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Abstract Electronic waste or E-waste comprises Keywords E-waste management · Best available
of old, end-of-life electronic appliances such as practices · Environmental and health impact ·
computers, laptops, TVs, DVD players, refrig- Developing countries
erators, freezers, mobile phones, MP3 players,
etc., which have been disposed of by their orig-
inal users. E-waste contains many hazardous Introduction
constituents that may negatively impact the envi-
ronment and affect human health if not properly E-waste and categorization
managed. Various organizations, bodies, and gov-
ernments of many countries have adopted and/or Electronics industry is the world’s largest and
developed the environmentally sound options and fastest growing manufacturing industry. Rapid
strategies for E-waste management to tackle the growth combined with rapid product obsolescence
ever growing threat of E-waste to the environ- resulted in discarded electronics which is now the
ment and human health. This paper presents fastest growing waste stream in the industrialized
E-waste composition, categorization, Global and world. The growing quantity of E-waste from elec-
Indian E-waste scenarios, prospects of recover- tronic industry is beginning to reach disastrous
able, recyclable, and hazardous materials found proportions. Electronic Waste or E-waste is the
in the E-waste, Best Available Practices, recy- term used to describe old, end-of-life electronic
cling, and recovery processes followed, and their appliances such as computers, laptops, TVs, DVD
environmental and occupational hazards. Based players, refrigerators and freezers, mobile phones,
on the discussion, various challenges for E-waste MP3 players, etc. which have been disposed of
management particularly in India are delineated, by their original users. Thus, E-waste is generated
and needed policy interventions were discussed. out of relatively expensive and essentially durable
products used for data processing, telecommuni-
cations, or entertainment in private households
and businesses.
Technically, electronic waste is only a subset
S. B. Wath (B) · P. S. Dutt · T. Chakrabarti of Waste Electrical and Electronic Equipment
National Environmental Engineering Research
(WEEE). According to the Organization for Eco-
Institute (NEERI), Nehru Marg, Nagpur,
440 020, Maharashtra, India nomic Cooperation and Development (OECD),
e-mail: sb_wath@neeri.res.in any appliance using an electric power supply that
Environ Monit Assess
has reached its end-of-life would come under materials found in electric and electronic waste
WEEE (EU 2002). are ferrous material (38%), non-ferrous material
Composition of the E-waste is very diverse (28%), plastic (19%), glass (4%), other including
and complex. E-waste contains more than 1,000 wood, rubber, ceramic, etc. (11%).
substances, which can be classified as hazardous Table 1 shows the average weight and composi-
and nonhazardous substances. The electrical and tion of WEEE of selected electronic and electrical
electronic equipment can be broadly categorized equipment commonly used in any household. The
into following categories (EU 2002): various items found in E-waste in different range
make the E-waste more diverse and complex in
1. Large household appliances (refrigerator, nature (UNEP 2007). However, it shows that E-
freezer, washing machine, cooking appliances, waste from these items can be dismantled into
etc.) relatively small number of common components
2. Small household appliances (vacuum clean- for further treatment. The materials found in the
ers, watches, grinders, etc.) WEEE can be categorized as hazardous and non-
3. IT and telecommunication equipment (PCs, hazardous materials. Table 2 shows the possible
printers, telephones, telephones, etc.) hazardous content in the component. The sub-
4. Consumer equipment (TV, radio, video cam- stances within the mentioned components, which
era, amplifiers, etc.) cause most concern, are the heavy metals such
5. Lighting equipment (CFL, high intensity so- as lead, mercury, cadmium, chromium (VI), halo-
dium lamp, etc.) genated substances (e.g., CFCs), polychlorinated
6. Electrical and electronic tools (drills, saws, biphenyls, plastics, and circuit boards that contain
sewing machine, etc.) brominated flame retardants (BFRs). BFR can
7. Toys, leisure, and sport equipment (computer/ give rise to dioxins and furans during incinera-
video games, electric trains, etc.) tion. Other materials and substances that can be
8. Medical devices (with the exception of all present are arsenic, asbestos, nickel, and copper.
implanted and infected products radiotherapy These substances may act as a catalyst to increase
equipment, cardiology, dialysis, nuclear medi- the formation of dioxins during incineration
cine, etc.) (DEFRA 2004).
