt]mb'belshaPe'Electrl.alrePulsionbetweenth€.wopositivelychartedpartsofth5.in
€3C ro fissron. produclng two new radroactive nuclel, the fisson produccs- A few
free neurrons (n) and gamma radiaron ( /)
n (!ed n the p.ocess. and the fiss,on products are likey ro emit beta Parricles (D'
ll didn't take long for the news to spread. In Januarv lg39 Niels Bc'hJ
{l igure in New York on his way to Prillceton, mel Fermi J recently
10. I I ),
arrir ed dmigrd ft om fascist ltaly. Two week:' laler, at a physics conlpt en' e
in Washingirn, Bohr describedihe fissiou results. and Fermi suggested thrt
free neutrJns miSht be rFleascd in rhe pruces'' Everyonn kl)Pw lll'rt l')"-e
would bc surplus-neutrons (seo Box 10.5) bLll it did llol nececsdrily t;llL r\
that free neuirons would appear. ThP siEnificdnce of Icrmis suggesti' n
lraP
was immcdialely obvious to his alldience. Neulrons cause lisslon' so a
neutron could cause a further fission' and more than one hee neubon from
(Figr e l0',1 -)'
ea( h iission event could produce a divergenr chain reaction 'r
with only lhousandths oIa second between elenls thu resull would l-'r'a
very greai deal of enetgy in a very short time a nuclear cxplosion'
This suggeslioil threw the meetjnB inln n uproar lvhile Phy'rri'ls
who h#facititins initialed calls lo their laborclorips lo slarl lhF
search for fission neutrons'
(Manley, 19621
APTER IO NUCLEAR POWER l9l
lirL ir Lla!. ,'ission lppcarecl 1.,r the tlrst tirlc in the nolvs heacllincs
riu a ycur a huudred papers trad beeu published in scieutific iounais
.iuring that vear th€ Second lVorld lVar broke out.
y lrotrr li$ion
rculating the ener8y
ras ni)t necessary for l\'leitier al1d Frisch lo wait lbr measurem-onts of lhe
rgv reieased in fission. The masses oI individual atoms and the tleutron
re knolvr quite accurately by the 1930s. so the total masses belore aod
rr the fission could be calculated by the method used in Box 10.2. The
ial rDass is that of the U'235 nLlcleus plus the initiating neutron. Thc final
rs is the sum ofthe masses of the duclei of the two fissiou products plus
masses ofanv spare free neutrons. Ifthe final nrass is less than the iritial
is, the clillerence must be the mass-energv released io the process.
r lission of U'235 can load to many outconles, *'ith differenl pairs ofnew
ilei and difierent numbers of free neutroDs; but calculations ghoived that -
average the final ass was less than lhe initial mass by slightly over one-
r of an atomic mass unit - about 0.21u.
described irl Box 10.1, EIMeV) = rn(u) x 931, so the energy rcleased bv the
version o[ 0.21 u will be about 2o0 MeV per ff$sioD.
s is onll'about ll.2 x 10-1r joules, which nray seem very small, hut ihe
iurc changes if \r'e consider not one atom but ono kilograru.
Ir ktonl ol t -:35 h.j a robss olapproxiu.arelr 235 u.
ce I u = 1.060 x 10 17 kg (see Bo\ 10.11:
js of oDe atom ol U-235 = 235 x 1.660 x 10-27 kB = 390 x 10-" k8.
)re are thus approximateiy 2.5 x 1o2a atoms iD one kilogam of U-235, so the
r8y released in its complete fissioo is:
E=2.5x1O2\x3.2, 10 11, = 80 x 10r'z, = 00TJ per kg
i.lr is equal to the energy released in burnint about 30OO tonnes of coal! Fi8ure l0.l I Niels Eohr
e howevcr that, as explained above, less than one per cent of natuml ( 1885-1962) was born inro a
nillm is l.l-235. Most ofthe rest, as we shall see, does not undergo fission. {amily ol academics and bznkers.
He a.tended Cop€nhagen
tributint the enerty U niversity, where he late.
established rhe worldJamous
urning to the individual fission event shown in Figure 10.10, what lnstitute of Theoreical Phyecs
,pens to the eoergy that is rcleased? The answer depends orl lhe details of
He applied the ideas of Plafck
process, but (,n average the energy is distributed as follows:
and Einstein to Rurhedords
r4rrre thaD [our-fifths ofthe 20oM€V is carried offas kinetic eneBy of the n!clear arom. and the reluhrng
lvo ftsslon producr truclei. Collistons lrlrh su$ounding atoms eventually 'Bohr a(om was a remartable
r..listribrte rhis energy as hcat. imag nadve leap. He was in la.t
ust under 30 MeV is accounted fbr by gamma rays, beta particles, etc.
. remarkable man:an aooallinry
bad lecturer who was revered
ior e of these ure very penetratirg and lhcir energy may be 'lost' out il1to
and loved by studenG and
hc surroundings.
colleagues alike For many
\hout 5 MeV becomo6 the kinetic €nargy of th6 fi6e neutrons. theoretlcal physicrlts in the
mrd'cwentieEh cen.ur/, Boh. wi,
s lhird ilem lyas to become extemely important in practice. A neutroD
a Sreater inllueice even than
I kinclic energv of an Mev or so travels at a very hith speed (see Box 1o.1),
Eansrein.with whom he shared ,
as discussed belo\r'. those fast neutron6 produced in the frssion prccess
mutual respect and affe.!on
vr,(l r)ot tr) bL. idcal 10r Nnning a nuclear rcactor.
191 ENERCY 5Y5TEM5 AND SUSTAINAAILITY
FiSure tO. t2 An explosive chain reacnon Suppose rhrr a fre€ neuron rnioates rhe iiE; fission {left-hand Panel) rnd that two
neurons from this initiate new fisiioni (centre panel). and thar on averate two neutrons from each of these niiate lurther
frsion, tiSh!-hand pan€l),and so on. Muhiplyint the so.cesrive genemrions in rhis way at int€rvals o, a {ew millisetondt rhe
gower ouQut.ould re.ch meSawatts in less than a tecond (Note that this needs a verl hiSh concentralioi of U 2l5 )
A uranium-2 3 5 nucleus underSoes fission into tt\'o new nuclei U one al these .
ptodticts js boium, whot is thi other, and how m(ny sutPlos netttons sho ld
rcsultfrcm this pracess?
