Beruflich Dokumente
Kultur Dokumente
Properties of Matter
2.0 INTRODUCTION
Matter is anything that has weight and occupies space. Matter can be in the
form of a
• solid
• a liquid
• a gas
See the figure 2.1
The knowledge about the properties of matter and their different states is
necessary to understand the refrigeration process in later modules.
A solid is matter that has a definite shape and volume. A solid also resists
forces that try to alter its shape or volume at normal temperatures and pressures.
Solids have the following properties:
• Volume
• Weight
• Density
• Solubility
2.1
2.1.1 Volume
2.1.2 Weight
2.1.3 Density
2.1.4 Solubility
2.2
Figure 2.4: Solubility
A liquid is a matter that flows freely without the tendency for its molecules to
separate. Liquids have the following properties:
• Volume • Volatility
• Weight • Viscosity
• Density and • Cohesion
Specific Gravity
• Compressibility • Adhesion
• Miscibility
2.2.1 Volume
Liquids are normally measured by their volume. The volume of a liquid is the
space the liquid occupies. The volume of a liquid is usually measured by the size of
its container, for example gallons, liters, and barrels.
2.2.2 Weight
The weight of a liquid is how heavy it is. Although liquids are usually
measured by volume, they are sometimes measured by weight also.
In servicing AC&R units, the weight of a liquid refrigerant is important while
charging a unit.
2.3
2.2.3 Density and Specific Gravity
Density is mass per unit volume. This means how heavy a liquid is for a
given volume. When we compare the densities of different liquids, we do not
compare them directly with each other; instead, we compare each with the density of
water. The ratio of the density of any liquid to the density of water is called the
specific gravity of that liquid. The specific gravity of water is 1.0. Liquids denser
than water have specific gravities higher than 1.0. Liquids less dense than water
have specific gravities lower than 1.0. For example, the specific gravity of gasoline is
0.751, and the specific gravity of mercury is 13.546.
2.2.4 Compressibility
2.2.5 Volatility
2.2.6 Viscosity
2.2.7 Cohesion
Cohesion is the property of a liquid that shows how well the molecules of the
liquid stick together. Motor oil is an example of a liquid with high cohesion.
2.2.8 Adhesion
2.4
2.2.9 Miscibility
Miscibility is the property that shows how easily a liquid can mix with another
liquid.
Liquids that do not mix are called immiscible. For example, oil and water are
immiscible, they do not mix. See figure 2.6 below
A gas is a state of matter that has neither a definite shape nor volume, but
tends to expand indefinitely. Gases have the following properties:
• Volume, Pressure and Temperature.
• Density
• Compressibility
• Toxicity
• Flammability
• Inertness
Boyle’s law
Boyle’s law states that the pressure of a gas increases as its volume
decreases, if the temperature does not change. Molecules of the gas are pushed
closer together when the pressure is increased. Thus, the volume decreases. See
figure 2.7. Reverse occurs when the pressure decreases. The volume of gas
increases.
2.5
Figure 2.7: Gas Volume-Pressure Relationship At Constant Temperature
Charles’ law
Charles’ law states that the volume of a gas increases as its temperature
increases, if the pressure is not changed. See figure 2.8. Heating a gas causes it to
expand. Gas molecules gain energy when they are heated. They move faster,
travel farther, and strike the walls of the container more often. If the walls of the
container are flexible, the gas pushes them out, causing an increase in volume.
2.6
Charles’ law
Gay Lussac’s law states that the pressure of a gas increases as the
temperature increases, if the volume is not changed. See figure 2.9 below.
2.3.2 Density
2.7
of the natural gas vapors are denser (heavier) than air, and so will fall to the bottom
of a room or low place on the ground.
2.3.3 Compressibility
2.3.4 Toxicity
Some gases are toxic. This means they are poisonous. In the AC&R
industry, there are some refrigerants that are toxic. Some examples of toxic
refrigerants are ammonia and sulfur dioxide (rarely used)
2.3.5 Flammability
Some gases are flammable. This means they will burn, if ignited, in air.
Hydrocarbon gases are flammable whereas Freon refrigerants aren’t
2.3.6 Inertness
Some gases are inert. This means they do not react chemically with other
matter. They are not flammable under normal conditions. Nitrogen is an inert gas
which is used to remove air or clean AC&R tubing systems. Carbon dioxide and
halon are inert gases which are used to extinguish fires.