9. Monitoring and control instruments (smoke
detector, heating regulators, thermostat, etc.)
10. Automatic dispensers (for hot drinks, money,
hot and cold bottles, etc.) Indian Scenario: E-waste scenario in India and its
management
The waste electrical or electronic equipment
include all components, sub-assemblies, and con- The problems associated with E-waste in India
sumables, which are either a part or whole of started surfacing after the first phase of economic
such products at the time of discarding. The main liberalization, after 1990. Due to the stiff compe-
Table 1 Average weight and composition of WEEE of selected EEE commonly used
Appliances Average Iron (Fe) % Non-Fe % Glass % Plastic % Electronic Others %
weight (kg) weight metal weight weight weight component % weight
weight
Refrigerators and freezers 48 64.4 6 1.4 13 15.1
Washing machine 40 to 47 59.8 4.6 2.6 1.5 31.5
PC 29.6 53.3 8.4 15 23.3 17.3 0.7
TV sets 36.2 5.3 5.4 62 22.9 0.9 3.5
Cellular phones 0.08 to 0.1 8 20 10.6 59.6 1.8
UNEP E-waste Assessment Manual Vol I (1) Data compiled from Waste from electrical and electronic equipment
(WEEE)—quantities, dangerous substances and treatment methods, EEA Copenhagen (2003); (2) QWERTY and Eco-
Efficiency analysis on cellular phone treatment in Sweden. TU the Netherland (2004)
Environ Monit Assess
4000000 3124422
3000000 2344617
1715620
2000000
1000000
0
2001-02 2002-03 2003-04 2004-05 2005-06 2006-07 2007-08 2008-09
Environ Monit Assess
Bangalore, Chennai, Kolkata, Ahmadabad, Hy- and dangerous (MPCB 2007). Improper recycling
derabad, Pune, Surat, and Nagpur. Table 3 shows and disposal operations found in different cities
quantity of WEEE generation in different states of India often involve the open burning of plas-
in India (IRGSSA 2005). tic waste, exposure to toxic solders, dumping of
acids, and widespread general dumping. As a re-
sult, pollutants are dumped into the land, air,
Present E-waste management system in India and water, which are the cause of serious en-
vironmental problems in India. Also, the labors
Most of the activities right from the collection, and workers employed in the dismantling and
transportation, segregation, dismantling, etc., are recycling units are poorly literate and unedu-
done by unorganized sectors manually. Being a cated, lacking the basic knowledge about the
rich source of reusable and precious material, E- serious occupational and health risks associated
waste is also a good source of revenue generation with the operations. Most of the time, disman-
for many people in India. The big portion (rag tling and recycling operations are performed by
pickers) of the Indian population earned their the workers without proper Personnel Protection
livelihood by collecting and selling the inorganic Equipment. Mostly hammers, chisels, hand drills,
waste-like plastics, polythene bags, glass bot- cutters, electric torch/burners, and some time elec-
tles, cardboards, paper, other ferrous metals, etc. tric drills were used for dismantling the WEEE
Figure 2 shows the road map/trade chain of Elec- (MPCB 2007). These operations are carried out
tronic and Electrical Equipment’s journey from in very congested places in the center of cities
manufacture/ importer to recycler/disposer found and slums. Mostly, the dismantling and recycling
in most of the Indian cities (MPCB 2007). areas are without any proper lighting and ven-
In India, most of the operations related to tilation. In absence of suitable techniques and
E-waste such as collections, segregation, disman- infrastructure, the workers and laborers working
tling, recycling, and disposals are performed man- in such areas are prone to serious occupational
ually. In absence of the adequate technologies health hazards (Empa 2004) Thus, there is no or-
and equipment, most of the techniques used for ganized or formal E-waste management system in
the recycling/treatments of E-waste are very raw India.