The atomic numbers ofuanium and barium are 92 and 56 resPectively So
the atomic numbor of tbe other elemcnl must be 92 minus 56 i o 36' This
is the gas krypton.
Suppose now that ihe producti are the heaviest stable isotopes oflhese two
elemonts. The first column irI Table 10,2 shows the mass DuDbers (prctons
plus neutrons) for these, and subtmctlng the numbe$ of Prolons Sives the
iiSures in the third column. InsPection shows that the original U-235IlLrs thc
initiating neuton provide lwelve more neutrons than arc needed by the lwo
product elemeflts.
Nu'nber of neutrons
u-215 92 l4l
8a-ll8 56 82
Kr-86 36 50
neutron loss rale oluoys cxceeds th{r ral{r of production. no mattcr how large
the bkxrk. So, as mentioned above, a chain rcaciioll usjng last Deutrons in
Datura) uranium is not possible.
'lhere was, however, another option. Iremi had shown in the 1930s that
slou,ing clown the fast noutrons made them much ]nore iikely to initiate
fission, increasing the chances ofa chair reaction, and this lvas the method
he used in the first reactor (see belowl. But the main problem at the time
rvas the iack oI the experimcntal data n eeded to assess thc possibi litics. I he
scientisls in the USA persuaded Einstein to writo to President Roosevelt
(Einstein, 1939). to which he responded positjvely (Presidert Roosevelt,
lg3g). and in February 19ao ttte sum of US$000O (!) was made available
lor fission research,
Meanr.vhile, in EnBland, otto FIisch and Rudolf Peierls at Birmingham
Univelsity wcre using the available data and inspired guesses to tackle the
issue oI $itical mass. They concluded thar for pure'100% U 235, about
one krlogm,l would be enough.
At that poiflt we stared at each other and realized that an atomic
oumb rniBhl alter rll bP po-r,hln.
(Pais, 1991, p. 4giJ. quothg Frisch, 1979)
They presented their results in two memora[da (Frisch and Peierls, 1940a'
1940b1, including the idea that an explosion could be achieved by rapidiy
bringing to8ether two sub caitical masses of U_235. Their value for the
critical mass prcved rather optimistic, but even ilten times this was required
(which proved to be the casel, it would still bc practicable
By 1941, Sroups iD sevelal count es had projects for the construction of a
contmllabie nuclear reactor {ca-lled at that lime &n atomic pile in the UK,
uranium-pile in the USA and Uranbren[er in Germany). Everyone kneh'
that a susiained chain reactioD in natural uraniulrl might be possible. And
evelyone kncw that the others knew.
The bomb programme, now called the Manhattan Proiect, became a )ojnt
allied effori and most oi the scientists working on it in the UK, inclr'rdin8
manyrefuSees ftom Germany and occupied countdes, crossed the Atlantic'
The Chicago group and a Canadian-Brjtish-French team in Monlreal
uorked on;xperimeDtal reactors; the main site for weapoDs devclopmenl
was Los Alamos in New Mexico ald there werc reactors lbr plutoniull
production (see'New fissile lruclei , belorv) clscwherc in the USA
In Chica8o on 2 llecember 1s42, by carefully pilinS uP lurnps of uranirlnl
metal, sirrounded by graphile to slow down the fasl noulrons, and wilh
strips of cadmium (a neL,tron absorber) tD control the process, the Fermi
CHAPT€R IO NUCLEAR POWER lt7
team a.hicved criticalit! -lho first controllcd chair rea iion (Figurc 10 13)
The N'lo)-rtreal reactor and plutonium-producing react ,rs elsewhere in the
llSA follorved.'lhe Ccrmao proicct includ0d a plant in occupiod No.iir'ay
produr:ing hoovy watcr. coDtainin8 the hydlogen isotnpc dcuteriunl, but
they still had no operertional reactor at the eod of the 1tar. Unknown k)
the.{}lies. it had been decided in 19.12 to continue thc ruclear work on a
snrallsr:alr: onlv.'lho docisioD was nlflde br th{r politi ians, bLlt the extent
Io uhich thc Gcrrnan scicntists, Ied by We|ner l{eiseirberg. were aclively
pursuing the deveiopment of a weapon has remained the subject of debate
ever since- (For more on graphite and heavv water, sec Box 10.6.)
fiss on 2 fssion 3
235
n fission carbon neutron
prodtrct
FiSu I
re I O. I A conko lled chain reaction. Some of the hsr neurrons released in the firsr firsion (left-hand panel) are slowed
down in collis ons with carbon nlclea lusr one ofthe resuiting slow neutrons causes a s€cond lission (centre panel), and jusr one
from $j3 causes another (right-hand panel). mainraining a seady chain rerction, even in natural uranium. (Th€ many U-238 nu(le
are not shown in the diaeram.)
end tlle res lting slow neuh'ons lviil also carty tl s rcsidual enelgl '
Thc-1
ursn r'r.r
,1" result when lhpv eslaoll5hcd lh" presenc' -'Jl .d
"."fi.*.,i
rsorooe rhat pmrlted B p,rrlrclPs. As shown in Figure
Irr.) o-enlr::illl
uranll'ln tllt
rrrcre'ase*th"oromicrrumberbr"rre,'"0pnli5sior lrom l:-:li
'o urrrI
.rre elernont rvith atorn iu llmbpr 9J. WhPn lhis in lurn wa' Iorno
t.., "
i;;;;;,,;i;"ni ,t e4 was arso being prod.ced'
i:;;,;;;;;, ", "t"",""'
Product.on ol llle\e r\^o lrr \\ cl'lnPn'c ln qll
rnlilie(iust l' r' ' -rouBrr'nt
achieveci in rs41' and rb-] \vPr."
o'i\"'n
.;;::;i;*l;;'. i,o. 'rirnrrs
,fr"
"'"n"'',l''
i"p*"ir. and plrrlr)nium l'rll(-r rhe prdnPls b"\ "n'
l
""a., Iionisillrrsl-'rl'1JtnFt'''rr tll'll TIr|
Ihe'ro'r,'nc' l"rdingroth"rrpr "lur ps
iiI:,:;'i:';"'':;';;;;; ;';i"' \.,,'rnD'hu. h'conrins rr'|p
",,1u
CHAPTER IO NUCLEAR POWER 195
]]]9 _
'ii,
Figure 10.14 Production of plutonium 219 from uranium-238
:
bn.!
l'r
|
I .,
.:_, t.