The key words in changing the state of matter are heat and pressure. Matter
can be changed from one state to another state by adding or taking away heat.
Pressure affects the point at which matter changes. Water is a good example.
Water is a liquid. It can be changed from liquid into vapor (gas) by heating it to its
boiling point. Reducing the pressure lowers the boiling point. The water vapor is
called steam. Water can be changed from the liquid state to the solid state by taking
away heat until its freezing point is reached. The solid state of water is called ice.
See figure 2.10. The refrigeration cycle is based on vaporization and condensation.
In this section, water is used as an example for a discussion on the basic principles
of liquid vapor pressure temperature relationship.
Water can change from a liquid to a gas or a vapor. It can change slowly or it
can change rapidly. Two things in combination affect this change, the temperature
2.8
of the water and the pressure on the water. A slow change is called evaporation and
a fast change is called vaporization or boiling.
2.4.1 Evaporation
Why does water in an open dish at room temperature slowly disappear, even
if it is not boiling? Heat is the key to change of state. All molecules above absolute
zero, -4600F, have motion from heat energy. The individual water molecules in the
liquid water eventually get enough energy to break away from the surface of the
water and go into the atmosphere as a vapor. The hotter the water, the faster it
evaporates. The colder the water, the slower it evaporates. Evaporation occurs
even at very low temperatures.
If some water is put in an open container over a fire, after a period of time it
starts to boil or vaporize. Boiling is a rapid change of state from liquid to gas. The
molecules in the liquid get more energy from the heat and can break away much
2.9
faster. At sea level the temperature of boiling water is 2120F. This is the boiling
point of water at sea level.
At its boiling point, the vapor pressure of a liquid equals the pressure of the
surrounding atmosphere. Therefore, the boiling point changes with changes to the
pressure of the atmosphere. As the pressure decreases, less heat energy is needed
to cause the water to boil, causing the boiling point to drop.
Atmospheric pressure decreases at high elevations. With lower atmospheric
pressure on a mountain top, liquids boil at lower temperatures. The boiling point of a
liquid is the point where the vapor pressure is equal to the surrounding pressure on
the liquid. See the figure 2.11 below.
If you increase the pressure, more energy is needed to vaporize the liquid,
and the boiling point goes up. Pressure caps on automobile radiators prevent the
water from boiling at 2120F. A 15 Psi cap will prevent the water from boiling until it
reaches about 2500F. Pressure cookers use the same principle for faster cooking.
The temperature of boiling water inside a pressure cooker is hotter than the
temperature of water boiling in the atmosphere.
2.5 CONDENSATION
2.10
condensed water vapor. As water vapor from the surface of the earth rises in the
atmosphere, it gets colder. The water molecules lose the energy they gained to
become a vapor and return to the liquid state.
A vapor can also be condensed by compressing it. By compressing a gas, it
raises the temperature at which it will condense.
Sensible heat is the heat that causes a change in temperature. The amount
of sensible heat needed by different liquids to reach the boiling point is different. In
other words, different liquids need different amounts of Btu’s to raise their
temperature one degree Fahrenheit.
Different liquids need different amounts of sensible heat to reach the boiling
point. Once the boiling point is reached, however, the temperature of the liquid stays
at the boiling point until all the liquid is vaporized. The vapor is also at the same
temperature. The temperature of boiling water is 2120F and the temperature of the
steam coming from the boiling water is also 2120F.
Heat which brings about a change of state, with no change in temperature, is
called latent (hidden) heat. There are two kinds of latent heat.
2.11
required to vaporize 1 pound of boiling water. To condense 1 pound of steam at
2120F, 970 Btu’s need to be removed. Different liquids require different amounts of
latent heat for vaporization. Figure 2.12 shows the required heat to vaporize one
pound of ice.
Figure 2.12: Sensible and latent Heats to Vaporize one Pound of ICE
From A to B, 36.3 Btu’s were added to heat ice from -400F to 320F.
From B to C, 144 Btu’s were added to melt ice. From C to D, 180 Btu’s were added
to heat water from 320F to 2120F. From D to E, 970 Btu’s were added to vaporize
the water. Note that the temperature did not change. Most of the heat is absorbed
between D and E. The same idea is applied in refrigeration. A refrigerant absorbs
lot of heat when changing from liquid to vapor.
2.12