Environ Monit Assess
Global scenario of E-waste management 2007. The legislation has put the responsi-
bility of the reporting, financing, and treat-
Internationally, various legal frameworks have ment compliance obligations on the operators
been enacted and enforced to regulate E-waste. (private sector) of the producer compliance
The Basel Convention on the Control of Trans- schemes, instead on each individual producer.
boundary Movements of Hazardous Waste and Also, the operator is responsible for register-
its Disposal plays a significant role in curbing ing its members with the appropriate national
the E-waste trade from OECD countries to Non- regulator and for providing the details of
OECD countries. The EU has taken a lead to equipment produced by the members. The
protect the environment from hazards of E-waste producers, preprocessors, and exporters need
in Europe by framing two important directives, to get registered with the producer compliance
WEEE directive and Restriction of Use of Certain scheme by paying the fee, which can be used
Hazardous Substances (RoHS) in Electrical and as an operational cost for running the scheme.
Electronic Equipment Regulations directives. The national regulator fixes the household
Many countries have implemented WEEE Direc- WEEE quota for each producer compliance
tives (2002/96/EC) with detailed guidelines to as- scheme. And the operator has to ensure that
sist the producers and consumers in understanding the WEEE allotted must be treated using best
their duty to handle E-waste in environmentally available treatment, recovery, and recycling
sound manner (EU 2003): techniques (Turner and Callaghan 2007).
• USA: US Environmental Protection Agency
• UK: Waste Electrical and Electronic Equip- has initiated a green National Electronics Ac-
ment, as derived from the WEEE directive, tion Plan (NEAP) to address environmental
an EU directive, transcribed into UK legis- concerns of electronics. The scope of NEAP
lation after being passed by Parliament in is restricted to computers, televisions, and
Environ Monit Assess
July 1, 2006.
Status/date
friendly manner. Fifteen states have intro-
duced the producer responsibility bills. The
state of California has introduced a law for
collecting the Advance Recycling Fee (ARF)
from the consumer at the time of purchase of
new product. The system charges ARF rang-
BAN (2002); Guo et al. (2005, Draft); NDRC (2004, Draft); SEPA (1995, 2000, 2004, 2005); Chen (2004)
appliances, and recycling enterprises.
instruments for restricting and regulating the haz-
to local EPBs.
Major content
Transporters
Stores
Recyclers
Raw EEE Distributors
Material Manufactures & Retailers Consumers Disposers
Producers & Importers Collection
Points
ARF ARF
ARF SWICO
Environmental
commission
SENS
Direction of Material Flow Control Direction of Financial Flow Direction of Dialogue & influence
and prescribed procedures for handling E- ious management methodologies reported in the
waste in an environmentally sound manner,” available literature include segregation, recycle,
(MoEF 2008). But there is no law or reg- and recovery options and combinations thereof.
ulation specifically addressing the E-waste However, there is no standard or proven method-
problem (MoEF 2008); however, most of the ology evolved as yet for the management of
hazardous material found in the E-waste are E-waste. In this context, the best available prac-
covered under purview of “The Hazardous
and Waste Management Rules, 2008” under
the category of “hazardous” and “nonhaz- Table 6 Recoverable Quantity of Elements in a PC
ardous” waste. Material type % Recovered
CFCs 0.20
Management of E-waste is a formidable task Oil 0.32
and involves multidisciplinary approach. The var- Ferrous metals 46.61
Non-Ferrous metals 4.97
Table 5 Recoverable quantity of elements in a TV Plastics 13.84
Compressors 23.80
Elements % PPM Recoverable Wt.
Cables/Plugs 0.55
of element (Kg)
Spent PurFoam 7.60
Aluminum 1.2 0.4344 Glass 0.81
Copper 3.4 1.2308 Mixed waste 1.30
Lead 0.2 0.0724 Total 100.00
Zinc 0.3 0.1086 Materials disposed of to incinerator 0.20
Nickel 0.038 0.013756 Materials disposed of to landfill 8.90
Iron 12 4.344 Materials sent for recovery 90.90
Plastic 26 9.412
Glass 53 19.186 Compiled from data presented in (1) Exporting Harm—
Silver 20 0.000724 High-Tech Trashing of Asia. Basel Action Network and
Silicon Valley Toxics Coalition, US, 2005; (2) Management
Gold 10 0.000362
of Waste Electrical and Electronic Equipment, ACRR
Compiled from data presented in Cui (2005) (2003)
Environ Monit Assess
tices of management of E-waste have also been in the legislative framework making EPR a
reviewed. mandatory activity associated with the pro-
duction of electronic and electrical equipment
over a period of time (OECD 2001).