\
h tecond pilecomplex
b lefinery for crude u ran ium
c chemr.aland meta ltu rg icat work k separating pl.nt tor isoropes
d complex of ura nium piles fo. prepaldrro n ofptuo^rum I manufactueof ba6frompureorcon.envated U-235
m re.ond power stataon
f ra(tory fo.the 5eparation orrhe plutonium fom€d andfssio. products n possible rubsidiary for making se(et weapon5
g PreDaration oI pure pluroni!m o factory for makinq ..dioacive conpounds
igure l0.l5 A larte aromic ener$/ ptanr oi the fucur€,as for€seen in t945 (source:red.awn from Hahn. tgSO)
Al th€ time of writing (2010), virtually all operational nuclear power stations
use thermsl fissionr;actors usitrg modorators (Box 10.6). so thoyare'thermal
power stations usin8 rhermal roactors'.
Fost neullon rcoctors (descibsd in Secliotr 10.81 do not require amod6ralor'
Th€ nsuuons ar€ thus not G€rmalized Pow$ stations using thess leactors are
therefore lhemal power stations usinS last neutrJn reactoB'.
The reactor
Fuel
A nurnber of early power plants used nolu?oj lrlori.tm fuel, bul ost of
these have reached the cnd ofthcil productivc Iiir, and the remai[irrg l-eu',
CHAPTER NUCLEAR POWER
'O
ljke Irore r'ecen{ designs. rro!1 use eorichcd Lrrauium, with [J 2:r5 c()utent
botwocn 2olo tnd;o1,.
Thr: 1\\'o olher kno\vn iissile nucloi rnontioned in .Ncr,r, fissile nuclei, above
have both Leen userl as minor componL,rrts together with the uranium-
2lJ5 iri reactor fuels Plutonium 239 is brod in any uranium reactol., as we
have seen, but can also he aclderl as a componetrt of the fuei. Altlough
plulonium does not exist in nature. there are loday many potential sorrrces.
The spent fuel removed from a reactor inevitabiv stiil contains some ofthe
Dlutoniunl l-,red drtrinB ir. use. and rcprnr cssing this i. one optio . Therr
there are the manv tonnes of plutonium potentially becomj;g available
\,r,iLh thc decommissioning of nuclear weapons. A further opiion is the
usc oI thorium. As desariLed above. a fast noutron teaction with this can
hroed the fissile isotope Lrraniunr-233. Theso possibilities ale described
lurther in Chapter 11.
IJraniLlm reactorf[el is usua]lv in the lbrm ofthe oxide U(J2, a hard c-"mmic
suitable for forming into pellets. lf ihe fuel is to include plutorium, tliis
cal,l be in the folm ofp]utonium oride, Ptror. In this case the fuel is called
a nixed oxide, or MOX. The fuel pellets must be contained in a Way that
allows : eplacernent ofbatches ofspent fuel. and the fuel rods, the containels
or claclding holding the fuel, are usually metal tubes. Steel, the obvious
r:hoicc, is excluded in most cases due to its high neubon absorptiol, so
otlrer rnetallic alloys are used, as will be showD in the accounls of reacior
lvpes helow.
A typical reactor might hold in the order of 100 ionnes of fuel, a third
of this being replaccd cvcry year or eighteen months. 'I he resulting heal
output ofsome 2-3GW would besufficient forturbo generators supplying
600-1000MW ol electric power. The firels for specific reactors a.{l firi)l
Inodrr.tion are dis(iussed in Scctions 10.6 and 10.7.
Moderator
'fhe frLnctioD of the Drodcrator in a nuclear reactor has been described in
llox 10.6, and the Iact that many preselrt-day reactor types are iderltified by
the moderator they use is an indicator ofthe inlportance ofthis choice. As
urill be shown in Section '10-6, the maiority of the world's present nuclear
plants havc light water reactors, with ordinary water as moderator, and il'te
nrajn allematives are heaW water reactors. The third moderator, graphjtc,
has been used in reactols cleveloped in thc UK and insome Rr.lssian plants
Iur tiru reasons discussed in Box 10.6, both graphite and heavy water iverc
rrriginally choseu to allow the use of natual uranium, avoiding the nec.l lbr
oDrichmcnt; brtt as mefltioned abovc, near]y all cunenlly opemling reactors,
ir(:lrding lhese types, now use fuei with somc degree of enrichment.
Coolant
I he coolant is the heflt exchairge rnodiunr: the fluid - liquid or gas - that
rirrrics heal liom the reador corc. ('Ihe namc, rather inappropriat{i iD a
s\,s{enr whose rnai purposc is 1oprca/.rcehcal, rcflectsits original iunction,
rr.lrir:L rvas to pre\rent ovorheating irl reaclors designed tbr plutoniunl
produ(1ion.) A signilicarlt advantage of a /iquid moderator, whelhcr heaYy
\,!ater or normal (liBht) water. is that it can also acl as the .oolant. Craphitc
rs of ( rLLlrse a soltcl so a Sraphile nlodelated rcnctol rl:qLtires a dLlferent
. late.i,tl .ls (r,,olnnt. Sorne l!pes. includilrg lhoso rlevr:l,rperl in the t K. usr:
.drbon lioxide gas-
Controi system
Routin, .ontrol of the heat output of a rea(:tor is achioved by designing lor'
a slightil irrcreosirrg rate of fissioo but ircorpolating a neutroD-absorbing
materi;l in the svstem. Caclmium ancl boron are good absorbers. arld the
reactioi iran be conlrolied by increasillg or decreasing the amount ol lheso
prcsent in Ure reactor core, either by adding absorber to the moderator or
with control rods that can be moved in crr out (or by some combinatio[ ol
these and other uethods). Another aspect of control is the ability to deal
wilh ei (rnts such as an unplanned increase in the rate of fission, and all
reador. need to incl de systems for rapid responsc to such emergencies.
