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Where [Ag+] and [Cl-] reperesent concentrations of ions of Ag+ and Cl- and [AgCl] is an value representing an amount of moles in a liter of solid AgCl.
[AgCl] is a constant, therefore, writing a following equation:
Kc x [AgCl] = [Ag+][Cl-]
+ -
we can notice that product of equilibrium concentartions of Ag and Cl is equal to a constant. This constant is called solubility product constant or Ksp
Ksp = [Ag+][Cl-]
http://www.solubilityofthings.com/basics
In General
In general, SOLUBILITY is an ability of a substance to dissolve. In the process of dissolving, the substance which is being dissolved is called a solute and
the substance in which the solute is dissolved is called a solvent. A mixture of solute and solvent is called a solution.
To put it in simple words:
When we insert sugar into water it will dissolve. In this process:
http://www.solubilityofthings.com/basics/definition_of_solubility.php
Degree to which a substance dissolves in a solvent to make a solution (usually expressed as grams of solute per litre of solvent). Solubility of one fluid
(liquid or gas) in another may be complete (totally miscible; e.g., methanol and water) or partial (oil and water dissolve only slightly). In general, "like
dissolves like" (e.g., aromatic hydrocarbons dissolve in each other but not in water). Some separation methods (absorption, extraction) rely on differences
in solubility, expressed as the distribution coefficient (ratio of a material's solubilities in two solvents). Generally, solubilities of solids in liquids increase
with temperature and those of gases decrease with temperature and increase with pressure. A solution in which no more solute can be dissolved at a given
tempera
http://www.solubilityofthings.com/basics/factors_affecting_solubility.php
Temperature
Basically, solubility increases with temperature. It is the case for most of the solvents. The situation is though different for gases. With increase of the
temperature they became less soluble in each other and in water, but more soluble in organic solvents.
Polarity
In most cases solutes dissolve in solvents that have a similar polarity. Chemists use a popular aphorism to describe this feature of solutes and solvents:
"Like dissolves like". Nonpolar solutes do not dissolve in polar solvents and the other way roud.
Pressure
Gas solutes
As for gasses the Henry's law states that solubility of gas is directly proportional to the pressure of this gas. This is mathematically presented as: p = kc,
where k is a tempreture dependent constant for a gas. A good proof of Henry's law can be observed when opening a bottle of carbonated dring. When we
decrease the pressure in a bottle, the gas that was dissolved in the drink bubbles out of it.
Molecular size
The larger the molecules of the solute are, the larger is their molecular wieght and their size. It is more difficult it is for solvent molecules to surround
bigger molecules. If all of the above mnetioned factors ale excluded, a general rule can be found that larger particles are generaly less soulble. If the
pressure, and temperature are the same than out of two solutes of the same polarity, the one with smaller particles is usually more soluble.
Stirring increares the speed of dissolving
Stirring does not have an affect on solubility of a substance, but everyone knows that if he puts sugar in his tea and does not stirr, it will not dissolve.
Actually, if we left the tea to stand for a long enough time, the sugar would dissolve. Stirring only increases the speed of the process - it increases move of
the solvent what esposes solute to fresh portions of it, thus eabling solubility. As molecules in liquide substances are in costant move, the process would
take place anyway, but it would take more time.