• Switzerland is the first country in the world
Best Available Practices (BAP)
to have established a formal E-waste man-
• The Extended Producer Responsibility (EPR) agement system. The existing E-waste man-
is an environment protection strategy that agement system based on the ARF approach
makes the producer responsible for the en- is given in Fig. 3. The effective collection
tire lifecycle of the product, especially for of E-waste in Switzerland is primarily due
take back, recycle, and final disposal of the to the efficient management of the E-
product. Thus, the producer’s responsibility is waste stream by two producer responsibility
extended to the post-consumer stage of the organizations—The Swiss Association for In-
product life cycle. This needs to be included formation, Communication and Organization
Technology and Stiftung Entsorgung Schweiz dismantling is practiced. A variety of tools is in-
(Khetriwal et al. 2005). volved in the dismantling process for removing the
• RoHS in the Electronic and Electrical Equip- hazardous components and recovery of reusable
ment: There is an increasing trend in the or valuable components and materials. Mainly the
reduction in the use of hazardous sub- mechanical/ physical recycling process practiced
stances such as lead, cadmium, mercury, poly- involved screening, shape separation, magnetic
chlorinated biphenyls, and other toxic and separation, electric conductivity-based separation,
hazardous substances for which safe substi- density-based separation, etc.; techniques depend-
tutes have been found. Many countries have ing upon the quantity, type, size, and shape of the
adopted the RoHS regulations in the manu- material and component in E-waste. Tables 5, 6,
facture of electrical and electronic equipment and 7 show the recoverable quantity of elements
(EU 2002). in various WEEE.
1. Hammering
2. Shredding
Second Level 3. Special treatment processes like Disposal
Treatment a. CRT treatment consisting of separation of funnels and screen glass
b. Electromagnetic separation
c. Eddy current separation
d. Density separation using water
Recycling Processes
Third Level • Chemical - Refinery/metal smelter (Plastic/Metal)
• Mechanical – Shredding, breaking (Plastic/Glass)
Treatment • Thermal – Power generator/cement kiln (Plastic) Disposal of
Recovery Processes Process Waste
• Reverberatory furnace, Blast Furnace, Electrolytic (Lead, Cu)
• Leaching, Smelting, Electrolytic (Precious Metal)
Output
(Recovered materials)
Table 8 Occupational and environmental hazards associated with E-waste processing
Computer/E-waste components Processes used Potential occupational hazard Potential environmental hazard
Cathode ray tubes (CRT) Regunning, breaking, removal of Silicosis Lead, barium, and other heavy metals
yoke and dumping Cuts from CRT glass in case of implosion leaching into ground water, release
Inhalation or contact with phosphor of toxic phosphor
containing cadmium or other metals
Glass Dust inhaling
Printed circuit board (PCB) De-soldering and removing Tin and lead inhalation Air emission of same substances
computer chips Possible brominated dioxin, beryllium
cadmium and mercury inhalation
Printed circuit board processing Open burning and acid bath of waste Toxicity to workers and nearby residents Hydrocarbons, heavy metals, brominated
boards that had chips removed to from tin, lead, brominated dioxin, beryllium substances, etc., discharged directly into
remove final metals cadmium and mercury inhalation river and banks
Respiratory irritation Acidifies the river destroying fish
Acid contact with eyes, skin may result in and flora.