Safety
Structures
Certain basic requiaements determiDe the general form of all the reautors
discussed here. The fuel mustbe distributed at the right de4sity, surlounded
by the modemtor and in good thermal contact with the coolant. The coolant
must st:eam freelV past the hot fuel and for maximunr plalrt efficiency musl
attain thc highcst possible temperature, which implies a high pressure
This has a rrrajor effect oo the design bocause, as meutioned above, steel or
other sh uctural materials will absorb neutrons. The metals magnesium and
zirconiurD are oflen used in rcactors because of theiJ low neutron capture.
Onlv thos e ,eactors withvery low neuiron lo$s in themodemtor and coolant
can alford to have individual pressure tubes carrying thc cooiant. Itr most
designs, the whole core is submerged in the flolr,ing coolant in a sinel{i
large pre;sure vessel.
It is v,,orth cooside ng lor a rnoment the interior of the reactor cora. The
coola-nt musl not orrrrf\ loo tlur.h spdre. whtrh mr.rns that.l mu.t l,p
[luwirrg l"cv Ias' il it is to carry away thc BiBawa s oI heat. So a vpr] hoi
fluid strearns at high speed and high pressure through narrow gaps and
channels past thc fuel rods, subjecting materials to mechanical stress as
well as the combined ef{ecls oftemperaturc and pressure, chemicalattack
and bombardment by sub-nuclear particles. The designer nrust ellsurc that
even under these conditions fuel rods do not distorl, control rods can movo
heely and nothing impedes the flow of coolant.
ShieldinB
Containmenc
The safe containment of the raclioactivc material itselI is obvious]v
-l
I mPortant. hP hrgh prpss' rr" r,qu Ir ps ph r.si, ,lh <rrong, ontait rl."r r. anri
as nlentionod above. this is o[ten achie\ cd bv su$ounditlg the enlire corc
hl'a stroo6; pressure vessel. The fissioD !rcducts will include radioactive
sascs. so containing tlrese and monitoring thcir emission from the plant is
an ill1portar)t aspect of routine operaiioD FinallV, the containment system
should be rlesigned lo safeguard persoloel in the plant atd people in the
slrrroundings in the case of'non routine events'.
Accidents
A rrrain soulce oI public.oncem about the safety ofnuclearreactors is the
potential for the release ofr.ery large quantities ofradioactive substances.
which can occrlr onlv if the containment fails Major structural failure
during nornral operatiorr is possiirlc, but tras uevcr uccul ed, alrd the rnore
likcly event is that the pressure vessel is unable to withstand a sudden
unplanned rise in core temperature aDd pressure, or an explosion resultiDg
frorn this. Any exploslon - nuclear or chemical - is the result ofa runa\,!ay
energv-producing chajn rcaction, multiplving so fastthatthe energy doesn't
havc time to escape by nor;nal 'peaceful'means as heat and lighl. hrstcad,
thc eoergy dcnsity rises u!rtil the honds holding the matcrial togeth-"r are
brokcn and it blou,s aparl. In thc words of the unfortunatc spokesperson
alior olle accideni. it is aD 'energetic disasseDlbly'. Obvious]v, a chemical
explosion cao ol)lv haplen if stlilahle (rhemical$ are prcsent, particularl]'
h! drogen. One possibilit!, iD reactors u ith water as a moderator or (:oolart
is that the tempemture l iscs to the poini whe.e ihe water turDs itlto steam,
ivhich reacts u,ith the zirconium allol used as luel cladding to produce
hydrogen and zirconium oxide [i.e. a lbml of'rusting']. The nccessarv
colrditioDs lbr srrch a chernical explosion might a sc in a nnclear rcactor
as a rcsult ofeither a sudden loss ofcoolant or a 'lunaway chain roactior1,
and we look briefly at each of these. The specilic accidents mentioned are
dist:ussed in more delail in Chapters 11 and 13.
A ffaior Ioss ofcoolant cao have parlicularly scrious consequences in a
nuclear reactor. ln a fi)ssil-fliel plant, such [ailure would be dangerous, but
at lcast the Beneralion ofho:rt encrgv could be stopped by cuttinB off the fuel
ol air supply. Nol so iD a rluclear icactor. Even if the chain reaction stops
instantly. radioactive decay of lhe lissi<rtr products contiDues, and the rate
oI oncrgv release immediatelv after shutdown caD be almost a tcnth of firll
normal power- eDough to cause thc corc tcmperafure to rise at 100'C Pcr
minutc if lhc coolant is lost The hal[-li\ r!s oimanv of the prodtrcts ar'e vol\'
short. and the ratc may have lallen to a ieith rrf this level within an hoLrr;
brt the tieal pLorlucird duriDg this shurt tilne is enough to n)elt the core
arr<l perhaps the lloor olthc rr:actor building as well - a'China Synclrorne'
sccoado (the ficlional idca lhat the contrDts might continue to siuk towards
t}le diametricalh opposite point on theglobe!lThe most se otrs kno!!nioss'
of (:oolant accldenis we.{, thos(i ai Tlx(xr Milo Islaxll ('lMI) i11 Perlrsylvarriil
ANO SUSTAINABILlTY
ENERGY SYSTEHS
ffii$ffi*tl+'*
****ffi
u*****$*r[-tffi1*
i..a"d Pu,t ot
'h"
screenlng dLUur
hillid;*U**',Sffi
;;l','C
;xx';','.ffi ;l J-l i ;:
fi:Hifi :-:":":iiiil'i#'i':1""7
i;:*;::llH3:lsl"u"l:
regiou'
snrall
,fl*s***l***ffi
CHAPTER IO NUCLEAR POWER
f 1,.rrr, ,1 efficiency
'l'he studr of coal-fired power stations in Chapter 6 showcd that the heai-
t,) cl,{ tri( r,v efficien{ )' of thp plant depends critically on the lcmperature
ol'llre stc.rll rnput lo thc turbines. and that lbe maxlmum permissjble
steaot tenrrreratulo and Presstre is determiDed by th{l availability ofhiglt-
temporal rr: r: steel allovs. The same rcasoning applies to nuclear plants. b[t
witl'rsero|al imporlant differe[ces ln all types of nuclear p]ant excePt thc
hoiling w.1t.ir re;cto$ tsee Scction 10.6), the steam for the turbines is not
pnxluZed directly in the reactor, but by the cooiant carrying heat ftom the
core to stcam generators, and this of course involves some tempemture
drop and etTiciency loss. But the really significant differeace is that all
the materials in the reactor core or its su[oundings are subject to constant
neutron bombardmeut, leading to embrittlement of metallic comPonents
anrl furthcr limiting the maximum Permissible temperatures'
Or.0rall. the effect of these constraints is that the steam enters the turbincs
at significaltly lower tomperatures than the 500'C ofa modern suPercritical
coailfircd claot, and the resutting efficiencies aro correspondingly lower'
The earlicit nuclear Power plants, with steam temPeratures only-slightly
above 300'C, achieved little more than zoyo heat-to-electricity efficiency'
un,lalthorrgh there has boen considetable improvemenl, the cu-rrent 35o/o.
. ,r so of th;esl pressurizcd water reaclors {see Seclion
10'6) fails short ol
morlcrn c,r,rl-fi red plants.
reactor aontarnment
burldint (biolotical
shield)
fi,.::,
Figure 10.17 The main features of a pressurized water reacor (PwR) (source:adapred
lrom RS and RA Eng,2009)
the fuel rods. Heated as it passes throrLBh the corc, it lhen Eives up its heat
iD one o! more steam generators (boilers) to prcduce steam for the porver
station iurbines. RefuellinB involves replacing perhaps a third of the fuol
assernblies every year or so.
As in an\, therural plant, the highcr the steam temperature the greater lhc
heat-to-elsctricit), efliciency, but ii 1s essential that tho water coolAnt must
lemaiD liquid. and to achieve this at a temperaturc of 300'C or more. it
needs to be at a pressLrre of over 100 atmospheles. ln a PWR. the cor-e is
co[laiDed iD a pressure l,essel sulrourded by a primary concrete shield, and
the entire system, including the steam generators, is enclosed in a concrete
co[tainment structure to prevent the cscape ofradioactive materials,lvith
a stesl lining to capture high-energv rarliation. (The Russian WER diffels
significantly in havii8 several separate coolant cilcuits rather than 6 single
ptessrrre vessel.)
Maintaining the high pressure of tllc coolant lvater is very important. If one
of tho largo pipes caEying heate(l u,ater lo the steam genemtors fracturod,
the water would at once flash to steam, losing its cooling ellect- So a fast
and effective ernergency cooling svstenr is needed, and the PWRs usually
harre several in place. ('Ihe lailurc in the l'hree Mile Islaud PWR rvas due
in part to bumall intelvention in the automatic safety systems.)
CHAPIER IO NUCLEAR POWER 409
].]l,l,l.i].ll.,\.,,.ll:.\,.,.i].\.i].l.ll:'],lL,
'l'i:-.l:-:rllr-''-r
.li ir rrr I' Lr.. rr, , r'l,rL i.
;rrlr',rrrr erl IrrssLrrrzfli rr,rlIr rr'.rr lors ( \l\\'R.)
Fisure lO.l8 The nrain rea.ures of a borlins waler reactor (8wR) Gourcc adapted from
RS and RA E.8.2009)
Gas-cooled reactors
As rnentioned earlier, the UK had rlo cnrichfient
facilitv al the start of its
fi,ii:;; ;;;"';;;;;:,o G" ,1"'ig" oi its rors $ ds sov4rned h-v rle necd
'e'rr
;ilil;;;;i;
'rr""", *."i"ii i, nti"'l (non-enrit'hed) uraniutn' The original
';*ion
f."e Box l0'91 use Eraphile as modetalor'
carbon dioxide
jll"^'1".".i."i ."a rt"tt er than neutron-ab"orhing steell
^lnn".iu* "tto!
" A". u.rul, thn i'lti'i"ncv is limited bv I he maximutn
i;; i;"1;l ;i;d,;t. surreturn r arl tf ilhaidrr'l
i""r,r"t"rr.,r" ,rEssrrre thdt the mdlprial'''rnd
".a
::'it;;;;, ;;"I;;'.i".',i''it' crficiencr rlaimed f()r , MaBn')\ plarrt rs
slightly over 30%.
followed alio
The advanced gas-cooled reactors {AGRs) that
rn ",t".gt:pli::
tnelt Iuer r5
moderator and carbon dioxide coolart but lhe uranlum
u 235 As 5bown in Figure l0 lg theresirlli']9 tllt:liIsolln
"rrJh"a,J.r'^
i" aif"."nt lrr,m a PWR or BWR ThP main (ore is ellccllvely
"..,
;;;i,;';;;;;i.al channels extended bv metal tubes uP
ro lhc re,,clor
Ioos rrom du')vE
iitJ cao to allow insertion of fucl elemenls and control
I# ;"" ;;.;;i;;;o iu"i.lu''"" not lons and thin as i' the PwR'
"'"
,iu"k"a utou" each other' The carbon dioxide
gas
#;;;i;;il;Jy, dlrnospherL:s'
IJotuni l, ou*r.a tnrough tho core at a !ressure ofabout 40
absorbing heat from the fuel and delivering it lo lhe boilers'
steel-lned conffere
(biologicalshield)
tas
(source:
FiSure I O. I 9 Th e marn fealu res ol a n advanced gas cooled reacror (AG R)
adapted from RS and RA En8,2009)
j
flrc reactor 1' .'n66'g'l in a (.on':rple l)lessur., rcs'ul $l'i' h ll 'r''^lh"
l' 'l I'p
."r,",,*. ,"t, f,t" , -bon ,l,o\i'le cool rrit gas ancl "" " clPcl
i'
"J 'rro'r 'h'"1'
r
.iI.d
1 a Heysham
I land2
, /",
!* SEewell A
)
2L,- ,aaerle ey
ii Repro.ess ng pli.t
"-"'-\-'^L
"r"<."r d'.l.rr
l:K Dower ttitiont
ENERGY SYSTEMS AND SUSTAINABILITY
MaSnox
t968 20 t0
Oldburt-oo-Severn
Wylfa t97t 20 r2
AGR
1916 20 r6
H nk ey Point B
1977 20 r6
1984 2014
t984 ?0 t4
t985 20 r8
DunSeness B
1988 2023
Heysham 2
t989 20?3
r995 2019
Sizewell
Fo. det.ilt of re.ent proPo5al3, s€e ChaPrcr I l.