permanent injury
Printed circuit board processing Open burning and acid bath of waste Inhalation of mists and fumes of acids, Tin lead and contamination of immediate
boards that had chips removed chlorine and sulfur dioxide gases can environment including surface and
to remove final metals cause respiratory irritation to severe groundwater
effects including pulmonary ederm, Brominated dioxins, beryllium cadmium
circulatory failure and death and mercury emissions
Chips and other gold plated Chemical stripping using nitric and Toxicity to workers and nearby residents from Hydrocarbons, heavy metals, brominated
components hydrochloric acid and burning tin, lead, brominated dioxin, beryllium substances, etc., discharged directly into
of chips cadmium and mercury inhalation river and banks
Environ Monit Assess
Respiratory irritation Acidifies the river destroying fish
Acid contact with eyes, skin may result in and flora
permanent injury Tin lead and contamination of immediate
Inhalation of mists and fumes of acids, environment including surface and
chlorine and sulfur dioxide gases can groundwater
cause respiratory irritation to severe Brominated dioxins, beryllium cadmium
effects including pulmonary ederm, and mercury emissions
Environ Monit Assess
All the three levels of E-waste treatment are Challenges and opportunities
based on the material flow. The material flows
from 1st level to 3rd level treatment. Figure 4 Under the scenario, the E-waste management
shows the three level treatments. Each level treat- strategy for India has the following challenges,
ment consists of unit operations where E-waste is which need to be studied and addressed in more
treated, and output of 1st level treatment serves systematic and scientific manner:
as input to the next level treatment. After the
3rd level treatment, the residues are disposed Scientific challenges
of either in hazardous waste Treatment Storage
• Eco-friendly recovery solutions
and Disposal Facility (TSDF) or incinerated. The
efficiency at 1st and 2nd levels determines the ◦ Precious metals
quantity of residues going to TSDF or inciner- ◦ Base metals
ation, while the 3rd level E-waste treatment is
• Value addition to recyclables for reuse
mostly carried out mainly to recover ferrous, non-
ferrous metals, plastics, and other items of eco- ◦ Plastics
nomic value (Johri 2008). ◦ Glass and other recyclables
• Disposal of process waste and residues
Environmental and health implications ◦ Size reduction
◦ Toxic reduction
E-waste is a serious issue, and in absence of
Engineering challenges
the globally acceptable E-waste definition, its re-
lated environmental and health hazards cannot • Scientific collection, transport, handling, seg-
be addressed in a global manner. In India, there regation, and disposal of E-waste
is no law or regulation specifically addressed to • Integrated/distributed processing facilities
the E-waste problem; however, most of the haz-
ardous materials found in E-waste are cover under ◦ Unorganized to organized
purview of “The Hazardous and Waste Manage- ◦ Involvement of SMEs and NGOs
ment Rules, 2008” under the category of “haz- • Feasible techno-economical solutions
ardous” and “nonhazardous” waste. In most of
the Indian cities, E-waste is treated as the mu- ◦ Processing
nicipal waste, and no special attention is given ◦ Recycling
to the activities related to its collection, handling, ◦ Recovery
dismantling, and recycling. Most of the activities Organizational challenges
related to the E-waste collection, handling, dis-
mantling, and recycling are mainly being per- • Appropriate definition for E-waste in Indian
formed by the unorganized or informal sectors context
lacking the technical and infrastructural abilities • Inventorization of E-waste generation, im-
and knowledge about the serious implications of port, and its characterization
the E-waste handling and disposal on environ- • Organization and structuring E-waste man-
ment and human health. The environmental im- agement system
pact and health risk associated with E-waste are • Training and awareness on safety, health, and
of very critical and serious in nature leading to environment
degradation and pollution of the natural resources
and can lead to chronic diseases in human beings. Further, the role and responsibility of the gov-
Due to the hazards involved, disposing and recy- ernment is very important for developing the E-
cling E-waste pose serious environmental and oc- waste management strategy for India in terms
cupation implications. Table 8 lists its associated of transboundary hazardous waste flow, effect of
impacts. the government policies on employment, in both
Environ Monit Assess
E-waste recycle exporting and importing coun- very few private enterprises have established the
tries. And as global hazardous waste always flows facilities for the E-waste treatment in few cities
to destinations with weaker environmental regula- like Bangalore, Chennai, and Noida which are
tions or low economic development, the dirty side handling and treating the E-waste in more sci-
of its recycling process would never be properly entific and environmental-friendly manner, more
addressed. The policy should be to design and find such enterprises need to be established in other
out the effective ways to improve job quality in the cities too.
recycling industry in India, where low-skilled la- There is a need for further research and con-
bor is abundant and people are desperate for any sideration on policy as well as technical level to
income. Any approach should maintain balance answer how to adopt and successfully combined
between environmental and occupational health the experience and know-how of the existing E-
along with the economic development. waste management models from abroad, with the
current E-waste system in India, in order to have
the formal and well-regulated E-waste Manage-
Conclusion ment system for India.
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