,,ver rhe rel"livc merils ol lh" A(;R and SCHWR for lhe oext Sonerol'on
bal'le,a1d
nuaoui o"*",.rd'ions lhe SCHWR evFntuitlly losl thc
"iiir
in Is78 two m;rc AGR' heru nlJered But Ihcse were Io bs thP lasl
0l lne
tr'r break inlo the LwR-dominated
world
i;;';;i;;";;;anagerl
it;;.
-"ri."i * i*r, long ielore the final two plants were-operationai'
The u
a
""a
irrii*,1", rn,af "ubmiLtcd for the UK s firct PWR >:lP dJ
:"; ;;;:li;;;";"te;
"il""inn lor rhe sGHwR' at srreweli on the sur[o]r Lon{r'
;r,"i;:t.""J v"e.,"- pi*t Arter a lons artd bitrerl)-r.'Lshl
'itf.ii*dl;"
prtil. lnqriry. tt u phn w,r. approved, and lhe 1 2 G\t Sizowell PWR ' anF
online in 1995.
fuel
assembly
Fi8ure 10.21 Thc nra.n fe.ro.es ol3 CANDU reacror (source:adaPted from RS and RA
E.g.2009)
llrr shrrlt fLrel brrrclles (t"igrrre 10.21). A major arlvartaSe, possible onh'
,,,r rrLrser crf tlre verv lo',i, noutt'o absorptioD by hcavy wator, is that thcso
11,,.s t an bc douhle-vr'.,.1/cd, irstLlatiDg the hot, higl't-prossule ccrolanl frorn
lL,. .tLtrr]ulrdilg lno(lerat{rr. lvhich docs not Docd 1o llr- ptessurized ;rs il
r rir., irrs l)0lo\v 100 '(i. l he lrtoclt:rator fiils a horizol)tal sleel cilinclcr cillr,,l
.r r alandlia. r!ilh th{) insllliln'd trtlrcs (:arrvitlg tho llot coolaDi in.lu(l otll
thr',r rgh thi: r:ncls of l)rr: r:ylittrlt:r'.
tl.\\DUs hayc a relulivelv Ion ttrermal efficir:ncv. but their high ncutlc'rr
,:rrorrorrtv allows lhe usc ol a range ofdiffercDt fuels, 'IlTev have even LLstrtl
Ih(rsl)cn1 h)ei fi otll P\{Ils. rrud havo becn rrcnsirleleclbv the USA for rleallttg
l| Lth sLIplus !veapors-,.]r'rtrlo plLrtoniuot. In roc0nt ycitrs, as \/aliants ol llrl)
,ri: rrrl(-,,\Nl)ljshavc(()ln()int.ruse.amorogencral term has been adoplo(l
,,, r,,r.lof.iofthjsttpc: prcssurized heavy water reactors {PHIVRs). India,
.r iri, h conrmissiollcd its first CANDLi reactor ovcr thifi\" vcars ago. nou'
rrs - this ternr fol all its roat:tors ofthis tvpe, u'hilst Canada calls its ncu'r:st
rL,r'sroll the advanced CANDU !eactor (ACR).
n:l MK reactors
rr ,rlrlition to thc VVIIR ontioDed abovc, Rrrssia developed other types oi
nT
LL,,i t,rr'. l)1 $'hich the nl:rin .) .r rvas the high power channel-type reaclol'
Illl\lK). l){r|el.,Pcd fr-onr,:a|l\-Russian plutoni u rn- proi] ucing reactors. it
.rs,,. lrayrhite as rrro(ler,rlor,rl(l li3il !{ater (:rx)liInt (fiqurc 10 22)
ENERGY SYSTEMS ANO 5USTAINABILITY
shield
tu rr,re
The RBMK. like parly reaclors elservbere was oriEillall! de\i8ncd
nalural uranium. bul subsequently chalged to sliShtl!'enriched
tuel' llrc
Chcrnobvl reactor! wer. oithis type and after the events
in l986 lsec
:o..ia".ir * i".ir.n 10.51 a number ol RBMKs in Russi" and elrewhcre
T)rere are no plans to build morc' but at the time
of
*"."
"f"1"4a"..
writing (2010) aboul a dozen ate still oPeratins'
lhc
As mentioned al ihe slarl o[ this chapter' durinB lhe ]rasl lirw !cilrs ol
lhc raln
overall rate of d.;, u,rrllrissioning of nuclear Plnrrlt hrs excooded
;onstruction At'hc trmo oiwritinS, ill ldle 2010' ovcr fiftv neu plants
arc
,,ndor con.tructio,, loflr of them accotlnted Ior by four uountries:,(ihrrra'
lhe lrnv
Russia, India and south Korea {WNA 20lo) WhBn completed
CHAPTER IO NUCLEAR POWER
plants shoul(l add a tothl of aboul 50(;\V ol ellltrical {)apacitl to thc 2010
t{)lal of 375 C\ry. But the la ller figllre is of course falliflg as rnorc pld)rts aro
de(uIlr lll issio ned. Chapter 11 discusses these and othpr issues con([ninil
the fulure of nuclear porlor.
rai,ngs
(\l r lri..lr \r(x ceot ol [J poin the rot:k ltrr a high-g,rade ore, dou'n to a Lowtr
Limit of ibout one nart ill d t]iousand. i\ft9r exlraclion' tlle ll3OB is ir the
krrnt oI a r:ompresied pc,rvrler called 'yellorvcake' l]ra)rium itself is onl,i
mildl-r' rarlioaitive, so lhis porrdcr does noi prcsent I nlrior llazarcl alld is
the Iorm normally transporlcil to the nexl sta8e of processing
'Ivpicaiir.
a nu(lear plani generating f000lvlw ol electriu po$'er reqrLires aboLrr
2001onnes ol yellortcake per year, so the rtorld's presont ouclear po\^ei
stations necd ; loial annual srrpPlv of some 70 000 lonlles Currerll! onl\
dbout tlvo'thirds oI this is 'ne\'\,' uranium. tho resl (ronrillS lionl stockpil(''
accLunulaled in earlier vears. Ilt is estimated tl]11 ovel t$'o million lonnes
ol uranirrn have ber:n produced lvorldwide sill(]e 1sJ45 )
The tailinSs, thc residucs after extraction oI the rtranjum, do give rise
to,,nn""arr". As described in Section 10.3. the ore \'ill havc contaire(l
radioactive daughter products that have accumulatcd in the ground for'
rillions ofyears- Moreover, one interlncdiate product is the radioactive 3as
radon {Fjgure'10.4), which has in the pasi had verY serious conseqrtent:es
lor workeis undergrouncl {see Chapter 13). lnitially in the foror of a slurtr'-
the tailings may hive up to twenlv tinles thc radioadivity of the extlacted
r,ranium,-and ian also include chemically or biologlcally undesirable
materials, so appropriate sa[e storage is obvlously essential' Depencling
on the gracle oioro, there can he betweeD 100 and 1U00 tonnes of tailings
for cach tonne of unentiched uranium, implyillS a current worldu'idr
acculnulation of up to fifty million tonnes per year'
lr(,r Lrnr . i.irercn(,, in rDiiss \vas not easv, artd this tethodhasonlYit1rrcer]t
\ cirrs lrrr , lre ecot:lrmicallv c()mpctitive rvjth diffusjon. The startillg i)oint
is d8airr r\'()r'sr.,:l irti) hex. nhicir is llten sl)[D at ver],high speeds to
I{rlricre i Lsol.1, , se|iralion Thc n)ajor advrnlage ovcr difflrsi{)11 is iLflt
lirr'hrvcr': Detilir,ns irre ncedocl, rerlur inq thc enr)rg\, cosl IoIaparticular
deqrec o; Lrrir:hr]lr'rrt b\ d Ia(:tor ol about fifly
\,Vith ei ,,r proc{r!s. t[c cnrichcd uranium is not thc on]y end product.
lllo\ itabli there must be a cofiesponding quantity oI depleted uranium
the fractl,,n left rIith iess than the original proportioll of U-235. 1'h-"
prodLrctirir of oD,r toDDe of 3.5'lo eDriched uranium. foa instal]ae, aoulrl
Ioave as i:r r.h as !ix toDnes of dcplcted uranium lvith onl\- a quarter of a
llcr ccnt I -lii5. Dppleted ruaDium is at present tnainlv storecl lbr possible
frrlur{r fu( . JSe lscri C]raptor 11), although sonte, in metalljc form. has harl
(non nu.l')ar-) milttary uses.
Spent it:el
No reactor lullv burns all the U-235 in its fuei. The usual reason for replacing
spent lirei :s a builcl up of fission products and actinoids, 'poisoning' tho
fuol and r ,.iLLcing lhe Ileat output ofthe reactor. Replacement details differ'
[or difft,r.:): tvpes ol reactor. l)ut typicall\, a lhird of the fuel elemoots in a
PWR atc r'',placetl ,rach vear or so, each ollc therefore remainilrg lor al)orlt
thrco \,{rars. I able I0.5 indicates possible contonts oftlle spcnt fLLel removed
at the eni ,: f ihis period.
The data,r :yprcalfo. spent iuel f.om a PwR usint enriched fuel conurninS 1.5%
U-215 and 96 5% U'218 but rhe quantities can depend on rhe mode ofoperaton
ard coirld be signifcantly difierent lor o.her t/pes of reactor
Initially thts speDt fucl is highiy raclioactivc, and the energ-!r transferred bv thc
cnrittcd irir!ricles to thc sulloul1ding aioms as ]leat is sufficient to ll10lt solid
ENEBCY SYSTEHS AND sUS.IAINABILITY
Direct disposal
The direct disposal route iDvolves l{"avi e the sPcnt fuel in tanks ior 40 or
50 vcars, bv which the time the radioictifilv and heat production will
have fallen to levels that in princitrlt: all,-rrv otl'ier. more col'nPaci forlns of
storage (Box 10.10).
Reprocessing
another fissile material such as Pu_239 as a nrinor con s tit u€nt lt mav seem
odd to use plutonillm in the fuel when th€ aim is to produce plutonium'
hrrr orovided rh"r'e are cpdrc Iree oeulrons lor the breeding prnce"s'
"nouqh
tho;uantitv ot Dlulonium siouid eradually burld up' urrl il a fuel uvclc can
tre iri orinciole be achi,:v"d rn which mure lrssile mdlenal ls c\lracled al
cach rphrelling lhan was loddP(l ru the he5h tucl
Plants likethis. where rhe fi ssi lc content of the extra'ted tuelis Sreatertharr
rhat oi the orisinal fuel, are rcterred to ds breeders' OlhPr tvpes' !vhere the
lissite conteni of th" e\tracied fuPl. is less lhan lhat ot lhc original fuel'
plutonium or undesirable actinoids'
ferhaps because the aim is to conrume
arc called burners
primary sodrum
- secondary sodrum
. tecondary sodiom
borcnzed-- \-.
traphite
neutronshield . - -t-
5ater,'
Tlre main conccrl1s al,or,t breeder Programlne centre oD its fuel. for thrco
a
Ioasousi the concentr'ati,ro {rffissile malerial. lhe necessltv lor reProcessins,
dncl llre celltral role ol plutoriu r [Box 10.11) The r:oncentrated fuel raises
the questior whethcr a runaway nudear reaction could occur. A flrlly
cliicrenl atomic bomb' rs not possiblc, and even a 'nuclear fizzle' would
requIo a number of imProbable conditions sLmulta]reousLy. Nevertheless,
rh;re is some disa8rcemDnt about probabllities and the unlikelihood doos
sccm to be of a di-ffcrel)t orde. from the virtual imPossibilily of a nuclear
explosion in a thermal reactor. Similarly with reprocessin6' rvhere thc
si8nificart differencc is that whilst this is an option in a thermal reactor
programme (soc Ser:tion 10.7), it is a necessity in a breeder programme,
wherc the nairr purpos. is the cxtmction of plutonium.
Ii could be arSued that boorbs can also be made ftom highlv enrichod U'235,
bur rh- imporianr drfterpnce i" rh.r eDrichmPn! r,qrires compler .nd I o'll!
)eotop? s.poratrcn. How' vcr. Plulonrum ( dn be +parated irom uantum b)
slrnpiar cnemrcoimcans. The fissile Pu'239 produced in rcactors does have
'diluting' isotopes, and lrue weapons_grade materiat should have less than 7%
otthe non fissile P -2a0ib\rt the Plutonium hom a breeder reactor, 'ontainin8
80-eo% Pr'239. could srrll be us€d in a weapon - ifa rather urreliable o e
Widr a growinS world suLplus of Pluionium, the concept bas dev€loped oi
using fait.eacio.s as b,rnicrs, consuming more piutonium than ihey pmdxce
(i.e. ihe reverse ora breeder). Many tonnes otw€apoos-8rado plutonium arc
hecoming'availablc' through decollmissioninSof nuclearweaponsbvRLrssia
and the r'isa Top l lhis j; context, abouteiSht kiloSrams of weapons-grade
plutoniun are required f.,r a bomb. and lhe loial quantity ofplutoflium iD
;xrsronce is thought to be over 1ouLl tonnes _a million kiloSrams The rne ts
and problenrs of dealjng uith plutonlum 3Je discussed turthor in ChaPtcr 11'
,lr, r,lrrr ..'dnJ ' l''- rr!'. . 'r' lr'r rr' l0 '_'l U' \ ln'l_i
qhur :
"n '..
,"1 ,,'1",,,n.^..r rh,.\l,r'l"o r".ri r,1-'l -, npr"\ r' lr.'"n pPr i rloi
of lIIel should be consi(lcrablv Sreato lhar f{rr Iissjo
+ +
'A .HE
lH
u_Prt'le
i m ol. .,r h' r"rt wrln a deLlcron rnd ' lrilon "nd
-thmerrc sh^w. rnar rt
,hp Lor I m"* wrll hrve derrea'c'l br
",'J'rr,i,-r" ".,,.r, '" *d a n" , on
0.01891r.
lr,ll rh,\ sum-u''nJs\ iuD"irs h' li'' i' an"rgt i Hn' usrnB lhe laclors Brl " r
Bor tu.t.ii:"c.part.cieoi,d 1h. .,-. rrol wrll shJred rurdl of 'harrr
'n
r
0.0189 x 931 = 17.6MeV = 17.6 x 1 602 x 1o'r I = 2 S2 10-'' ioules
Haw tnuch energywould be rcledsed )A lhc t'usion olzktoldeuteiun wit\
3keol triti1n?
AseiventnBo\ l01.1u= l.b60 10'18 Theredethu'aboul6x102i
i",.i"',,,. i*" r rtosrams or deut;riunr' arrd rle )druc omber ot
"t-.,"
ldtium aioms in threc kilog.ams ol lriiium'
of th{:
So tho energy releas0d in the complete iusion ot ths five kiloS'ams
tnixture'becomes:
6 x 106 x 2.82 x 10-r, J= i.63 ! 10rr lor 34oTJperkB
Comoarison k'ill, rhl ronpsl,ondrnq lrC rrP tn Bo\ 1o 4 shows Ihal fusion
-"..iJ .'"a,,"" r,,' rimes. nuin enerer a'Iss on from cach kilosn'rt'
i """, rnp sirr' rJrr .' rr^r rhi. rinpl'' (>P" mdin P\lI
^ir".t buL unlonurrarclv '
'l hero is. {rt coLrrse. ihe issrre of hou' ilrc trvo initial parlides in FiEure 10 25
nrn to t" otrru,ne.l. neulcrium ar carlier' dL!DuI(s tur dLotrl unrl
'liscltsscd
i" ,ooo.f *,rtal hvdrogen. arr(l r:an be extractcd tuom lvater Bnl
"i"-
i,,iir,, i"*air""1"", p-emittei s rth a haLtlife ofonlv 12 vears and occurs
" (o
,t.' auinlrr,Fs. rn' rlrtrrrrn rur r 1' hr\ion rea' rion des(r 'h''d
,;;i;i;;;;
,r'n".<ro.r!",,.it, pr"ducodin'l lrn'le'rrlv Or"PUssrbililvrsrlrpnrrrlr'1r
rcaoron shown rrr Frgrrru I o 26 1"rr'rur b^mbdrdrn'r'I ^l lrlhrr'm_b l " r\
CIIAPTER IO NUCLEAi POWER l1l
+ +
Fi8urc 10.26 Collision of. n.utron wth.lithium nucleus p.oducinS a hetium nucles
(o.piro.le).nd a lr'ton
10. l0 Summary
Tl .r essentials
'l'hi: i:haprcr has extended th. accour)ls of tvpes ot energy and the nature
oI nL"tier in (lhapter.l. Its contenl mav be sunmarized as follou,s:
a,r intlodlrction to radioactivity, th0 inevitable acconlpaniment lo n u.ilear
ENERCY SYSTEtIS AND SUSTAINAgILITY
in cor' ilusion
In looking at the uses of nuclear energy, we notice one maior difference
from earLier chapters. There, we have seen a multiPlicity ofsystems Lrsing
drfferent tvpes of energy for a range of different purposes Here we find
that almost all present-day operational nuclcar_fuel led systcms are versions
of iLlst one typ;i a tlennoi rission , eoaJor, used for one msin purpose: the
Be :nemti o 1 o f e I ect ric i I),.